CN107254314A - A kind of soil-solidified-agent and its preparation method and application - Google Patents

A kind of soil-solidified-agent and its preparation method and application Download PDF

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Publication number
CN107254314A
CN107254314A CN201710487272.2A CN201710487272A CN107254314A CN 107254314 A CN107254314 A CN 107254314A CN 201710487272 A CN201710487272 A CN 201710487272A CN 107254314 A CN107254314 A CN 107254314A
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China
Prior art keywords
soil
solidified
agent
content
less
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CN201710487272.2A
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Chinese (zh)
Inventor
刘诚斌
高秀清
张昊
刘春鸣
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Beijing Vocational College of Agriculture
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Beijing Vocational College of Agriculture
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Priority to CN201710487272.2A priority Critical patent/CN107254314A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K17/00Soil-conditioning materials or soil-stabilising materials
    • C09K17/02Soil-conditioning materials or soil-stabilising materials containing inorganic compounds only
    • C09K17/06Calcium compounds, e.g. lime
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2103/00Civil engineering use

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  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Soil Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Consolidation Of Soil By Introduction Of Solidifying Substances Into Soil (AREA)
  • Soil Conditioners And Soil-Stabilizing Materials (AREA)

Abstract

The invention discloses a kind of soil-solidified-agent and its preparation method and application, belong to civil engineering material technical field.Described soil-solidified-agent is consisted of the following components in percentage by weight:1% 3% sodium chloride, 5% 10% light calcined magnesia, 5% 15% plaster of Paris, 5% 10% building lime and 70% 80% ground granulated blast furnace slag.The soil-solidified-agent of the present invention, preparation method is simple, is remarkably improved the unconfined compressive strength of solidified earth, and can also improve the water stability of solidified earth.

Description

A kind of soil-solidified-agent and its preparation method and application
Technical field
The present invention relates to soil-solidified-agent and its preparation method and application, belong to civil engineering material technical field.
Background technology
Soil-solidified-agent is also a new things in China, from research, is produced to application and construction, it may be said that be one complicated System engineering, is related to many ambits such as chemical industry, machinery, architectural engineering, road engineering, hydraulic engineering.
In soil solidification engineering at home, mostly using soil curing materials such as traditional lime, cement, flyash, But these soil-solidified-agents often have certain deficiency.For example, the firming body intensity of rendzinas formation is formed slowly, it is past Toward influenceing, big, easy to crack construction speed, particularly rendzinas drying shrinkage, easy softening, water stability are poor.Soil cement there is also drying shrinkage compared with Greatly, easy to crack the problems such as, and the soil cement easily volume caused by hydrated reaction of cement, environment temperature, the change of humidity of exposure Uneven change and produce crack, the appearance in this crack can cause the compression strength, impervious, anti-of firming body (soil cement) Freeze and scour resistance reduction, it is a large amount of in soil cement to use cement as curing agent, also increase engineering cost.In recent years, stone Ash-flyash is widely used in the stable processing of the soil body, but finds that the early strength of lime-coal ash soil is low in use, directly Influence construction speed is connect, two-ash soil have impact on construction quality there is also the shortcoming of water stability difference in addition.
The content of the invention
The technical problems to be solved by the invention are the unconfined compressive strength and water stability for significantly improving solidified earth, so that Solve the problem of solidification of soil.
An object of the present invention is to provide a kind of soil for the unconfined compressive strength and water stability for significantly improving solidified earth Earth curing agent.Described soil-solidified-agent is consisted of the following components in percentage by weight:1%-3% sodium chloride, 5%-10% Light calcined magnesia, 5%-15% plaster of Paris, 5%-10% building lime, 70%-80% ground granulated blast furnace slag.
Preferably, described soil-solidified-agent is consisted of the following components in percentage by weight:2% sodium chloride, 8% it is light Burned magnesium oxide, 10% plaster of Paris, 5% building lime, 75% ground granulated blast furnace slag.
Each percentage in the present invention, in the case of without special instruction, all referring to mass percent or percentage by weight.
Preferably, the sodium chloride is for the salt of digging in seawater, lake salt or with salt lake bittern, rock salt or subsurface brine The industrial salt being made for raw material, sodium chloride content >=92%, moisture≤2%, water-insoluble≤0.4%.
Preferably, the light calcined magnesia, be for used in magnesite product by magnesite through calcining, grinding it is light Burned magnesium oxide, content of magnesia is more than 80%, wherein, active oxidation content of magnesium > 60%, free magnesium content is not more than 2.0%, 80 μm of square hole screens tail over no more than 10%.
Preferably, the plaster of Paris be the natural gypsum or industry by-product gypsum through made from dewater treatment, with the water of β types half Calcium sulfate is main component, not the powdery binder materials of any additive of pre-add or additive, and the content of β type half-H 2 O calcium sulphates is not Square hole screen less than 60%, 0.2mm tails over no more than 10%.
Preferably, the calcareous quick lime that it is architectural engineering that the building lime, which is, effective calcium adds content of magnesia not small In 80%, relict content is not digested and is not more than 11%.
Preferably, described ground granulated blast furnace slag is, using granulated blast-furnace slag as primary raw material, can to mix a small amount of gypsum mill The powder of certain fineness is made, apparent density is not less than 2.8g/cm3, and specific surface area is not less than 400m2/kg, 7 days activity indexs Activity index is not less than 95% within not less than 75%, 28 day.
Another goal of the invention of the present invention is to provide a kind of preparation method of above-mentioned soil-solidified-agent, described soil solidification The preparation method of agent is:Sodium chloride, light calcined magnesia, plaster of Paris, building lime, ground granulated blast furnace slag are put into proportion In mixing plant, stir, obtain soil-solidified-agent product.
Another goal of the invention of the present invention is to provide a kind of application of above-mentioned soil-solidified-agent, according to mixing for soil-solidified-agent Measure to be cured the 10%~30% of native wet soil quality.Volume should be tests determined according to solidifying requirements and wet soil water content.
The beneficial effects of the present invention are:
The soil-solidified-agent of the present invention can make the unconfined compressive strength of solidified earth improve 40%, and water stability improves 40%, Solve the application problem of soil solidification;Its preparation method is simple, and component is chemical materials and construction material, is easily obtained.
The embodiment of the present invention is described further with reference to embodiment.The present invention can be wanted according to solidification Summation wet soil water content suitably adjust formula, operated according to the method described in following examples, make meet performance want The soil-solidified-agent and the solidification soil body asked.
Embodiment
Embodiment:It is prepared by soil-solidified-agent
Sodium chloride, light calcined magnesia, plaster of Paris, building lime, ground granulated blast furnace slag are proportionally put into stirring In equipment, stir.The constituent content that each component is implemented is as shown in table 1.
Wherein, the sodium chloride used in embodiment is for the salt of digging in seawater, lake salt or with salt lake bittern, rock salt Or the highly industry salt that subsurface brine is made for raw material, sodium chloride content >=92%, moisture≤2%, water-insoluble≤ 0.4%.
Used light calcined magnesia be for used in magnesite product by light-burned oxygen of the magnesite through calcining, grinding Change magnesium.The soil-solidified-agent light calcined magnesia of the present invention, content of magnesia 85%, wherein, active oxidation content of magnesium 70%, trip From content of magnesia 1.0%, 80 μm of square hole screens tail over 6%.
Used " plaster of Paris " be the natural gypsum or industry by-product gypsum through made from dewater treatment, with the water of β types half Calcium sulfate is main component, not the powdery binder materials of any additive of pre-add or additive.The soil-solidified-agent of the present invention is used Plaster of Paris, square hole screen of the content not less than 67%, 0.2mm of β type half-H 2 O calcium sulphates tails over 8%.
Used " building lime " is the calcareous quick lime of architectural engineering.The soil-solidified-agent paring stone of the present invention Ash, effective calcium adds content of magnesia 89%, and relict content 6% is not digested.
Used " ground granulated blast furnace slag " is, using granulated blast-furnace slag as primary raw material, can to mix a small amount of gypsum and be milled into The powder of certain fineness.The soil-solidified-agent ground granulated blast furnace slag of the present invention, apparent density 2.8g/cm3, specific surface area 426m2/kg, 7 days activity indexs are 82%, and 28 days activity indexs are 101%.
The constituent content (wt.%) of each embodiment of table 1
Performance test and result
In order to verify the impact of performance of soil-solidified-agent of the present invention, the selection common loess in Beijing area is tested (experiment With native water content 19.1%).According to《Stir powder spray method reinforces soft layer technical specification》TB10113-96 carries out the system of test block Make, prepare test block with 30% that water is dry ground, curing agent incorporation is the 15% of wet soil, surveys its 7d unconfined compressive strength and water Stability.The method of testing of wherein water stability is to immerse 24h in fresh water, then survey it solidified earth test specimen standard curing 6d, 7d Unconfined compressive strength fu1;Testing standard conserves the unconfined compressive strength fu2 of 7d solidified earth test specimens, calculates solidified earth softening COEFFICIENT K:K=(fu1/fu2) × 100%.Its performance test results is as shown in table 2.
Comparative example 1 uses the Ji east cement of PO 42.5;Comparative example 2 is removed using by A3 sodium chloride, keeps other components Proportioning is constant;Soil-solidified-agent raw material are:Shandong sea prince bio tech ltd Nacl, Liaoning Province's Haicheng City day is contained Mining industry Co., Ltd light calcined magnesia, the plaster of Paris of Taian Shandong Mount Taishan Gao Ye Co., Ltds, Hebei province Jingxing County Jinyang work The building lime of trade Co., Ltd, the ground granulated blast furnace slag of Hebei steel construction group building material Co., Ltd.
The performance test results of table 2
As shown in Table 2, by filling embodiment A1, A2, A3, A4 and A5 soil-solidified-agent, solidified earth it is anti-without lateral spacing Compressive Strength is significantly improved, and the water stability of solidified earth is significantly enhanced.Compared with comparative example 1, A3 soil-solidified-agent can make solid The unconfined compressive strength for changing soil improves 40%, and water stability improves 40%.Compared with comparative example 2, the soil of incorporation sodium chloride is consolidated Agent, can make the unconfined compressive strength of solidified earth improve 70%, water stability improves 70%.
Finally it should be noted that above embodiment is merely illustrative of the technical solution of the present invention and it is unrestricted, to the greatest extent The present invention is described in detail with reference to example for pipe, it will be understood by those within the art that, can be to the present invention's Technical scheme is modified or equivalent substitution, and without departing from the spirit and scope of technical solution of the present invention, it all should cover Among scope of the presently claimed invention.

Claims (8)

1. a kind of soil-solidified-agent, it is characterised in that consist of the following components in percentage by weight:1%-3% sodium chloride, 5%-10% light calcined magnesia, 5%-15% plaster of Paris, 5%-10% building lime and 70%-80% granulation are high Stove slag powders.
2. soil-solidified-agent as claimed in claim 1, it is characterised in that the sodium chloride is to be used for digging in seawater, lake salt Salt or the industrial salt that is made using salt lake bittern, rock salt or subsurface brine as raw material, sodium chloride content >=92%, moisture≤ 2%, water-insoluble≤0.4%.
3. soil-solidified-agent as claimed in claim 1, it is characterised in that the light calcined magnesia is used for used in magnesite product By magnesite through calcining, grinding light calcined magnesia, content of magnesia be more than 80%, active oxidation content of magnesium > 60%, free magnesium content is not more than 2.0%, and 80 μm of square hole screens tail over no more than 10%.
4. soil-solidified-agent as claimed in claim 1, it is characterised in that the plaster of Paris is the natural gypsum or industrial by-product Gypsum is through made from dewater treatment, using β types half-H 2 O calcium sulphate as main component, not the powdery of any additive of pre-add or additive Binder materials, square hole screen of the content not less than 60%, 0.2mm of β type half-H 2 O calcium sulphates tails over no more than 10%.
5. soil-solidified-agent as claimed in claim 1, it is characterised in that the building lime is be architectural engineering it is calcareous Quick lime, effective calcium adds content of magnesia to be not less than 80%, and relict content is not digested and is not more than 11%.
6. soil-solidified-agent as claimed in claim 1, it is characterised in that described ground granulated blast furnace slag refers to granulated blast-furnace Slag mixes gypsum and is milled into powder, and apparent density is not less than 2.8g/cm3, specific surface area is not less than 400m2/ kg, 7 days activity indexs Activity index is not less than 95% within not less than 75%, 28 day.
7. the preparation method of soil-solidified-agent as claimed in claim 1, it is characterised in that by sodium chloride, light calcined magnesia, build Build gypsum, building lime, ground granulated blast furnace slag to be put into mixing plant in proportion, stir, obtain soil-solidified-agent product.
8. application of the soil-solidified-agent as any one of claim 1-6 in soil solidification, it is characterised in that described Soil-solidified-agent volume is to be cured the 10%~30% of native wet soil quality.
CN201710487272.2A 2017-06-23 2017-06-23 A kind of soil-solidified-agent and its preparation method and application Pending CN107254314A (en)

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Cited By (6)

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CN110387867A (en) * 2019-07-25 2019-10-29 上海隧道工程有限公司 The method reinforced suitable for three axes agitating pile under cumulosol formation condition
CN110408408A (en) * 2019-08-27 2019-11-05 江苏泽晟新材料科技有限公司 Soil-solidified-agent and its application method
CN110952409A (en) * 2019-12-17 2020-04-03 成都安能吉科技有限公司 Concrete road paving method using soil curing agent
CN115557737A (en) * 2022-10-21 2023-01-03 东南大学 Preparation method of silt solidifying agent and solidified soil for scouring protection of offshore wind turbines
CN115807366A (en) * 2022-11-03 2023-03-17 深圳宏垚环保科技有限公司 Roadbed construction method for recycling premixed solidified soil from aggregate-containing filling screening tailings
CN115947557A (en) * 2023-01-06 2023-04-11 中绎建设科技集团有限公司 Additive for improving strength of self-compacting solidified soil

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Publication number Priority date Publication date Assignee Title
CN110387867A (en) * 2019-07-25 2019-10-29 上海隧道工程有限公司 The method reinforced suitable for three axes agitating pile under cumulosol formation condition
CN110387867B (en) * 2019-07-25 2021-07-06 上海隧道工程有限公司 Method suitable for reinforcing triaxial mixing pile under condition of peat soil stratum
CN110408408A (en) * 2019-08-27 2019-11-05 江苏泽晟新材料科技有限公司 Soil-solidified-agent and its application method
CN110952409A (en) * 2019-12-17 2020-04-03 成都安能吉科技有限公司 Concrete road paving method using soil curing agent
CN115557737A (en) * 2022-10-21 2023-01-03 东南大学 Preparation method of silt solidifying agent and solidified soil for scouring protection of offshore wind turbines
CN115807366A (en) * 2022-11-03 2023-03-17 深圳宏垚环保科技有限公司 Roadbed construction method for recycling premixed solidified soil from aggregate-containing filling screening tailings
CN115947557A (en) * 2023-01-06 2023-04-11 中绎建设科技集团有限公司 Additive for improving strength of self-compacting solidified soil

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