CN108250864A - A kind of preparation method of the water lustering oil of high abrasion - Google Patents
A kind of preparation method of the water lustering oil of high abrasion Download PDFInfo
- Publication number
- CN108250864A CN108250864A CN201711413246.1A CN201711413246A CN108250864A CN 108250864 A CN108250864 A CN 108250864A CN 201711413246 A CN201711413246 A CN 201711413246A CN 108250864 A CN108250864 A CN 108250864A
- Authority
- CN
- China
- Prior art keywords
- high abrasion
- wax
- weight
- water
- lustering oil
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of preparation methods of the water lustering oil of high abrasion.The water lustering oil is made of soft film-forming acrylic lotion, hard non-film acrylic emulsion, levelling agent, antifoaming agent and wax liquor, wherein, wax liquor is made of water-soluble acrylic dispersion resin, nonionic surfactant, wax powder and water.It goes to substitute wax powder with wax liquor, to produce wear-resistant gloss oil, in the case where ensureing gloss oil high abrasion, can effectively extend the storage stability of gloss oil.
Description
Technical field
The present invention relates to ink area, specifically a kind of preparation method of the water lustering oil of high abrasion.
Background technology
Water lustering oil is essential one of technique in ink printing process.In the surface of printed matter roller coating one again
Layer gloss oil, on the one hand, the protection layer of ink that can play the role of provides waterproof or the performances such as wear-resistant；On the other hand, Ke Yifeng
The other performance of rich printed matter, such as：Bloom, dumb light, heatproof etc..
In many performances of water lustering oil, layer of ink is protected, it is a kind of particularly important and universal performance to improve wear resistence.
The wear resistence of gloss oil is improved, is mainly realized by the collocation of resin and wax.Wherein, the selection of wax is crucial！
For the abrasion-resistance water oil polish of high request, Normal practice is all realized by wax powder.It is produced with wax powder resistance to
Buffing oil, after placing a period of time, layering will be precipitated in wax powder, influence construction and performance.
Therefore, the gloss oil of high abrasion, it is ensured that in the case that properties of product are up to standard, how to improve the storage stability of product
It is a great problem.This patent mainly makes wax liquor by oneself with wax powder, is then used for producing high wear-resistant water lustering oil.By wax powder
Wax liquor is made to can be very good to extend the time that layering is precipitated in wax powder, ensures the storage stability of gloss oil.
Invention content
The object of the present invention is to provide a kind of preparation methods of the water lustering oil of high abrasion.
The present invention to achieve the above object, takes following technical scheme to be achieved：
A kind of water lustering oil of high abrasion, formula composition are as follows：
Preferably, it is -20 DEG C~7 DEG C, acid value 50-70mgKOH/g that the soft film-forming acrylic lotion, which is Tg, and solid content is
38%~50% lotion.
Preferably, it is 80 DEG C~105 DEG C that the hard film-forming acrylic lotion, which is Tg, acid value 50-70mgKOH/g, Gu
Content is 38%~50% lotion.
Preferably, the levelling agent is：The levelling agent is polysiloxanes analog copolymer, alkyl succinic acid salt substance
With the one of which of polyether substance.
Preferably, the antifoaming agent is：One of which of the antifoaming agent for mineral oil and organosilicon material.
Another object of the present invention is to disclose a kind of formula of the wax liquor for the water lustering oil for being used to produce high abrasion
And technique.
Wax liquor formula is as follows：
| Wax powder | 10~30 parts by weight |
| Dispersion resin | 20~40 parts by weight |
| Auxiliary agent | 0.5~2 parts by weight |
| Water | 30~70 parts by weight |
Preferably, the wax powder described in wax liquor is PP wax powders and the one of which of PE wax powders.
Preferably, dispersion resin described in wax liquor is aqueous solution type polyacrylic resin, and acid value is 140~240mgKOH/
G, weight average molecular weight are 6000~12000, and solid content is 30%~40%.
Preferably, the nonionic surfactant described in wax liquor is nonylphenol polyoxyethylene ether class, octyl phenol polyoxy second
One of which in alkene ethers, isomery carbon tridecanol polyoxyethylene ether, alkyl alcohol block polyether, PO/EO block copolymers.
Wax liquor production technology is as follows：
Disposably the water of metering, dispersion resin and auxiliary agent are added in high speed dispersor, open dispersion machine, then adds in metering
Wax powder be stirred dispersion 2~2.5 hours, you can prepare wax liquor.
The invention also discloses a kind of production technology of the water lustering oil of high abrasion is as follows：
Under homogenizer, the soft film-forming acrylic lotion of metering, hard non-film acrylic emulsion, wear-resistant is backed into successively
Slurry is stirred 5~10 minutes, then sequentially adds the levelling agent and antifoaming agent of metering, is stirred 1.5~2 hours, you can is made
The water lustering oil of high abrasion.
Compared with prior art, beneficial effects of the present invention are as follows：The present invention is produced by the way that wax powder is prepared into wax liquor
Aqueous wear-resistant gloss oil, under the premise of the high-wearing feature for ensureing gloss oil, the drawbacks of being layered is precipitated in the wax powder effectively solved, improves
The storage stability of wear-resistant gloss oil.
Specific embodiment
Below in conjunction with specific embodiment, the present invention is further illustrated：
In the embodiment of the present invention, dispersion resin is BASF Joncryl HPD 96；Soft film-forming acrylic lotion is BASF
Joncryl1661；Hard non-film acrylic emulsion is BASF Joncryl 89.
Embodiment 1
The preparation of wax liquor：Disposably by the water of 40 parts by weight, 30 parts by weight dispersion resins and 1 parts by weight isomery carbon tridecanol polyoxy
Vinethene is added in high speed dispersor, opens dispersion machine, and the PP wax powders for then adding in 30 parts by weight are stirred dispersion 2.5
Hour, you can prepare required wax liquor.
The preparation of high abrasion water lustering oil：Homogenizer is opened, then backs into the soft film forming of 60 parts by weight successively
Acrylic emulsion, the hard non-film acrylic emulsion of 20 parts by weight, the above-mentioned wax liquor of 20 parts by weight are stirred 5~10 minutes,
Then 1 parts by weight polysiloxanes analog copolymer levelling agent and 0.5 parts by weight organic silicon antifoaming agent are sequentially added, is stirred 2 hours,
It can be prepared by the water lustering oil of high abrasion.
Embodiment 2
The preparation of wax liquor：Disposably by the water of 45 parts by weight, 30 parts by weight dispersion resins and 1 parts by weight isomery carbon tridecanol polyoxy
Vinethene is added in high speed dispersor, opens dispersion machine, and then adding in the PE wax powders of 25 parts by weight, to be stirred dispersion 2.5 small
When, you can prepare required wax liquor.
The preparation of high abrasion water lustering oil：Homogenizer is opened, then backs into the soft film forming of 55 parts by weight successively
Acrylic emulsion, the hard non-film acrylic emulsion of 25 parts by weight, the above-mentioned wax liquor of 20 parts by weight are stirred 5~10 minutes,
Then 1 parts by weight polysiloxanes analog copolymer levelling agent and 0.5 parts by weight organic silicon antifoaming agent are sequentially added, is stirred 2 hours,
It can be prepared by the water lustering oil of high abrasion.
The water lustering oil testing result of high abrasion is as follows made from embodiment 1 and embodiment 2：
Wear-resistant test method：The water lustering oil of high abrasion made from embodiment 1 and embodiment 2 is diluted with water to 40 ± 2 seconds
(applying 4 viscosimeters, 25 DEG C of room temperature) then carries out wear-resistant under wear-resistant instrument (the international Instrument Ltd. of sea-freight, model HD-507)
600 tests.
Experiment is understood：The water lustering oil of high abrasion is made in embodiment 1 and embodiment 2, have good abrasion resistance and
Storage stability.
The technical solution provided above the embodiment of the present invention is described in detail, specific case used herein
The principle and embodiment of the embodiment of the present invention are expounded, the explanation of above example is only applicable to help to understand this
The principle of inventive embodiments；Meanwhile for those of ordinary skill in the art, embodiment according to the present invention, in specific embodiment party
There will be changes in formula and application range, in conclusion the content of the present specification should not be construed as limiting the invention.
Claims (11)
1. a kind of water lustering oil of high abrasion, it is characterised in that：By the soft film-forming acrylic lotion of 40 ~ 60 parts by weight, 20 ~
The hard non-film acrylic emulsion of 40 parts by weight, the levelling agent of 0.5 ~ 2 parts by weight, the antifoaming agent of 0.1 ~ 0.8 parts by weight and 5 ~
The wax liquor composition of 20 parts by weight.
2. a kind of water lustering oil of high abrasion according to claim 1, it is characterised in that：The soft film-forming acrylic
Lotion Tg is -20 DEG C ~ 7 DEG C, acid value 50-70mgKOH/g, and solid content is 38% ~ 50%.
3. a kind of water lustering oil of high abrasion according to claim 1, it is characterised in that：The hard film-forming acrylic
Lotion Tg is 80 DEG C ~ 105 DEG C, acid value 50-70mgKOH/g, and solid content is 38% ~ 50%.
4. a kind of water lustering oil of high abrasion according to claim 1, it is characterised in that：The levelling agent is poly- silica
The one of which of alkanes copolymer, alkyl succinic acid salt substance and polyether substance.
5. a kind of water lustering oil of high abrasion according to claim 1, it is characterised in that：The antifoaming agent is mineral oil
With the one of which of organosilicon material.
6. a kind of water lustering oil of high abrasion according to claim 1, it is characterised in that：The wax liquor is by 10 ~ 30 weights
Measure the wax powder of part, the dispersion resin of 20 ~ 40 parts by weight, the nonionic surfactant of 0.5 ~ 2 parts by weight and 30 ~ 70 parts by weight
Water forms.
7. a kind of water lustering oil of high abrasion according to claim 6, it is characterised in that：Wax powder described in wax liquor is
The one of which of PP wax powders and PE wax powders.
8. a kind of water lustering oil of high abrasion according to claim 6, it is characterised in that：Dispersion resin described in wax liquor
For aqueous solution type polyacrylic resin, acid value is 140 ~ 240mgKOH/g, and weight average molecular weight is 6000 ~ 12000, and solid content is
30%~40%。
9. a kind of water lustering oil of high abrasion according to claim 6, it is characterised in that：Nonionic described in wax liquor
Surfactant is nonylphenol polyoxyethylene ether class, octyl phenol polyoxyethylene ether class, isomery carbon tridecanol polyoxyethylene ether, alkyl
One of which in alcohol block polyether, PO/EO block copolymers.
10. a kind of water lustering oil of high abrasion according to claim 6, it is characterised in that：The production technology of wax liquor is：
Disposably the water of metering, dispersion resin and auxiliary agent are added in high speed dispersor, open dispersion machine, then adds in the wax of metering
Powder is stirred dispersion 2 ~ 2.5 hours, you can prepares wax liquor.
11. a kind of water lustering oil of high abrasion according to claim 1, it is characterised in that：Its production technology is：It opens
Homogenizer, soft film-forming acrylic lotion, hard non-film acrylic emulsion, the wax liquor for then sequentially adding metering carry out
Then stirring 5 ~ 10 minutes sequentially adds the levelling agent and antifoaming agent of metering, stir 1.5 ~ 2 hours, you can high abrasion is made
Water lustering oil.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711413246.1A CN108250864B (en) | 2017-12-24 | 2017-12-24 | Preparation method of high-wear-resistance water-based varnish |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711413246.1A CN108250864B (en) | 2017-12-24 | 2017-12-24 | Preparation method of high-wear-resistance water-based varnish |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN108250864A true CN108250864A (en) | 2018-07-06 |
| CN108250864B CN108250864B (en) | 2020-05-05 |
Family
ID=62723523
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711413246.1A Active CN108250864B (en) | 2017-12-24 | 2017-12-24 | Preparation method of high-wear-resistance water-based varnish |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108250864B (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109233517A (en) * | 2018-08-21 | 2019-01-18 | 广东天龙油墨有限公司 | A kind of preparation method of the pre- print-polishing oil of water-based temperature resistant anti-skid wearable |
| CN113897094A (en) * | 2021-10-29 | 2022-01-07 | 广东英科集团股份有限公司 | Water-based gravure preprinting gloss oil and preparation method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101974269A (en) * | 2010-10-28 | 2011-02-16 | 苏州凯康化工科技有限公司 | High gloss and high abrasion resistant water-based overprinting varnish and preparation method thereof |
-
2017
- 2017-12-24 CN CN201711413246.1A patent/CN108250864B/en active Active
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101974269A (en) * | 2010-10-28 | 2011-02-16 | 苏州凯康化工科技有限公司 | High gloss and high abrasion resistant water-based overprinting varnish and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 朱万强: "《涂料基础教程》", 30 June 2012, 西南交通大学出版社 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109233517A (en) * | 2018-08-21 | 2019-01-18 | 广东天龙油墨有限公司 | A kind of preparation method of the pre- print-polishing oil of water-based temperature resistant anti-skid wearable |
| CN113897094A (en) * | 2021-10-29 | 2022-01-07 | 广东英科集团股份有限公司 | Water-based gravure preprinting gloss oil and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN108250864B (en) | 2020-05-05 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101845255A (en) | Water-based baking paint for glass substrate and preparation and use methods thereof | |
| CN102675989B (en) | Coating liquid used for surface of environment-friendly rich mineral paper | |
| CN105524537A (en) | Environment-friendly high wear-resistant water-based polishing oil and preparation method thereof | |
| CN103613717A (en) | Self-emulsifying acrylic acid organic silicon wax protection material as well as preparation method and application thereof | |
| CN109021688B (en) | Environment-friendly water-based printing ink and preparation method thereof | |
| CN106147451A (en) | Fire resistant water-based aluminizing transfer paint compositions and preparation method thereof | |
| CN108250864A (en) | A kind of preparation method of the water lustering oil of high abrasion | |
| CN104530930A (en) | Orange-peel coating | |
| CN109233517A (en) | A kind of preparation method of the pre- print-polishing oil of water-based temperature resistant anti-skid wearable | |
| CN110256883A (en) | A kind of aqueous UV woodware high-gloss clear finish and preparation method and implementing process | |
| CN104263146A (en) | Water-soluble electroplating glazing oil and manufacturing method thereof | |
| CN107236405A (en) | A kind of aqueous PU varnish | |
| CN111777905A (en) | Environment-friendly water-based coating and preparation method thereof | |
| CN110157263A (en) | A kind of environment-friendly type high abrasion high glaze water-based gloss oil and its preparation process | |
| CN105038533A (en) | Aqueous baking varnish coating specially used for antitheft doors, and preparation method thereof | |
| CN102702411A (en) | Core-shell matte emulsion as well as preparation method and application of core-shell matte emulsion in water matte gloss oil | |
| CN103526639B (en) | Lubricant and apply the coating of this lubricant | |
| CN105331188B (en) | Art printing ink for crystallized metal printing | |
| CN105936796A (en) | Anti-wear finishing paint | |
| CN103965766B (en) | A kind of sense of touch water oil and preparation method thereof | |
| CN103275539A (en) | Weather-proof pigment composition for painting stone surface | |
| CN107043444B (en) | A kind of water-based gloss oil base bond material and preparation method thereof | |
| CN106245430B (en) | A kind of paper grade (stock) water-based lubricant and preparation method thereof | |
| CN107573750A (en) | A kind of waterproof inner wall putty powder and preparation method thereof | |
| CN106519836A (en) | Water-based coating for cigarette lined paper and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |