CN107699071A - A kind of environment-friendly water-based finishing oil of UV levels high light wearable and preparation method thereof - Google Patents

A kind of environment-friendly water-based finishing oil of UV levels high light wearable and preparation method thereof Download PDF

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Publication number
CN107699071A
CN107699071A CN201610640160.1A CN201610640160A CN107699071A CN 107699071 A CN107699071 A CN 107699071A CN 201610640160 A CN201610640160 A CN 201610640160A CN 107699071 A CN107699071 A CN 107699071A
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CN
China
Prior art keywords
water
environment
high light
oil
finishing oil
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Pending
Application number
CN201610640160.1A
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Chinese (zh)
Inventor
肖天运
郭汾阳
廖良福
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zhuhai Cailong Plastic Printing Ink Products Co Ltd
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Zhuhai Cailong Plastic Printing Ink Products Co Ltd
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Filing date
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Application filed by Zhuhai Cailong Plastic Printing Ink Products Co Ltd filed Critical Zhuhai Cailong Plastic Printing Ink Products Co Ltd
Priority to CN201610640160.1A priority Critical patent/CN107699071A/en
Publication of CN107699071A publication Critical patent/CN107699071A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

Abstract

The invention discloses a kind of environment-friendly water-based finishing oil of UV levels high light wearable, its parts by weight composition is:Aqueous solid acrylic resin:15‑20%;Acrylic emulsion A:25‑35%;Acrylic emulsion B:15‑25%;Deionized water:10‑15%;25% ammoniacal liquor:5‑10%;Levelling agent:1‑1.5%;Defoamer:0.2‑0.5%;Wear-resisting scratch-resisting agent:8‑10%.The preparation method of the finishing oil is:Deionized water, 25% ammoniacal liquor, aqueous solid acrylic resin are mixed to prepare water-base resin liquid first;Then acrylic emulsion A, acrylic emulsion B, it is stirred 10 minutes, water-base resin liquid made from addition, stirs 15 minutes;Secondly increase speed of agitator and be slowly added to successively defoamer, wear-resisting scratch-resisting agent, levelling agent stirring 1 hour;Normal temperature is finally cooled to, adjustment gloss oil viscosity, filters and packages the i.e. environment-friendly water-based finishing oil of obtained UV level high light wearables.Finishing oil glossiness provided by the invention is high, and wearability is good, nonhazardous and price are low, and its preparation method energy consumption is low, without special ultraviolet light curing apparatus.

Description

A kind of environment-friendly water-based finishing oil of UV levels high light wearable and preparation method thereof
Technical field
The present invention relates to a kind of finishing oil and preparation method thereof, particularly a kind of environment-friendly water-based Lacquer finish of UV levels high light wearable Oil and preparation method thereof.
Background technology
Finishing oil is to complete the coating of duplicate face cap one of picture and text printing, and printed matter surface obtains layer protecting film Layer, protection trace, beautify product, glossiness and wearability are to evaluate the two big leading indicator of performance of finishing oil.Existing finishing oil The problem of existing be:1)The shortcomings that glossiness and poor wearability be present, printing it in common water borne gloss oil due to formulation challenges Product definition goes wrong during brush, has a strong impact on follow-up use;2)Ultraviolet curing varnish has high glaze(It can reach 75 degree The above/60 ° of vancometers), high abrasion the characteristics of, but ultraviolet curing varnish is by the ultraviolet lighting in certain wavelength Under, it is changed into the oil polish of solid-state from liquid, it is necessary to expend a large amount of electric energy, it is expensive;3)Ultraviolet curing varnish is in UV light During oily curing reaction, the ozone with penetrating odor can be produced, and UV photocurings gloss oil has to human body skin in itself It is corrosive;4)The solidification of ultraviolet curing varnish needs ultraviolet source, therefore it is required that have special ultraviolet light curing apparatus with It is supporting, user's usability is not strong.
The content of the invention
In view of the shortcomings of the prior art, the present invention provides a kind of environment-friendly water-based finishing oil of UV levels high light wearable and its preparation side Method.
The technical scheme is that:A kind of environment-friendly water-based finishing oil of UV levels high light wearable, it is characterised in that by following heavy Measure the component composition of part:
Aqueous solid acrylic resin:15-20%;
Acrylic emulsion A:25-35%;
Acrylic emulsion B:15-25%;
Deionized water:10-15%;
25% ammoniacal liquor:5-10%;
Levelling agent:1-1.5%;
Defoamer:0.2-0.5%;
Wear-resisting scratch-resisting agent:8-10%.
Present invention also offers the preparation method of the described environment-friendly water-based finishing oil of UV level high light wearables.
The preparation method of the described environment-friendly water-based finishing oil of UV level high light wearables is:
(1)Deionized water, 25% ammoniacal liquor, aqueous solid acrylic resin are sequentially added into reactor, resin is completely dissolved system Obtain water-base resin liquid;
(2)Acrylic emulsion A, acrylic emulsion B are sequentially added into container, is stirred 10 minutes;
(3)To step(2)Step is slowly added in the mixture of acquisition(1)In obtained water-base resin liquid, and stir 15 minutes;
(4)Increase mixing speed, to step(3)Defoamer, wear-resisting scratch-resisting agent, levelling agent are put into the mixture of acquisition successively simultaneously Rotating speed is kept to stir 1 hour;
(5)Normal temperature is cooled to, adjustment gloss oil viscosity, filters and packages the i.e. environment-friendly water-based finishing oil of obtained UV level high light wearables.
Step(1)The condition of the reactor for preparing water-base resin liquid is:Temperature control is 60 DEG C, and the time 1.5-2 is small When;Step(2)And step(3)The rotating speed of middle stirring is 400-600 revs/min;Step(4)The rotating speed of described high-speed stirred is 600-800 revs/min.
Present invention also offers the application method of the described environment-friendly water-based finishing oil of UV level high light wearables.
The application method of the described environment-friendly water-based finishing oil of UV level high light wearables is:
(1)Please first gloss oil is stirred before use;
(2)Diluent uses ethanol:Water=1:(0.8~1.2), control viscosity is in the 20-25 seconds(Wipe 25 DEG C of grace 2# cups);
(3)By gloss oil with 50-200m/min print speed printing speed coated on base material;
(4)The base material for being coated with gloss oil is put into baking oven and carries out baking irradiation, and oven temperature is controlled at 80-110 DEG C, so as to realize Volatile dry.
Beneficial effects of the present invention are:
1st, the environment-friendly water-based gloss oil of UV levels high light wearable of the present invention has the characteristics of high gloss and high abrasion, solves general Logical water-based gloss oil glossiness and the problem of wearing no resistance;
2nd, the environment-friendly water-based gloss oil of UV levels high light wearable of the present invention is by acrylic emulsion, water-based acrylic resin, auxiliary agent group Into no organic volatile(VOC), pollution-free, nonhazardous, be advantageous to keep the safety in production and improve worker's working condition;
3rd, reach the curing of volatile dry using baking irradiation, there is the characteristics of rapid curing and low-temperature setting, can save More than 80% power consumption, solve electricity consumption it is excessive, waste national resources the problem of;
4th, the environment-friendly water-based finishing oil of UV levels high light wearable of the present invention is that volatile dry type, infrared ray, hot blast etc. dries dress Put the drying for being used equally for the water-based finishing oil so that the water-based gloss oil adapts to the requirement of nearly all printing equipment, solves The problem of UV gloss oil needs special ultraviolet light curing apparatus matched;
5th, the environment-friendly water-based gloss oil of UV levels high light wearable is compared to UV gloss oil prices low 30% or so.
Embodiment
Specific embodiments of the present invention are described further below:
A kind of environment-friendly water-based gloss oil of UV levels high light wearable, is made up of the component of following parts by weight:Aqueous solid acrylic resin: 15-20%;Acrylic emulsion A:25-35%;Acrylic emulsion B:15-25%;Deionized water:10-15%;25% ammoniacal liquor:5-10%;Stream Flat agent:1-1.5%;Defoamer:0.2-0.5%;Wear-resisting scratch-resisting agent:8-10%.
The preparation method of the described environment-friendly water-based finishing oil of UV level high light wearables is:
(1)Put into deionized water, 25% ammoniacal liquor, aqueous solid acrylic resin successively into reactor, temperature of reaction kettle control exists 60 DEG C, 1.5 hours time made resin be completely dissolved obtained water-base resin liquid;
(2)Put into acrylic emulsion A, acrylic emulsion B successively into container, and move to 400-600 revs/min of low speed of mixer Stirring 10 minutes;
(3)To step(2)Step is slowly added in the mixture of acquisition(1)In obtained water-base resin liquid, and stir 15 minutes;
(4)By mixer adjustment of rotational speed to 600-800 revs/min, to step(3)Slowly input disappears successively in the mixture of acquisition Infusion, wear-resisting scratch-resisting agent, levelling agent simultaneously keep rotating speed to stir 1 hour;
(5)It is cooled to normal temperature, adjustment gloss oil viscosity, filters and packages that UV levels high light wearable of the present invention is made is environment-friendly water-based Finishing oil.
The environment-friendly water-based finishing oil of UV levels high light wearable of the present invention, meets《YCT 207-2006 tobacco shreds and box bag Fill the measure of VOC in paper》、《The measure high-efficient liquid phase color of YCT 332-2010 smoke aqueous gel formaldehyde Spectrometry》Standard.
The application method of the environment-friendly water-based finishing oil of UV levels high light wearable provided by the present invention, comprises the following steps:(1)Use Before please first gloss oil is stirred;(2)Diluent uses ethanol:Water=1:(0.8~1.2), control viscosity is in the 20-25 seconds(Wipe grace 25 DEG C of 2# cups);(3)By gloss oil with 50-200m/min print speed printing speed coated on base material;(4)It is coated with the base material of gloss oil It is put into baking oven and carries out baking irradiation, oven temperature is controlled at 80-110 DEG C, so as to realize volatile dry.

Claims (4)

1. a kind of environment-friendly water-based finishing oil of UV levels high light wearable, it is characterised in that be made up of the component of following parts by weight:It is water-based solid Body acrylic resin:15-20%;Acrylic emulsion A:25-35%;Acrylic emulsion B:15-25%;Deionized water:10-15%;25% Ammoniacal liquor:5-10%;Levelling agent:1-1.5%;Defoamer:0.2-0.5%;Wear-resisting scratch-resisting agent:8-10%.
2. the preparation method of the environment-friendly water-based finishing oil of UV levels high light wearable according to claim 1, it is characterised in that including Following steps:
(1)Deionized water, 25% ammoniacal liquor, aqueous solid acrylic resin are sequentially added into reactor, resin is completely dissolved system Obtain water-base resin liquid;
(2)Acrylic emulsion A, acrylic emulsion B are sequentially added into container, is stirred 10 minutes;
(3)To step(2)Step is slowly added in the mixture of acquisition(1)In obtained water-base resin liquid, and stir 15 minutes;
(4)Increase mixing speed, to step(3)Defoamer, wear-resisting scratch-resisting agent, levelling agent are put into the mixture of acquisition successively simultaneously Rotating speed is kept to stir 1 hour;
(5)Normal temperature is cooled to, adjustment gloss oil viscosity, filters and packages the i.e. environment-friendly water-based finishing oil of obtained UV level high light wearables.
3. the preparation method of the environment-friendly water-based finishing oil of UV levels high light wearable according to claim 2, it is characterised in that:Step (1)The condition of the reactor for preparing water-base resin liquid is:Temperature control is 60 DEG C, 1.5-2 hours time;Step(2)With Step(3)The rotating speed of middle stirring is 400-600 revs/min;Step(4)The rotating speed of described high-speed stirred is 600-800 revs/min Clock.
4. a kind of application method of the environment-friendly water-based finishing oil of UV levels high light wearable, it is characterised in that comprise the following steps:
(1)Please first gloss oil is stirred before use;
(2)Diluent uses ethanol:Water=1:(0.8~1.2), control viscosity is in the 20-25 seconds(Wipe 25 DEG C of grace 2# cups);
(3)By gloss oil with 50-200m/min print speed printing speed coated on base material;
(4)The base material for being coated with gloss oil is put into baking oven and carries out baking irradiation, and oven temperature is controlled at 80-110 DEG C, so as to realize Volatile dry.
CN201610640160.1A 2016-08-08 2016-08-08 A kind of environment-friendly water-based finishing oil of UV levels high light wearable and preparation method thereof Pending CN107699071A (en)

Priority Applications (1)

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CN201610640160.1A CN107699071A (en) 2016-08-08 2016-08-08 A kind of environment-friendly water-based finishing oil of UV levels high light wearable and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610640160.1A CN107699071A (en) 2016-08-08 2016-08-08 A kind of environment-friendly water-based finishing oil of UV levels high light wearable and preparation method thereof

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Publication Number Publication Date
CN107699071A true CN107699071A (en) 2018-02-16

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111662601A (en) * 2020-06-19 2020-09-15 深圳九星印刷包装集团有限公司 Aqueous wear-resistant gloss oil and preparation method thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101974269A (en) * 2010-10-28 2011-02-16 苏州凯康化工科技有限公司 High gloss and high abrasion resistant water-based overprinting varnish and preparation method thereof
EP3138825A1 (en) * 2015-09-04 2017-03-08 Dresdner Lackfabrik novatic GmbH Co. KG Coating system for concrete surfaces

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101974269A (en) * 2010-10-28 2011-02-16 苏州凯康化工科技有限公司 High gloss and high abrasion resistant water-based overprinting varnish and preparation method thereof
EP3138825A1 (en) * 2015-09-04 2017-03-08 Dresdner Lackfabrik novatic GmbH Co. KG Coating system for concrete surfaces

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111662601A (en) * 2020-06-19 2020-09-15 深圳九星印刷包装集团有限公司 Aqueous wear-resistant gloss oil and preparation method thereof

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Application publication date: 20180216

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