CN108285323A - A kind of water-permeable brick and preparation method thereof prepared using sludge - Google Patents

A kind of water-permeable brick and preparation method thereof prepared using sludge Download PDF

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Publication number
CN108285323A
CN108285323A CN201711285399.2A CN201711285399A CN108285323A CN 108285323 A CN108285323 A CN 108285323A CN 201711285399 A CN201711285399 A CN 201711285399A CN 108285323 A CN108285323 A CN 108285323A
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water
parts
permeable brick
sludge
prepared
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Inventor
王文静
阳重阳
曹姝文
李锐敬
刘小平
许嘉辉
曾华洁
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GUANGZHOU ENVIRONMENTAL PROTECTION ENGINEERING DESIGNING INST Co Ltd
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GUANGZHOU ENVIRONMENTAL PROTECTION ENGINEERING DESIGNING INST Co Ltd
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Priority to CN201711285399.2A priority Critical patent/CN108285323A/en
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Abstract

The water-permeable brick and preparation method thereof that the invention discloses a kind of to be prepared using sludge, the water-permeable brick include the following raw material calculated by weight:40 ~ 45 parts of sludge, 20 ~ 23 parts of common stone, 15 ~ 18 parts of slag, 8 ~ 10 parts of flyash, 10 ~ 15 parts of haydite, 12 ~ 15 parts of waterglass, 10 ~ 12 parts of quartz sand, 10 ~ 15 parts of absorbing material, 6 ~ 7 parts of monkey grass, 2 ~ 3 parts of sepiolite fibre.The water-permeable brick being prepared has the performance of electromagnetic wave absorption, also maintains good water permeability, the overall performance of water-permeable brick is met the requirements.In sponge Process of Urban Development, needs to use a large amount of water-permeable bricks, water-permeable brick is prepared using sludge and building waste, increases the environmental-protecting performance of water-permeable brick, can be salvaged, reduce waste discharge, greatly improve the resource utilization in city.

Description

A kind of water-permeable brick and preparation method thereof prepared using sludge
Technical field
The present invention relates to sponge urban architecture field of material technology, and the saturating of sludge preparation is utilized more particularly, to a kind of Water brick and preparation method thereof.
Background technology
The urban waterlogging problem being concerned in recent years, rainwater mainly passes through row in traditional urban construction pattern theory Drainage facility is drained, and ponding can not penetrate into underground on road surface, and rainwater resource is not fully utilized, often result in meet rain must flood, The negative environmental consequences such as tropical island effect.And mainly there is the solution of the above problem in China and increases drainage pipe diameter, online at present Water storage builds cistern etc., and these measures shortcomings such as not only generally existing investment is big, occupied space is big, but also constructs Time is long, efficiency is low.Sponge urban construction can more preferably solve the problems, such as urban waterlogging.
With the extensive use of electronic technology, artificial electromagnetic energy increases rapidly, and urban electromagnetic radiation pollutes producing cause There are broadcast emission tower, communication tool and mobile communication station.The newest announcement of the World Health Organization:Electromagenetic wave radiation has become 21 century The fourth-largest global environmental problem after water pollution, air pollution and noise pollution.Be particular about the feature of environmental protection, electromagnetism in sponge city The pollution of wave radiation is urgently to be resolved hurrily.
During building sponge city, water-permeable brick is largely used, and still, existing water-permeable brick can not solve electricity The problem of electromagnetic wave radiation, causes water-permeable brick to hold in use in addition, the toughness of existing water-permeable brick, fracture resistance are insufficient It is broken, it is not durable enough.
Invention content
The present invention is the defect overcome described in the above-mentioned prior art, provides a kind of water-permeable brick prepared using sludge.
In order to solve the above technical problems, the technical solution adopted by the present invention is:
A kind of water-permeable brick prepared using sludge, including the raw material that calculates by weight as follows:40 ~ 45 parts of sludge, common stone 20 ~ 23 parts, 15 ~ 18 parts of slag, 8 ~ 10 parts of flyash, 10 ~ 15 parts of haydite, 12 ~ 15 parts of waterglass, 10 ~ 12 parts of quartz sand, suction wave 10 ~ 15 parts of material, 6 ~ 7 parts of monkey grass, 2 ~ 3 parts of sepiolite fibre.
During preparing water-permeable brick, sludge, flyash are as fine aggregate;Slag, common stone, haydite are as thick bone Material;Waterglass cohesive force is strong, intensity is higher, acid resistance, heat-resist;Quartz sand is hard, wear-resisting, stable chemical performance;Sludge Municipal sludge, industrial sludge etc. may be used, general dehydration to 70 wt% of water content ~ 80wt%.
Absorbing material is the material for capableing of electromagnetic wave absorption, and in the art, absorbing material is typically chosen can be permeable Stable absorbing material is kept in the sintering process of brick, is in cost consideration, is typically chosen traditional absorbing material, wherein common Have ferrite, barium titanate, graphite, silicon carbide.
Monkey grass and sepiolite fibre are introduced into water-permeable brick, can increase the porosity of water-permeable brick.Since tradition is inhaled The general density of wave material is big, porosity is low, is added in water-permeable brick the water permeability decline so that water-permeable brick, passes through monkey grass With the effect of sepiolite fibre, increase porosity so that the water-permeable brick prepared using absorbing material is having electromagnetic wave absorption While energy, moreover it is possible to keep excellent water permeability.
Haydite is made of discarded ceramic slag, and slag and flyash are trade waste, and waste utilization is provided Sourceization utilizes.Other materials can also be added according to the prior art by preparing the raw material of above-mentioned water-permeable brick, ensure the entirety of water-permeable brick Performance is provided simultaneously with the ability of electromagnetic wave absorption.
Preferably, the absorbing material is the mixture of one or more of ferrite, barium titanate, graphite, silicon carbide.
Preferably, the absorbing material is reduction-oxidation graphite-ferroso-ferric oxide composite wave-suction material.Ferroso-ferric oxide with Reduction-oxidation graphite is compound, and ferriferrous oxide particles is avoided to assemble, the surface with bigger, and the effect of electromagnetic wave absorption is more preferable. On the other hand, reduction-oxidation graphite-ferroso-ferric oxide composite wave-suction material contains reduction-oxidation graphite, and reduction-oxidation graphite can Increase the toughness and cracking resistance of water-permeable brick.
Preferably, the content of ferroso-ferric oxide is in the reduction-oxidation graphite-ferroso-ferric oxide composite wave-suction material 80wt%~90wt%.When the content of ferroso-ferric oxide is more than 90wt% in reduction-oxidation graphite-ferroso-ferric oxide composite wave-suction material, Ferriferrous oxide particles aggregation, distribution can be caused not uniform enough, influence the performance of the electromagnetic wave absorption for the water-permeable brick being prepared; When the content of ferroso-ferric oxide is less than 80wt% in reduction-oxidation graphite-ferroso-ferric oxide composite wave-suction material, although can also prepare The water-permeable brick with electromagnetic wave absorption is obtained, but since ferroso-ferric oxide content reduces, when adding the absorbing material of same weight, The reduced performance for the water-permeable brick electromagnetic wave absorption being prepared may influence to make if increasing the additive amount of absorbing material The water permeability of standby obtained water-permeable brick.
Preferably, the preparation method of the reduction-oxidation graphite-ferroso-ferric oxide composite wave-suction material includes the following steps:
S1. graphite oxide is prepared;
S2. graphite oxide, iron chloride, sodium acetate and ethylenediamine are dispersed in ethylene glycol, it is washing, dry after hydro-thermal reaction To reduction-oxidation graphite-ferroso-ferric oxide composite wave-suction material.
Preferably, the sludge is municipal sludge.Sludge is formed in water treatment procedure using organic matter as main component Gunk;Its high organic content, easy corruption is smelly, and particle is thinner, and density is smaller, and moisture content is high and is not easy to be dehydrated, It is the hydroaropic substance of jelly structure.Municipal sludge refers mainly to the sludge of sewage plant, further includes the sludge of waterworks;Municipal administration Sludge is the byproduct after sewage disposal, be it is a kind of by organic debris, inorganic particle, colloid etc. form it is extremely complex it is non- Plastid.Municipal sludge is during urban life, and the waste largely generated prepares water-permeable brick, waste by using municipal sludge It utilizes, has effectively saved resource.When municipal sludge prepares water-permeable brick, generally through dehydration to moisture content be 70 wt% ~ 80wt%。
Preferably, the slag crosses 10 mesh sieve, and the quartz sand crosses 10 mesh sieve, and the grain size of the flyash is less than or equal to The grain size of 0.15 mm, the haydite are 1.5 ~ 7.0 mm.In ability, the grain size of flyash is 5 μm or more, fine coal in the present invention The grain size of ash is less than or equal to 0.15 mm.
Another object of the present invention is to provide a kind of methods preparing water-permeable brick.
A method of above-mentioned water-permeable brick is prepared, is included the following steps:
S1. by absorbing material and sludge, common stone, slag, flyash, haydite, waterglass, quartz sand, monkey grass, sea Afrodite fiber is mixed into pug;
S2. adobe is made by the pug of S1. is dry-pressing formed, then will be dried;
S3. the adobe of S2. is sintered, obtains water-permeable brick.
Preferably, the moisture content of the pug is 15wt% ~ 18wt%.
Preferably, the temperature of the drying is 105 ~ 108 DEG C, and the moisture content after the brick bat drying is less than or equal to 6wt%. Moisture content is less than or equal to 6wt% after brick bat drying, generally in order to improve working efficiency, energy consumption is reduced, without dropping moisture content As low as 4wt% and following.
Preferably, the condition of the sintering is:Heating rate is 3.5 ~ 4.0 DEG C/min, is warming up to 1025-1150 DEG C and protects Cool down after warm 2.5-3 h.
Compared with prior art, the beneficial effects of the invention are as follows:
The present invention is fine by absorbing material and sludge, common stone, slag, flyash, haydite, waterglass, quartz sand, palm Water-permeable brick has been prepared in dimension, sepiolite fibre, which has the performance of electromagnetic wave absorption, also maintains good permeable The overall performance of performance, water-permeable brick is met the requirements.
In sponge Process of Urban Development, needs largely to use water-permeable brick, water-permeable brick is prepared using sludge and building waste, The environmental-protecting performance for increasing water-permeable brick, can be salvaged, and reduces waste discharge, greatly improves the resource utilization in city.
Specific implementation mode
The present invention is further illustrated With reference to embodiment.
In the embodiment of the present invention, the sludge used is generally dehydrated using belt filter press by conventional for municipal sludge After use, dewatered municipal sludge moisture content is 70wt% ~ 80wt%, and pH value be 7.0 ~ 8.5, carbon-nitrogen ratio for (20 ~ 35):1, have Machine object content is 40% ~ 60%.
Commonly stone, waterglass, quartz sand, monkey grass, sepiolite fibre are common commercial product;The grain of haydite Diameter is between 1.5 mm and 7 mm;Slag crosses 10 mesh sieve, and the grain size of the flyash is less than or equal to 0.15 mm.
For barium titanate, graphite, silicon carbide as absorbing material by being commercially available, barium titanate uses commercially available barium titanate Powder, graphite use commercially available electrically conductive graphite powder, silicon carbide to use commercial carbonized silicon powder;
Reduction-oxidation graphite-ferroso-ferric oxide composite wave-suction material as absorbing material is prepared with the following method, in addition, making For control, it is also prepared for the ferroferric oxide powder of no composite reduction graphite oxide.
The reduction-oxidation graphite used in embodiment-ferroso-ferric oxide composite wave-suction material uses to be obtained following preparation method It arrives:
S1. by 9 in ice-water bath:1 dense H2SO4/H3PO4(270 mL:30 mL)It pours into the flask equipped with 3 g graphite powders After mixing, 18 g potassium permanganate are slowly added to, reaction temperature is controlled at 35 ~ 40 DEG C;
S2. continue to stir 20 h under 50 DEG C of water bath conditions.Reaction terminates, and pours into and is equipped with after reaction solution is cooled to room temperature In the beaker of 200 mL ice, 30% hydrogen peroxide to solution colour is then slowly added dropwise and turns yellow;
S3., acquired solution is centrifuged to 1 min at 1000 rpm and removes not fully oxidized graphite, later 4000 rpm from Heart 1h.After removing supernatant, distilled water, 30% hydrochloric acid and absolute ethyl alcohol is used to wash successively 2 times;
S4. the product centrifuged is dissolved in n-hexane, is filtered with Teflon film, and filter cake is dried in vacuo 12 h at 60 DEG C, grinds To graphite oxide;
S5. it takes 0.6 g graphite oxides ultrasonic dissolution in 150 mL ethylene glycol, 6.0g FeCl is then added3•6H2O, 18.0 G sodium acetates and 60 mL ethylenediamines, 2 h of ultrasound make it dissolve.Then mixture is transferred in 200 mL water heating kettles, at 200 DEG C 9 h of lower reaction.Product is filtered and is washed for several times with water and ethyl alcohol, it is multiple to obtain reduction-oxidation graphite-ferroso-ferric oxide after dry Close absorbing material(RGO-Fe3O4), four oxidation three in the reduction-oxidation graphite-ferroso-ferric oxide composite wave-suction material being prepared Iron content is 85wt%.By adjusting graphite oxide and FeCl3•6H2The rate of charge of O, ferroso-ferric oxide content, which is also prepared, is Reduction-oxidation graphite-ferroso-ferric oxide composite wave-suction material of 76 wt%, 80wt%, 90 wt%, 95 wt%.
In the present invention, the test method of water-permeable brick,
(1)The coefficient of permeability of water-permeable brick is tested, and is used《Water-permeable brick》(CJ/T945-2005)Method carry out;
(2)The performance of absorbing electromagnetic wave of water-permeable brick is tested:The test that space field strength is carried out using field intensity meter, in same building sky Between, under the same cases such as same emission source, test the field strength of water-permeable brick prepared by different embodiments or comparative example to spatial points Influence, selection data wherein are compared.Since the frequency of electromagnetic radiation existing for space is different, so adopting It is recorded with spatial electromagnetic energy value, is converted into decibel value.By testing in the same position of the same space, blank value subtracts Test value after the water-permeable brick in the present invention absorbs is absorbed value, and blank value is when not using water-permeable brick of the invention The result of test.Although the performance of absorbing electromagnetic wave test about water-permeable brick not yet also locate by relevant criterion, correlative study work In the primary stage, but the above method is able to demonstrate that the water-permeable brick of the present invention has the performance of electromagnetic wave absorption radiated wave, has Practicability and feasibility;
(3)The anti-folding breaking load of water-permeable brick is tested, and is used《Water-permeable brick》(CJ/T945-2005)Method carry out.
Embodiment 1
The present embodiment prepares a kind of water-permeable brick prepared using sludge, and preparation method includes the following steps:
S1. 42 parts of the municipal sludge that will be calculated by weight, 21 parts of common stone, 16 parts of slag, 9 parts of flyash, haydite 10 Part, 15 parts of waterglass, 12 parts of quartz sand, reduction-oxidation graphite -12 parts of ferroso-ferric oxide composite wave-suction material, 7 parts of monkey grass, Pug is stirred into after 2 parts of mixing of sepiolite fibre, and it is 15% to control moisture content(Weight percent);- four oxygen of reduction-oxidation graphite It is 80wt% to change ferroso-ferric oxide content in three-iron composite wave-suction material;
S2. the pug of S1. is put into block forming in dry-pressing formed machine, the pressure of dry-pressing formed machine is 28Mpa, and difference is made The permeable brick adobe of shape and size;By permeable brick adobe obtained by spontaneously drying or being put into drying box drying, if being put into Dry in drying box, then drying temperature is 108 DEG C, and control moisture content is 5%(Weight percent);
S3. the permeable brick adobe sintering after S2. being dried, is warming up to 1130 DEG C with the speed of 3.8 DEG C/min when sintering, continues It is sintered after 3 h and is down to room temperature to get to water-permeable brick.
Embodiment 2
The present embodiment is a kind of second embodiment of the water-permeable brick prepared using sludge of the present invention, a kind of to utilize the saturating of sludge preparation Water brick, preparation method include the following steps:
S1. 40 parts of the municipal sludge that will be calculated by weight, 23 parts of common stone, 18 parts of slag, 8 parts of flyash, haydite 15 Part, 12 parts of waterglass, 10 parts of quartz sand, reduction-oxidation graphite -10 parts of ferroso-ferric oxide composite wave-suction material, 6 parts of monkey grass, Pug is stirred into after 3 parts of mixing of sepiolite fibre, and it is 18% to control moisture content(Weight percent);- four oxygen of reduction-oxidation graphite It is 80wt% to change ferroso-ferric oxide content in three-iron composite wave-suction material;
S2. the pug of S1. is put into block forming in dry-pressing formed machine, the pressure of dry-pressing formed machine is 30Mpa, and difference is made The permeable brick adobe of shape and size;By permeable brick adobe obtained by spontaneously drying or being put into drying box drying, if being put into Dry in drying box, then drying temperature is 107 DEG C, and control moisture content is 6%(Weight percent);
S3. the permeable brick adobe sintering after S2. being dried, is warming up to 1125 DEG C with the speed of 4.0 DEG C/min when sintering, continues It is sintered after 2.5 h and is down to room temperature to get to water-permeable brick.
Embodiment 3
The present embodiment is a kind of 3rd embodiment of the water-permeable brick prepared using sludge of the present invention, a kind of to utilize the saturating of sludge preparation Water brick, preparation method include the following steps:
S1. 45 parts of the municipal sludge that will be calculated by weight, 20 parts of common stone, 15 parts of slag, 10 parts of flyash, haydite 12 Part, 13 parts of waterglass, 11 parts of quartz sand, reduction-oxidation graphite -15 parts of ferroso-ferric oxide composite wave-suction material, 6 parts of monkey grass, Pug is stirred into after 2 parts of mixing of sepiolite fibre, and it is 16% to control moisture content(Weight percent);- four oxygen of reduction-oxidation graphite It is 80wt% to change ferroso-ferric oxide content in three-iron composite wave-suction material;
S2. the pug of S1. is put into block forming in dry-pressing formed machine, the pressure of dry-pressing formed machine is 35Mpa, and difference is made The permeable brick adobe of shape and size;By permeable brick adobe obtained by spontaneously drying or being put into drying box drying, if being put into Dry in drying box, then drying temperature is 105 DEG C, and control moisture content is 6%(Weight percent);
S3. the permeable brick adobe sintering after S2. being dried, is warming up to 1150 DEG C with the speed of 3.5 DEG C/min when sintering, continues It is sintered after 3 h and is down to room temperature to get to water-permeable brick.
Embodiment 4
The present embodiment is a kind of fourth embodiment of the water-permeable brick prepared using sludge of the present invention, as different from Example 1, also Ferroso-ferric oxide content is 76wt% in former graphite oxide-ferroso-ferric oxide composite wave-suction material.
Other raw materials and preparation method are same as Example 1.
Embodiment 5
The present embodiment is a kind of 5th embodiment of the water-permeable brick prepared using sludge of the present invention, as different from Example 1, also Ferroso-ferric oxide content is 85wt% in former graphite oxide-ferroso-ferric oxide composite wave-suction material.
Other raw materials and preparation method are same as Example 1.
Embodiment 6
The present embodiment is a kind of sixth embodiment of the water-permeable brick prepared using sludge of the present invention, as different from Example 1, also Ferroso-ferric oxide content is 90wt% in former graphite oxide-ferroso-ferric oxide composite wave-suction material.
Other raw materials and preparation method are same as Example 1.
Embodiment 7
The present embodiment is a kind of 7th embodiment of the water-permeable brick prepared using sludge of the present invention, as different from Example 1, also Ferroso-ferric oxide content is 95wt% in former graphite oxide-ferroso-ferric oxide composite wave-suction material.
Other raw materials and preparation method are same as Example 1.
Embodiment 8
The present embodiment is that a kind of 8th embodiment of the water-permeable brick prepared using sludge of the present invention is inhaled as different from Example 1 Wave material uses ferroferric oxide powder.
Other raw materials and preparation method are same as Example 1.
Embodiment 9
The present embodiment is that a kind of 9th embodiment of the water-permeable brick prepared using sludge of the present invention is inhaled as different from Example 1 Wave material uses barium titanate.
Other raw materials and preparation method are same as Example 1.
Embodiment 10
The present embodiment is that a kind of tenth embodiment of the water-permeable brick prepared using sludge of the present invention is inhaled as different from Example 1 Wave material uses graphite.
Other raw materials and preparation method are same as Example 1.
Embodiment 11
The present embodiment is a kind of 11st embodiment of the water-permeable brick prepared using sludge of the present invention, as different from Example 1, Absorbing material uses silicon carbide.
Other raw materials and preparation method are same as Example 1.
Comparative example 1
As different from Example 1, absorbing material, monkey grass and sepiolite fibre are not added.
Other raw materials and preparation method are same as Example 1.
Comparative example 2
As different from Example 1, monkey grass and sepiolite fibre are not added.
Other raw materials and preparation method are same as Example 1.
Test result
The coefficient of permeability and electro-magnetic wave absorption value of embodiment 1 ~ 11 and comparative example 1 ~ 2 are tested, the results are shown in Table 1.
Table 1
As shown in Table 1, the effect of the electromagnetic wave absorption of the embodiment of the present invention 1 ~ 11 is better than comparative example 1, and comparative example 1 is common Water-permeable brick, and the coefficient of permeability of embodiment 1 ~ 11 is all higher than 1 × 10-2Cm/s meets the water permeability requirement of water-permeable brick;
Comparative example 2 is added to reduction-oxidation graphite-ferroso-ferric oxide composite wave-suction material, does not add monkey grass and sepiolite The effect of fiber, the electromagnetic wave absorption of comparative example 2 is better than comparative example 1, but 2 water permeability of comparative example is not so good as comparative example 1, is not inconsistent Close the water permeability requirement of water-permeable brick, it may be possible to because being added to reduction-oxidation graphite-ferroso-ferric oxide composite wave-suction material, lead Water-permeable brick porosity is caused to decline, the water permeability of water-permeable brick declines.Therefore, addition absorbing material may influence water-permeable brick merely Water permeability, need to add monkey grass and sepiolite fibre, ensure the porosity of water-permeable brick, make the coefficient of permeability of water-permeable brick Meet the performance requirement of water-permeable brick.
The effect of the electromagnetic wave absorption of embodiment 1 ~ 7 is better than embodiment 8, it is seen that aoxidizes three by reduction-oxidation graphite-four Water-permeable brick prepared by iron composite wave-suction material is better than water-permeable brick prepared by ferroferric oxide powder, it may be possible to due to oxygen reduction fossil In ink-ferroso-ferric oxide composite wave-suction material, reduction-oxidation graphite can prevent ferriferrous oxide particles from assembling so that four oxidations Three-iron particle size smaller is more uniformly spread, surface area bigger, and the effect of the water-permeable brick electromagnetic wave absorption of preparation is more preferable.
The effect for implementing 1,5,6 electromagnetic wave absorption is better than embodiment 4 and embodiment 7, it is seen that-four oxygen of reduction-oxidation graphite When ferroso-ferric oxide content is 80wt% ~ 90 wt% in change three-iron composite wave-suction material, the absorption electromagnetism for the water-permeable brick being prepared The performance of wave is more preferable, it may be possible to which when being more than 90 wt% due to ferroso-ferric oxide content, the reduction-oxidation graphite-ferroso-ferric oxide is multiple Ferriferrous oxide particles size bigger, the distribution for closing absorbing material are not uniform enough;And ferroso-ferric oxide content be less than 80 wt% when, Ferroso-ferric oxide content reduces, and leads to the performance for the water-permeable brick electromagnetic wave absorption that the absorbing material for adding same weight is prepared Decline, in order to enhance the performance of electromagnetic wave absorption, then needs that more absorbing materials are added, the water penetration of water-permeable brick may be influenced Energy.
The anti-folding breaking load of embodiment 1 ~ 11 reaches the performance requirement of water-permeable brick, in addition, implementing 1 ~ 7 anti-folding destruction Load is higher than embodiment 8, it is seen that and after ferroso-ferric oxide composite reduction graphite oxide, anti-folding breaking load is improved, so Reduction-oxidation graphite can promote the toughness of water-permeable brick, fracture resistance.
Obviously, the above embodiment of the present invention be only to clearly illustrate example of the present invention, and not be to this hair The restriction of bright embodiment.For those of ordinary skill in the art, it can also do on the basis of the above description Go out other various forms of variations or variation.There is no necessity and possibility to exhaust all the enbodiments.It is all in the present invention Spirit and principle within made by all any modification, equivalent and improvement etc., should be included in the guarantor of the claims in the present invention Within the scope of shield.

Claims (9)

1. a kind of water-permeable brick prepared using sludge, which is characterized in that including the raw material calculated by weight as follows:Sludge 40 ~ 45 parts, 20 ~ 23 parts of common stone, 15 ~ 18 parts of slag, 8 ~ 10 parts of flyash, 10 ~ 15 parts of haydite, 12 ~ 15 parts of waterglass, quartz 10 ~ 12 parts of sand, 10 ~ 15 parts of absorbing material, 6 ~ 7 parts of monkey grass, 2 ~ 3 parts of sepiolite fibre.
2. water-permeable brick according to claim 1, which is characterized in that the absorbing material be ferrite, barium titanate, graphite, The mixture of one or more of silicon carbide.
3. water-permeable brick according to claim 2, which is characterized in that the absorbing material aoxidizes for reduction-oxidation graphite-four Three-iron composite wave-suction material.
4. water-permeable brick according to claim 3, which is characterized in that the reduction-oxidation graphite-compound suction of ferroso-ferric oxide The content of ferroso-ferric oxide is 80wt% ~ 90wt% in wave material.
5. water-permeable brick according to claim 1, which is characterized in that the slag crosses 10 mesh sieve, and the quartz sand crosses 10 mesh The grain size of sieve, the flyash is less than or equal to 0.15 mm, and the grain size of the haydite is 1.5 ~ 7.0 mm.
6. a kind of method preparing any one of claim 1 ~ 5 water-permeable brick, which is characterized in that include the following steps:
S1. by absorbing material and sludge, common stone, slag, flyash, haydite, waterglass, quartz sand, monkey grass, sea Afrodite fiber is mixed into pug;
S2. adobe is made by the pug of S1. is dry-pressing formed, then will be dried;
S3. the adobe of S2. is sintered, obtains water-permeable brick.
7. according to the method described in claim 6, it is characterized in that, the moisture content of the pug is 15wt% ~ 18wt%.
8. according to the method described in claim 6, it is characterized in that, the temperature of the drying is 105 ~ 108 DEG C, the adobe is dry Moisture content after dry is less than or equal to 6wt%.
9. according to the method described in claim 6, it is characterized in that, the condition of the sintering is:Heating rate is 3.5 ~ 4.0 DEG C/min, it is warming up to 1025-1150 DEG C and cools down after keeping the temperature 2.5-3 h.
CN201711285399.2A 2017-12-07 2017-12-07 A kind of water-permeable brick and preparation method thereof prepared using sludge Pending CN108285323A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108951344A (en) * 2018-08-31 2018-12-07 广州市环境保护工程设计院有限公司 One kind cutting dirty water-permeable brick and preparation method thereof
CN109400181A (en) * 2018-12-24 2019-03-01 马元乡 It is a kind of to utilize ecology sponge brick made of sludge and construction waste and preparation method thereof

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Publication number Priority date Publication date Assignee Title
JPH04367576A (en) * 1990-11-26 1992-12-18 Iwao Jiki Kogyo Kk Production of water-permeable tile
CN105399443A (en) * 2015-10-29 2016-03-16 合肥正拓装饰材料有限公司 Sintered water permeable brick with smooth and mildew-proofing surface
CN106045403A (en) * 2016-06-08 2016-10-26 福建江夏学院 Pervious recycled aggregate concrete with microwave absorbing function and preparation method of pervious recycled aggregate concrete
CN106278373A (en) * 2016-08-12 2017-01-04 上海洗霸科技股份有限公司 Utilize water-permeable brick prepared by heavy metal sewage sludge and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04367576A (en) * 1990-11-26 1992-12-18 Iwao Jiki Kogyo Kk Production of water-permeable tile
CN105399443A (en) * 2015-10-29 2016-03-16 合肥正拓装饰材料有限公司 Sintered water permeable brick with smooth and mildew-proofing surface
CN106045403A (en) * 2016-06-08 2016-10-26 福建江夏学院 Pervious recycled aggregate concrete with microwave absorbing function and preparation method of pervious recycled aggregate concrete
CN106278373A (en) * 2016-08-12 2017-01-04 上海洗霸科技股份有限公司 Utilize water-permeable brick prepared by heavy metal sewage sludge and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108951344A (en) * 2018-08-31 2018-12-07 广州市环境保护工程设计院有限公司 One kind cutting dirty water-permeable brick and preparation method thereof
CN109400181A (en) * 2018-12-24 2019-03-01 马元乡 It is a kind of to utilize ecology sponge brick made of sludge and construction waste and preparation method thereof

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