CN106381041A - Aqueous ultrafast drying two-component acrylic-polyurethane middle coating and preparation method thereof - Google Patents

Aqueous ultrafast drying two-component acrylic-polyurethane middle coating and preparation method thereof Download PDF

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Publication number
CN106381041A
CN106381041A CN201610799258.1A CN201610799258A CN106381041A CN 106381041 A CN106381041 A CN 106381041A CN 201610799258 A CN201610799258 A CN 201610799258A CN 106381041 A CN106381041 A CN 106381041A
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China
Prior art keywords
component
dry type
acrylic acid
acid polyurethane
fast dry
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Pending
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CN201610799258.1A
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Chinese (zh)
Inventor
于义田
胡中源
程璐
段客春
赵从胜
周旺
柳现林
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Hebei Chenyang Industry and Trade Group Co Ltd
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Hebei Chenyang Industry and Trade Group Co Ltd
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Priority to CN201610799258.1A priority Critical patent/CN106381041A/en
Publication of CN106381041A publication Critical patent/CN106381041A/en
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • C08K3/36Silica
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/265Calcium, strontium or barium carbonate

Abstract

The invention discloses an aqueous ultrafast drying two-component acrylic-polyurethane middle coating and a preparation method thereof. The aqueous ultrafast drying two-component acrylic-polyurethane middle coating comprises a component A and a component B, and the component A comprises 20-30% of aqueous acrylic resin, 10-20% of an aqueous acrylic emulsion, 2-6% of an environmentally-friendly solvent, 0.5-2% of a wetting dispersant, 0.3-0.8% of an antifoaming agent and 0.3-0.8% of a thickener; a pigment filler comprises, by weight, 15-25% of titanium dioxide, 10-15% of calcium carbonate, 10-20% of talcum powder, 0.1-0.5% of aerosil and 5-15% of deionized water; and the component B is an aqueous fast drying curing agent. The a coating film formed by the ultrafast drying two-component acrylic-polyurethane middle coating has the advantages of slow drying, easiness in polishing, and no pollution to environment.

Description

A kind of waterborne ultra-fast dry type double-component acrylic acid polyurethane floating coating and preparation method thereof
Technical field
The present invention relates to metal protection field, apply in more particularly, to a kind of waterborne ultra-fast dry type double-component acrylic acid polyurethane Paint and preparation method thereof.
Background technology
With the pay attention to day by day to environment and health for the people, water paint obtains and is increasingly widely applied, tradition The pollution that the volatile organic content (VOC) that solvent based coating is discharged during production and use produces, becomes row at present City primary pollution source after automobile, water paint, as one of the substitute of traditional solvent-borne coating, can reduce VOC Discharge, the generation of waste, reduce the contact to poisonous releaser for the workman.It is reported that, during " 13 ", the whole nation will be strengthened to waving Nitrogen oxides and VOC are carried out collaborative reduction of discharging by the control of the property sent out organic compound (VOC) total amount.
Aqueous industrial coating is mainly used in automobile, rolling stock, public transport big bus, and the field such as engineering machinery is domestic at present The Water-borne modification level of industrial coating has very big gap with technology compared with industrially developed country.Priming paint has been commonly used water Property electrophoretic paint, and middle apply and finish paint major part producer still using oil paint, reason be water paint do speed, the performance such as grinability with oil Paint has a certain distance, has that hardness of paint film is not high enough, easily goes out cut, chemical resistance is poor, the low shortcoming of solidification.Therefore middle painting Can get more and more with finish paint Water-borne modification needs, develop a quick-drying, grinability is good, in the high aqueous double-component self-drying type of paint hardness Japanning, thus greatly reducing the discharge capacity of VOC, reducing environmental pollution, energy-saving and emission-reduction, low-carbon environment-friendly being had very important existing Sincere justice.
Content of the invention
The purpose of the present invention is for the problems referred to above, provides a kind of waterborne ultra-fast dry type double-component that a kind of drying varniss is fast Acroleic acid polyurethane floating coating and preparation method thereof.
For reaching above-mentioned purpose, present invention employs following technical proposal:A kind of double group of waterborne ultra-fast dry type of the present invention Part acroleic acid polyurethane floating coating, described waterborne ultra-fast dry type double-component acrylic acid polyurethane floating coating includes component A and B group Point, described component A is made up of base material, auxiliary agent and color stuffing and deionized water, and described base material is by weight percentage by following components Composition:
Water-borne acrylic resin 20-30%,
Aqueous acrylic emulsion 10-20%;
Described auxiliary agent is composed of the following components by weight percentage:
Described color stuffing is composed of the following components by weight percentage:
B component is the quick-drying firming agent of aqueouss.
Further, the weight of described component A and B component is than for 100:10-15.
Further, described base material is composed of the following components by weight percentage:
Water-borne acrylic resin 25%,
Aqueous acrylic emulsion 15%;
Described auxiliary agent is composed of the following components by weight percentage:
Described color stuffing is composed of the following components by weight percentage:
B component is the quick-drying firming agent of aqueouss.
Further, the weight of described component A, B component is than for 100:10-15.
Further, described wetting dispersing agent is the aqueous copolymers solution type dispersant containing high pigment affinity groups, institute The environmentally friendly solvent stated is high boiling point environmentally friendly solvent, and described thickening agent is low sheraing association thickener.
Further, described environmentally friendly solvent is the mixture of dipropylene and dipropylene glycol methyl ether, described dipropyl The mass ratio of glycol butyl ether and dipropylene glycol methyl ether is 1:1.
Further, described defoamer is efficient organic modified silicas class defoamer.
Further, described thickening agent is polyurethaness association thickener, and described pigment is imperial boa titanium dioxide.
The preparation method of waterborne ultra-fast dry type double-component acrylic acid polyurethane floating coating of the present invention, walks including following Suddenly:
(1) weigh each component of described mass percent, by described water-borne acrylic resin, deionized water, environmentally friendly solvent It is added sequentially to get the raw materials ready in pot, stirring at low speed 5-10min;
(2) will be added to described in get the raw materials ready in pot dispensing carry out stirring at low speed, until after stirring, adding described moistening Dispersant, defoamer and color stuffing, more than high-speed stirred dispersion 15-20 minute, form uniform mill base;Wherein, described color stuffing Including titanium dioxide, Calcium Carbonate, Pulvis Talci, aerosil;
(3) described uniform mill base is ground, being ground to fineness is less than or equal to 20 microns;
(4) after mill base qualified for grinding stirring, acrylic emulsion and thickening agent are added, material is packed, that is, For component A, B component is the quick-drying firming agent of aqueouss, prepared waterborne ultra-fast dry type double-component acrylic acid polyurethane floating coating.
Further, in step (1), the rotating speed of described stirring at low speed is 400-600 rev/min, in step (2), The rotating speed of described high-speed stirred is 800-1000 rev/min.
Beneficial effect:There is drying varniss is slow, easily polishing, and oil paint VOC content is low, free from environmental pollution etc. in the present invention Advantage.With priming paint, finish paint has good adhesion.VOC content is extremely low, < 50g/L, simultaneously capable of purifying air.
Compared with prior art, the invention has the advantages that:
(1) present invention adopts interior catalytic type water-borne acrylic resin and quick-dry type high TG acrylic emulsion blending as film forming Material, prepares a kind of ultrafast dry type double-component acrylic acid polyurethane floating coating, 30min can surface drying, in the case of normal temperature self-drying, 3 is little When can be polished with machine, greatly improve production efficiency, formula adds high boiling point environmentally friendly solvent, make this invention product do not contain benzene, The poisonous and harmful substances such as dimethylbenzene, VOC content is extremely low, < 50g/L, and the healthy impact on environment and workmen is less.
(2) present invention adopts interior catalysis technique, reaches the balance of most preferably dry speed and useful life, fast drying.Common water borne Floating coating, is dried and is 25 DEG C to the time that can polish, more than 6 hours, and the quick-drying floating coating of aqueouss of the present invention is dried and extremely can polish Time be 25 DEG C, can polish within 3 hours from dry.
(3) adopt the acrylic emulsion of high TG, surface drying is fast, and grinability is good, non-sticky sand paper;3rd, adopt HDI and IPDI hydridization The quick-drying firming agent of type, improves dry speed and pot-life.
Specific embodiment
Following examples only exist in illustrative purpose, rather than want to limit the scope of the present invention.
Embodiment 1
A kind of waterborne ultra-fast dry type double-component acrylic acid polyurethane floating coating of the present invention, the double group of described waterborne ultra-fast dry type Part acroleic acid polyurethane floating coating includes component A and B component, and described component A is by base material, auxiliary agent and color stuffing and deionized water group Become, described base material is composed of the following components by weight percentage:
Water-borne acrylic resin 21%,
Aqueous acrylic emulsion 11%;
Described auxiliary agent is composed of the following components by weight percentage:
Described color stuffing is composed of the following components by weight percentage:
B component is the quick-drying firming agent of aqueouss,
The weight of described component A and B component is than for 100:12.
Described water-borne acrylic resin is COVESTRO A 2601 resin, and described aqueous acrylic emulsion is COVESTRO A 2427 emulsion, described firming agent is Perstorp XD803 firming agent, and described wetting dispersing agent is containing Gao Yan The aqueous copolymers solution type dispersant TEGO Dispers 755W of material affinity groups.
Described environmentally friendly solvent is dipropylene for high boiling point environmentally friendly solvent and dipropylene glycol methyl ether presses 1:1 ratio is mixed The mixture closing.
Described defoamer is efficient organic modified silicas class defoamer Bi Ke chemistry BYK024.
Described thickening agent is polyurethaness association thickener.
Described pigment is imperial boa titanium dioxide R996.
The preparation method of waterborne ultra-fast dry type double-component acrylic acid polyurethane floating coating of the present invention, walks including following Suddenly:
(1) weigh each component of described mass percent, by described water-borne acrylic resin, deionized water, environmentally friendly solvent It is added sequentially to get the raw materials ready in pot, the rotating speed of stirring at low speed is 500 revs/min, stirs 5min;
(2) will be added to described in get the raw materials ready in pot dispensing carry out stirring at low speed, until after stirring, adding described moistening Dispersant, defoamer and color stuffing, the rotating speed of described high-speed stirred is 1000 revs/min, and dispersed with stirring more than 18 minutes is formed Uniformly mill base;Wherein, described color stuffing includes titanium dioxide, Calcium Carbonate, Pulvis Talci, aerosil;
(3) described uniform mill base is ground, being ground to fineness is less than or equal to 20 microns;
(4) after mill base qualified for grinding stirring, acrylic emulsion and thickening agent are added, material is packed, that is, For component A, B component is the quick-drying firming agent of aqueouss, prepared waterborne ultra-fast dry type double-component acrylic acid polyurethane floating coating.
Embodiment 2
Embodiment 2 is with the difference of embodiment 1:
A kind of waterborne ultra-fast dry type double-component acrylic acid polyurethane floating coating of the present invention, the double group of described waterborne ultra-fast dry type Part acroleic acid polyurethane floating coating includes component A, B component and deionized water, and described component A is by base material, auxiliary agent and color stuffing group Become, described base material is composed of the following components by weight percentage:
Water-borne acrylic resin 20%,
Aqueous acrylic emulsion 20%;
Described auxiliary agent is composed of the following components by weight percentage:
Described color stuffing is composed of the following components by weight percentage:
B component is the quick-drying firming agent of aqueouss.
The weight of described component A and B component is than for 100:13.
The preparation method of waterborne ultra-fast dry type double-component acrylic acid polyurethane floating coating of the present invention, walks including following Suddenly:
In step (1), weigh each component of described mass percent, by described water-borne acrylic resin, deionized water, Environmentally friendly solvent is added sequentially to get the raw materials ready in pot, and the rotating speed of stirring at low speed is 400 revs/min, stirs 10min;
In step (2), will be added to described in get the raw materials ready in pot dispensing carry out stirring at low speed, until after stirring, plus Enter described wetting dispersing agent, defoamer and color stuffing, the rotating speed of described high-speed stirred is 900 revs/min, dispersed with stirring 15 minutes More than, form uniform mill base;Wherein, described color stuffing includes titanium dioxide, Calcium Carbonate, Pulvis Talci, aerosil;
In step (3), described uniform mill base is ground, is ground to fineness and is 18 microns.
Embodiment 3
Embodiment 3 is with the difference of embodiment 1:
A kind of waterborne ultra-fast dry type double-component acrylic acid polyurethane floating coating of the present invention, the double group of described waterborne ultra-fast dry type Part acroleic acid polyurethane floating coating includes component A, B component and deionized water, and described component A is by base material, auxiliary agent and color stuffing group Become, described base material is composed of the following components by weight percentage:
Water-borne acrylic resin 30%,
Aqueous acrylic emulsion 10%;
Described auxiliary agent is composed of the following components by weight percentage:
Described color stuffing is composed of the following components by weight percentage:
B component is the quick-drying firming agent of aqueouss.
The weight of described component A and B component is than for 100:15.
The preparation method of waterborne ultra-fast dry type double-component acrylic acid polyurethane floating coating of the present invention, walks including following Suddenly:
In step (1), weigh each component of described mass percent, by described water-borne acrylic resin, environmentally friendly solvent It is added sequentially to get the raw materials ready in pot, stirring at low speed 8min;The rotating speed of described stirring at low speed is 600 revs/min,
In step (2), will be added to described in get the raw materials ready in pot dispensing carry out stirring at low speed, until after stirring, plus Enter described wetting dispersing agent, defoamer and color stuffing, high-speed stirred is disperseed more than 20 minutes, form uniform mill base;Wherein, described Color stuffing includes titanium dioxide, Calcium Carbonate, Pulvis Talci, aerosil;The rotating speed of described high-speed stirred is 800 revs/min.
In step (3), described uniform mill base is ground, is ground to fineness and is 17 microns.
Test 1
Embodiment 1 is detected to the product of embodiment 3, polishing the time all at 25 DEG C, within 3 hours.
Specific embodiment described herein is only explanation for example to present invention spirit.The affiliated technology of the present invention is led The technical staff in domain can be made various modifications or supplement or replaced using similar mode to described specific embodiment Generation, but the spirit without departing from the present invention or surmount scope defined in appended claims.

Claims (10)

1. a kind of waterborne ultra-fast dry type double-component acrylic acid polyurethane floating coating it is characterised in that:Described waterborne ultra-fast dry type is double Component acrylic acid polyurethane floating coating includes component A and B component, and described component A is by base material, auxiliary agent and color stuffing and deionized water Composition, described base material is composed of the following components by weight percentage:
Water-borne acrylic resin 20-30%,
Aqueous acrylic emulsion 10-20%;
Described auxiliary agent is composed of the following components by weight percentage:
Described color stuffing is composed of the following components by weight percentage:
B component is the quick-drying firming agent of aqueouss.
2. waterborne ultra-fast dry type double-component acrylic acid polyurethane floating coating according to claim 1 it is characterised in that:Described The weight of component A and B component is than for 100:10-15.
3. waterborne ultra-fast dry type double-component acrylic acid polyurethane floating coating according to claim 1 it is characterised in that:Described Base material is composed of the following components by weight percentage:
Water-borne acrylic resin 25%,
Aqueous acrylic emulsion 15%;
Described auxiliary agent is composed of the following components by weight percentage:
Described color stuffing is composed of the following components by weight percentage:
B component is the quick-drying firming agent of aqueouss.
4. waterborne ultra-fast dry type double-component acrylic acid polyurethane floating coating described in 2 is wanted according to right it is characterised in that:Described A Component, the weight of B component are than for 100:10-15.
5. waterborne ultra-fast dry type double-component acrylic acid polyurethane floating coating according to claim 1 it is characterised in that:Described Wetting dispersing agent be aqueous copolymers solution type dispersant containing high pigment affinity groups, described environmentally friendly solvent is high boiling point ring Protect solvent, described thickening agent is low sheraing association thickener.
6. waterborne ultra-fast dry type double-component acrylic acid polyurethane floating coating according to claim 5 it is characterised in that:Described Environmentally friendly solvent be dipropylene and dipropylene glycol methyl ether mixture, described dipropylene and dipropylene glycol methyl ether Mass ratio be 1:1.
7. waterborne ultra-fast dry type double-component acrylic acid polyurethane floating coating according to claim 1 it is characterised in that:Described Defoamer be efficient organic modified silicas class defoamer.
8. waterborne ultra-fast dry type double-component acrylic acid polyurethane floating coating according to claim 1 it is characterised in that:Described Thickening agent be polyurethaness association thickener, described pigment is imperial boa titanium dioxide.
9. the preparation method of the waterborne ultra-fast dry type double-component acrylic acid polyurethane floating coating described in any one of claim 1 to 8, It is characterized in that comprising the steps:
(1) weigh each component of mass percent described in claim 1, by described water-borne acrylic resin, deionized water, environmental protection Solvent is added sequentially to get the raw materials ready in pot, stirring at low speed 5-10min;
(2) will be added to described in get the raw materials ready in pot dispensing carry out stirring at low speed, until after stirring, adding described wetting and dispersing Agent, defoamer and color stuffing, more than high-speed stirred dispersion 15-20 minute, form uniform mill base;Wherein, described color stuffing includes Titanium dioxide, Calcium Carbonate, Pulvis Talci, aerosil;
(3) described uniform mill base is ground, being ground to fineness is less than or equal to 20 microns;
(4) after mill base qualified for grinding stirring, acrylic emulsion and thickening agent are added, material is packed, as A group Point, B component is the quick-drying firming agent of aqueouss, prepared waterborne ultra-fast dry type double-component acrylic acid polyurethane floating coating.
10. the preparation method of waterborne ultra-fast dry type double-component acrylic acid polyurethane floating coating according to claim 9, it is special Levy and be:In step (1), the rotating speed of described stirring at low speed is 400-600 rev/min, in step (2), described high-speed stirring The rotating speed mixed is 800-1000 rev/min.
CN201610799258.1A 2016-08-31 2016-08-31 Aqueous ultrafast drying two-component acrylic-polyurethane middle coating and preparation method thereof Pending CN106381041A (en)

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107353795A (en) * 2017-06-30 2017-11-17 河北晨阳工贸集团有限公司 A kind of water-based orange-peel paint of low VOC content
CN107880764A (en) * 2017-10-11 2018-04-06 湖南文理学院 A kind of water based shop primer, preparation method and application
CN109251647A (en) * 2018-08-02 2019-01-22 雅图高新材料有限公司 Aqueous priming paint and preparation method thereof for fibre reinforced epoxy resin composite
CN109280470B (en) * 2018-08-02 2020-08-14 雅图高新材料股份有限公司 Intermediate coating for fiber-reinforced epoxy resin composite material and preparation method thereof
CN112574661A (en) * 2020-12-31 2021-03-30 郑州双塔涂料有限公司 Double-component acrylic polyurethane middle paint and preparation method thereof
CN113045989A (en) * 2021-03-17 2021-06-29 山东七维新材料有限公司 High-toughness quick-drying water-based primer surfacer for rail transit and preparation method thereof
CN116082906A (en) * 2023-02-28 2023-05-09 雅图高新材料股份有限公司 Single-component ultrafast-drying wear-free water-based middle coating for automobile repair and preparation method thereof

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107353795A (en) * 2017-06-30 2017-11-17 河北晨阳工贸集团有限公司 A kind of water-based orange-peel paint of low VOC content
CN107353795B (en) * 2017-06-30 2020-07-28 河北晨阳工贸集团有限公司 Water-based orange-peel finish with low VOC content
CN107880764A (en) * 2017-10-11 2018-04-06 湖南文理学院 A kind of water based shop primer, preparation method and application
CN109251647A (en) * 2018-08-02 2019-01-22 雅图高新材料有限公司 Aqueous priming paint and preparation method thereof for fibre reinforced epoxy resin composite
CN109280470B (en) * 2018-08-02 2020-08-14 雅图高新材料股份有限公司 Intermediate coating for fiber-reinforced epoxy resin composite material and preparation method thereof
CN112574661A (en) * 2020-12-31 2021-03-30 郑州双塔涂料有限公司 Double-component acrylic polyurethane middle paint and preparation method thereof
CN113045989A (en) * 2021-03-17 2021-06-29 山东七维新材料有限公司 High-toughness quick-drying water-based primer surfacer for rail transit and preparation method thereof
CN116082906A (en) * 2023-02-28 2023-05-09 雅图高新材料股份有限公司 Single-component ultrafast-drying wear-free water-based middle coating for automobile repair and preparation method thereof
CN116082906B (en) * 2023-02-28 2023-09-26 雅图高新材料股份有限公司 Single-component ultrafast-drying wear-free water-based middle coating for automobile repair and preparation method thereof

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