CN108265136A - A kind of leather care products and preparation method thereof - Google Patents
A kind of leather care products and preparation method thereof Download PDFInfo
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- CN108265136A CN108265136A CN201810242462.2A CN201810242462A CN108265136A CN 108265136 A CN108265136 A CN 108265136A CN 201810242462 A CN201810242462 A CN 201810242462A CN 108265136 A CN108265136 A CN 108265136A
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- parts
- care products
- oil
- leather care
- leather
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- 239000010985 leather Substances 0.000 title claims abstract description 92
- 238000002360 preparation method Methods 0.000 title claims abstract description 25
- VYGQUTWHTHXGQB-FFHKNEKCSA-N Retinol Palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC\C=C(/C)\C=C\C=C(/C)\C=C\C1=C(C)CCCC1(C)C VYGQUTWHTHXGQB-FFHKNEKCSA-N 0.000 claims abstract description 74
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 46
- 239000000194 fatty acid Substances 0.000 claims abstract description 46
- 229930195729 fatty acid Natural products 0.000 claims abstract description 46
- HJVAFZMYQQSPHF-UHFFFAOYSA-N 2-[bis(2-hydroxyethyl)amino]ethanol;boric acid Chemical compound OB(O)O.OCCN(CCO)CCO HJVAFZMYQQSPHF-UHFFFAOYSA-N 0.000 claims abstract description 41
- 150000004665 fatty acids Chemical class 0.000 claims abstract description 39
- 229940108325 retinyl palmitate Drugs 0.000 claims abstract description 37
- 235000019172 retinyl palmitate Nutrition 0.000 claims abstract description 37
- 239000011769 retinyl palmitate Substances 0.000 claims abstract description 37
- 239000003921 oil Substances 0.000 claims abstract description 36
- 235000019198 oils Nutrition 0.000 claims abstract description 36
- 244000060011 Cocos nucifera Species 0.000 claims abstract description 35
- 235000013162 Cocos nucifera Nutrition 0.000 claims abstract description 35
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 33
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims abstract description 28
- 235000007303 Thymus vulgaris Nutrition 0.000 claims abstract description 24
- 239000008367 deionised water Substances 0.000 claims abstract description 24
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 24
- 239000001585 thymus vulgaris Substances 0.000 claims abstract description 24
- 239000000341 volatile oil Substances 0.000 claims abstract description 24
- LDVVTQMJQSCDMK-UHFFFAOYSA-N 1,3-dihydroxypropan-2-yl formate Chemical compound OCC(CO)OC=O LDVVTQMJQSCDMK-UHFFFAOYSA-N 0.000 claims abstract description 22
- 235000021355 Stearic acid Nutrition 0.000 claims abstract description 22
- 239000004359 castor oil Substances 0.000 claims abstract description 22
- 235000019438 castor oil Nutrition 0.000 claims abstract description 22
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims abstract description 22
- LXCFILQKKLGQFO-UHFFFAOYSA-N methylparaben Chemical compound COC(=O)C1=CC=C(O)C=C1 LXCFILQKKLGQFO-UHFFFAOYSA-N 0.000 claims abstract description 22
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims abstract description 22
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims abstract description 22
- 239000008117 stearic acid Substances 0.000 claims abstract description 22
- 238000003756 stirring Methods 0.000 claims abstract description 22
- 239000004166 Lanolin Substances 0.000 claims abstract description 20
- 229940008099 dimethicone Drugs 0.000 claims abstract description 20
- 239000004205 dimethyl polysiloxane Substances 0.000 claims abstract description 20
- 235000013870 dimethyl polysiloxane Nutrition 0.000 claims abstract description 20
- 235000019388 lanolin Nutrition 0.000 claims abstract description 20
- 229940039717 lanolin Drugs 0.000 claims abstract description 20
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims abstract description 20
- 239000002994 raw material Substances 0.000 claims abstract description 18
- 229940060184 oil ingredients Drugs 0.000 claims abstract description 13
- 229960004274 stearic acid Drugs 0.000 claims abstract description 13
- 241000246358 Thymus Species 0.000 claims description 23
- 235000019197 fats Nutrition 0.000 claims description 22
- 239000003240 coconut oil Substances 0.000 claims description 16
- 235000019864 coconut oil Nutrition 0.000 claims description 16
- 239000007788 liquid Substances 0.000 claims description 16
- 239000000203 mixture Substances 0.000 claims description 15
- 150000001408 amides Chemical class 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 11
- 230000002045 lasting effect Effects 0.000 claims description 8
- 238000010792 warming Methods 0.000 claims description 8
- 238000001816 cooling Methods 0.000 claims description 6
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 4
- -1 acyl Amine Chemical class 0.000 claims description 4
- 241001494479 Pecora Species 0.000 claims description 2
- 238000010438 heat treatment Methods 0.000 claims description 2
- 239000006210 lotion Substances 0.000 claims description 2
- XUPKQJGWOGGTQN-UHFFFAOYSA-N 2-[bis(2-hydroxyethyl)amino]ethanol;boron Chemical compound [B].OCCN(CCO)CCO XUPKQJGWOGGTQN-UHFFFAOYSA-N 0.000 claims 2
- 150000002148 esters Chemical class 0.000 claims 2
- VYGQUTWHTHXGQB-UHFFFAOYSA-N Retinol hexadecanoate Natural products CCCCCCCCCCCCCCCC(=O)OCC=C(C)C=CC=C(C)C=CC1=C(C)CCCC1(C)C VYGQUTWHTHXGQB-UHFFFAOYSA-N 0.000 claims 1
- ZZVUWRFHKOJYTH-UHFFFAOYSA-N diphenhydramine Chemical compound C=1C=CC=CC=1C(OCCN(C)C)C1=CC=CC=C1 ZZVUWRFHKOJYTH-UHFFFAOYSA-N 0.000 claims 1
- 235000015112 vegetable and seed oil Nutrition 0.000 claims 1
- 230000001408 fungistatic effect Effects 0.000 abstract description 16
- 239000003795 chemical substances by application Substances 0.000 abstract description 9
- 230000002787 reinforcement Effects 0.000 abstract description 7
- 240000002657 Thymus vulgaris Species 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 25
- 239000004519 grease Substances 0.000 description 14
- 241000894006 Bacteria Species 0.000 description 8
- 210000003491 skin Anatomy 0.000 description 8
- 239000010410 layer Substances 0.000 description 7
- 150000002942 palmitic acid derivatives Chemical class 0.000 description 7
- 230000000844 anti-bacterial effect Effects 0.000 description 6
- 239000000835 fiber Substances 0.000 description 6
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 5
- 239000005864 Sulphur Substances 0.000 description 5
- 239000003205 fragrance Substances 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 239000004530 micro-emulsion Substances 0.000 description 4
- 230000000474 nursing effect Effects 0.000 description 4
- 230000035699 permeability Effects 0.000 description 4
- 230000035943 smell Effects 0.000 description 4
- FPIPGXGPPPQFEQ-UHFFFAOYSA-N 13-cis retinol Natural products OCC=C(C)C=CC=C(C)C=CC1=C(C)CCCC1(C)C FPIPGXGPPPQFEQ-UHFFFAOYSA-N 0.000 description 3
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 3
- FPIPGXGPPPQFEQ-BOOMUCAASA-N Vitamin A Natural products OC/C=C(/C)\C=C\C=C(\C)/C=C/C1=C(C)CCCC1(C)C FPIPGXGPPPQFEQ-BOOMUCAASA-N 0.000 description 3
- FPIPGXGPPPQFEQ-OVSJKPMPSA-N all-trans-retinol Chemical compound OC\C=C(/C)\C=C\C=C(/C)\C=C\C1=C(C)CCCC1(C)C FPIPGXGPPPQFEQ-OVSJKPMPSA-N 0.000 description 3
- 238000013475 authorization Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- IPCSVZSSVZVIGE-UHFFFAOYSA-M hexadecanoate Chemical compound CCCCCCCCCCCCCCCC([O-])=O IPCSVZSSVZVIGE-UHFFFAOYSA-M 0.000 description 3
- 235000019155 vitamin A Nutrition 0.000 description 3
- 239000011719 vitamin A Substances 0.000 description 3
- 229940045997 vitamin a Drugs 0.000 description 3
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
- MKYBYDHXWVHEJW-UHFFFAOYSA-N N-[1-oxo-1-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propan-2-yl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(C(C)NC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 MKYBYDHXWVHEJW-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 125000002252 acyl group Chemical group 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 239000002280 amphoteric surfactant Substances 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 230000003115 biocidal effect Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000004327 boric acid Substances 0.000 description 2
- 238000009395 breeding Methods 0.000 description 2
- 230000001488 breeding effect Effects 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000001804 emulsifying effect Effects 0.000 description 2
- 210000002615 epidermis Anatomy 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 230000001050 lubricating effect Effects 0.000 description 2
- 210000004400 mucous membrane Anatomy 0.000 description 2
- 239000002736 nonionic surfactant Substances 0.000 description 2
- 229920002545 silicone oil Polymers 0.000 description 2
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 2
- 238000007920 subcutaneous administration Methods 0.000 description 2
- 239000002344 surface layer Substances 0.000 description 2
- 230000002195 synergetic effect Effects 0.000 description 2
- 229940088594 vitamin Drugs 0.000 description 2
- 229930003231 vitamin Natural products 0.000 description 2
- 235000013343 vitamin Nutrition 0.000 description 2
- 239000011782 vitamin Substances 0.000 description 2
- 150000003722 vitamin derivatives Chemical class 0.000 description 2
- DHKVCYCWBUNNQH-UHFFFAOYSA-N 2-[5-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]-1,3,4-oxadiazol-2-yl]-1-(1,4,5,7-tetrahydropyrazolo[3,4-c]pyridin-6-yl)ethanone Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C1=NN=C(O1)CC(=O)N1CC2=C(CC1)C=NN2 DHKVCYCWBUNNQH-UHFFFAOYSA-N 0.000 description 1
- 241000228197 Aspergillus flavus Species 0.000 description 1
- 229920001661 Chitosan Polymers 0.000 description 1
- 235000005979 Citrus limon Nutrition 0.000 description 1
- 244000131522 Citrus pyriformis Species 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- JAWMENYCRQKKJY-UHFFFAOYSA-N [3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-ylmethyl)-1-oxa-2,8-diazaspiro[4.5]dec-2-en-8-yl]-[2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidin-5-yl]methanone Chemical compound N1N=NC=2CN(CCC=21)CC1=NOC2(C1)CCN(CC2)C(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F JAWMENYCRQKKJY-UHFFFAOYSA-N 0.000 description 1
- 239000010634 clove oil Substances 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229940031098 ethanolamine Drugs 0.000 description 1
- 230000000855 fungicidal effect Effects 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229920005615 natural polymer Polymers 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 239000003346 palm kernel oil Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 229910001961 silver nitrate Inorganic materials 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C14—SKINS; HIDES; PELTS; LEATHER
- C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
- C14C11/00—Surface finishing of leather
-
- C—CHEMISTRY; METALLURGY
- C14—SKINS; HIDES; PELTS; LEATHER
- C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
- C14C9/00—Impregnating leather for preserving, waterproofing, making resistant to heat or similar purposes
- C14C9/02—Impregnating leather for preserving, waterproofing, making resistant to heat or similar purposes using fatty or oily materials, e.g. fat liquoring
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Treatment And Processing Of Natural Fur Or Leather (AREA)
- Cosmetics (AREA)
Abstract
The invention discloses a kind of leather care products and preparation method thereof, belong to care agent preparing technical field.The leather care products, including following raw material：Methyl hydroxybenzoate, monoglyceride, white oil, stearic acid, lanolin, dimethicone, sulfated castor oil, thyme essential oil, nano silver, deionized water, Retinol Palmitate, triethanolamine borate, cocoanut fatty acid diethanolamide；The leather care products be by substep mixing, stirring and etc. be made.The present invention is reinforcement system by using Retinol Palmitate, triethanolamine borate, cocoanut fatty acid diethanolamide, improves the fungistatic effect and color fastness of leather care products.
Description
Technical field
The invention belongs to care agent preparing technical fields, and in particular to a kind of leather care products and preparation method thereof.
Background technology
It is appeared in life as the improvement of people's living standards, corium fabricated product is more and more, the nursing to leather
Maintenance also becomes required.Converted products of the corium fabricated product as natural polymer, rich in collagenic protein and fat
Fat, Long Term Contact air, the easy rough wear in surface, smoothness decline, need periodically to nurse.Because its be exposed in air contact it is mould
Bacterium spore easily generates mould, mildew occurs；And grease easily occurs oxidation and generates peculiar smell.All it is in existing leather nursing product
It adds in a large amount of greases and moistens leather surface, increase brightness.To go to eliminate the unusual smell, in bating agent, environment-friendly type care agent and skin
It removes from office and the inhibition grease smell such as lemon, clove oil is added in preservative, assign leather fragrance.But the fragrance essence of existing report
Oil does not have antibiotic property, it is impossible to leather be carried out antibacterial.Nano silver colloidal sol is the metallic silver simple substance that grain size is less than 100nm, right
About 650 various bacterias have spectrum bactericidal effect.The packaging nanometer of molecule is prepared as raw material using chitosan and silver nitrate at present
Silver-colored leather fungicide obtains certain fungistatic effect, but manufacture craft is cumbersome, takes 10-20h, and price is costly.With this
Meanwhile there are still grease smells for leather itself.Why soft leather is, and when basic reason is that process hides, grease is introduced
The inside of Animal Skin forms the oil film for covering intradermal fiber surface comprehensively, i.e., with one layer suitable for thick between intradermal fiber surface
The oil film of degree separates, in this way, the frictional force moved between leather internal fiber is equivalent to the frictional force of oil molecule, thus leather
It will be very soft.But due to introducing the grease inside leather in its natural state, can slowly volatilize with the remote of time
It wanders away or is destroyed oil film due to other, if water occurs under hydrolysis or hot environment, oil film is destroyed, grease
Volatilization is wandered away, thus will be mutually bonded together between leather internal fiber, so as to which leather be made to be hardened, become fragile.
Leather care products are for nursing the leather and fur products such as fur clothing, leather sofa, suitcase, skin chair, leather shoes, and make the extensive light of leather
It is bright multiple soft such as new product.Although existing leather care products have good effect in terms of softening cortex, feel on the market
Fruit, but it is too big to the injury of leather, also easily skin is made to fade.
A kind of Chinese patent literature " fragrance leather care products and its preparation method and application (Authorization Notice No.：
CN105734187B a kind of fragrant leather care products and preparation method thereof) " are disclosed, are made of the raw material of following weight parts：
1.25-4.90 parts of methyl hydroxybenzoate, 0.90-2.08 parts of monoglyceride, 5.30-6.83 parts of white oil, 3.90-4.90 parts of stearic acid, sheep
3.60-6.42 parts of fat of hair, 4.90-5.95 parts of dimethicone, 5.66-8.88 parts of sulfated castor oil, thyme essential oil 4.00-
8.00 parts, 1.00-5.00 parts of nano silver, 50.27-67.97 parts of deionized water.Fragrant leather care products prepared by the present invention can
Make leather surface smooth soft bright, assign fragrance, improve antibiotic property, but there are the problem of color fastness is inadequate, fungistatic effect is insufficient.
Invention content
The object of the present invention is to provide a kind of leather care products and preparation method thereof, to solve in a kind of patent document " virtue
Fragrant leather care products and its preparation method and application (Authorization Notice No.：CN105734187B the base of leather care products disclosed in) "
On plinth, how to optimize component, dosage, method etc., the color fastness for improving leather care products is inadequate, fungistatic effect is insufficient asks
Topic.
In order to solve the above technical problems, the present invention uses following technical scheme：
A kind of leather care products, including following raw material：Methyl hydroxybenzoate, monoglyceride, white oil, stearic acid, lanolin, diformazan
Base silicone oil, sulfated castor oil, thyme essential oil, nano silver, deionized water, Retinol Palmitate, triethanolamine boric acid
Ester, cocoanut fatty acid diethanolamide；
The Retinol Palmitate, triethanolamine borate, the weight ratio of cocoanut fatty acid diethanolamide are
(0.50-1.50)：(1.26-3.32)：(3.24-5.18).
Further, the Retinol Palmitate, triethanolamine borate, cocoanut fatty acid diethanolamide
Weight ratio is 1.00:2.29:4.21.
Further, the leather care products are as unit of parts by weight, including following raw material：Methyl hydroxybenzoate 1.25-
4.90 parts, 0.90-2.08 parts of monoglyceride, 5.30-6.83 parts of white oil, 3.90-4.90 parts of stearic acid, 3.60-6.42 parts of lanolin,
4.90-5.95 parts of dimethicone, 5.66-8.88 parts of sulfated castor oil, 4.00-8.00 parts of thyme essential oil, nano silver
1.00-5.00 parts, 50.27-67.97 parts of deionized water, 0.50-1.50 parts of Retinol Palmitate, triethanolamine borate
1.26-3.32 parts, 3.24-5.18 parts of cocoanut fatty acid diethanolamide.
Further, the grain size of the nano silver is 20-50nm.
The present invention also provides a kind of preparation methods according to above-mentioned leather care products, include the following steps：
1) methyl hydroxybenzoate, monoglyceride, white oil, stearic acid, lanolin, dimethicone, sulphur are weighed according to parts by weight
It is acidified castor oil, thyme essential oil, nano silver, Retinol Palmitate, triethanolamine borate, coco-nut oil fatty acid diethyl
Alkylolamides and deionized water；
2) methyl hydroxybenzoate, monoglyceride, white oil, stearic acid, lanolin, dimethicone, sulfated castor oil, dimension are given birth to
Plain A palmitates are mixed and are heated, and are warming up to 70-85 DEG C and are obtained liquid fat mixture；
3) liquid fat obtained in step 2) after triethanolamine borate deionized water solution heating stirring, will be added in mix
Object is closed, it is lasting to stir；
4) when the mixed liquor that step 3) obtains being down to 25-30 DEG C with whipping process natural cooling, temperature, add respectively successively
Enter cocoanut fatty acid diethanolamide, thyme essential oil and nano silver, persistently stir 40-60min, obtain leather care products.
Further, coco-nut oil fatty acid diethanol is separately added into the rate of addition of 3mL/min successively in the step 4
Amide, thyme essential oil and nano silver.
Further, liquid fat mixture obtained in step 2) is added in step 3, is persistently stirred 60-120 minutes,
It is not detached until standing lotion.
Further, triethanolamine borate deionized water solution is warming up to 70-85 DEG C in step 3, is 400- in rotating speed
The stirring condition of 450r/min adds in liquid fat mixture obtained in step 2).
The invention has the advantages that：
(1) as the data of embodiment 1-3 and comparative example 5 as it can be seen that the fungistatic effect of leather care products made from embodiment 1-3
It is significantly higher than the fungistatic effect and color fastness of leather care products made from comparative example 5 with color fastness；Simultaneously by the number of embodiment 1-3
According to as it can be seen that embodiment 1 is optimum embodiment.
(2) by embodiment 1 and the data of comparative example 1-4 as it can be seen that Retinol Palmitate, triethanolamine borate, coconut
Fatty acid oil diglycollic amide plays synergistic effect in leather care products are prepared, and collaboration improves the antibacterial of leather care products
Effect and color fastness；This is：
Retinol Palmitate is a kind of liposoluble vitamin, and the oil film with covering intradermal fiber surface has good
Intermiscibility, can Transdermal absorption, by coordinating with cocoanut fatty acid diethanolamide, can be enriched with, make in oil-water interfaces
With subcutaneous oil layer in the process, is infiltrated through with the evaporation of moisture, increase the thickness of epidermis and corium, so as to enhance color jail
Degree, while it can form mucous membrane in grease layer surface, so as to avoid the breeding of bacterium, enhance fungistatic effect；Triethanolamine boric acid
Ester is water white transparency body of paste, can be dispersed in water phase, has strong permeability, can strongly penetrate into the various gaps of leather surface
And formed on the surface and store one layer of lubricating film, corrosion caused by moisture and many other chemical analysis can be inhibited, so as to
Color fastness is improved, and prevents bacterium from invading and going mouldy, cocoanut fatty acid diethanolamide is as non-ionic surfactant
Agent, have emulsifying capacity, improve Retinol Palmitate, triethanolamine borate amphipathic property, make three formed micro emulsion
Drop, so as to improve permeability and rapid film forming capabilities, while Retinol Palmitate, triethanolamine borate are worked in coordination,
It forms a film in grease and simultaneously on skin, so as to form multiple film, compared with a kind of individually substance film forming, the multiple unshielded dead angle of film is simultaneously
And since its thickness and toughness are improved, the film of formation is more securely invaded with resistance to bacterium, so can be more lasting
It realizes protection, is protected in all directions so as to be formed, so as to improve the fungistatic effect of leather care products and color fastness.
(3) by the data of comparative example 6-8 as it can be seen that Retinol Palmitate, triethanolamine borate, coco-nut oil fatty acid
The weight ratio of diglycollic amide is not at (0.50-1.50)：(1.26-3.32)：When in the range of (3.24-5.18), leather obtained
The fungistatic effect and color fastness and the numerical value of embodiment 1-3 of care agent are very different, much smaller than the numerical value of embodiment 1-3.This hair
Bright Retinol Palmitate, triethanolamine borate, cocoanut fatty acid diethanolamide are as reinforcement system, embodiment 1-3
When preparing leather care products by adding Retinol Palmitate, triethanolamine borate, coco-nut oil fatty acid diethanol acyl
The weight ratio of amine is (0.50-1.50)：(1.26-3.32)：(3.24-5.18) is realized and coconut grease is utilized in reinforcement system
Fat acid diglycollic amide is dispersed in oil phase, and triethanolamine borate is dispersed in water phase, and utilizes coco-nut oil fatty acid diethyl
Alkylolamides as amphoteric surfactant formed micro emulsion drop, so as to fulfill quickly grease surface layer form a film, and on skin gap into
Film forms in all directions quickly protection so that Retinol Palmitate, triethanolamine borate, coco-nut oil fatty acid diethanol
The reinforcement system that amide is formed improves the fungistatic effect and color fastness of leather care products in the leather care products of the present invention.
Specific embodiment
It for ease of more fully understanding the present invention, is illustrated by following instance, these examples belong to the protection of the present invention
Range, but do not limit the scope of the invention.
In embodiment, leather care products are as unit of parts by weight, including following raw material：Methyl hydroxybenzoate 1.25-4.90
Part, 0.90-2.08 parts of monoglyceride, 5.30-6.83 parts of white oil, 3.90-4.90 parts of stearic acid, 3.60-6.42 parts of lanolin, diformazan
4.90-5.95 parts of base silicone oil, 5.66-8.88 parts of sulfated castor oil, 4.00-8.00 parts of thyme essential oil, nano silver 1.00-
5.00 parts, 50.27-67.97 parts of deionized water, 0.50-1.50 parts of Retinol Palmitate, triethanolamine borate 1.26-
3.32 parts, 3.24-5.18 parts of cocoanut fatty acid diethanolamide.
The preparation method of the leather care products, includes the following steps：
1) methyl hydroxybenzoate, monoglyceride, white oil, stearic acid, lanolin, dimethicone, sulphur are weighed according to parts by weight
It is acidified castor oil, thyme essential oil, nano silver, Retinol Palmitate, triethanolamine borate, coco-nut oil fatty acid diethyl
Alkylolamides and deionized water；
2) methyl hydroxybenzoate, monoglyceride, white oil, stearic acid, lanolin, dimethicone, sulfated castor oil, dimension are given birth to
Plain A palmitates are mixed and are heated, and are warming up to 70-85 DEG C and are obtained liquid fat mixture；
3) triethanolamine borate deionized water solution is heated to 70-85 DEG C, is 400-450r/min in rotating speed
Stirring condition under, add in liquid fat mixture obtained in step 2), it is lasting to stir；
4) when the mixed liquor that step 3) obtains being down to 25-30 DEG C with whipping process natural cooling, temperature, add respectively successively
Enter cocoanut fatty acid diethanolamide, thyme essential oil and nano silver, persistently stir 40-60min, obtain leather care products.
Embodiment 1
A kind of leather care products are as unit of parts by weight, including following raw material：2.45 parts of methyl hydroxybenzoate, monoglyceride 1.49
Part, 6.06 parts of white oil, 4.08 parts of stearic acid, 4.15 parts of lanolin, 5.42 parts of dimethicone, 7.27 parts of sulfated castor oil,
6.00 parts of thyme essential oil, 3.00 parts of nano silver, 59.12 parts of deionized water, 1.00 parts of Retinol Palmitate, triethanolamine
2.29 parts of borate, 4.21 parts of cocoanut fatty acid diethanolamide.
The preparation method of the leather care products, includes the following steps：
1) methyl hydroxybenzoate, monoglyceride, white oil, stearic acid, lanolin, dimethicone, sulphur are weighed according to parts by weight
It is acidified castor oil, thyme essential oil, nano silver, Retinol Palmitate, triethanolamine borate, coco-nut oil fatty acid diethyl
Alkylolamides and deionized water；
2) methyl hydroxybenzoate, monoglyceride, white oil, stearic acid, lanolin, dimethicone, sulfated castor oil, dimension are given birth to
Plain A palmitates are mixed and are heated, and are warming up to 70-85 DEG C and are obtained liquid fat mixture；
3) triethanolamine borate deionized water solution is heated to 70-85 DEG C, is 400-450r/min in rotating speed
Stirring condition under, add in liquid fat mixture obtained in step 2), it is lasting to stir；
4) when the mixed liquor that step 3) obtains being down to 25-30 DEG C with whipping process natural cooling, temperature, add respectively successively
Enter cocoanut fatty acid diethanolamide, thyme essential oil and nano silver, persistently stir 40-60min, obtain leather care products.
Embodiment 2
A kind of leather care products are as unit of parts by weight, including following raw material：4.90 parts of methyl hydroxybenzoate, monoglyceride 0.90
Part, 6.83 parts of white oil, 3.90 parts of stearic acid, 6.42 parts of lanolin, 4.90 parts of dimethicone, 8.88 parts of sulfated castor oil,
4.00 parts of thyme essential oil, 5.00 parts of nano silver, 50.27 parts of deionized water, 1.50 parts of Retinol Palmitate, triethanolamine
1.26 parts of borate, 5.18 parts of cocoanut fatty acid diethanolamide.
The preparation method of the leather care products, includes the following steps：
1) methyl hydroxybenzoate, monoglyceride, white oil, stearic acid, lanolin, dimethicone, sulphur are weighed according to parts by weight
It is acidified castor oil, thyme essential oil, nano silver, Retinol Palmitate, triethanolamine borate, coco-nut oil fatty acid diethyl
Alkylolamides and deionized water；
2) methyl hydroxybenzoate, monoglyceride, white oil, stearic acid, lanolin, dimethicone, sulfated castor oil, dimension are given birth to
Plain A palmitates are mixed and are heated, and are warming up to 70-85 DEG C and are obtained liquid fat mixture；
3) triethanolamine borate deionized water solution is heated to 70-85 DEG C, is 400-450r/min in rotating speed
Stirring condition under, add in liquid fat mixture obtained in step 2), it is lasting to stir；
4) when the mixed liquor that step 3) obtains being down to 25-30 DEG C with whipping process natural cooling, temperature, add respectively successively
Enter cocoanut fatty acid diethanolamide, thyme essential oil and nano silver, persistently stir 40-60min, obtain leather care products.
Embodiment 3
A kind of leather care products are as unit of parts by weight, including following raw material：1.25 parts of methyl hydroxybenzoate, monoglyceride 2.08
Part, 5.30 parts of white oil, 4.90 parts of stearic acid, 3.60 parts of lanolin, 5.95 parts of dimethicone, 5.66 parts of sulfated castor oil,
8.00 parts of thyme essential oil, 1.00 parts of nano silver, 67.97 parts of deionized water, 0.50 part of Retinol Palmitate, triethanolamine
3.32 parts of borate, 3.24 parts of cocoanut fatty acid diethanolamide.
A kind of preparation method of leather care products, which is characterized in that include the following steps：
1) methyl hydroxybenzoate, monoglyceride, white oil, stearic acid, lanolin, dimethicone, sulphur are weighed according to parts by weight
It is acidified castor oil, thyme essential oil, nano silver, Retinol Palmitate, triethanolamine borate, coco-nut oil fatty acid diethyl
Alkylolamides and deionized water；
2) methyl hydroxybenzoate, monoglyceride, white oil, stearic acid, lanolin, dimethicone, sulfated castor oil, dimension are given birth to
Plain A palmitates are mixed and are heated, and are warming up to 70-85 DEG C and are obtained liquid fat mixture；
3) triethanolamine borate deionized water solution is heated to 70-85 DEG C, is 400-450r/min in rotating speed
Stirring condition under, add in liquid fat mixture obtained in step 2), it is lasting to stir；
4) when the mixed liquor that step 3) obtains being down to 25-30 DEG C with whipping process natural cooling, temperature, add respectively successively
Enter cocoanut fatty acid diethanolamide, thyme essential oil and nano silver, persistently stir 40-60min, obtain leather care products.
Comparative example 1
It is essentially identical with the preparation process of embodiment 1, have only unlike prepare in the raw materials of leather care products and lack dimension
Raw element A palmitates, triethanolamine borate, cocoanut fatty acid diethanolamide.
Comparative example 2
It is essentially identical with the preparation process of embodiment 1, have only unlike prepare in the raw materials of leather care products and lack dimension
Raw element A palmitates.
Comparative example 3
It is essentially identical with the preparation process of embodiment 1, have only unlike prepare in the raw materials of leather care products and lack three
Ethanol amine borate.
Comparative example 4
It is essentially identical with the preparation process of embodiment 1, have only unlike prepare in the raw materials of leather care products and lack coconut palm
Seed oil fatty diglycollic amide.
Comparative example 5
Using a kind of Chinese patent literature " fragrance leather care products and its preparation method and application (Authorization Notice No.：
CN105734187B the method in) " described in specific embodiment 1-5 prepares leather care products.
Comparative example 6
It is essentially identical with the preparation process of embodiment 1, have only unlike prepare vitamin A in the raw materials of leather care products
Palmitate is 0.10 part, triethanolamine borate is 5.32 parts, cocoanut fatty acid diethanolamide is 2.24 parts.
Comparative example 7
It is essentially identical with the preparation process of embodiment 1, have only unlike prepare vitamin A in the raw materials of leather care products
Palmitate is 2.5 parts, triethanolamine borate is 0.63 part, cocoanut fatty acid diethanolamide is 6.18 parts.
Comparative example 8
It is essentially identical with the preparation process of embodiment 1, have only unlike prepare vitamin A in the raw materials of leather care products
Palmitate is 2.0 parts, triethanolamine borate is 5.32 parts, cocoanut fatty acid diethanolamide is 2.24 parts.
Antibacterial circle diameter under aspergillus flavus environment is carried out to product made from embodiment 1-3 and comparative example 1-8 to test, and use
Leather fade tester is measured the color fastness of leather, and the results are shown in table below.
| Experimental project | Antibacterial circle diameter mm | Color fastness |
| Embodiment 1 | 20 | 6 |
| Embodiment 2 | 19 | 6 |
| Embodiment 3 | 19 | 6 |
| Comparative example 1 | 6 | 2 |
| Comparative example 2 | 18 | 5 |
| Comparative example 3 | 15 | 5 |
| Comparative example 4 | 17 | 5 |
| Comparative example 5 | 2-5 | 2-3 |
| Comparative example 6 | 12 | 4 |
| Comparative example 7 | 10 | 3 |
| Comparative example 8 | 11 | 4 |
As seen from the above table：(1) as the data of embodiment 1-3 and comparative example 5 as it can be seen that leather nursing made from embodiment 1-3
The fungistatic effect and color fastness of agent are significantly higher than the fungistatic effect and color fastness of leather care products made from comparative example 5；While by
The data of embodiment 1-3 are as it can be seen that embodiment 1 is optimum embodiment.
(2) by embodiment 1 and the data of comparative example 1-4 as it can be seen that Retinol Palmitate, triethanolamine borate, coconut
Fatty acid oil diglycollic amide plays synergistic effect in leather care products are prepared, and collaboration improves the antibacterial of leather care products
Effect and color fastness；This is：
Retinol Palmitate is a kind of liposoluble vitamin, and the oil film with covering intradermal fiber surface has good
Intermiscibility, can Transdermal absorption, by coordinating with cocoanut fatty acid diethanolamide, can be enriched with, make in oil-water interfaces
With subcutaneous oil layer in the process, is infiltrated through with the evaporation of moisture, increase the thickness of epidermis and corium, so as to enhance color jail
Degree, while it can form mucous membrane in grease layer surface, so as to avoid the breeding of bacterium, enhance fungistatic effect；Triethanolamine boric acid
Ester is water white transparency body of paste, can be dispersed in water phase, has strong permeability, can strongly penetrate into the various gaps of leather surface
And formed on the surface and store one layer of lubricating film, corrosion caused by moisture and many other chemical analysis can be inhibited, so as to
Color fastness is improved, and prevents bacterium from invading and going mouldy, cocoanut fatty acid diethanolamide is as non-ionic surfactant
Agent, have emulsifying capacity, improve Retinol Palmitate, triethanolamine borate amphipathic property, make three formed micro emulsion
Drop, so as to improve permeability and rapid film forming capabilities, while Retinol Palmitate, triethanolamine borate are worked in coordination,
It forms a film in grease and simultaneously on skin, so as to form multiple film, compared with a kind of individually substance film forming, the multiple unshielded dead angle of film is simultaneously
And since its thickness and toughness are improved, the film of formation is more securely invaded with resistance to bacterium, so can be more lasting
It realizes protection, is protected in all directions so as to be formed, so as to improve the fungistatic effect of leather care products and color fastness.
(3) by the data of comparative example 6-8 as it can be seen that Retinol Palmitate, triethanolamine borate, coco-nut oil fatty acid
The weight ratio of diglycollic amide is not at (0.50-1.50)：(1.26-3.32)：When in the range of (3.24-5.18), leather obtained
The fungistatic effect and color fastness and the numerical value of embodiment 1-3 of care agent are very different, much smaller than the numerical value of embodiment 1-3.This hair
Bright Retinol Palmitate, triethanolamine borate, cocoanut fatty acid diethanolamide are as reinforcement system, embodiment 1-3
When preparing leather care products by adding Retinol Palmitate, triethanolamine borate, coco-nut oil fatty acid diethanol acyl
The weight ratio of amine is (0.50-1.50)：(1.26-3.32)：(3.24-5.18) is realized and coconut grease is utilized in reinforcement system
Fat acid diglycollic amide is dispersed in oil phase, and triethanolamine borate is dispersed in water phase, and utilizes coco-nut oil fatty acid diethyl
Alkylolamides as amphoteric surfactant formed micro emulsion drop, so as to fulfill quickly grease surface layer form a film, and on skin gap into
Film forms in all directions quickly protection so that Retinol Palmitate, triethanolamine borate, coco-nut oil fatty acid diethanol
The reinforcement system that amide is formed improves the fungistatic effect and color fastness of leather care products in the leather care products of the present invention.
More than content is it cannot be assumed that present invention specific implementation is confined to these explanations, for the technical field of the invention
Those of ordinary skill for, under the premise of present inventive concept is not departed from, several simple deduction or replace can also be made, all should
When being considered as belonging to present invention scope of patent protection determined by the appended claims.
Claims (8)
1. a kind of leather care products, which is characterized in that including following raw material：Methyl hydroxybenzoate, monoglyceride, white oil, stearic acid, sheep
Hair fat, dimethicone, sulfated castor oil, thyme essential oil, nano silver, deionized water, Retinol Palmitate, three second
Hydramine borate, cocoanut fatty acid diethanolamide；The Retinol Palmitate, triethanolamine borate, coconut oil
The weight ratio of fatty diglycollic amide is (0.50-1.50)：(1.26-3.32)：(3.24-5.18).
2. leather care products according to claim 1, which is characterized in that the Retinol Palmitate, triethanolamine boron
Acid esters, cocoanut fatty acid diethanolamide weight ratio be 1.00:2.29:4.21.
3. leather care products according to claim 1, which is characterized in that the leather care products as unit of parts by weight,
Including following raw material：1.25-4.90 parts of methyl hydroxybenzoate, 0.90-2.08 parts of monoglyceride, 5.30-6.83 parts of white oil, stearic acid
3.90-4.90 parts, 3.60-6.42 parts of lanolin, 4.90-5.95 parts of dimethicone, 5.66-8.88 parts of sulfated castor oil,
4.00-8.00 parts of thyme essential oil, 1.00-5.00 parts of nano silver, 50.27-67.97 parts of deionized water, Retinol Palmitate
0.50-1.50 parts, 1.26-3.32 parts of triethanolamine borate, 3.24-5.18 parts of cocoanut fatty acid diethanolamide.
4. leather care products according to claim 1, which is characterized in that the grain size of the nano silver is 20-50nm.
5. a kind of preparation method according to claim 1-4 any one of them leather care products, which is characterized in that including following
Step：
1) methyl hydroxybenzoate, monoglyceride, white oil, stearic acid, lanolin, dimethicone, sulphation are weighed according to parts by weight
Castor oil, thyme essential oil, nano silver, Retinol Palmitate, triethanolamine borate, coco-nut oil fatty acid diethanol acyl
Amine and deionized water；
2) by methyl hydroxybenzoate, monoglyceride, white oil, stearic acid, lanolin, dimethicone, sulfated castor oil, vitamin A
Palmitate is mixed and is heated, and is warming up to 70-85 DEG C and is obtained liquid fat mixture；
3) will be after triethanolamine borate deionized water solution heating stirring, liquid fat obtained mixes in addition step 2)
Object, it is lasting to stir；
4) when the mixed liquor that step 3) obtains being down to 25-30 DEG C with whipping process natural cooling, temperature, it is separately added into coconut palm successively
Seed oil fatty diglycollic amide, thyme essential oil and nano silver, persistently stir 40-60min, obtain leather care products.
6. the preparation method of leather care products according to claim 5, which is characterized in that with 3mL/min in the step 4
Rate of addition be separately added into cocoanut fatty acid diethanolamide, thyme essential oil and nano silver successively.
7. the preparation method of leather care products according to claim 5, which is characterized in that added in step 2) in step 3
Liquid fat mixture obtained persistently stirs 60-120 minutes, is not detached until standing lotion.
8. the preparation method of leather care products according to claim 5, which is characterized in that by triethanolamine boron in step 3
Acid esters deionized water solution is warming up to 70-85 DEG C, adds in step 2) and is made in the stirring condition that rotating speed is 400-450r/min
Liquid fat mixture.
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|---|---|---|---|
| CN201810242462.2A CN108265136B (en) | 2018-03-23 | 2018-03-23 | Leather care agent and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110129144A (en) * | 2019-05-31 | 2019-08-16 | 深圳市润贝化工有限公司 | A kind of aircraft passenger compartment leather cleaning glazing agent |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1633983A (en) * | 2004-11-02 | 2005-07-06 | 黄扶民 | Camellia chrysantha containing skin-care, washing product |
| CN103599021A (en) * | 2013-11-15 | 2014-02-26 | 上海应用技术学院 | Roselle extract as well as preparation method thereof and application thereof in whitening skincare cosmetics |
| CN105734187A (en) * | 2016-02-29 | 2016-07-06 | 上海应用技术学院 | Fragrant leather care agent and preparation method and application thereof |
-
2018
- 2018-03-23 CN CN201810242462.2A patent/CN108265136B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1633983A (en) * | 2004-11-02 | 2005-07-06 | 黄扶民 | Camellia chrysantha containing skin-care, washing product |
| CN103599021A (en) * | 2013-11-15 | 2014-02-26 | 上海应用技术学院 | Roselle extract as well as preparation method thereof and application thereof in whitening skincare cosmetics |
| CN105734187A (en) * | 2016-02-29 | 2016-07-06 | 上海应用技术学院 | Fragrant leather care agent and preparation method and application thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110129144A (en) * | 2019-05-31 | 2019-08-16 | 深圳市润贝化工有限公司 | A kind of aircraft passenger compartment leather cleaning glazing agent |
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Effective date of registration: 20210715 Address after: 410205 Room 307, Building A, Lugu Business Center, 199 Lulong Road, Changsha High-tech Development Zone, Changsha City, Hunan Province Patentee after: Tang Aiguo Address before: Room 307, building a, Lugu business center, No. 199, Lulong Road, high tech Development Zone, Changsha City, Hunan Province, 410205 Patentee before: CHANGSHA XIAOXIN NEW ENERGY TECHNOLOGY Co.,Ltd. |