CN106478012A - A kind of sludge curing agent and preparation method thereof - Google Patents
A kind of sludge curing agent and preparation method thereof Download PDFInfo
- Publication number
- CN106478012A CN106478012A CN201610840268.5A CN201610840268A CN106478012A CN 106478012 A CN106478012 A CN 106478012A CN 201610840268 A CN201610840268 A CN 201610840268A CN 106478012 A CN106478012 A CN 106478012A
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- China
- Prior art keywords
- parts
- curing agent
- sludge curing
- sludge
- mud
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
- C04B28/04—Portland cements
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F11/00—Treatment of sludge; Devices therefor
- C02F11/12—Treatment of sludge; Devices therefor by de-watering, drying or thickening
- C02F11/14—Treatment of sludge; Devices therefor by de-watering, drying or thickening with addition of chemical agents
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00767—Uses not provided for elsewhere in C04B2111/00 for waste stabilisation purposes
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Ceramic Engineering (AREA)
- Organic Chemistry (AREA)
- Environmental & Geological Engineering (AREA)
- Hydrology & Water Resources (AREA)
- Water Supply & Treatment (AREA)
- Life Sciences & Earth Sciences (AREA)
- Inorganic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Treatment Of Sludge (AREA)
Abstract
The invention discloses a kind of sludge curing agent, count by weight, its raw material includes：4 ~ 6 parts of ardealite, 15 ~ 18 parts of cement, 26 ~ 30 parts of quick lime, 7 ~ 9 parts of limestone, 28 ~ 32 parts of flyash, 1 ~ 2 part of hydroxypropyl methyl cellulose, 6 ~ 8 parts of glass-cermic powder, 6 ~ 8 parts of ceramic, 10 ~ 15 parts of furfural dregs, 4 ~ 6 parts of Maifanitum and 8 ~ 10 parts of smectite clay.The sludge curing agent of the present invention can significantly reduce the moisture content of high-moisture percentage mud, can effectively reduce the internal strain of mud after solidification, prevent from ftractureing, and solidification intensity is high, hardening time is short, enables to coagulate soon, hard soon；And can heavy metal in active adsorption curing sludge, reach the requirement that landfill and building are banketed.The sludge curing agent of the present invention has carried out recycling to mud, the problems such as solve the pollution environment caused by a large amount of siltations, energy-conserving and environment-protective, and low engineering cost, profitable.
Description
Technical field
The invention belongs to environmental technology field is and in particular to a kind of sludge curing agent and preparation method thereof.
Background technology
Natural sludge water content is high, and low intensity also contains some harmful components such as toxic chemical substance, causal organism, work
Journey poor performance, if without process, will cause very big pollution to environment.At present, domestic main employing sludge curing agent pair
Mud carries out cured, to reduce the moisture content of mud with this, improves the intensity of mud to meet the requirement that the earthwork is filled.Pass
The sludge curing agent of system（As Calx, cement, flyash etc.）Although improving in terms of intensity, hardening time is relatively
Long, solidification effect is inconspicuous, and soaking effect in a short time is poor.It would therefore be highly desirable to develop one kind can improve mud intensity, and
Water in mud can effectively be absorbed in a short time, improve the Novel curing agent of mud optimum moisture content.
Content of the invention
Present invention aims to prior art is not enough, provide a kind of sludge curing agent and preparation method thereof.
For achieving the above object, the present invention adopts the following technical scheme that：
A kind of sludge curing agent, counts by weight, and its raw material includes：4 ~ 6 parts of ardealite, 15 ~ 18 parts of cement, quick lime 26 ~
30 parts, 7 ~ 9 parts of limestone, 28 ~ 32 parts of flyash, 1 ~ 2 part of hydroxypropyl methyl cellulose, 6 ~ 8 parts of glass-cermic powder, ceramic 6 ~ 8
Part, 10 ~ 15 parts of furfural dregs, 4 ~ 6 parts of Maifanitum and 8 ~ 10 parts of smectite clay.
Preferably, a kind of sludge curing agent, counts by weight, and its raw material includes：5 parts of ardealite, 16 parts of cement, calculogenesis
28 parts of ash, 8 parts of limestone, 30 parts of flyash, 1.5 parts of hydroxypropyl methyl cellulose, 7 parts of glass-cermic powder, 7 parts of ceramic, furfural
12 parts of slag, 5 parts of Maifanitum and 9 parts of smectite clay.
Described ardealite adopt secondary standard and more than, wherein sulfate dihydrate calcium content be more than 75wt%, attachment water content little
In 8wt%.
Described cement is 425 grades of Portland cements.
Described flyash adopt two grades of ashes and more than, fineness is not more than 25%, sulfur trioxide content be less than 3wt%.
The preparation method of sludge curing agent is as above：By after the feed components combined grinding of firming agent so that
Firming agent is in specific surface area is 450 ~ 650m2The powder of/kg.
The beneficial effects of the present invention is：
（1）The sludge curing agent of the present invention can reduce the moisture content of high-moisture percentage mud now, becomes silted up after can effectively reducing solidification
The internal strain of mud, prevents from ftractureing, and solidification intensity is high, hardening time is short, enables to coagulate soon, hard soon；
（2）The sludge curing agent of the present invention can heavy metal in active adsorption curing sludge, and with mud water content
Reduction, the heavy metal ion being originally free in water is cured, and reaches the requirement that landfill and building are banketed；
（3）The sludge curing agent of the present invention has carried out recycling to mud, solves the dirt caused by a large amount of siltations
The problems such as dye environment, energy-conserving and environment-protective, low engineering cost, profitable.
Specific embodiment
Below in conjunction with specific embodiment, the present invention will be further described, but the present invention is not limited only to these embodiments.
Embodiment 1
A kind of sludge curing agent, counts by weight, and its raw material includes：4 parts of ardealite, 15 parts of cement, 26 parts of quick lime, Calx
7 parts of stone, 28 parts of flyash, 1 part of hydroxypropyl methyl cellulose, 6 parts of glass-cermic powder, 6 parts of ceramic, 10 parts of furfural dregs, Maifanitum 4
Part and 8 parts of smectite clay.
The preparation method of sludge curing agent is as above：By after the feed components combined grinding of firming agent so that
Firming agent is in specific surface area is 450m2The powder of/kg.
Embodiment 2
A kind of sludge curing agent, counts by weight, and its raw material includes：6 parts of ardealite, 18 parts of cement, 30 parts of quick lime, Calx
9 parts of stone, 32 parts of flyash, 2 parts of hydroxypropyl methyl cellulose, 8 parts of glass-cermic powder, 8 parts of ceramic, 15 parts of furfural dregs, Maifanitum 6
Part and 10 parts of smectite clay.
The preparation method of sludge curing agent is as above：By after the feed components combined grinding of firming agent so that
Firming agent is in specific surface area is 650m2The powder of/kg.
Embodiment 3
A kind of sludge curing agent, counts by weight, and its raw material includes：5 parts of ardealite, 16 parts of cement, 28 parts of quick lime, Calx
8 parts of stone, 30 parts of flyash, 1.5 parts of hydroxypropyl methyl cellulose, 7 parts of glass-cermic powder, 7 parts of ceramic, 12 parts of furfural dregs, wheat meal
5 parts of stone and 9 parts of smectite clay.
The preparation method of sludge curing agent is as above：By after the feed components combined grinding of firming agent so that
Firming agent is in specific surface area is 550m2The powder of/kg.
Performance test
Using the sludge curing agent that embodiment 1 ~ 3 is obtained, silt from the bottom of lake is carried out with dehydrating and curing process, the addition ratio of firming agent is
15wt%, mud moisture content is 97.8wt%, and content of beary metal is detected according to international standard GB18918-2002, test result
As shown in table 1.
The foregoing is only presently preferred embodiments of the present invention, all impartial changes done according to scope of the present invention patent with
Modify, all should belong to the covering scope of the present invention.
Claims (6)
1. a kind of sludge curing agent it is characterised in that：Count by weight, the raw material of described firming agent includes：Ardealite 4 ~ 6
Part, 15 ~ 18 parts of cement, 26 ~ 30 parts of quick lime, 7 ~ 9 parts of limestone, 28 ~ 32 parts of flyash, 1 ~ 2 part of hydroxypropyl methyl cellulose,
6 ~ 8 parts of glass-cermic powder, 6 ~ 8 parts of ceramic, 10 ~ 15 parts of furfural dregs, 4 ~ 6 parts of Maifanitum and 8 ~ 10 parts of smectite clay.
2. sludge curing agent according to claim 1 it is characterised in that：Count by weight, described firming agent former
Material includes：5 parts of ardealite, 16 parts of cement, 28 parts of quick lime, 8 parts of limestone, 30 parts of flyash, hydroxypropyl methyl cellulose 1.5
Part, 7 parts of glass-cermic powder, 7 parts of ceramic, 12 parts of furfural dregs, 5 parts of Maifanitum and 9 parts of smectite clay.
3. sludge curing agent according to claim 1 and 2 it is characterised in that：Described ardealite adopt secondary standard and with
On, wherein sulfate dihydrate calcium content is more than 75wt%, and attachment water content is less than 8wt%.
4. sludge curing agent according to claim 1 and 2 it is characterised in that：Described cement is 425 grades of normal silicate water
Mud.
5. sludge curing agent according to claim 1 and 2 it is characterised in that：Described flyash adopt two grades of ashes and more than,
Fineness is not more than 25%, and sulfur trioxide content is less than 3wt%.
6. a kind of method preparing sludge curing agent as claimed in claim 1 or 2 it is characterised in that：Raw material by firming agent
So that firming agent is in specific surface area is 450 ~ 650m after each component combined grinding2The powder of/kg.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610840268.5A CN106478012A (en) | 2016-09-22 | 2016-09-22 | A kind of sludge curing agent and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610840268.5A CN106478012A (en) | 2016-09-22 | 2016-09-22 | A kind of sludge curing agent and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106478012A true CN106478012A (en) | 2017-03-08 |
Family
ID=58267614
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610840268.5A Pending CN106478012A (en) | 2016-09-22 | 2016-09-22 | A kind of sludge curing agent and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106478012A (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108706920A (en) * | 2018-05-23 | 2018-10-26 | 上海隧道工程有限公司 | Slurry balance shield sedimentation basin sludge curing agent and its modification method for mud, the application after mud improvement |
| CN110228924A (en) * | 2019-06-06 | 2019-09-13 | 广东聚晟建设工程有限公司 | Riverway sludge inorganic agent |
| CN110470516A (en) * | 2019-08-25 | 2019-11-19 | 天津大学 | A method of solidification effect is studied using orthogonal experiment using compounding curing agent |
| CN111448968A (en) * | 2020-02-28 | 2020-07-28 | 南京工业大学 | Method for preparing greening soil by improving tail mud of water works |
| CN111848038A (en) * | 2020-07-22 | 2020-10-30 | 中国电建集团华东勘测设计研究院有限公司 | Mixture and method for controlling cracking of sludge solidified soil |
| CN112551837A (en) * | 2020-12-03 | 2021-03-26 | 中国市政工程华北设计研究总院有限公司 | Silt curing agent based on induced calcification of high-molecular polysaccharide |
| CN112960710A (en) * | 2021-02-02 | 2021-06-15 | 大连盛博环境工程有限公司 | Efficient and rapid curing agent for landfill leachate |
| CN113321351A (en) * | 2021-08-02 | 2021-08-31 | 清大国华环境集团股份有限公司 | Method for treating cadmium wastewater and solidifying cadmium slag |
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| CN1278519A (en) * | 1999-06-18 | 2001-01-03 | 上海市建筑科学研究院 | Cement for foundation treatment and its preparation |
| KR101112719B1 (en) * | 2011-01-20 | 2012-03-13 | 이한재 | The solidification block composition and its manufacturing method that using the sludge and inorganic waste resources |
| CN103910503A (en) * | 2014-02-18 | 2014-07-09 | 祝建中 | Curing sintering-free granulation method for sludge |
| CN104016626A (en) * | 2014-06-10 | 2014-09-03 | 广州市水电建设工程有限公司 | Sludge curing agent and sludge curing process employing sludge curing agent |
| CN104108905A (en) * | 2014-07-09 | 2014-10-22 | 浙江建设职业技术学院 | Early-strength composite curing agent for high-organic-matter mudflat silt and application thereof |
| CN105859068A (en) * | 2016-06-20 | 2016-08-17 | 广州市水电建设工程有限公司 | Sludge treatment process |
-
2016
- 2016-09-22 CN CN201610840268.5A patent/CN106478012A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1278519A (en) * | 1999-06-18 | 2001-01-03 | 上海市建筑科学研究院 | Cement for foundation treatment and its preparation |
| KR101112719B1 (en) * | 2011-01-20 | 2012-03-13 | 이한재 | The solidification block composition and its manufacturing method that using the sludge and inorganic waste resources |
| CN103910503A (en) * | 2014-02-18 | 2014-07-09 | 祝建中 | Curing sintering-free granulation method for sludge |
| CN104016626A (en) * | 2014-06-10 | 2014-09-03 | 广州市水电建设工程有限公司 | Sludge curing agent and sludge curing process employing sludge curing agent |
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| CN105859068A (en) * | 2016-06-20 | 2016-08-17 | 广州市水电建设工程有限公司 | Sludge treatment process |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108706920A (en) * | 2018-05-23 | 2018-10-26 | 上海隧道工程有限公司 | Slurry balance shield sedimentation basin sludge curing agent and its modification method for mud, the application after mud improvement |
| CN110228924A (en) * | 2019-06-06 | 2019-09-13 | 广东聚晟建设工程有限公司 | Riverway sludge inorganic agent |
| CN110470516A (en) * | 2019-08-25 | 2019-11-19 | 天津大学 | A method of solidification effect is studied using orthogonal experiment using compounding curing agent |
| CN111448968A (en) * | 2020-02-28 | 2020-07-28 | 南京工业大学 | Method for preparing greening soil by improving tail mud of water works |
| CN111448968B (en) * | 2020-02-28 | 2022-02-11 | 南京工业大学 | Method for preparing greening soil by improving tail mud of water works |
| CN111848038A (en) * | 2020-07-22 | 2020-10-30 | 中国电建集团华东勘测设计研究院有限公司 | Mixture and method for controlling cracking of sludge solidified soil |
| CN112551837A (en) * | 2020-12-03 | 2021-03-26 | 中国市政工程华北设计研究总院有限公司 | Silt curing agent based on induced calcification of high-molecular polysaccharide |
| CN112960710A (en) * | 2021-02-02 | 2021-06-15 | 大连盛博环境工程有限公司 | Efficient and rapid curing agent for landfill leachate |
| CN113321351A (en) * | 2021-08-02 | 2021-08-31 | 清大国华环境集团股份有限公司 | Method for treating cadmium wastewater and solidifying cadmium slag |
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| TA01 | Transfer of patent application right |
Effective date of registration: 20170418 Address after: 350000 -C0398 (Free Trade Zone), A District, Fuzhou, Fuzhou Free Trade Zone, Fujian, China () Applicant after: Fujian harbor new material Co., Ltd. Address before: Jin Rong Bei Lu Cangshan District Fuzhou Fujian province 350028 City Hospital No. 17 No. 2 building sixth layer Applicant before: Fujian harbour Geotechnical Engineering Group Co., Ltd. |
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Application publication date: 20170308 |
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