CN101974269A - High gloss and high abrasion resistant water-based overprinting varnish and preparation method thereof - Google Patents
High gloss and high abrasion resistant water-based overprinting varnish and preparation method thereof Download PDFInfo
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Abstract
The invention discloses a high gloss and high abrasion resistant water-based overprinting varnish and a preparation method thereof. The overprinting varnish comprises the following components: deionized water, water-soluble solid acrylic resin, non film-forming material, film material, ammonia water, water-soluble emulsion wax, wetting and leveling agent, defoaming agent and thickener. The overprinting varnish of the invention uses water as solvent; when the overprinting varnish is used, only water is volatilized, thus the overprinting varnish is environmentally friendly; and the overprinting varnish does not contain heavy metals and can pass through the volatile organic compound (VOC) detection, thus being a safe and green product. The product of the invention uses water-soluble acrylic emulsion as the main matrix which combines with water-soluble solid acrylic resin, thus the safety and environmental friend of the product can be further ensured; and by adopting the special raw material combination, the product has good printing and glazing effects, high transparency and lustrousness and excellent wear resistance and is color-fast and scratch resistant; and after printed and glazed, the product has good water resistance and is not easy to scratch.
Description
Technical field
The present invention relates to the printed apcksging material field.Relate to be used for behind the paper printing glazing specifically, improve paper printing
A kind of high smooth high abrasion water-based coating oil of effect.
Background technology
Printing packaging industry now, people more and more pay attention to the perfection of packing, the most last layer of crossing of the paper after the printing
Coating oil is used for improving the glossiness of paper, prevents to fade to wipe flower.Be used in the market Lacquer finish have the water-based coating oil,
UV coating oil, pure dissolubility coating oil and oiliness coating oil also have plenty of the compound BOPP film of employing.It is as follows at this these Lacquer finish products to be carried out market analysis:
UV coating oil: mainly form, use with a small amount of alcohol dilution during last machine, by the ultra violet lamp fast setting by epoxy acrylate, reactive thinner, light trigger, defoamer, flow agent etc.The high light high abrasion of this series products, but product price height, in addition the UV coating oil easily infiltrates the middle level of paper fibre, causes the ultraviolet light polymerization weak effect even can not solidify, and have certain toxicity, so can not be used for the Lacquer finish of packages printings such as food and medicine industry.
Alcohol dissolubility coating oil: mainly be with alcohol as solvent synthetic acrylic resin, products characteristics be cost low,
Glossiness height, but this series products has the volatilization of a large amount of alcohol when last machine, there are very big problem in environment, production safety etc., the wear-resisting wiping of paper of printing in addition behind the Lacquer finish is poor.
The oiliness coating oil: this series products is owing to have a large amount of benzene kind solvent volatilizations, not environmental protection and serious shadow in use
Ring personnel safety, manufacturer production is seldom arranged on the market now, almost eliminated by market.
The multiple film of BOPP: the BOPP film is to be compounded on the paper printing ink by glue, has the characteristic of high abrasion Gao Guang,
But not very difficult the recovery and biological degradation of paper after environmentally friendly machine is used.
More than these Lacquer finish products all have environmental protection and safety problem; and along with the development of society; human protection consciousness to living environment also improves constantly; environmental protection has been not only economic problems; but be related to the big problem of whole human survival; print product is infiltration human lives one of product the most widely, is paid close attention to by society and people in the nature of things.In the printing packaging industry, increased the requirement and the restriction condition of aspects such as many health, environmental protection, labour protection in recent years gradually, particularly more strict to the requirement of food product pack printing, thus meet the requirement of international hygiene standard.Under this megatrend, effort development and application pollution-free, non-harmful " green " material is imperative.The water-based coating oil is a luminescent material on developed country's novel printing of falling over each other to research and develop in recent years, be subjected to printing the attention on boundary day by day, it is as a kind of emerging environmental protection printing material, its feature of environmental protection, security are self-evident, be environmental protection and energy saving the most in the above Lacquer finish product, but aqueous product because of glossiness friction property etc. not as other series products, being not easy to promote and use on market, is developing aqueous product market, response national environmental protection policy and the key that is beneficial to personnel safety so strengthen the quality of its research and development dynamics, raising water-based Lacquer finish product.
Summary of the invention
The present invention is just in order to overcome above-mentioned deficiency, technical problem to be solved provides a kind of water-based printing coating oil, not only environmental protection of this product, nontoxic, and have transparency height, glossiness height, good, the anti-zoned trace of scratch-resistant performance, film forming speed is fast, drying characteristic rapidly.
The technical problem that the present invention also will solve provides the manufacture method of above-mentioned high light high abrasion water-based coating oil.
For solving the problems of the technologies described above, the technical solution adopted in the present invention is as follows:
A kind of high smooth high abrasion water-based coating oil, it comprises the component of following parts by weight:
10～20 parts of deionized waters;
5～15 parts of water-soluble solid acrylic resins;
Non-film forming matter: 40～60 parts of the aqueous acrylic emulsions of high glass transition temperature;
Film forming matter: 21～32 parts of the aqueous acrylic emulsions of low Tg;
2～10 parts of ammoniacal liquor;
10～15 parts of water-based wax breasts;
0.5～1.5 part of moistening flatting agent;
0.1～1 part of defoamer;
0.5～2 part of thickening material.
Described high glass transition temperature is preferably 80～90 ℃.
Described low Tg is preferably 10～30 ℃.
The preferred use palm wax of described water-based wax breast is as the water-based palm wax 2644 of Guangzhou Si Luoke chemistry company limited production.
Described moistening flatting agent is preferably used organic-silicon-modified polyacrylate, the moistening flatting agent BYK333 that produces as German Bi Ke company.
Described defoamer is preferably used organosilicon polymer, as the defoamer WDF-568 of the loyal Fine Chemical Co., Ltd in Shanghai production.
Polyurethane acroleic acid fat is preferably used in described thickening.
Make the method for above-mentioned high light high abrasion water-based coating oil, comprise the steps:
(1) dispersing and dissolving: press formula ratio with deionized water, the water-soluble solid acrylic resin add to disperse to add ammoniacal liquor while stirring in the cylinder, and the back that finishes disperseed 2～3 hours, dissolves fully to the water-soluble solid acrylic resin;
(2) stir: in the above-mentioned solution of dissolved, add non-film forming matter, film forming matter, water-based wax breast, moistening flatting agent, defoamer and thickening material successively, after adding finishes, stir 30～60min to evenly complete;
(3) detect: it is 7.5～8.5 that sampling detects pH value; Detection viscosity is 25 ℃ and is coated with 4
#Cup 40～60 seconds, viscosity can adopt the thickening material adjustment; Survey solid content again, solid content is salable product between (40 ± 2) %, the measuring method of solid content: sampling 1～2 restrains in 120 ℃ of oven dry 1.5 hours, claims dry film weight, calculates solid content;
(4) filter and package: adopt the filtration of 120 or 200 order filter bags, packing to get final product the above-mentioned product that is up to the standards.
The method of calculation of solid content are in the above-mentioned steps (3): (dry film Chong Liang ∕ original sample weight) * 100%.
Beneficial effect: high light high abrasion water-based coating oil of the present invention has the following advantages:
1, this product as solvent, in use, has only the moisture content volatilization with water, and is environmentally friendly, and do not contain heavy metal, can detect by VOC fully, and be a kind of safe green product;
2, this product is the main body base-material with the water-soluble acrylic emulsion, be equipped with the aqueous solid acrylic resin that adds lustre to, not only further guaranteed the Safety and Environmental Protection of product, and special material combination, make that the product printing coating is effective, transparency is high, glossiness is high, have excellent wear-resisting wiping, and do not fade, anti-zoned trace;
3, water-tolerant behind this product printing coating is difficult for sticking flower;
4, this product price is cheap, constructional method is simple, with machine method unanimity on other printing coating oil, directly uses rubber-surfaced roll seasoning machine glazing, realizes easily, can be mass-produced;
5, this product is not flammable, does not have corrodibility, uses transportation to store safety.
Embodiment
Use raw material:
The aqueous acrylic emulsion of high glass transition temperature: purchase in the village, Shanghai minister polymkeric substance company limited;
The aqueous acrylic emulsion of low Tg: purchase in the village, Shanghai minister polymkeric substance company limited;
Water-based wax breast: purchase in Guangzhou Si Luoke chemistry company limited, the water-based palm wax 2644 of its production;
Moistening flatting agent: purchase company, the moistening flatting agent BYK333 of its production in German Bi Ke;
Defoamer: purchase loyal Fine Chemical Co., Ltd, the defoamer WDF-568 of its production in Shanghai.
Embodiment 1:
With deionized water 10g, water-soluble solid acrylic resin 10g adds the people and disperses in the cylinder, adds ammoniacal liquor while stirring
6g adds the back that finishes and disperses to dissolve fully to the water-soluble solid acrylic resin in 2 hours; Adding high glass transition temperature in the above-mentioned solution of dissolved successively is 90 ℃ aqueous acrylic emulsion 40g, aqueous acrylic emulsion 26g, water-based palm wax 2644 15g, BYK333 1g, WDF-568 0.1g and the polyurethane acroleic acid fat 2.2g that low Tg is 20 ℃, after adding finishes, stir 30min to even fully; It is 8.0 that sampling detects pH value, and detection viscosity is 25 ℃ and is coated with 4
#Cup is 58 seconds, detects solid content again, and sampling 1 restrains in 120 ℃ of oven dry 1.5 hours, claims that dry film weight is 0.395g, and calculating solid content is 39.5%, and it is qualified to detect, and adopts the filtration of 120 order filter bags, packing to get final product.
Embodiment 2:
With deionized water 10g, water-soluble solid acrylic resin 10g adds the people and disperses in the cylinder, adds ammoniacal liquor while stirring
2g adds the back that finishes and disperses to dissolve fully to the water-soluble solid acrylic resin in 3 hours; Adding high glass transition temperature in the above-mentioned solution of dissolved successively is 80 ℃ aqueous acrylic emulsion 60g, aqueous acrylic emulsion 21g, water-based palm wax 2644 10g, BYK333 0.5g, WDF-568 1g and the polyurethane acroleic acid fat 1.5g that low Tg is 10 ℃, after adding finishes, stir 45min to even fully; It is 8.2 that sampling detects pH value, detects viscosity, adopts thickening material 2g to adjust, and is 25 ℃ and is coated with 4
#Cup 50 seconds detects solid content again, and sampling 2 restrains in 120 ℃ of oven dry 1.5 hours, and surveying dry film weight is 0.800g, and calculating solid content is 40%, and it is qualified to detect, adopts 120 order filter bags to filter, pack and get final product.
Embodiment 3:
With deionized water 20g, water-soluble solid acrylic resin 15g adds the people and disperses in the cylinder, adds ammoniacal liquor while stirring
10g adds the back that finishes and disperses to dissolve fully to the water-soluble solid acrylic resin in 2.5 hours; Adding high glass transition temperature in the above-mentioned solution of dissolved successively is 90 ℃ aqueous acrylic emulsion 50g, aqueous acrylic emulsion 32g, water-based palm wax 12g, BYK333 1.5g, defoamer 0.5g and the thickening material 1g that low Tg is 30 ℃, after adding finishes, stir 60min to even fully; It is 7.8 that sampling detects pH value, detects viscosity, adopts thickening material 1g to adjust, and is 25 ℃ and is coated with
#4 glasss 47 seconds, detect solid content again, sampling 2 restrains in 120 ℃ of oven dry 1.5 hours, surveying dry film weight is 0.806g, solid content is 40.3%, it is qualified to detect, adopts 200 order filter bags to filter, pack and get final product.
The water-based coating oil of the foregoing description 1～3 preparation is directly used rubber-surfaced roll seasoning machine glazing, the glazing product is carried out the gloss oil Performance Detection, its result is as follows:
| ? | Embodiment 1 | Embodiment 2 | Embodiment 3 |
| PH | 8.0 | 8.0 | 8.0 |
| Viscosity | 58 seconds | 50 seconds | 47 seconds |
| Solid content | 39.5% | 40% | 40.3% |
| Glossiness | 65℃ | 78℃ | 70℃ |
| Wear-resisting wiping | 200 times | 100 times | 150 times |
| Resistance to blocking | Qualified | Qualified | Qualified |
Claims (8)
1. one kind high smooth high abrasion water-based coating oil is characterized in that it comprises the component of following parts by weight:
10～20 parts of deionized waters;
5～15 parts of water-soluble solid acrylic resins;
Non-film forming matter: 40～60 parts of the aqueous acrylic emulsions of high glass transition temperature;
Film forming matter: 21～32 parts of the aqueous acrylic emulsions of low Tg;
2～10 parts of ammoniacal liquor;
10～15 parts of water-based wax breasts;
0.5～1.5 part of moistening flatting agent;
0.1～1 part of defoamer;
0.5～2 part of thickening material.
2. a kind of high smooth high abrasion water-based coating oil according to claim 1, it is characterized in that: described high glass transition temperature is 80～90 ℃.
3. a kind of high smooth high abrasion water-based coating oil according to claim 1, it is characterized in that: described low Tg is 10～30 ℃.
4. according to each described a kind of high smooth high abrasion water-based coating oil of claim 1 to 3, it is characterized in that: described water-based wax breast is water-based palm wax.
5. according to each described a kind of high smooth high abrasion water-based coating oil of claim 1 to 3, it is characterized in that: described moistening flatting agent is organic-silicon-modified polyacrylate.
6. according to each described a kind of high smooth high abrasion water-based coating oil of claim 1 to 3, it is characterized in that: described defoamer is an organosilicon polymer.
7. according to each described a kind of high smooth high abrasion water-based coating oil of claim 1 to 3, it is characterized in that: described thickening material is a polyurethane acroleic acid fat.
8. prepare the method for the described a kind of high smooth high abrasion water-based coating oil of claim 1, it is characterized in that: it comprises the steps:
(1) dispersing and dissolving: press formula ratio with deionized water, the water-soluble solid acrylic resin add to disperse to add ammoniacal liquor while stirring in the cylinder, and the back that finishes disperseed 2～3 hours, dissolves fully to the water-soluble solid acrylic resin;
(2) stir: in the above-mentioned solution of dissolved, add non-film forming matter, film forming matter, water-based wax breast, moistening flatting agent, defoamer and thickening material successively, after adding finishes, stir 30～60min to evenly complete;
(3) detect: it is 7.5～8.5 that sampling detects pH value; Viscosity is 25 ℃ and is coated with 4
#Cup 40～60 seconds, viscosity can adopt the thickening material adjustment; Survey solid content again, solid content is salable product between (40 ± 2) %, the measuring method of solid content: sampling 1～2 restrains in 120 ℃ of oven dry 1.5 hours, claims dry film weight, calculates solid content;
(4) filter and package: adopt the filtration of 120 or 200 order filter bags, packing to get final product the above-mentioned product that is up to the standards.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201010522964A CN101974269B (en) | 2010-10-28 | 2010-10-28 | High gloss and high abrasion resistant water-based overprinting varnish and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201010522964A CN101974269B (en) | 2010-10-28 | 2010-10-28 | High gloss and high abrasion resistant water-based overprinting varnish and preparation method thereof |
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| Publication Number | Publication Date |
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| CN101974269A true CN101974269A (en) | 2011-02-16 |
| CN101974269B CN101974269B (en) | 2012-08-29 |
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Cited By (22)
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| CN102337704A (en) * | 2011-07-11 | 2012-02-01 | 武汉迪赛高科技研究发展有限公司 | Temperature-resisting printing paper water base varnish and preparation method thereof |
| CN102732103A (en) * | 2012-07-23 | 2012-10-17 | 上海睿途新材料科技有限公司 | High-printing-property environment-friendly water-based back surface coating for packaging materials as well as preparation method thereof |
| CN102757721A (en) * | 2012-07-12 | 2012-10-31 | 上海盖特建筑技术咨询有限公司 | Protective agent for protecting corroded art steel plates |
| CN103031773A (en) * | 2012-12-25 | 2013-04-10 | 上海睿途新材料科技有限公司 | Environment-friendly high-gloss water-based back coating and preparation method thereof |
| CN103031774A (en) * | 2012-12-24 | 2013-04-10 | 东莞市鸿海化工涂料有限公司 | Aqueous universal oil polish and preparation method thereof |
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| CN103911904A (en) * | 2014-03-28 | 2014-07-09 | 昆山荣成纸业有限公司 | Waterproof gloss oil for paperboard and preparation method of waterproof gloss oil |
| CN104005262A (en) * | 2014-06-03 | 2014-08-27 | 山西金博雅油墨科技有限责任公司 | Water-based lotus-leaf-structured hydrophobic over-printing varnish for wallpaper and preparation method of over-printing varnish |
| CN104046276A (en) * | 2014-05-26 | 2014-09-17 | 范振捷 | Environment-friendly polishing wax and usage method thereof |
| CN104277631A (en) * | 2014-09-24 | 2015-01-14 | 安徽省中彩印务有限公司 | Non-toxic brightening oil for glazing technique |
| CN105315782A (en) * | 2015-10-28 | 2016-02-10 | 苏州市博来特油墨有限公司 | Water-based paint gloss oil |
| CN105385285A (en) * | 2015-12-30 | 2016-03-09 | 上海奇想青晨新材料科技股份有限公司 | High wear resistance water-borne gloss oil and preparing method thereof |
| CN104530892B (en) * | 2015-01-20 | 2016-08-31 | 中山市博海精细化工有限公司 | A kind of compound gold card paper environment-friendly type aqueous varnish and preparation method thereof |
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| CN102337704B (en) * | 2011-07-11 | 2014-03-26 | 武汉迪赛高科技研究发展有限公司 | Temperature-resisting printing paper water base varnish and preparation method thereof |
| CN102337704A (en) * | 2011-07-11 | 2012-02-01 | 武汉迪赛高科技研究发展有限公司 | Temperature-resisting printing paper water base varnish and preparation method thereof |
| CN102757721B (en) * | 2012-07-12 | 2015-09-23 | 上海盖特建筑技术咨询有限公司 | A kind of protective material for the protection of corrosion art steel plate |
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| CN105315782A (en) * | 2015-10-28 | 2016-02-10 | 苏州市博来特油墨有限公司 | Water-based paint gloss oil |
| CN105385285A (en) * | 2015-12-30 | 2016-03-09 | 上海奇想青晨新材料科技股份有限公司 | High wear resistance water-borne gloss oil and preparing method thereof |
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| CN108587363A (en) * | 2018-03-30 | 2018-09-28 | 江苏劲嘉新型包装材料有限公司 | Environmentally friendly high abrasion high glaze water-based gloss oil |
| CN112236484A (en) * | 2018-06-07 | 2021-01-15 | 阿克佐诺贝尔国际涂料股份有限公司 | Aqueous binder composition, coating composition comprising the aqueous binder composition, method of coating a substrate and coated substrate |
| US12091539B2 (en) | 2018-06-07 | 2024-09-17 | Akzo Nobel Coatings International B.V. | Two-component coating composition, method for homogeneously mixing a curing component into a binder component, and use of nano pigments for providing a marker color to a curing component |
| CN112638069A (en) * | 2019-09-20 | 2021-04-09 | 北京小米移动软件有限公司 | Mobile terminal shell, preparation method and mobile terminal |
| CN114456660A (en) * | 2022-01-25 | 2022-05-10 | 北京金印联国际供应链管理有限公司 | High-anti-after-tack water-based gloss oil and preparation method thereof |
| CN114806270A (en) * | 2022-05-11 | 2022-07-29 | 北京金印联国际供应链管理有限公司 | Water-based gloss oil composition, water-based gloss oil and application of water-based gloss oil in medicine packaging |
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