CN108277634A - 一种泳衣面料及其制造工艺 - Google Patents
一种泳衣面料及其制造工艺 Download PDFInfo
- Publication number
- CN108277634A CN108277634A CN201810081091.4A CN201810081091A CN108277634A CN 108277634 A CN108277634 A CN 108277634A CN 201810081091 A CN201810081091 A CN 201810081091A CN 108277634 A CN108277634 A CN 108277634A
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- Prior art keywords
- fabric
- fiber
- oxidant
- parts
- swimming suit
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- 239000004744 fabric Substances 0.000 title claims abstract description 43
- 230000009182 swimming Effects 0.000 title claims abstract description 29
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 10
- 239000000835 fiber Substances 0.000 claims abstract description 34
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 27
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 27
- 235000006708 antioxidants Nutrition 0.000 claims abstract description 27
- 239000002245 particle Substances 0.000 claims abstract description 19
- 239000002759 woven fabric Substances 0.000 claims abstract description 14
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000000460 chlorine Substances 0.000 claims abstract description 13
- 229910052801 chlorine Inorganic materials 0.000 claims abstract description 13
- 238000000034 method Methods 0.000 claims abstract description 12
- 238000001125 extrusion Methods 0.000 claims abstract description 11
- 229920002334 Spandex Polymers 0.000 claims abstract description 10
- 239000004759 spandex Substances 0.000 claims abstract description 10
- 239000000203 mixture Substances 0.000 claims abstract description 9
- 239000012744 reinforcing agent Substances 0.000 claims abstract description 9
- 229920000728 polyester Polymers 0.000 claims abstract description 7
- 238000002844 melting Methods 0.000 claims abstract description 3
- 230000008018 melting Effects 0.000 claims abstract description 3
- -1 polyethylene terephthalate Polymers 0.000 claims description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 12
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 11
- 239000007788 liquid Substances 0.000 claims description 11
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 11
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims description 10
- 238000007590 electrostatic spraying Methods 0.000 claims description 10
- 229920000139 polyethylene terephthalate Polymers 0.000 claims description 10
- 238000009987 spinning Methods 0.000 claims description 10
- 239000003795 chemical substances by application Substances 0.000 claims description 8
- 238000012545 processing Methods 0.000 claims description 7
- 239000004594 Masterbatch (MB) Substances 0.000 claims description 6
- 239000003921 oil Substances 0.000 claims description 6
- SPSPIUSUWPLVKD-UHFFFAOYSA-N 2,3-dibutyl-6-methylphenol Chemical group CCCCC1=CC=C(C)C(O)=C1CCCC SPSPIUSUWPLVKD-UHFFFAOYSA-N 0.000 claims description 5
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 5
- 239000004698 Polyethylene Substances 0.000 claims description 5
- 235000010323 ascorbic acid Nutrition 0.000 claims description 5
- 239000011668 ascorbic acid Substances 0.000 claims description 5
- 229960005070 ascorbic acid Drugs 0.000 claims description 5
- CDQSJQSWAWPGKG-UHFFFAOYSA-N butane-1,1-diol Chemical compound CCCC(O)O CDQSJQSWAWPGKG-UHFFFAOYSA-N 0.000 claims description 5
- 229910052593 corundum Inorganic materials 0.000 claims description 5
- 239000011521 glass Substances 0.000 claims description 5
- 238000009998 heat setting Methods 0.000 claims description 5
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 claims description 5
- 229920000573 polyethylene Polymers 0.000 claims description 5
- ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical compound C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 claims description 5
- 229910001845 yogo sapphire Inorganic materials 0.000 claims description 5
- 239000000654 additive Substances 0.000 claims description 4
- 230000000996 additive effect Effects 0.000 claims description 4
- 239000002994 raw material Substances 0.000 claims description 4
- 229920000049 Carbon (fiber) Polymers 0.000 claims description 3
- 239000004917 carbon fiber Substances 0.000 claims description 3
- 238000010035 extrusion spinning Methods 0.000 claims description 3
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 3
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical group C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 3
- 239000011707 mineral Substances 0.000 claims description 3
- 238000009941 weaving Methods 0.000 claims description 2
- LHGVFZTZFXWLCP-UHFFFAOYSA-N guaiacol Chemical group COC1=CC=CC=C1O LHGVFZTZFXWLCP-UHFFFAOYSA-N 0.000 claims 1
- 230000002688 persistence Effects 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 description 10
- 239000002184 metal Substances 0.000 description 10
- 239000000463 material Substances 0.000 description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 229910010272 inorganic material Inorganic materials 0.000 description 4
- 239000011147 inorganic material Substances 0.000 description 4
- 230000003647 oxidation Effects 0.000 description 4
- 238000007254 oxidation reaction Methods 0.000 description 4
- 238000004513 sizing Methods 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- CZBZUDVBLSSABA-UHFFFAOYSA-N butylated hydroxyanisole Chemical group COC1=CC=C(O)C(C(C)(C)C)=C1.COC1=CC=C(O)C=C1C(C)(C)C CZBZUDVBLSSABA-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 2
- 235000010354 butylated hydroxytoluene Nutrition 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000004579 marble Substances 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- 238000000304 warm extrusion Methods 0.000 description 2
- 238000004383 yellowing Methods 0.000 description 2
- HXKKHQJGJAFBHI-UHFFFAOYSA-N 1-aminopropan-2-ol Chemical compound CC(O)CN HXKKHQJGJAFBHI-UHFFFAOYSA-N 0.000 description 1
- JFDFFRYBIFYDKP-UHFFFAOYSA-N 1-chloro-3-methoxy-2-nitrobenzene Chemical class COC1=CC=CC(Cl)=C1[N+]([O-])=O JFDFFRYBIFYDKP-UHFFFAOYSA-N 0.000 description 1
- NETSQGRTUNRXEO-UHFFFAOYSA-N 3,6,9-Trimethylidene-3a,4,5,6a,7,8,9a,9b-octahydroazuleno[4,5-b]furan-2-one Chemical compound C12OC(=O)C(=C)C2CCC(=C)C2C1C(=C)CC2 NETSQGRTUNRXEO-UHFFFAOYSA-N 0.000 description 1
- SFUGSFCZHFPQBZ-UHFFFAOYSA-N 4-(3-phenylpropyl)-2h-triazole Chemical compound C=1C=CC=CC=1CCCC=1C=NNN=1 SFUGSFCZHFPQBZ-UHFFFAOYSA-N 0.000 description 1
- XMWRBQBLMFGWIX-UHFFFAOYSA-N C60 fullerene Chemical compound C12=C3C(C4=C56)=C7C8=C5C5=C9C%10=C6C6=C4C1=C1C4=C6C6=C%10C%10=C9C9=C%11C5=C8C5=C8C7=C3C3=C7C2=C1C1=C2C4=C6C4=C%10C6=C9C9=C%11C5=C5C8=C3C3=C7C1=C1C2=C4C6=C2C9=C5C3=C12 XMWRBQBLMFGWIX-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 description 1
- 229920004934 Dacron® Polymers 0.000 description 1
- WKSUCCVMYJRMFR-UHFFFAOYSA-N Dehydrocostus lactone Natural products C12OC(=O)C(=C)C2CCC(=C)C2(C)C1(C)C(=C)CC2 WKSUCCVMYJRMFR-UHFFFAOYSA-N 0.000 description 1
- NIPNSKYNPDTRPC-UHFFFAOYSA-N N-[2-oxo-2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 NIPNSKYNPDTRPC-UHFFFAOYSA-N 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- BHHGXPLMPWCGHP-UHFFFAOYSA-N Phenethylamine Chemical compound NCCC1=CC=CC=C1 BHHGXPLMPWCGHP-UHFFFAOYSA-N 0.000 description 1
- YGSDEFSMJLZEOE-UHFFFAOYSA-N Salicylic acid Natural products OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 229960000583 acetic acid Drugs 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 235000019282 butylated hydroxyanisole Nutrition 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 229910021387 carbon allotrope Inorganic materials 0.000 description 1
- 239000002041 carbon nanotube Substances 0.000 description 1
- 229910021393 carbon nanotube Inorganic materials 0.000 description 1
- 229910010293 ceramic material Inorganic materials 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- YAZBKDRDYPAXAO-UHFFFAOYSA-N dehydro-alpha-curcumene Natural products CC(C)=CCCC(=C)C1=CC=C(C)C=C1 YAZBKDRDYPAXAO-UHFFFAOYSA-N 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 229910003460 diamond Inorganic materials 0.000 description 1
- 239000010432 diamond Substances 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 229910003472 fullerene Inorganic materials 0.000 description 1
- 239000012362 glacial acetic acid Substances 0.000 description 1
- 229910021389 graphene Inorganic materials 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 229940102253 isopropanolamine Drugs 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 150000001247 metal acetylides Chemical class 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 229910001463 metal phosphate Inorganic materials 0.000 description 1
- 229910052914 metal silicate Inorganic materials 0.000 description 1
- 229910052976 metal sulfide Inorganic materials 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 150000002927 oxygen compounds Chemical class 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002310 reflectometry Methods 0.000 description 1
- 229960004889 salicylic acid Drugs 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 229910021332 silicide Inorganic materials 0.000 description 1
- FVBUAEGBCNSCDD-UHFFFAOYSA-N silicide(4-) Chemical compound [Si-4] FVBUAEGBCNSCDD-UHFFFAOYSA-N 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- 239000012798 spherical particle Substances 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- UONOETXJSWQNOL-UHFFFAOYSA-N tungsten carbide Chemical compound [W+]#[C-] UONOETXJSWQNOL-UHFFFAOYSA-N 0.000 description 1
- 239000011800 void material Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M10/00—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
- D06M10/04—Physical treatment combined with treatment with chemical compounds or elements
- D06M10/06—Inorganic compounds or elements
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D31/00—Materials specially adapted for outerwear
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D7/00—Bathing gowns; Swim-suits, drawers, or trunks; Beach suits
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/88—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
- D01F6/92—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyesters
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06C—FINISHING, DRESSING, TENTERING OR STRETCHING TEXTILE FABRICS
- D06C7/00—Heating or cooling textile fabrics
- D06C7/02—Setting
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M10/00—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
- D06M10/04—Physical treatment combined with treatment with chemical compounds or elements
- D06M10/08—Organic compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/46—Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic Table; Titanates; Zirconates; Stannates; Plumbates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/68—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof
- D06M11/70—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof with oxides of phosphorus; with hypophosphorous, phosphorous or phosphoric acids or their salts
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/227—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/32—Polyesters
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/38—Polyurethanes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/25—Resistance to light or sun, i.e. protection of the textile itself as well as UV shielding materials or treatment compositions therefor; Anti-yellowing treatments
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Artificial Filaments (AREA)
- Woven Fabrics (AREA)
Abstract
本发明涉及一种泳衣面料及其制造工艺，种泳衣面料，其特征在于：包括涤纶纤维和耐氯氨纶，织布工序包括热定型以及抗紫外线整理。涤纶纤维采用熔融挤出的方式制成纤维，在纤维成分挤出之前或挤出时添加抗氧化增强剂，其为至少4.5莫氏硬度、直径为0.1‑10微米的颗粒或纤维。面料具有挺括、颜色持久度高、优异的抗氧化、抗紫外的性能等特点。
Description
技术领域
本发明涉及一种泳衣面料，属于纺织领域。
背景技术
现有的布料品种众多，但随着人们生活水平的提高，需要提供能满足不同人群需要的新品种，而泳衣面料就是随着时代的发展逐渐被人们所需要的。泳衣有一件式和两截式和三点式（比基尼）等变化。最初的泳装紧贴身体，遮裹着身体的大部三点式泳装分。20世纪初男子泳装才开始穿不连上衣的短裤。第一次世界大战结束后，妇女穿的紧身连裤泳装流行法国，其他泳装逐渐被淘汰。1935年开始，女子开始穿由乳罩和短裤配成的两件一套的游泳衣。1947年，比基尼装流行开来，带动泳装向新的方向发展。现代泳装无论从色彩、式样、质料几方面都超越以往，形成了多色彩、多式样、高质量的泳装新潮流。最常见的泳衣面料分为以下三种：1、杜邦莱卡泳衣会比普通材质的泳衣有更长的使用寿命，多适用于连体泳衣。2、锦纶面料的泳衣属于中等价位，当然与杜邦莱卡面泳衣相比，扎实度不够，但是弹性度与柔软度是不相上下的，是现在人们最常使用最常见的泳衣面料了。3、涤纶面料的泳衣弹性小，受限制，而且属于低价产品，一般都是设计为分体式泳衣，不适合连体泳衣。
泳衣在绝大多数时间在游泳池中，游泳池中因为需要进行消毒，一般会有大量的氯，这样就会造成颜色脱落，现有技术中会有不少耐氯的涤纶织物，但是在人不游泳的时候，泳衣存放过程中，在紫外线照射下，泳衣的耐氯能力会下降。
同时泳衣面料在使用过程中，由于多次洗涤，暴晒，大气污染紫外线照射等等的影响，有很多原因可能会造成氧化现象，使得衣物产生黄变或褪色问题，这在很大程度上影响了衣服的美观度。因此，对于泳衣面料而言抗氧化性和耐氯能力显得尤为重要。现有市面上存在一些抗氧化处理面料，例如用于织物的化学品、染整工艺的加工条件、包装和储存条件等，但是存在成本较高、对产品有针对性，缺乏普适性的问题，至今也没有一个能够有效解决或预防抗氧化的好的办法。
CN105839395A提供一种防透视浅色全棉高支色织面料的制造方法，利用该制造方法可以制造出防透视性能好的的浅色全棉色织面料。
CN105568592A对面料做了四防处理，可以有效防止沾上污渍、油渍，防止黄变，防止油污、水、污渍渗入纤维里层，可以保持面料长期干爽、洁净。
CN107401047A公开了一种抗黄变整理剂，所述的抗变黄整理剂，主要成分是4-羟基苯乙胺、异丙醇胺、冰醋酸、4-氯-2-硝基苯甲醚、苯丙三氮唑、2-硝基-3-氯苯基肼、邻乙酰水杨酸、蒸馏水和去氢木香内酯。
目前，但是都没能很好的解决泳衣面料抗氧化的问题，大多数面料都不具备抗氧化的功能，由此导致面料掉色、褪色，不美观，并且有一些金属编制的衣服还会由于氧化做工，失去应有的效果。
发明内容
本发明的目的在于针对现有技术的不足，提供一种操作简单，能够有效防止面料氧化、抗紫外线以及耐氯的泳衣面料及制造工艺。
本发明提供了一种泳衣面料，其特征在于：包括涤纶纤维和耐氯氨纶，织布工序包括热定型和抗紫外线整理。
涤纶纤维采用熔融挤出的方式制成纤维，在纤维成分挤出之前或挤出时添加至少4.5莫氏硬度、直径为0.1-10微米的纤维或颗粒。
面料的具体制造工艺，包括以下步骤：
1.纤维制造
将色母粒切片与聚对苯二甲酸乙二醇酯切片混合，混合比例为2～15：98～85（重量），然后经高温挤压纺丝，在挤出之前或挤出时添加抗氧化增强剂，其为至少4.5莫氏硬度、直径为0.1-10微米的纤维或颗粒，添加量为0.1-10重量％；
2.抗氧化整理
将抗氧化整理液采用静电喷涂的方式附着与涤纶纤维表面，然后进行微波处理，频率为80-150MHZ，处理时间为10-15min；静电喷涂距离为15-50mm，电压为30-100v；其中抗氧化整理液包括以下重量份原料：丁二醇8-10份、三氧化二铝3-5份、软化油5-6份、抗坏血酸15-20份、二丁基羟基甲苯（BHT）10-30份、丁基羟基茴香醚（BHA）0-15份。
3.纺纱及织造
将上述纤维与耐氯氨纶混合纺纱，然后进行织布，织布工序包括热定型和抗紫外线整理；其中热定型步骤为，将面料放入蒸箱，然后注水，水量与面料高度齐平，温度为30℃，然后对箱体抽真空，并加热到60℃后保温30min，再降温到45℃，保温30min，完成真空热定型；抗紫外线整理剂按重量份包括纳米二氧化钛10-15%、亚磷酸1-3%、聚乙烯2-5%、受阻酚4-10%。
所述抗氧化增强剂可以是有机的或者无机的。优选地，该材料是无机材料。在本发明的上下文中，“无机材料”被理解为基本上没有共价键碳原子的材料，因此排除了诸如烃、尤其聚合物材料的任何有机材料。具体地，无机材料指的是如下化合物，包括金属、金属氧化物、粘土、二氧化硅、硅酸盐或它们的混合物，而且包括碳化物、碳酸盐、氰化物以及碳的同素异形体，诸如钻石、石墨、石墨烯、富勒烯和碳纳米管。优选地，无机材料是玻璃、矿物或金属，或者是碳纤维。
具有至少4.5的莫氏硬度的可用的材料包括但不限于金属、金属氧化物诸如铝氧化物、金属碳化物诸如碳化钨、金属氮化物、金属硫化物、金属硅酸盐、金属硅化物、金属硫酸盐、金属磷酸盐和金属硼化物。其它实例包括二氧化硅和碳化硅。也可以使用其他陶瓷材料以及上述材料的组合。
抗氧化增强剂的颗粒尺寸、颗粒尺寸分布、颗粒直径和颗粒的数量都是优化抗氧化强度同时保持模制制品的机械性质的重要参数。可以使用抗氧化增强剂的颗粒形式，其中粉末形式通常是合适的。对于基本上球形的颗粒来说，平均颗粒尺寸基本上等于平均颗粒直径。对于基本上椭圆形(oblong)的颗粒诸如针状物或纤维来说，颗粒尺寸可以指沿颗粒长轴的长度维度，而平均颗粒直径或简称直径指的是垂直于该椭圆形长度方向的横截面的平均直径。
合适的颗粒尺寸和直径的选择取决于加工过程和模制制品尺寸。在通 过纺丝方法生产的模制制品的情况下，颗粒应该足够小，从而容易地穿过喷丝头孔。可以选择足够小的颗粒尺寸和直径，以避免纤维拉伸性质明显恶化。颗粒尺寸和直径可以具有对数(log)正态分布。
本申请的有益效果：
1.通过添加抗氧化增强剂，在纤维内部形成容易与抗氧剂整理的结构空隙，以便抗氧化剂整理液能够很好的附着，产生持久的效果。
2.采用特定的抗氧化整理液组分，使得抗氧化效果优于其他传统抗氧化剂。
3.微波整理以及真空整理的方式，使得织物定型挺括，色泽艳丽，色牢度好同时持久。
具体实施方式
现将通过如下实施例和对比实验来进一步说明本发明，但不限于此。
实施例1
将色母粒切片与聚对苯二甲酸乙二醇酯切片混合，混合比例为2：98（重量），然后经高温挤压纺丝，在挤出之前添加5重量％的矿物纤维(在商品名 RB215-RoxulTM1000下出售，矿物纤维的平均直径为5.5微米)；
将抗氧化整理液采用静电喷涂的方式附着与涤纶纤维表面，然后进行微波处理，频率为80MHZ，处理时间为10min；静电喷涂距离为15-50mm，电压为30-100v；抗氧化整理液包括以下重量份原料：丁二醇8份、三氧化二铝5份、软化油5份、抗坏血酸15份、二丁基羟基甲苯（BHT）30份、丁基羟基茴香醚（BHA）1份。
将上述纤维与耐氯氨纶混合纺纱，然后进行织布，织布工序包括热定型和抗紫外线整理；其中热定型步骤为，将面料放入蒸箱，然后注水，水量与面料高度齐平，温度为30℃，然后对箱体抽真空，并加热到60℃后保温30min，再降温到45℃，保温30min，完成真空热定型；抗紫外线整理剂按重量份包括纳米二氧化钛10%、亚磷酸1%、聚乙烯2%、受阻酚10%。
实施例2
将色母粒切片与聚对苯二甲酸乙二醇酯切片混合，混合比例为10：90（重量），然后经高温挤压纺丝，挤出时添加直径为3微米的玻璃球，添加量为0.5重量％；
将抗氧化整理液采用静电喷涂的方式附着与涤纶纤维表面，然后进行微波处理，频率为100MHZ，处理时间为11min；静电喷涂距离为15mm，电压为30v；其中抗氧化整理液包括以下重量份原料：丁二醇8份、三氧化二铝3份、软化油5份、抗坏血酸15份、二丁基羟基甲苯（BHT）10-30份、丁基羟基茴香醚（BHA）0-15份。
将上述纤维与耐氯氨纶混合纺纱，然后进行织布，织布工序包括热定型和抗紫外线整理；其中热定型步骤为，将面料放入蒸箱，然后注水，水量与面料高度齐平，温度为30℃，然后对箱体抽真空，并加热到60℃后保温30min，再降温到45℃，保温30min，完成真空热定型；抗紫外线整理剂按重量份包括纳米二氧化钛15%、亚磷酸3%、聚乙烯5%、受阻酚10%。
实施例3
将色母粒切片与聚对苯二甲酸乙二醇酯切片混合，混合比例为2～15：98～85（重量），然后经高温挤压纺丝，在挤出之前添加直径为5微米的碳纤维，其为短纤维，长度为1-10um，添加量为10重量％；
将抗氧化整理液采用静电喷涂的方式附着与涤纶纤维表面，然后进行微波处理，频率为80-150MHZ，处理时间为10-15min；静电喷涂距离为15-50mm，电压为30-100v；丁二醇8份、三氧化二铝5份、软化油6份、抗坏血酸20份、二丁基羟基甲苯（BHT）30份、丁基羟基茴香醚（BHA）15份。
将上述纤维与耐氯氨纶混合纺纱，然后进行织布，织布工序包括热定型和抗紫外线整理；其中热定型步骤为，将面料放入蒸箱，然后注水，水量与面料高度齐平，温度为30℃，然后对箱体抽真空，并加热到60℃后保温30min，再降温到45℃，保温30min，完成真空热定型；抗紫外线整理剂按重量份包括纳米二氧化钛10%、亚磷酸3%、聚乙烯5%、受阻酚4%。
对比例1
不添加直径为3微米的玻璃球，其余与实施例2相同。
对比例2
抗氧化剂采用受阻胺类抗氧化剂，其余与实施例1相同。
对比例3
不进行真空定型步骤，其余与实施例3相同。
使用数据分光光度计进行颜色强度测量，以确定织物的反射(R)并使用反射率测量结果评估面料色彩艳丽程度，表示为K/S因子。将反射读数(R)代入到Kubelka Munck方程的变形形式K/S＝(1-R)2/2R中，并被报道为K/S值(E.R.Trotman，“Dying and ChemicalTechnology of Textile Fibers”第643页，第4版，1970，Charles Griffin & CompanyLtd.，London，England)。
表1
注：黄变情况针对色母粒为白色，面料为白色面料时，采用高温高湿热处理24小时后进行观测。
由此可见，未使用本申请技术方案的对比例1-3由于光热的作用，面料耐氧化性以及抗紫外线性能较差，产生了颜色的改变，而本申请显现出优异的耐氧化性能。
Claims (5)
1.一种泳衣面料，其特征在于：包括涤纶纤维和耐氯氨纶，织布工序包括热定型以及抗紫外线整理。
2.如权利要求1所述的泳衣面料，其特征在于：涤纶纤维采用熔融挤出的方式制成纤维，在纤维成分挤出之前或挤出时添加抗氧化增强剂，其为至少4.5莫氏硬度、直径为0.1-10微米的颗粒或纤维。
3.如权利要求1所述的泳衣面料的制造方法，包括以下步骤：
纤维制造
将色母粒切片与聚对苯二甲酸乙二醇酯切片混合，混合比例为2～15：98～85（重量），然后经高温挤压纺丝，在挤出之前或挤出时添加抗氧化增强剂，其为至少4.5莫氏硬度、直径为0.1-10微米的纤维或颗粒，添加量为0.1-10重量％；
抗氧化整理
将抗氧化整理液采用静电喷涂的方式附着与涤纶纤维表面，然后进行微波处理，频率为80-150MHZ，处理时间为10-15min；静电喷涂距离为15-50mm，电压为30-100v；
纺纱及织造
将上述纤维与耐氯氨纶混合纺纱，然后进行织布，织布工序包括热定型和抗紫外线整理；其中热定型步骤为，将面料放入蒸箱，然后注水，水量与面料高度齐平，温度为30℃，然后对箱体抽真空，并加热到60℃后保温30min，再降温到45℃，保温30min，完成真空热定型；抗紫外线整理剂按重量份包括纳米二氧化钛10-15%、亚磷酸1-3%、聚乙烯2-5%、受阻酚4-10%。
4.如权利要求3所述的制造方法，其中抗氧化整理液包括以下重量份原料：丁二醇8-10份、三氧化二铝3-5份、软化油5-6份、抗坏血酸15-20份、二丁基羟基甲苯（BHT）10-30份、丁基羟基茴香醚（BHA）0-15份。
5.如权利要求3所述的制造方法，其特征在于，抗氧化增强剂为碳纤维、矿物纤维或玻璃球。
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