CN102337704A - Temperature-resisting printing paper water base varnish and preparation method thereof - Google Patents
Temperature-resisting printing paper water base varnish and preparation method thereof Download PDFInfo
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- CN102337704A CN102337704A CN2011101925896A CN201110192589A CN102337704A CN 102337704 A CN102337704 A CN 102337704A CN 2011101925896 A CN2011101925896 A CN 2011101925896A CN 201110192589 A CN201110192589 A CN 201110192589A CN 102337704 A CN102337704 A CN 102337704A
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Abstract
The invention discloses a temperature-resisting printing paper water base varnish and a preparation method thereof, belonging to the technical field of high molecular materials. The preparation method comprises the following steps of: successively adding 20-60 parts of organic silicon modified acrylate emulsion, 2-5 parts of compound emulsifying agent, 10-30 parts of water solution of water-soluble amino resin, 1-10 parts of wax emulsion, 1-5 parts of water solution of flatting agent, 2-10 parts of water solution of antifoaming agent and 9-35 parts of deionized water into a mixing container, dispersing and emulsifying the mixture for 30 min under 800-2000 rpm, and filtering the mixture to obtain the water base varnish. In the invention, an acrylate monomer and an silicon monomer containing carbon-carbon double bonds are emulsified and copolymerized to prepare the organic silicon modified acrylate emulsion, the organic silicon modified acrylate emulsion as a film forming agent, the water-soluble amino resin, the wax emulsion, the flatting agent, the anti-foaming agent and the like are compounded to form the printing water base varnish with excellent temperature resistance and wear resistance.
Description
Technical field
The invention belongs to technical field of polymer materials, be specifically related to a kind of heat-resistance type printing paper product water lustering oil and preparation method thereof.
Background technology
Printing gloss oil is claimed finishing oil or glazing paint again, is a kind of printing coating material.At present the oil polish of use mainly contains three kinds on solvent-borne type, UV light-cured type and water-based type in the printing of papery article.The solvent-borne type oil polish has advantages such as good anti-solvent, chemicals-resistant, high gloss, but can volatilize a large amount of organic solvents in use, thereby influences the healthy of people, and serious environment pollution is progressively eliminated; UV light-cured type oil polish has that rate of drying is fast, and advantages such as chemicals-resistant, high gloss, but complex process cost an arm and a leg, thereby large tracts of land is promoted and received certain limitation; Water lustering oil is the novel environment-friendly product that grows up the nineties in 20th century, and it has strong, colourless, tasteless, nontoxic, low-cost, and the advantages such as good glossiness, folding resistance of transparent feel, thereby becomes the main at present kind of using.
Printing paper product glazing divides common glazing, online glazing and preprints several kinds of glazings.Wherein preprint only corrugated case and preprint the step of one in production special process.The characteristics that corrugated case is preprinted production are in advance the facial tissue of corrugated case to be printed, then directly and corrugated paper carry out the mount pressing, and then be die-cut to case.The facial tissue that prints needs through the elevated temperature heat pressure roller when carrying out the mount pressing with corrugated paper, and temperature is about 160-220 ℃, and therefore the heat resistance to employed glazing paint has proposed higher requirement.
Water lustering oil is mainly polyacrylate dispersion, and polyacrylate has good filming performance, transparent, the pliable and tough and high resilience of the film of formation; But because its structure is generally the chain linear structure; Belong to thermoplastics type's material, very responsive to temperature, the phenomenon of " hot sticky cold crisp " can appear.Organosilicon-modified acrylate class emulsion has been because of having introduced the Si-O key that bond energy is big, strand is submissive, can effectively improve resistant of high or low temperature, resistance to water, hardness of polyacrylate etc.The organosilicon-modified acrylate emulsion polymerization is divided into two kinds of emulsion dispersion and emulsion copolymerization methods according to method of modifying.When emulsion dispersion prepares organosilicon-modified acrylate emulsion; Be earlier organic silicon emulsion to be mixed with stabilizing agent; Mix according to a certain percentage with acrylic acid ester emulsion again after regulating pH value, but the organosilicon-modified acrylate emulsion less stable of this blending and modifying, be easy to generate two be separated, the storage life lacks; And not having chemical bond to combine between organosilicon polymer and acrylate polymer, the raising of its weatherability and adhesive force is also not obvious.It is that organosiloxane that has active group (carbon-to-carbon double bond etc.) and acrylic ester monomer are carried out copolymerization that the emulsion copolymerization legal system is equipped with the organosilicon-modified acrylate emulsion; Generate emulsion polymers such as random, grafting, block or interpenetrating networks; Thereby obtain stable organosilicon-modified acrylate emulsion system, and improve polymer-modified performance greatly.
The present invention carries out emulsion copolymerization with the organic silicon monomer of acrylate monomer and carbon-carbon double key, the preparation organosilicon-modified acrylate emulsion.With it is that film forming agent and water soluble amino resin, wax emulsion, levelling agent, antifoaming agent etc. are re-dubbed the brightening water-based oil for printing with good heat resistance.
Summary of the invention
To the deficiency that exists in the prior art; The object of the present invention is to provide a kind of heat-resistance type printing paper product water lustering oil and preparation method thereof; Can not resistant to elevated temperatures defective thereby overcome common acrylic acid ester oil polish, introduce the waterproof and dampproof ability that functional organic silicon monomer can also reinforcing membrane simultaneously.
The object of the invention is mainly realized through following technical scheme:
A kind of heat-resistance type printing paper product water lustering oil, its weight portion is formed as follows:
Aqueous solution 10-30 part of organic-silicon-modified acrylic acid ester emulsion 20-60 part, compound emulsifying agent 2-5 part, water soluble amino resin, wax emulsion 1-10 part, levelling agent aqueous solution 1-5 part, antifoaming agent aqueous solution 2-10 part and deionized water 9-35 part.
Described organic-silicon-modified acrylic acid ester emulsion gets according to following method preparation:
In agitated reactor, adding 2000kg deionized water, 100g lauryl sodium sulfate, 100g molecular weight successively and be 2000 polyether-type nonionic surfactant and 200g dispersion resin stirs well.1200g initator benzoyl peroxide is added in 500L acrylate monomer and the 100L organic silicon monomer mixed liquor, take out 5% of gross mass behind its mixing, in the adding agitated reactor; With the speed emulsification of 800-2000rpm 30 minutes; Be warming up to 80-90 ℃ then, reacted 2 hours, remaining mix monomer was splashed into agitated reactor in 2 hours; Be incubated 1 hour again, be chilled to room temperature naturally.Regulate pH to 9-10 with ammoniacal liquor at last, filter and promptly get organic-silicon-modified acrylic acid ester emulsion.
Dispersion resin among the above-mentioned preparation method is water soluble polymer resin such as sodium polymethacrylate, polyvinyl alcohol etc.
Described organic silicon monomer is one or both the mixture in 4-methacryloxypropyl methyl dimethoxysilane, vinyl three (2-methoxy ethyl) silane.
Described acrylate monomer is the two or more mixture in methyl methacrylate, butyl methacrylate, butyl acrylate, acrylic acid, butyl acrylate and the N methacrylamide.
Described compound emulsifying agent is that lauryl sodium sulfate and molecular weight are that both gross mass marks that 2000 polyether-type nonionic surfactant is hybridly prepared into by mass ratio at 1: 1 are 5% the aqueous solution.
Described water soluble amino resin is Ineos methyl-etherified amino resins IneosR747.
Described wax emulsion is a polyvinyl acetate wax emulsion.
Described levelling agent is waterborne organic silicon levelling agent silok 8255.
Described antifoaming agent is waterborne organic silicon antifoaming agent SILCOLAPSE C546.
Preparation method's step of heat-resistance type printing paper product water lustering oil of the present invention is following:
A, organic-silicon-modified preparing acrylate emulsion;
B, water soluble amino resin is dissolved in the deionized water, is mixed with the aqueous solution of 30wt%;
C, silok 8255 usefulness deionized waters are mixed with the aqueous solution of 20wt%, process the waterborne organic silicon levelling agent aqueous solution;
D, SILCOLAPSE C546 system is made antifoaming agent with the aqueous solution that deionized water is made into 5wt%;
E, preparation compound emulsifying agent;
F, add ready organic-silicon-modified acrylic acid ester emulsion, the water soluble amino resin aqueous solution, compound emulsifying agent, wax emulsion, the levelling agent aqueous solution, the antifoaming agent aqueous solution and deionized water in the mixer successively; Dispersion and emulsion is 30 minutes under 800-2000rpm, filters promptly to get.
Compared with prior art, the invention has the advantages that:
Product of the present invention has overcome the shortcoming of gloss oil temperature tolerance difference traditionally, the high temperature that its ability is 180 ℃-220 ℃, and it also has good anti-wear performance simultaneously.Under the situation of same coated amount, its abrasion resistance improves greatly.
Its heatproof and anti-wear performance are respectively like table 1 and table 2.
The heat resistance of table 1 water lustering oil
| The cardboard temperature (℃) | Cross the line situation |
| 180 | Cardboard does not have the stubble of dragging |
| 200 | Cardboard does not have the stubble of dragging |
| 220 | Cardboard does not have the stubble of dragging |
| 260 | Cardboard has and drags bright trace on a small quantity |
The anti-wear performance of table 2 water lustering oil
| Coating weight | Common acrylic acid ester emulsion oil polish | The abrasion resistance of product of the present invention |
| Abrasion resistance | ||
| 5g/m 2 | ＞400 | ＞600 |
| 3-5g/m 2 | ＞200 | ＞400 |
| 1.2-3/m 2 | ＜200 | ＞300 |
The specific embodiment
Below in conjunction with concrete embodiment the inventive method is done further detailed description:
Embodiment 1
In agitated reactor, add 20 parts of organic-silicon-modified acrylic acid ester emulsions successively; 2 parts of compound emulsifying agents, 30 parts of water soluble amino resin solution, 10 parts of polyvinyl acetate wax emulsions; 1 part of the waterborne organic silicon levelling agent aqueous solution; 2 parts and 35 parts deionized waters of the waterborne organic silicon antifoaming agent aqueous solution, emulsification is 30 minutes under 1500rpm, filters promptly to get water lustering oil.Coat with it and to cross line on 180 ℃ the cardboard and do not have the stubble of dragging, when coating weight is 5g/m
2The time, its abrasion resistance is 620 times.
Embodiment 2
In agitated reactor, add 25 parts of organic-silicon-modified acrylic acid ester emulsions successively; 2 parts of compound emulsifying agents, 25 parts of water soluble amino resin solution, 8 parts of polyvinyl acetate wax emulsions; 2 parts of the waterborne organic silicon levelling agent aqueous solution; 4 parts and 34 parts deionized waters of the waterborne organic silicon antifoaming agent aqueous solution, emulsification is 30 minutes under 1200rpm, filters promptly to get water lustering oil.Coat with it and to cross line on 180 ℃ the cardboard and do not have the stubble of dragging, when coating weight is 5g/m
2The time, its abrasion resistance is 650 times.
Embodiment 3
In agitated reactor, add organic-silicon-modified acrylic acid ester emulsion successively and get 30 parts; 3 parts of compound emulsifying agents, 20 parts of water soluble amino resins, 8 parts of polyvinyl acetate wax emulsions; 3 parts of the waterborne organic silicon levelling agent aqueous solution; 5 parts and 34 parts deionized waters of the waterborne organic silicon antifoaming agent aqueous solution, emulsification is 30 minutes under 2000rpm, filters promptly to get water lustering oil.Coat with it and to cross line on 200 ℃ the cardboard and do not have the stubble of dragging, when coating weight is 4g/m
2The time, its abrasion resistance is 470 times.
Embodiment 4
In agitated reactor, add 40 parts of organic-silicon-modified acrylic acid ester emulsions successively; 3 parts of compound emulsifying agents, 15 parts of water soluble amino resins, 6 parts of polyvinyl acetate wax emulsions; 3 parts of the waterborne organic silicon levelling agent aqueous solution; 6 parts and 27 parts deionized waters of the waterborne organic silicon antifoaming agent aqueous solution, emulsification is 30 minutes under 2000rpm, filters promptly to get water lustering oil.Coat with it and to cross line on 200 ℃ the cardboard and do not have the stubble of dragging, when coating weight is 4g/m
2The time, its abrasion resistance is 530 times.
Embodiment 5
In agitated reactor, add 45 parts of organic-silicon-modified acrylic acid ester emulsions successively; 4 parts of compound emulsifying agents, 10 parts of water soluble amino resin solution, 5 parts of polyvinyl acetate wax emulsions; 3 parts of the waterborne organic silicon levelling agent aqueous solution; 8 parts and 25 parts deionized waters of the waterborne organic silicon antifoaming agent aqueous solution, emulsification is 30 minutes under 1500rpm, filters promptly to get water lustering oil.Coat with it and to cross line on 220 ℃ the cardboard and do not have the stubble of dragging, when coating weight is 5g/m
2The time, its abrasion resistance is 700 times.
Embodiment 6
In agitated reactor, add 50 parts of organic-silicon-modified acrylic acid ester emulsions successively; 4 parts of compound emulsifying agents, 10 parts of water soluble amino resin solution, 3 parts of polyvinyl acetate wax emulsions; 4 parts of the waterborne organic silicon levelling agent aqueous solution; 8 parts and 21 parts deionized waters of the waterborne organic silicon antifoaming agent aqueous solution, emulsification is 30 minutes under 2000rpm, filters promptly to get water lustering oil.Coat with it and to cross line on 220 ℃ the cardboard and do not have the stubble of dragging, when coating weight is 4g/m
2The time, its abrasion resistance is 530 times.
Embodiment 7
In agitated reactor, add 55 parts of organic-silicon-modified acrylic acid ester emulsions successively; 5 parts of compound emulsifying agents, 10 parts of water soluble amino resin solution, 2 parts of polyvinyl acetate wax emulsions; 4 parts of the waterborne organic silicon levelling agent aqueous solution; 9 parts and 15 parts deionized waters of the waterborne organic silicon antifoaming agent aqueous solution, emulsification is 30 minutes under 2000rpm, filters promptly to get water lustering oil.Coat with it and to cross line on 220 ℃ the cardboard and do not have the stubble of dragging, when coating weight is 3g/m
2The time, its abrasion resistance is 420 times.
Embodiment 8
In agitated reactor, add 60 parts of organic-silicon-modified acrylic acid ester emulsions successively; 5 parts of compound emulsifying agents, 10 parts of water soluble amino resins, 1 part of polyvinyl acetate wax emulsion; 5 parts of the waterborne organic silicon levelling agent aqueous solution; 10 parts and 9 parts deionized waters of the waterborne organic silicon antifoaming agent aqueous solution, emulsification is 30 minutes under 2000rpm, filters promptly to get water lustering oil.Coat with it and to cross line on 220 ℃ the cardboard and do not have the stubble of dragging, when coating weight is 3.5g/m
2The time, its abrasion resistance is 460 times.
Claims (3)
1. a heat-resistance type prints the paper product water lustering oil, and its weight portion is formed as follows:
Aqueous solution 10-30 part of organic-silicon-modified acrylic acid ester emulsion 20-60 part, compound emulsifying agent 2-5 part, water soluble amino resin, wax emulsion 1-10 part, levelling agent aqueous solution 1-5 part, antifoaming agent aqueous solution 2-10 part and deionized water 9-35 part;
Described organic-silicon-modified acrylic acid ester emulsion gets according to following method preparation:
In agitated reactor, adding 2000kg deionized water, 100g lauryl sodium sulfate, 100g molecular weight successively and be 2000 polyether-type nonionic surfactant and 200g dispersion resin stirs well; 1200g initator benzoyl peroxide is added in 500L acrylate monomer and the 100L organic silicon monomer mixed liquor, take out 5% of gross mass behind its mixing, in the adding agitated reactor; With the speed emulsification of 800-2000rpm 30 minutes; Be warming up to 80-90 ℃ then, reacted 2 hours, remaining mix monomer was splashed into agitated reactor in 2 hours; Be incubated 1 hour again, be chilled to room temperature naturally; Regulate pH to 9-10 with ammoniacal liquor at last, filter and promptly get organic-silicon-modified acrylic acid ester emulsion;
Described dispersion resin is the water soluble polymer resin;
Described organic silicon monomer is one or both the mixture in 4-methacryloxypropyl methyl dimethoxysilane and vinyl three (2-methoxy ethyl) silane;
Described acrylate monomer is the two or more mixture in methyl methacrylate, butyl methacrylate, butyl acrylate, acrylic acid, butyl acrylate and the N methacrylamide;
Described compound emulsifying agent is that lauryl sodium sulfate and molecular weight are that both gross mass marks that 2000 polyether-type nonionic surfactant is hybridly prepared into by mass ratio 1:1 are 5% the aqueous solution;
Described water soluble amino resin is Ineos methyl-etherified amino resins IneosR747;
Described wax emulsion is a polyvinyl acetate wax emulsion;
Described levelling agent is waterborne organic silicon levelling agent silok 8255;
Described antifoaming agent is waterborne organic silicon antifoaming agent SILCOLAPSE C546.
2. water lustering oil according to claim 1 is characterized in that: described dispersion resin is sodium polymethacrylate or polyvinyl alcohol.
3. the preparation method of a water lustering oil according to claim 1 or claim 2, its step is following:
A, organic-silicon-modified preparing acrylate emulsion;
B, water soluble amino resin is dissolved in the deionized water, is mixed with the aqueous solution of 30wt%;
C, silok 8255 usefulness deionized waters are mixed with the aqueous solution of 20wt%, process the waterborne organic silicon levelling agent aqueous solution;
D, SILCOLAPSE C546 system is made antifoaming agent with the aqueous solution that deionized water is made into 5wt%;
E, preparation compound emulsifying agent;
F, add ready organic-silicon-modified acrylic acid ester emulsion, the water soluble amino resin aqueous solution, compound emulsifying agent, wax emulsion, the levelling agent aqueous solution, the antifoaming agent aqueous solution and deionized water in the mixer successively; Dispersion and emulsion is 30 minutes under 800-2000rpm, filters promptly to get.
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| CN107419596A (en) * | 2017-06-17 | 2017-12-01 | 常州环际商贸有限公司 | A kind of printed matter oil polish |
| CN107869049A (en) * | 2017-11-30 | 2018-04-03 | 山东黄河三角洲纺织科技研究院有限公司 | A kind of glossy finishing agent of real wax print cloth cover and its preparation method and application technique |
| CN109439122A (en) * | 2018-09-12 | 2019-03-08 | 安徽康瑞高科新材料技术工程有限公司 | A kind of heat discoloration coating and preparation method thereof |
| CN110406287A (en) * | 2019-08-28 | 2019-11-05 | 蚌埠市比优特包装印务有限责任公司 | The highlighted color face oil glazing process of one kind |
| CN111334152A (en) * | 2020-04-17 | 2020-06-26 | 杭州海维特化工科技有限公司 | Water-based flame-retardant gloss oil and preparation method thereof |
| CN115109480A (en) * | 2022-07-25 | 2022-09-27 | 江苏海晟涂料有限公司 | High-performance middle coating for metal surface |
| CN115323783A (en) * | 2022-09-16 | 2022-11-11 | 福建华锦实业有限公司 | Fluorine-free waterproof finishing agent and preparation method thereof, waterproof fabric and finishing method thereof |
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| CN102719159A (en) * | 2012-07-18 | 2012-10-10 | 常州华狮化工有限公司 | Preparation method of energy-saving environment-friendly low-temperature high light-retaining oil |
| CN102719159B (en) * | 2012-07-18 | 2014-11-12 | 常州华狮化工有限公司 | Preparation method of energy-saving environment-friendly low-temperature high light-retaining oil |
| CN102808360A (en) * | 2012-08-03 | 2012-12-05 | 北京高盟新材料股份有限公司 | Temperature-resistant water-based gloss oil for high-gloss paper products and preparation method of temperature-resistant water-based gloss oil |
| CN102808360B (en) * | 2012-08-03 | 2014-12-03 | 北京高盟新材料股份有限公司 | Temperature-resistant water-based gloss oil for high-gloss paper products and preparation method of temperature-resistant water-based gloss oil |
| CN107419596A (en) * | 2017-06-17 | 2017-12-01 | 常州环际商贸有限公司 | A kind of printed matter oil polish |
| CN107869049A (en) * | 2017-11-30 | 2018-04-03 | 山东黄河三角洲纺织科技研究院有限公司 | A kind of glossy finishing agent of real wax print cloth cover and its preparation method and application technique |
| CN109439122A (en) * | 2018-09-12 | 2019-03-08 | 安徽康瑞高科新材料技术工程有限公司 | A kind of heat discoloration coating and preparation method thereof |
| CN110406287A (en) * | 2019-08-28 | 2019-11-05 | 蚌埠市比优特包装印务有限责任公司 | The highlighted color face oil glazing process of one kind |
| CN111334152A (en) * | 2020-04-17 | 2020-06-26 | 杭州海维特化工科技有限公司 | Water-based flame-retardant gloss oil and preparation method thereof |
| CN111334152B (en) * | 2020-04-17 | 2022-02-18 | 杭州海维特化工科技有限公司 | Water-based flame-retardant gloss oil and preparation method thereof |
| CN115109480A (en) * | 2022-07-25 | 2022-09-27 | 江苏海晟涂料有限公司 | High-performance middle coating for metal surface |
| CN115323783A (en) * | 2022-09-16 | 2022-11-11 | 福建华锦实业有限公司 | Fluorine-free waterproof finishing agent and preparation method thereof, waterproof fabric and finishing method thereof |
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