CN105384864B - A kind of multiple self-crosslinking nano acrylic ester copolymer emulsion of room temperature and preparation method thereof and using the lotion as the aqueous woodware paint of base-material - Google Patents
A kind of multiple self-crosslinking nano acrylic ester copolymer emulsion of room temperature and preparation method thereof and using the lotion as the aqueous woodware paint of base-material Download PDFInfo
- Publication number
- CN105384864B CN105384864B CN201510957083.8A CN201510957083A CN105384864B CN 105384864 B CN105384864 B CN 105384864B CN 201510957083 A CN201510957083 A CN 201510957083A CN 105384864 B CN105384864 B CN 105384864B
- Authority
- CN
- China
- Prior art keywords
- monomer
- room temperature
- emulsion
- acrylate
- ester copolymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000000839 emulsion Substances 0.000 title claims abstract description 82
- 238000004132 cross linking Methods 0.000 title claims abstract description 75
- 239000003973 paint Substances 0.000 title claims abstract description 57
- 229920001577 copolymer Polymers 0.000 title claims abstract description 51
- 238000002360 preparation method Methods 0.000 title claims abstract description 27
- 239000006210 lotion Substances 0.000 title claims abstract description 25
- 239000000463 material Substances 0.000 title claims abstract description 20
- 239000000178 monomer Substances 0.000 claims abstract description 72
- -1 vinylsiloxane Chemical class 0.000 claims abstract description 37
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 32
- 239000006185 dispersion Substances 0.000 claims abstract description 30
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 25
- 239000007788 liquid Substances 0.000 claims abstract description 22
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 19
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims abstract description 16
- 229910052681 coesite Inorganic materials 0.000 claims abstract description 14
- 229910052906 cristobalite Inorganic materials 0.000 claims abstract description 14
- 229910052682 stishovite Inorganic materials 0.000 claims abstract description 14
- 229910052905 tridymite Inorganic materials 0.000 claims abstract description 14
- 238000000034 method Methods 0.000 claims abstract description 11
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims abstract description 10
- 229920002554 vinyl polymer Polymers 0.000 claims abstract description 10
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 claims abstract description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 39
- 239000008367 deionised water Substances 0.000 claims description 31
- 229910021641 deionized water Inorganic materials 0.000 claims description 31
- 239000003995 emulsifying agent Substances 0.000 claims description 31
- 238000003756 stirring Methods 0.000 claims description 25
- 239000002114 nanocomposite Substances 0.000 claims description 17
- 239000007864 aqueous solution Substances 0.000 claims description 16
- 239000000203 mixture Substances 0.000 claims description 15
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 14
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 12
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims description 12
- 238000012986 modification Methods 0.000 claims description 12
- 230000004048 modification Effects 0.000 claims description 12
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 12
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 12
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 claims description 12
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 claims description 11
- 235000019394 potassium persulphate Nutrition 0.000 claims description 11
- 239000002518 antifoaming agent Substances 0.000 claims description 9
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims description 9
- 239000003431 cross linking reagent Substances 0.000 claims description 9
- 239000000243 solution Substances 0.000 claims description 9
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 claims description 8
- 239000002253 acid Substances 0.000 claims description 8
- 229910052921 ammonium sulfate Inorganic materials 0.000 claims description 8
- 235000011130 ammonium sulphate Nutrition 0.000 claims description 8
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 8
- 238000006243 chemical reaction Methods 0.000 claims description 8
- 239000003795 chemical substances by application Substances 0.000 claims description 8
- 239000003921 oil Substances 0.000 claims description 8
- 239000003755 preservative agent Substances 0.000 claims description 8
- 230000002335 preservative effect Effects 0.000 claims description 8
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 7
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims description 7
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 6
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 claims description 6
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 6
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 claims description 6
- 239000000908 ammonium hydroxide Substances 0.000 claims description 6
- 229910001870 ammonium persulfate Inorganic materials 0.000 claims description 6
- 230000015572 biosynthetic process Effects 0.000 claims description 6
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 5
- XDLMVUHYZWKMMD-UHFFFAOYSA-N 3-trimethoxysilylpropyl 2-methylprop-2-enoate Chemical compound CO[Si](OC)(OC)CCCOC(=O)C(C)=C XDLMVUHYZWKMMD-UHFFFAOYSA-N 0.000 claims description 5
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 claims description 5
- 125000000217 alkyl group Chemical group 0.000 claims description 5
- 238000004945 emulsification Methods 0.000 claims description 5
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 claims description 5
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 5
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 claims description 4
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 claims description 4
- 238000009835 boiling Methods 0.000 claims description 4
- 238000004090 dissolution Methods 0.000 claims description 4
- 239000011521 glass Substances 0.000 claims description 4
- OMNKZBIFPJNNIO-UHFFFAOYSA-N n-(2-methyl-4-oxopentan-2-yl)prop-2-enamide Chemical compound CC(=O)CC(C)(C)NC(=O)C=C OMNKZBIFPJNNIO-UHFFFAOYSA-N 0.000 claims description 4
- 238000004321 preservation Methods 0.000 claims description 4
- 238000010792 warming Methods 0.000 claims description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 3
- 238000013019 agitation Methods 0.000 claims description 3
- 125000005233 alkylalcohol group Chemical group 0.000 claims description 3
- 229940056585 ammonium laurate Drugs 0.000 claims description 3
- BTBJBAZGXNKLQC-UHFFFAOYSA-N ammonium lauryl sulfate Chemical compound [NH4+].CCCCCCCCCCCCOS([O-])(=O)=O BTBJBAZGXNKLQC-UHFFFAOYSA-N 0.000 claims description 3
- VJCJAQSLASCYAW-UHFFFAOYSA-N azane;dodecanoic acid Chemical compound [NH4+].CCCCCCCCCCCC([O-])=O VJCJAQSLASCYAW-UHFFFAOYSA-N 0.000 claims description 3
- ZLWPAELISNYYGM-UHFFFAOYSA-N azanium;2-dodecylbenzenesulfonate Chemical compound [NH4+].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O ZLWPAELISNYYGM-UHFFFAOYSA-N 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 claims description 3
- 239000002270 dispersing agent Substances 0.000 claims description 3
- 230000000694 effects Effects 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims description 3
- 239000012875 nonionic emulsifier Substances 0.000 claims description 3
- 239000002243 precursor Substances 0.000 claims description 3
- 239000011734 sodium Substances 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- BTURAGWYSMTVOW-UHFFFAOYSA-M sodium dodecanoate Chemical compound [Na+].CCCCCCCCCCCC([O-])=O BTURAGWYSMTVOW-UHFFFAOYSA-M 0.000 claims description 3
- 229940082004 sodium laurate Drugs 0.000 claims description 3
- 229940057950 sodium laureth sulfate Drugs 0.000 claims description 3
- WVCRHRMRVRZUBN-UHFFFAOYSA-N sodium;2,3,4-tributylphenol Chemical compound [Na].CCCCC1=CC=C(O)C(CCCC)=C1CCCC WVCRHRMRVRZUBN-UHFFFAOYSA-N 0.000 claims description 3
- SXHLENDCVBIJFO-UHFFFAOYSA-M sodium;2-[2-(2-dodecoxyethoxy)ethoxy]ethyl sulfate Chemical compound [Na+].CCCCCCCCCCCCOCCOCCOCCOS([O-])(=O)=O SXHLENDCVBIJFO-UHFFFAOYSA-M 0.000 claims description 3
- 239000002562 thickening agent Substances 0.000 claims description 3
- 238000005303 weighing Methods 0.000 claims description 3
- 239000000080 wetting agent Substances 0.000 claims description 3
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 claims description 2
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 claims description 2
- WBIQQQGBSDOWNP-UHFFFAOYSA-N 2-dodecylbenzenesulfonic acid Chemical compound CCCCCCCCCCCCC1=CC=CC=C1S(O)(=O)=O WBIQQQGBSDOWNP-UHFFFAOYSA-N 0.000 claims description 2
- YEQBHMVRNHTCPJ-UHFFFAOYSA-N 2-methylprop-2-enoic acid;3-oxobutanoic acid Chemical compound CC(=C)C(O)=O.CC(=O)CC(O)=O YEQBHMVRNHTCPJ-UHFFFAOYSA-N 0.000 claims description 2
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 claims description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 2
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 claims description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 2
- 125000002252 acyl group Chemical group 0.000 claims description 2
- 239000001361 adipic acid Substances 0.000 claims description 2
- 235000011037 adipic acid Nutrition 0.000 claims description 2
- 239000003945 anionic surfactant Substances 0.000 claims description 2
- 239000000872 buffer Substances 0.000 claims description 2
- HCOMFAYPHBFMKU-UHFFFAOYSA-N butanedihydrazide Chemical compound NNC(=O)CCC(=O)NN HCOMFAYPHBFMKU-UHFFFAOYSA-N 0.000 claims description 2
- 239000003054 catalyst Substances 0.000 claims description 2
- 229940060296 dodecylbenzenesulfonic acid Drugs 0.000 claims description 2
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical group CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 claims description 2
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 claims description 2
- 150000002170 ethers Chemical class 0.000 claims description 2
- 150000002191 fatty alcohols Chemical class 0.000 claims description 2
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 claims description 2
- 230000007062 hydrolysis Effects 0.000 claims description 2
- 238000006460 hydrolysis reaction Methods 0.000 claims description 2
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 claims description 2
- NZIDBRBFGPQCRY-UHFFFAOYSA-N octyl 2-methylprop-2-enoate Chemical compound CCCCCCCCOC(=O)C(C)=C NZIDBRBFGPQCRY-UHFFFAOYSA-N 0.000 claims description 2
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 claims description 2
- 238000006748 scratching Methods 0.000 claims description 2
- 230000002393 scratching effect Effects 0.000 claims description 2
- 239000011701 zinc Substances 0.000 claims description 2
- 229910052725 zinc Inorganic materials 0.000 claims description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims 4
- 238000010438 heat treatment Methods 0.000 claims 2
- YUYCVXFAYWRXLS-UHFFFAOYSA-N trimethoxysilane Chemical compound CO[SiH](OC)OC YUYCVXFAYWRXLS-UHFFFAOYSA-N 0.000 claims 2
- 241001597008 Nomeidae Species 0.000 claims 1
- 235000021355 Stearic acid Nutrition 0.000 claims 1
- 125000005192 alkyl ethylene group Chemical group 0.000 claims 1
- 229940044197 ammonium sulfate Drugs 0.000 claims 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 claims 1
- ARYZCSRUUPFYMY-UHFFFAOYSA-N methoxysilane Chemical compound CO[SiH3] ARYZCSRUUPFYMY-UHFFFAOYSA-N 0.000 claims 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims 1
- 229940079827 sodium hydrogen sulfite Drugs 0.000 claims 1
- 239000008117 stearic acid Substances 0.000 claims 1
- 239000002904 solvent Substances 0.000 abstract description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract description 5
- 239000004922 lacquer Substances 0.000 abstract description 2
- 230000001681 protective effect Effects 0.000 abstract description 2
- 150000001735 carboxylic acids Chemical class 0.000 abstract 1
- 239000004615 ingredient Substances 0.000 abstract 1
- 238000000576 coating method Methods 0.000 description 15
- 239000011248 coating agent Substances 0.000 description 14
- 229920000642 polymer Polymers 0.000 description 6
- 239000002023 wood Substances 0.000 description 6
- 238000007720 emulsion polymerization reaction Methods 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 5
- 230000007423 decrease Effects 0.000 description 4
- 239000000853 adhesive Substances 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- 238000011161 development Methods 0.000 description 3
- 230000018109 developmental process Effects 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- 238000003786 synthesis reaction Methods 0.000 description 3
- CUDYYMUUJHLCGZ-UHFFFAOYSA-N 2-(2-methoxypropoxy)propan-1-ol Chemical compound COC(C)COC(C)CO CUDYYMUUJHLCGZ-UHFFFAOYSA-N 0.000 description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 2
- 239000012298 atmosphere Substances 0.000 description 2
- 238000009833 condensation Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- 239000006071 cream Substances 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 238000011065 in-situ storage Methods 0.000 description 2
- 239000003999 initiator Substances 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 238000012827 research and development Methods 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
- RSWGJHLUYNHPMX-UHFFFAOYSA-N 1,4a-dimethyl-7-propan-2-yl-2,3,4,4b,5,6,10,10a-octahydrophenanthrene-1-carboxylic acid Chemical compound C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- PFWRHNFNTNMKPC-UHFFFAOYSA-N 4-trimethoxysilylbutan-2-yl prop-2-enoate Chemical compound CO[Si](OC)(OC)CCC(C)OC(=O)C=C PFWRHNFNTNMKPC-UHFFFAOYSA-N 0.000 description 1
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 description 1
- 229910000013 Ammonium bicarbonate Inorganic materials 0.000 description 1
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 description 1
- 206010053615 Thermal burn Diseases 0.000 description 1
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 1
- FWUVTRZUVDRJJI-UHFFFAOYSA-N [O].C(=C)[Si] Chemical compound [O].C(=C)[Si] FWUVTRZUVDRJJI-UHFFFAOYSA-N 0.000 description 1
- 238000007171 acid catalysis Methods 0.000 description 1
- 125000005396 acrylic acid ester group Chemical group 0.000 description 1
- IBVAQQYNSHJXBV-UHFFFAOYSA-N adipic acid dihydrazide Chemical compound NNC(=O)CCCCC(=O)NN IBVAQQYNSHJXBV-UHFFFAOYSA-N 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 235000012538 ammonium bicarbonate Nutrition 0.000 description 1
- 239000001099 ammonium carbonate Substances 0.000 description 1
- 229940063953 ammonium lauryl sulfate Drugs 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- AHVOFPQVUVXHNL-UHFFFAOYSA-N butyl prop-2-enoate;methyl 2-methylprop-2-enoate Chemical compound COC(=O)C(C)=C.CCCCOC(=O)C=C AHVOFPQVUVXHNL-UHFFFAOYSA-N 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000004567 concrete Substances 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 239000011258 core-shell material Substances 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 239000002552 dosage form Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 1
- 235000003642 hunger Nutrition 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 125000005397 methacrylic acid ester group Chemical group 0.000 description 1
- 150000004702 methyl esters Chemical class 0.000 description 1
- 239000000693 micelle Substances 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 229910000403 monosodium phosphate Inorganic materials 0.000 description 1
- 235000019799 monosodium phosphate Nutrition 0.000 description 1
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical group CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- VDGJOQCBCPGFFD-UHFFFAOYSA-N oxygen(2-) silicon(4+) titanium(4+) Chemical group [Si+4].[O-2].[O-2].[Ti+4] VDGJOQCBCPGFFD-UHFFFAOYSA-N 0.000 description 1
- 239000003002 pH adjusting agent Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000003678 scratch resistant effect Effects 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 230000036301 sexual development Effects 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- AJPJDKMHJJGVTQ-UHFFFAOYSA-M sodium dihydrogen phosphate Chemical compound [Na+].OP(O)([O-])=O AJPJDKMHJJGVTQ-UHFFFAOYSA-M 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000003827 upregulation Effects 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
- C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
- C08F2/26—Emulsion polymerisation with the aid of emulsifying agents anionic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
- C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
- C08F2/30—Emulsion polymerisation with the aid of emulsifying agents non-ionic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/44—Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/04—Ingredients treated with organic substances
- C08K9/06—Ingredients treated with organic substances with silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/10—Homopolymers or copolymers of methacrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/10—Homopolymers or copolymers of methacrylic acid esters
- C09D133/12—Homopolymers or copolymers of methyl methacrylate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1808—C8-(meth)acrylate, e.g. isooctyl (meth)acrylate or 2-ethylhexyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/10—Transparent films; Clear coatings; Transparent materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2312/00—Crosslinking
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
The embodiment of the invention discloses multiple self-crosslinking nano acrylic ester copolymer emulsion of a kind of room temperature and preparation method thereof and using the lotion as the aqueous woodware paint of base-material, the synthetic ingredient for preparing of the lotion includes vinyl unsaturated carboxylic acid, methacrylate, acrylate, styrene, modified SiO2With dispersion liquid, cross-linking monomer A, vinylsiloxane, the cross-linking monomer B of acrylate monomer etc., and by introducing modified Nano SiO2, cross-linking monomer, three kinds of cross-linking methods of vinylsiloxane through the multiple self-crosslinking nano acrylic ester copolymer emulsion of room temperature preparation in; three kinds of crosslinking technologicals mutually cooperate with; so that finally forming fine and close protective film as aqueous woodware paint prepared by base-material using the lotion; with excellent water-fast, resistance to alcohol, scratch resistance, resistant to high temperatures after-tack and relatively high hardness, paint film property can compare favourably with solvent type furniture lacquer.
Description
Technical field
The present invention relates to a kind of lotion and using the lotion as the aqueous woodware paint of base-material more particularly to a kind of room temperature it is multiple from
Cross-linked acrylic acid ester copolymer emulsion and using the lotion as the aqueous woodware paint of base-material, belongs to environmental protection base Material Field.
Background technique
China is manufacture type big country, with economic expansion sexual development, the whole nation of the severe haze of environmental pollution and atmosphere
Property outburst seriously threatened the environment that compatriots depend on for existence, and the VOC in coating and adhesive leads to the serious haze of atmosphere
The vertical chief culprit of crime, is the most important thing for causing haze.Although comprehensive performance after current woodcare paint Water-borne modification is still molten not as good as traditional
Dosage form paint, but because its is pollution-free, Environmental Safety and meets national environmental protection policy, it has also become the inevitable development trend of woodcare paint,
Especially China's new legislation for having promulgated coating industry in the end of the year 2014 and new legislation are aqueous after on 2 1st, 2015 comes into effect
The Water-borne modification of coating or coating has become the key of Enterprise's Sustainable Development, and former solvent based coating enterprise will gradually be eliminated.Numerous cities
City has also accordingly promulgated tightened up regulation, and solvent based coating and solvent type adhesive have been tightly controlled use, therefore develop
It develops excellent combination property, substitute the aqueous coating resins of traditional solvent-borne woodcare paint with boundless application prospect and society
It can benefit.
At present aqueous woodware paint base resin material research and development and application still based on emulsified acrylic acid ester copolymer,
Compared with solvent wood coatings, water-borne wood coating is in the side such as coating film gloss degree, richness, hardness, scratch resistance and wearability
Face all has a certain distance, this is also to restrict the major reason of water-borne wood coating development always, therefore how to improve water and milk
The performances such as hardness, scratch resistance, wearability, gloss and the rate of drying of type acrylate copolymer become current woodcare paint Water-borne modification
Key technology factor.It is made with Diacetone Acrylamide/adipic dihydrazide cross-linking system merely in patent CN201410238123
Lotion cause crosslink density low, thus with the hardness of woodcare paint made from such lotion since dosage of crosslinking agent cannot be too big
Only only reach to HB grades.Patent CN200910187305 relates to a kind of core-shell emulsion, wherein vinylsiloxane is added in shell
The aqueous woodware paint of preparation, but final hardness also can only achieve H grades, the requirement far below Wooden furniture paint to hardness.Even if
DSM N. V. leading in the world, hardness, the scratch resistance of the commercially available aqueous woodware paint acrylate copolymer emulsion of the Dow Chemical Company etc.
Performance is also not as good as traditional solvent type woodcare paint.
Due to Nano-meter SiO_22High reaction activity, high-specific surface area and excellent thixotropy, cause make it paint field
Using a kind of most nano materials.Nano-meter SiO_22Can be improved in coating the hardness of organic polymer, improve its wearability,
Scratch resistance, ultravioletlight screening performance or even thixotropy have become industry common recognition.But how powder nanometer silica is aqueous
Realize that good dispersion is always worldwide problem in coating.Therefore, many R&D institutions are all being dedicated to in-situ nano
How the exploitation of enhancing technology, i.e., be produced in situ in nanometer titanium dioxide silicon structure in acrylic acid ester emulsion polymerization process, or how
Preparing emulsion-type nano silica composite dispersion becomes the developing direction of coating industry.Research has shown that in aqueous wooden ware
Nano-meter SiO_2 is introduced in paint lotion2Preparation takes into account organic and inorganic characteristic nano-composite emulsion, realizes Nano-meter SiO_22In acrylic acid
Fine dispersion in ester polymer obtains high rigidity, high transparency, Qiang Shushui, the wood protection of the excellent combination properties such as high heat resistance
Material.
Reasonable application of the crosslinking technological in coating simultaneously is also a kind of strong hand for improving woodcare paint paint film comprehensive performance
Section.Introducing in polymer molecular chain can have been adjusted in lotion and pH value and then crosslinking has been added singly with post-crosslinking function monomer
Body mutually merges between latex particle as system pH gradually decreases, the function list in cross-linking monomer and polymer molecular chain
Self-crosslinking occurs for body, and the mode of this self-crosslinking improves hardness of paint film, scratch resistance capability significantly.But if using not conforming to
Reason, the internal stress that will lead to paint film and substrate increase, and not only adhesive force declines, and water-resistant capacity can also simultaneously decline.
Summary of the invention
In order to solve the above technical problems, a kind of multiple self-crosslinking acrylic ester copolymerization of room temperature is provided in the embodiment of the present invention
Object lotion and preparation method thereof, and aqueous woodware paint is prepared using the acrylate copolymer emulsion as base-material, it finally obtains high hard
Degree, high transparency, Qiang Shushui, the aqueous woodware paint of the excellent combination properties such as high heat resistance.
The multiple self-crosslinking nano acrylic ester copolymer emulsion of a kind of room temperature provided in the embodiment of the present invention, by following
The preparation synthesis of parts by weight substance:
40~50 parts of deionized water；0.1~1 part of emulsifier A；0.1~1 part of emulsifier B；PH buffer 0.02~
0.09 part；0.3 part of initiator；0.3~0.9 part of vinyl unsaturated carboxylic acid；25~35 parts of methacrylate；Acrylate 4
~6 parts；4~6 parts of styrene；Modified SiO2With 8~12 parts of dispersion liquid of acrylate monomer；Cross-linking monomer A 0.3~1.0
Part；0.1~0.9 part of vinylsiloxane；0.3~1.0 part of cross-linking monomer B；0.04 part of tert-butyl hydroperoxide；Bisulfite
0.04 part of sodium；0.05 part of defoaming agent；0.05 part and 1 part of ammonium hydroxide of preservative.
Preferably, the multiple self-crosslinking nano acrylic ester copolymer emulsion of above-mentioned room temperature, wherein the modified SiO2With
The dispersion liquid of acrylate monomer is using ethyl orthosilicate as silica precursor, and acrylate monomer is decentralized medium, dilute
Sulfuric acid is catalyst, and it is small to be stirred at room temperature 24 as active graft modification agent for γ-methacryloxypropyl trimethoxy silane
When hydrolysis be made.
Preferably, the multiple self-crosslinking nano acrylic ester copolymer emulsion of above-mentioned room temperature, wherein the cross-linking monomer A
Selected from one of Diacetone Acrylamide, glycidyl methacrylate, acetoacetate methacrylic acid glycol ester or
It is several；The cross-linking monomer B selects one of two hydrazine of adipic acid, carbon acid dihydrazide, careless acid dihydrazide, succinic acid hydrazide ii.
Preferably, the multiple self-crosslinking nano acrylic ester copolymer emulsion of above-mentioned room temperature, wherein the vinyl silicon oxygen
Alkane is selected from vinyltriethoxysilane, vinyltrimethoxysilane, γ-methacryloxypropyl trimethoxy silane
One of.
Preferably, the multiple self-crosslinking nano acrylic ester copolymer emulsion of above-mentioned room temperature, wherein the vinyl insatiable hunger
One of acrylic acid, methacrylic acid, itaconic acid are selected from carboxylic acid.
Preferably, the multiple self-crosslinking nano acrylic ester copolymer emulsion of above-mentioned room temperature, wherein the methacrylic acid
Ester is selected from one of butyl methacrylate, methyl methacrylate, 2-Propenoic acid, 2-methyl-, octyl ester.
Preferably, the multiple self-crosslinking nano acrylic ester copolymer emulsion of above-mentioned room temperature, wherein the acrylate choosing
From one of butyl acrylate, ethyl acrylate, 2-ethyl hexyl acrylate.
Preferably, the multiple self-crosslinking nano acrylic ester copolymer emulsion of above-mentioned room temperature, wherein the emulsifier A is
Anionic surfactant is selected from sodium laureth sulfate, alkyl phenol polyoxyethylene ether ammonium sulfate, detergent alkylate
Sulfonic acid, dodecyl benzene sulfonic acid ammonium, sodium laurate, ammonium laurate, lauryl sodium sulfate, ammonium lauryl sulfate, alkyl two
Phenylate disodium sulfonate salt, alkyl polyoxyethylene acyl sodium sulfonate, tributyl phenol sodium sulfonate of ethoxylated, allyl polyethenoxy ether
One of derivative ammonium sulfate and allyl polyethenoxy ether ammonium sulfate；The emulsifier B is selected from alkyl polyoxyethylene ether system
Column environment-friendly type nonionic emulsifier, alkyl alcohol ethoxylates series, the compound of alkyl phenol polyoxyethylene ether, fatty alcohol polyoxy
One of vinethene, alkyl phenol polyoxyethylene ether.
Preferably, the multiple self-crosslinking nano acrylic ester copolymer emulsion of above-mentioned room temperature, wherein the pH adjusting agent
For selected from one of sodium bicarbonate, ammonium hydrogen carbonate, sodium dihydrogen phosphate；The initiator is selected from ammonium persulfate, potassium peroxydisulfate
Or one of sodium peroxydisulfate.
The method for preparing the multiple self-crosslinking nano acrylic ester copolymer emulsion of above-mentioned room temperature, includes the following steps:
(1) modified SiO is prepared2With the dispersion liquid of acrylate monomer: emulsifier A and deionized water are weighed in beaker,
Sufficiently dissolution is stirred with glass bar, obtains emulsifier aqueous solution；Then suitable ethyl orthosilicate, γ-methacryloxypropyl are weighed
Base propyl trimethoxy silicane is dissolved in the mix monomer of methyl methacrylate and butyl acrylate, obtains oil mixture；
Then under being vigorously stirred of high-shear homogenizer, the oil mixture is added dropwise into above-mentioned emulsifier aqueous solution, is used in combination
Dilute sulfuric acid adjusts pH value, continues high speed dispersion 30min, is transferred in the ground boiling flask with plug therewith, at room temperature magnetic force
Stirring 24 hours, reacts it sufficiently, obtains modified SiO2With the dispersion liquid of acrylate monomer；
(2) it prepares nano-composite emulsion: deionized water is added in four round flask, is subsequently placed in stirring in water bath and rises
Temperature takes the potassium peroxydisulfate of 2/5 reaction dosage to be dissolved in 5g deionized water, adds round-bottomed flask, then when temperature reaches 75 DEG C
At the uniform velocity 1/5 modification SiO of a dropping step (1) preparation in 10min2Enter round-bottomed flask with the dispersion liquid of acrylate monomer, to
When blue light occurs in reaction solution in flask, remaining 3/5 potassium peroxydisulfate is dissolved in 5g deionized water, then by its with it is remaining
Modified SiO2It is added dropwise in round-bottomed flask simultaneously with the dispersion liquid of acrylate monomer, is dripped in about 3 hours, then keep the temperature 1
Hour, nano-composite emulsion is made；
(3) prepare monomer pre-emulsion: by deionized water, emulsifier A, emulsifier B and vinyl unsaturated carboxylic acid,
Methacrylate, acrylate, styrene and crosslinking agent A successively put into monomer pre-emulsification tank, and high-speed stirred emulsifies 1 hour shape
At monomer pre-emulsion；
(4) it prepares the multiple self-crosslinking nano acrylic ester copolymer emulsion of room temperature: adding deionized water, metering into polymeric kettle
The step of (2) preparation nano-composite emulsion, open stirring, be warming up to 80 DEG C -84 DEG C, after stablizing 15min, while a dropping step
(3) the monomer pre-emulsion and ammonium persulfate solution prepared in stops being added dropwise when being added drop-wise to residual monomer pre-emulsion 1/5；
Vinylsiloxane monomer stirring 10min is added to continue to be added dropwise later, controls entire time for adding in 210min-240min,
Dropping temperature is controlled at 78 DEG C -82 DEG C；1 hour is kept the temperature under dropping temperature after being added dropwise；Be cooled to after heat preservation 60 DEG C-
70 DEG C, add tert-butyl hydroperoxide aqueous solution, aqueous solution of sodium bisulfite is added dropwise after 10min, time for adding 30min is added dropwise
Temperature control at 63 DEG C -67 DEG C, subsequent continuation of insurance temperature 30min is added dropwise, be finally cooled to 40 DEG C hereinafter, with ammonium hydroxide adjusting pH to
7-9, be added metering crosslinking agent B stirring 30min, then plus defoaming agent, preservative after, with 200-500 mesh filter screen filter, preparation room
The multiple self-crosslinking nano acrylic ester copolymer emulsion of temperature.
It, should using the aqueous woodware paint that the multiple self-crosslinking nano acrylic ester copolymer emulsion of above-mentioned room temperature is prepared as base-material
The composition of aqueous woodware paint includes each component of following parts by weight:
16 parts of deionized water；75 parts of lotion；0.3 part of wetting agent；0.3 part of levelling agent；4 parts of dipropylene；Dipropyl two
4 parts of alcohol methyl ether；0.3 part of thickener；0.05 part of defoaming agent；0.05 part of preservative；0.1 part of dispersing agent；2.5 parts of scratching resistant and hard
5 parts of resin acid zinc.
The present invention combines silicone hydroxyl condensation cross-linking technology with ketone hydrazine crosslinking technological, solves because of excessive vinyl silicon oxygen
The introducing of alkane cause remaining silicone hydroxyl excessive and the problem of water resistance decline, wet adhesion decline；It solves simultaneously excessive
The problem of resistance to water-white ability difference caused by the introducing of Diacetone Acrylamide；The multiple self-crosslinking nano acrylic ester copolymer of room temperature
The internal silica hydrolyzed of micelle of lotion cream floats on surface on the procedure division that aqueous woodware paint forms a film, due to silicon
The hardness of aqueous woodware paint paint film, easy to polish property can be enhanced in particularity, its presence；Preparing nano acrylic ester copolymer
Polymerizable self-cross linking monomer during lotion cream, can introduce polymer chain and form flexible crosslinkable polymer, be crosslinked
Elastomeric polymer i.e. be easily deformed and have good resilience, so nano acrylic ester copolymer emulsion of the invention oneself
Crosslinked emulsions film adhesion strength with higher.
Compared with the existing technology, the invention has the following beneficial effects:
(1) Nano-meter SiO_2 is introduced in the multiple self-crosslinking nano acrylic ester copolymer emulsion of room temperature2Preparation have both it is organic and
The acrylic emulsion of inorganic characteristic, then prepares aqueous woodware paint by base-material of the lotion, and finally obtained woodcare paint paint film is high
Hardness, high transparency, Qiang Shushui, high heat resistance；
(2) the introducing crosslinked monomer in the multiple self-crosslinking nano acrylic ester copolymer emulsion polymerization process of room temperature, then
Aqueous woodware paint is prepared using the lotion as base-material, further occurrence is crosslinked and forms fine and close protection in woodcare paint film forming procedure
Film further improves the hardness of woodcare paint paint film, water resistance, resistance to alcohol, resistant to high temperatures after-tacks and scratch resistant ability；
(3) vinylsiloxane is introduced in the later period of the multiple self-crosslinking nano acrylic ester copolymer emulsion polymerization of room temperature,
Then aqueous woodware paint is prepared using the lotion as base-material, in woodcare paint film forming procedure, unhydrolysed part silicon oxygen bond and pigment, base
Material and the silicon oxygen bond condensation of itself, further increase the crosslink density of woodcare paint paint film；
(4) three of the above cross-linking method through the multiple self-crosslinking nano acrylic ester copolymer emulsion of room temperature preparation in,
Three kinds of crosslinking technologicals mutually cooperate with, and finally form fine and close protective film as aqueous woodware paint prepared by base-material using the lotion, have
Excellent water-fast, resistance to alcohol, resistant to high temperatures after-tacks and relatively high hardness, paint film property can be with solvent type furniture lacquers scratch resistance
It compares favourably.
Specific embodiment
Below in conjunction with the table in the embodiment of the present invention and embodiment, technical solution in the embodiment of the present invention into
Clear, the complete description of row, it is clear that described embodiments are only a part of the embodiments of the present invention, rather than whole realities
Apply example.Based on the embodiments of the present invention, those of ordinary skill in the art are obtained without creative efforts
Every other embodiment, shall fall within the protection scope of the present invention.
The present invention is with ethyl orthosilicate (TS) for SiO2Precursor, acrylate (BA) monomer are decentralized medium, γ-methyl
Acryloyloxypropyltrimethoxysilane (A174) is active graft modification agent, is made under dilute sulfuric acid catalysis with acrylate
For the SiO of continuous phase2/ acrylate monomer dispersion liquid (TM) then carries out emulsion polymerization, system by seed monomer of the dispersion liquid
It is able to the nano-composite emulsion that polyacrylate is carrier, then again using the nano-composite emulsion as seed, acrylic acid is added
Ester, methacrylate, styrene, cross-linking monomer, vinyl unsaturated carboxylic acid mix monomer, can through seeded emulsion polymerization
Obtain a kind of multiple self-crosslinking nano acrylic ester copolymer emulsion of room temperature；And using the acrylate copolymer emulsion as base-material system
Standby aqueous woodware paint, finally obtains high rigidity, high transparency, Qiang Shushui, the aqueous woodware paint of the excellent combination properties such as high heat resistance.
Embodiment 1
The multiple self-crosslinking nano acrylic ester copolymer emulsion of room temperature is prepared, dosage of each component is as shown in table 1:
Table 1
(1) monomer pre-emulsion is prepared: by metering system described in deionized water, emulsifier A, emulsifier B and table 1
Acid, methyl methacrylate, butyl acrylate, styrene and crosslinking agent A successively put into monomer pre-emulsification tank, high-speed stirred emulsification
1 hour formation monomer pre-emulsion；
(2) the multiple self-crosslinking nano acrylic ester copolymer emulsion of room temperature is prepared: to polymeric kettle plus deionized water, metering
Nano-composite emulsion opens stirring, is warming up to 80 DEG C -84 DEG C, after stablizing 15min, while the monomer prepared in a dropping step (1)
Pre-emulsion and ammonium persulfate solution stop being added dropwise when being added drop-wise to residual monomer pre-emulsion 1/5；Three second of vinyl is added
Continue to be added dropwise after oxysilane monomer stirring 10min, controls entire time for adding in 210min-240min, dropping temperature
Control is at 78 DEG C -82 DEG C；1 hour is kept the temperature under dropping temperature after being added dropwise；It is cooled to 60 DEG C -70 DEG C after heat preservation, adds
Aqueous solution of sodium bisulfite, time for adding 30min, dropping temperature control are added dropwise after 10min for tert-butyl hydroperoxide aqueous solution
At 63 DEG C -67 DEG C, subsequent continuation of insurance temperature 30min is added dropwise, is finally cooled to 40 DEG C hereinafter, adjusting pH to 7-9, addition with ammonium hydroxide
The crosslinking agent B of metering stirs 30min, then plus defoaming agent, preservative after, filtered with 200-500 mesh filter screen, preparation room temperature it is multiple from
Crosslinking nano acrylate copolymer emulsion.
The preparation method is the same as that of Example 1 for the multiple self-crosslinking nano acrylic ester copolymer emulsion of the former room temperature of embodiment 2-6, tool
Body raw material and dosage are as shown in table 1.Wherein emulsifier A is also an option that sodium laureth sulfate, alkyl phenol polyoxy
Ethylene ether ammonium sulfate, dodecyl benzene sulfonic acid, dodecyl benzene sulfonic acid ammonium, sodium laurate, ammonium laurate, dodecyl sulphate
Ammonium, alkyl diphenyl ether disodium sulfonate salt, tributyl phenol sodium sulfonate of ethoxylated, allyl polyethenoxy ether derivative ammonium sulfate
One or more of with allyl polyethenoxy ether ammonium sulfate；Emulsifier B is also an option that alkyl polyoxyethylene ether series of loops
Guarantor's type nonionic emulsifier, alkyl alcohol ethoxylates series, the compound of alkyl phenol polyoxyethylene ether, aliphatic alcohol polyethenoxy
One of ether, alkyl phenol polyoxyethylene ether are several；Cross-linking monomer A is also an option that acetoacetate methacrylic acid second two
Alcohol ester；The cross-linking monomer B is also an option that one or both of carbon acid dihydrazide, careless acid dihydrazide.
Wherein, the weight consumption of each component needed for the preparation of nano-composite emulsion described in embodiment 1-6 such as the following table 2 institute
Show:
Table 2
| MMA | BA | TS | A174 | Emulsifier A | Deionized water | PPS | Deionized water |
| 30.00 | 30.00 | 15.00 | 2.00 | 3.50 | 65.00 | 0.5 | 170 |
Nano-composite emulsion the preparation method is as follows:
(1) modified SiO is prepared2With the dispersion liquid (TM) of acrylate monomer: in 100mL beaker weighing emulsifier
A3.50g and deionized water 65.00g stirs sufficiently dissolution with glass bar, obtains emulsifier aqueous solution；Then 15.00g is weighed just
Silester (TS), γ-methacryloxypropyl trimethoxy silane (A174) of 2.00g are dissolved in the methyl-prop of 30.00g
In the mix monomer of the butyl acrylate (BA) of e pioic acid methyl ester (MMA) and 30.00g, oil mixture is obtained；Then equal in high speed
Under being vigorously stirred of matter machine, the oil mixture is added dropwise into above-mentioned emulsifier aqueous solution, and adjusts pH with dilute sulfuric acid
Value continues high speed dispersion 20min, is transferred in the 150mL ground boiling flask with plug therewith, magnetic agitation 24 is small at room temperature
When, it reacts it sufficiently, obtains preparing modified SiO2With the dispersion liquid of acrylate monomer, it is denoted as TM；
(2) it prepares nano-composite emulsion: 160g deionized water is added in 250mL four round flask, is subsequently placed in water-bath
It stirs and heats up, when temperature reaches 75 DEG C, 2/5 potassium peroxydisulfate (PPS) is taken to be dissolved in 5g deionized water, add round bottom burning
Bottle, 1/5 modification SiO is at the uniform velocity added dropwise in 10min2With the dispersion liquid (TM) of acrylate monomer, when there is blue light in reaction solution,
Remaining 3/5 PPS is dissolved in 5g deionized water, is then added dropwise to it in round-bottomed flask simultaneously with remaining TM, about 3 is small
When it is interior drip, then keep the temperature 1 hour, form the nano-composite emulsion of curing, the emulsion solid content 20% or so.
Embodiment 7
Waterborne wood is prepared as base-material using the multiple self-crosslinking acrylic ester copolymer emulsion of room temperature of above-described embodiment 1-6 synthesis
Device paint.The concrete component and dosage of the aqueous woodware paint are as shown in table 3.
Table 3
(1) lotion of the formula ratio that it is as shown in the table, dispersing agent, wetting agent, levelling agent, anti-zoned is added in a stirred tank
Hurt agent, zinc stearate is added in above-mentioned stirred tank, with revolving speed 900r/min stir 10min, obtain uniform dispersion；
(2) coalescing agent dipropylene glycol methyl ether (DPM), the dipropylene of formula ratio are taken in another stirred tank
(DPnB), deionized water and thickener RS-8W (polyurethane-modified class) are added in stirred tank and stir 10min, obtain mixed liquor；
(3) mixed liquor in step (2) in stirred tank is slowly added into step (1) stirred tank, with revolving speed 700r/
Min is added while stirring, stirs 10min；It is eventually adding defoaming agent, is again stirring for 10min, obtains uniform aqueous woodware paint,
It filters and packages.
Embodiment 8-12 preparation prepares Waterborne wood by base-material of the multiple self-crosslinking nano acrylic ester copolymer emulsion of room temperature
For the preparation method of device paint with embodiment 7, specific raw material and dosage are as shown in table 3.
Its performance detection knot of the multiple self-crosslinking nano acrylic ester copolymer emulsion of room temperature of 1-6 of embodiment of the present invention preparation
Fruit parameter is shown in Table 4, and the aqueous woodware paint performance test results prepared using this lotion as substrate are as shown in table 5.
Table 4
Table 5
By table 4 and table 5 it is found that using the preparation of multiple self-crosslinking technology aqueous woodware paint either pencil hardness, still
Scratch hardness sells that market product is good than now, while also to sell market product than now good for the wear-resisting property of paint film, in addition fixes seed
The amount of lotion changes the collocation of cross-linking monomer A and B and vinylsiloxane, and no matter how cross-linking monomer A and B change, with γ-
The lotion of methacryloxypropyl trimethoxy silane collocation synthesis, the hardness of final paint film have excellent all in 3H
Different water-fast, resistance to boiled water scald do not whiten, resistance to alcohol does not whiten, wearability is high, resist blocking and that and relatively high gloss and richness, with
Solvent type furniture paint performance is suitable.
Claims (8)
1. a kind of multiple self-crosslinking nano acrylic ester copolymer emulsion of room temperature characterized by comprising
40~50 parts of deionized water；0.1~1 part of emulsifier A；0.1~1 part of emulsifier B；PH buffer 0.02~0.09
Part；0.3 part of ammonium persulfate；0.3~0.9 part of vinyl unsaturated carboxylic acid；25~35 parts of methacrylate；Acrylate 4~6
Part；4~6 parts of styrene；Modified SiO2With 8~12 parts of dispersion liquid of acrylate monomer；0.3~1.0 part of cross-linking monomer A；Second
0.5~0.9 part of alkenyl siloxane；0.3~1.0 part of cross-linking monomer B；0.04 part of tert-butyl hydroperoxide；Sodium hydrogensulfite 0.04
Part；0.05 part of defoaming agent；0.05 part and 1 part of ammonium hydroxide of preservative；
The modification SiO2Dispersion liquid with acrylate monomer is the acrylic acid using ethyl orthosilicate as silica precursor
Ester monomer is decentralized medium, and dilute sulfuric acid is catalyst, and γ-methacryloxypropyl trimethoxy silane is as activity grafting
Modifying agent is stirred at room temperature hydrolysis in 24 hours and is made；
The cross-linking monomer A is selected from Diacetone Acrylamide, glycidyl methacrylate, acetoacetate methacrylic acid second
One of diol ester；The cross-linking monomer B select two hydrazine of adipic acid, carbon acid dihydrazide, careless acid dihydrazide, in succinic acid hydrazide ii
One kind；
The multiple self-crosslinking nano acrylic ester copolymer emulsion of room temperature is prepared by following methods；
(1) modified SiO is prepared2With the dispersion liquid of acrylate monomer: weighing emulsifier A and deionized water in beaker, use glass
Stick stirring sufficiently dissolution, obtains emulsifier aqueous solution；Then suitable ethyl orthosilicate, γ-methacryloxypropyl are weighed
Trimethoxy silane is dissolved in the mix monomer of methyl methacrylate and butyl acrylate, obtains oil mixture；Then exist
Under being vigorously stirred of high-shear homogenizer, the oil mixture is added dropwise into above-mentioned emulsifier aqueous solution, and use dilute sulfuric acid
PH value is adjusted, high speed dispersion 30min is continued, is transferred in the ground boiling flask with plug therewith, at room temperature magnetic agitation 24
Hour, it reacts it sufficiently, obtains modified SiO2With the dispersion liquid of acrylate monomer；
(2) it prepares nano-composite emulsion: deionized water is added in four round flask, is subsequently placed in stirring in water bath and heats up, when
When temperature reaches 75 DEG C, the potassium peroxydisulfate of 2/5 reaction dosage is taken to be dissolved in 5g deionized water, adds round-bottomed flask, subsequent 10min
Inside at the uniform velocity 1/5 modification SiO of a dropping step (1) preparation2Enter round-bottomed flask with the dispersion liquid of acrylate monomer, in flask
When blue light occurs in reaction solution, remaining 3/5 potassium peroxydisulfate is dissolved in 5g deionized water, then by itself and remaining modification
SiO2It is added dropwise in round-bottomed flask with the dispersion liquid of acrylate monomer, is dripped in about 3 hours simultaneously, then keep the temperature 1 hour,
Nano-composite emulsion is made；
(3) monomer pre-emulsion is prepared: by deionized water, emulsifier A, emulsifier B and vinyl unsaturated carboxylic acid, methyl
Acrylate, acrylate, styrene and crosslinking agent A successively put into monomer pre-emulsification tank, and it is single that high-speed stirred emulsifies formation in 1 hour
Body pre-emulsion；
(4) it prepares the multiple self-crosslinking nano acrylic ester copolymer emulsion of room temperature: adding deionized water, the step of metering into polymeric kettle
Suddenly the nano-composite emulsion of (2) preparation, opens stirring, is warming up to 80 DEG C -84 DEG C, after stablizing 15min, while a dropping step (3)
The monomer pre-emulsion and ammonium persulfate solution of middle preparation stop being added dropwise when being added drop-wise to residual monomer pre-emulsion 1/5；Add
Enter vinylsiloxane monomer stirring 10min to continue to be added dropwise later, controls entire time for adding in 210min-240min, drip
Heating degree is controlled at 78 DEG C -82 DEG C；1 hour is kept the temperature under dropping temperature after being added dropwise；60 DEG C -70 is cooled to after heat preservation
DEG C, add tert-butyl hydroperoxide aqueous solution, aqueous solution of sodium bisulfite is added dropwise after 10min, temperature is added dropwise in time for adding 30min
Subsequent continuation of insurance temperature 30min is added dropwise at 63 DEG C -67 DEG C in degree control, is finally cooled to 40 DEG C hereinafter, adjusting pH to 7- with ammonium hydroxide
9, be added metering crosslinking agent B stirring 30min, then plus defoaming agent, preservative after, with 200-500 mesh filter screen filter, be made room temperature
Multiple self-crosslinking nano acrylic ester copolymer emulsion.
2. the multiple self-crosslinking nano acrylic ester copolymer emulsion of room temperature according to claim 1, which is characterized in that described
Vinylsiloxane is selected from vinyltriethoxysilane, vinyltrimethoxysilane, γ-methacryloxypropyl three
One of methoxy silane.
3. the multiple self-crosslinking nano acrylic ester copolymer emulsion of room temperature according to claim 1, which is characterized in that described
Vinyl unsaturated carboxylic acid is selected from one of acrylic acid, methacrylic acid, itaconic acid.
4. the multiple self-crosslinking nano acrylic ester copolymer emulsion of room temperature according to claim 1, which is characterized in that described
Methacrylate is selected from one of butyl methacrylate, methyl methacrylate, 2-Propenoic acid, 2-methyl-, octyl ester.
5. the multiple self-crosslinking nano acrylic ester copolymer emulsion of room temperature according to claim 1, which is characterized in that described
Acrylate is selected from one of butyl acrylate, ethyl acrylate, 2-ethyl hexyl acrylate.
6. the multiple self-crosslinking nano acrylic ester copolymer emulsion of room temperature according to claim 1, which is characterized in that described
Emulsifier A is anionic surfactant, is selected from sodium laureth sulfate, sodium laurate, ammonium laurate, alkyl phenol
Polyoxyethylene ether ammonium sulfate, dodecyl benzene sulfonic acid, dodecyl benzene sulfonic acid ammonium, lauryl sodium sulfate, dodecyl sulphate
Ammonium, alkyl diphenyl ether disodium sulfonate salt, alkyl polyoxyethylene acyl sodium sulfonate, tributyl phenol sodium sulfonate of ethoxylated, allyl
One of polyoxyethylene ether derivant ammonium sulfate and allyl polyethenoxy ether ammonium sulfate；The emulsifier B is poly- selected from alkyl
Ethylene oxide ether series environment-friendly type nonionic emulsifier, alkyl alcohol ethoxylates series, alkyl phenol polyoxyethylene ether compound,
One of fatty alcohol polyoxyethylene ether, alkyl phenol polyoxyethylene ether.
7. preparing the side of the multiple self-crosslinking nano acrylic ester copolymer emulsion of room temperature of any of claims 1-6
Method, which comprises the steps of:
(1) modified SiO is prepared2With the dispersion liquid of acrylate monomer: weighing emulsifier A and deionized water in beaker, use glass
Stick stirring sufficiently dissolution, obtains emulsifier aqueous solution；Then suitable ethyl orthosilicate, γ-methacryloxypropyl are weighed
Trimethoxy silane is dissolved in the mix monomer of methyl methacrylate and butyl acrylate, obtains oil mixture；Then exist
Under being vigorously stirred of high-shear homogenizer, the oil mixture is added dropwise into above-mentioned emulsifier aqueous solution, and use dilute sulfuric acid
PH value is adjusted, high speed dispersion 30min is continued, is transferred in the ground boiling flask with plug therewith, at room temperature magnetic agitation 24
Hour, it reacts it sufficiently, obtains modified SiO2With the dispersion liquid of acrylate monomer；
(2) it prepares nano-composite emulsion: deionized water is added in four round flask, is subsequently placed in stirring in water bath and heats up, when
When temperature reaches 75 DEG C, the potassium peroxydisulfate of 2/5 reaction dosage is taken to be dissolved in 5g deionized water, adds round-bottomed flask, subsequent 10min
Inside at the uniform velocity 1/5 modification SiO of a dropping step (1) preparation2Enter round-bottomed flask with the dispersion liquid of acrylate monomer, in flask
When blue light occurs in reaction solution, remaining 3/5 potassium peroxydisulfate is dissolved in 5g deionized water, then by itself and remaining modification
SiO2It is added dropwise in round-bottomed flask with the dispersion liquid of acrylate monomer, is dripped in about 3 hours simultaneously, then keep the temperature 1 hour,
Nano-composite emulsion is made；
(3) monomer pre-emulsion is prepared: by deionized water, emulsifier A, emulsifier B and vinyl unsaturated carboxylic acid, methyl
Acrylate, acrylate, styrene and crosslinking agent A successively put into monomer pre-emulsification tank, and it is single that high-speed stirred emulsifies formation in 1 hour
Body pre-emulsion；
(4) it prepares the multiple self-crosslinking nano acrylic ester copolymer emulsion of room temperature: adding deionized water, the step of metering into polymeric kettle
Suddenly the nano-composite emulsion of (2) preparation, opens stirring, is warming up to 80 DEG C -84 DEG C, after stablizing 15min, while a dropping step (3)
The monomer pre-emulsion and ammonium persulfate solution of middle preparation stop being added dropwise when being added drop-wise to residual monomer pre-emulsion 1/5；Add
Enter vinylsiloxane monomer stirring 10min to continue to be added dropwise later, controls entire time for adding in 210min-240min, drip
Heating degree is controlled at 78 DEG C -82 DEG C；1 hour is kept the temperature under dropping temperature after being added dropwise；60 DEG C -70 is cooled to after heat preservation
DEG C, add tert-butyl hydroperoxide aqueous solution, aqueous solution of sodium bisulfite is added dropwise after 10min, temperature is added dropwise in time for adding 30min
Subsequent continuation of insurance temperature 30min is added dropwise at 63 DEG C -67 DEG C in degree control, is finally cooled to 40 DEG C hereinafter, adjusting pH to 7- with ammonium hydroxide
9, be added metering crosslinking agent B stirring 30min, then plus defoaming agent, preservative after, with 200-500 mesh filter screen filter, be made room temperature
Multiple self-crosslinking nano acrylic ester copolymer emulsion.
8. using the multiple self-crosslinking nano acrylic ester copolymer emulsion of room temperature of any of claims 1-6 as base-material system
Standby aqueous woodware paint, which is characterized in that the composition of the aqueous woodware paint includes each component of following parts by weight:
16 parts of deionized water；75 parts of lotion；0.3 part of wetting agent；0.3 part of levelling agent；4 parts of dipropylene；Dipropylene glycol first
4 parts of ether；0.3 part of thickener；0.05 part of defoaming agent；0.05 part of preservative；0.1 part of dispersing agent；2.5 parts of scratching resistant and stearic acid
5 parts of zinc.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510957083.8A CN105384864B (en) | 2015-12-18 | 2015-12-18 | A kind of multiple self-crosslinking nano acrylic ester copolymer emulsion of room temperature and preparation method thereof and using the lotion as the aqueous woodware paint of base-material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510957083.8A CN105384864B (en) | 2015-12-18 | 2015-12-18 | A kind of multiple self-crosslinking nano acrylic ester copolymer emulsion of room temperature and preparation method thereof and using the lotion as the aqueous woodware paint of base-material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105384864A CN105384864A (en) | 2016-03-09 |
| CN105384864B true CN105384864B (en) | 2019-04-16 |
Family
ID=55417681
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510957083.8A Active CN105384864B (en) | 2015-12-18 | 2015-12-18 | A kind of multiple self-crosslinking nano acrylic ester copolymer emulsion of room temperature and preparation method thereof and using the lotion as the aqueous woodware paint of base-material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105384864B (en) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105949381B (en) * | 2016-06-20 | 2018-07-13 | 衡水新光新材料科技有限公司 | Water-repellent paint without amine water-proof emulsion and preparation method thereof and containing no amine water-proof emulsion |
| CN106381709B (en) * | 2016-09-05 | 2018-07-06 | 南通纺织丝绸产业技术研究院 | For super-hydrophobic and anti UV finishing agent, the preparation method and applications of textile |
| KR102213455B1 (en) | 2017-02-01 | 2021-02-08 | 한화솔루션 주식회사 | Emulsion and manufacturing method of the same |
| CN107141937A (en) * | 2017-06-06 | 2017-09-08 | 常德金德镭射科技股份有限公司 | A kind of preparation method of polymolecularity antimildew and antibacterial coated film |
| CN107474604A (en) * | 2017-08-11 | 2017-12-15 | 河北晨阳工贸集团有限公司 | Woodenware sealing wax varnish suitable for dip-coating and preparation method thereof |
| CN108676116A (en) * | 2018-05-29 | 2018-10-19 | 德阳永盛无纺制品有限公司 | A kind of modified manometer silicon dioxide and the organic inorganic hybridization polyacrylate dispersion using the modified manometer silicon dioxide |
| CN108794682B (en) * | 2018-05-31 | 2020-10-23 | 华南农业大学 | Normal-temperature ketone hydrazine self-crosslinking acrylic resin emulsion and preparation method and application thereof |
| CN109054570B (en) * | 2018-07-18 | 2020-07-28 | 陕西科技大学 | Environment-friendly high-strength elastic coating and preparation method thereof |
| CN109337486A (en) * | 2018-10-18 | 2019-02-15 | 扬州中涂科技集团有限公司 | A kind of water-based metal antirust, anti-corrosive lotion |
| CN110028617B (en) * | 2019-04-28 | 2021-04-16 | 英德市雅家涂料有限公司 | Soap-free self-crosslinking nano acrylic emulsion and synthesis process and application thereof |
| CN111234118B (en) * | 2020-01-17 | 2022-07-12 | 日照广大建筑材料有限公司 | Double-crosslinking hyperbranched acrylic acid modified waterborne polyurethane emulsion, preparation method and application in wood lacquer finish paint |
| CN113025146A (en) * | 2021-05-06 | 2021-06-25 | 洋紫荆油墨股份有限公司 | High-wet-sticking-resistance polishing oil and preparation method thereof |
| CN113831791B (en) * | 2021-09-17 | 2022-08-26 | 恒昌涂料（惠阳）有限公司 | Water-based alcohol-resistant self-crosslinking nano emulsion and preparation method and application thereof |
| CN113980502B (en) * | 2021-11-01 | 2023-01-20 | 辽宁恒星精细化工有限公司 | Single-component water-based silicon-fluorine modified acrylate emulsion wood lacquer and preparation method thereof |
| CN115612024B (en) * | 2022-12-19 | 2023-03-21 | 北京市政路桥管理养护集团有限公司 | Concrete grouting material and preparation method thereof |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20030225190A1 (en) * | 2002-04-26 | 2003-12-04 | Janos Borbely | Polymeric product for film formation |
| CN101497729A (en) * | 2009-02-20 | 2009-08-05 | 上海三瑞化学有限公司 | Nano silicasol / acrylic ester composite emulsion and preparation thereof |
| CN101649153B (en) * | 2009-09-07 | 2011-12-21 | 大连工业大学 | Organic silicon modified acrylic ester aqueous wood lacquer latex and synthesizing method thereof |
| CN102030873B (en) * | 2010-10-27 | 2012-09-05 | 华南理工大学 | Method for preparing nano silicon dioxide/polyacrylate composite emulsion |
| CN104177939A (en) * | 2014-09-05 | 2014-12-03 | 上海展辰涂料有限公司 | Room-temperature self-crosslinking wood lacquer emulsion and preparation method thereof |
| CN104892816B (en) * | 2015-05-13 | 2017-07-14 | 衡水新光化工有限责任公司 | A kind of in-situ nano hybrid styrene-acrylic emulsion and using the emulsion as the antirust paint of base-material |
-
2015
- 2015-12-18 CN CN201510957083.8A patent/CN105384864B/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CN105384864A (en) | 2016-03-09 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105384864B (en) | A kind of multiple self-crosslinking nano acrylic ester copolymer emulsion of room temperature and preparation method thereof and using the lotion as the aqueous woodware paint of base-material | |
| AU2014230876B2 (en) | Hybrid water dispersions, (poly)ethylene (meth)acrylic acid copolymer composite latex emulsions, hybrid (poly)ethylene (meth)acrylic acid organosilane composite latex emulsions, and coating compositions formed therefrom | |
| CN107163198B (en) | The useful polymeric latex binder in zero or low VOC coatings composition | |
| WO2017020513A1 (en) | Hydroxyl polyacrylate emulsion and preparation method and application thereof | |
| CN101098902A (en) | Organic copolymers containing nanoparticles | |
| CN112194760B (en) | Polyacrylate emulsion and preparation method thereof | |
| CN104744639B (en) | A kind of preparation method of organic-silicon-modified normal-temperature multiple self-cross-linking epoxy resin emulsion | |
| CN102337704B (en) | Temperature-resisting printing paper water base varnish and preparation method thereof | |
| CN105622831A (en) | Preparation method of acrylic acid organic silicon soap-free copolymerization emulsion | |
| CN103965393A (en) | Water-based acrylic resin | |
| CN103834037B (en) | The preparation method of the acrylic resin modified hide finishes of a kind of water-soluble chitosan | |
| CN104892817A (en) | Preparation method of organosilicon styrene-acrylate fine emulsion | |
| JPH09188847A (en) | Aqueous dispersion for coating | |
| JP5283322B2 (en) | High durability coating composition | |
| WO2018110342A1 (en) | Emulsion | |
| JP2662352B2 (en) | Polymer latex composition containing silicone | |
| JP2005225956A (en) | Highly durable emulsion and method for producing the same | |
| JP5415339B2 (en) | Crosslinkable aqueous resin composition | |
| JP2006273919A (en) | High durability emulsion | |
| CN113831791A (en) | Water-based alcohol-resistant self-crosslinking nano emulsion and preparation method and application thereof | |
| JP4641743B2 (en) | High durability emulsion and method for producing the same | |
| JPH07118570A (en) | Water-based coating primer | |
| JP4266727B2 (en) | High durability emulsion and method for producing the same | |
| JP2003335806A (en) | High durability emulsion and method for producing the same | |
| CN109971102A (en) | A kind of hydrophobic latex film of low fluorine and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| CB02 | Change of applicant information | ||
| CB02 | Change of applicant information |
Address after: No. 50, west section of people West Road, Hengshui, Hebei Province Applicant after: HENGSHUI XINGUANG NEW MATERIAL TECHNOLOGY CO.,LTD. Address before: No. 50, west section of people West Road, Hengshui, Hebei Province Applicant before: HENGSHUI XINGUANG CHEMICAL Co.,Ltd. |
|
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Room temperature multiple self-crosslinking nano acrylate copolymer emulsion and preparation method and water-based woodenware paint using emulsion as base material Effective date of registration: 20200716 Granted publication date: 20190416 Pledgee: Renmin sub branch of Hengshui Bank Co.,Ltd. Pledgor: HENGSHUI XINGUANG NEW MATERIAL TECHNOLOGY Co.,Ltd. Registration number: Y2020130000017 |
|
| PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20210706 Granted publication date: 20190416 Pledgee: Renmin sub branch of Hengshui Bank Co.,Ltd. Pledgor: HENGSHUI XINGUANG NEW MATERIAL TECHNOLOGY Co.,Ltd. Registration number: Y2020130000017 |
|
| PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Room temperature multiple self crosslinking nano acrylate copolymer emulsion and preparation method thereof and waterborne wood paint based on the emulsion Effective date of registration: 20210713 Granted publication date: 20190416 Pledgee: Renmin sub branch of Hengshui Bank Co.,Ltd. Pledgor: HENGSHUI XINGUANG NEW MATERIAL TECHNOLOGY Co.,Ltd. Registration number: Y2021130000015 |
|
| PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
| PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20220708 Granted publication date: 20190416 Pledgee: Renmin sub branch of Hengshui Bank Co.,Ltd. Pledgor: HENGSHUI XINGUANG NEW MATERIAL TECHNOLOGY CO.,LTD. Registration number: Y2021130000015 |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: The invention relates to a room temperature multi self crosslinking nano acrylate copolymer lotion and a preparation method thereof, and an aqueous wood paint based on the lotion Effective date of registration: 20220713 Granted publication date: 20190416 Pledgee: Renmin sub branch of Hengshui Bank Co.,Ltd. Pledgor: HENGSHUI XINGUANG NEW MATERIAL TECHNOLOGY CO.,LTD. Registration number: Y2022130000047 |
|
| PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
| PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20230706 Granted publication date: 20190416 Pledgee: Renmin sub branch of Hengshui Bank Co.,Ltd. Pledgor: HENGSHUI XINGUANG NEW MATERIAL TECHNOLOGY CO.,LTD. Registration number: Y2022130000047 |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Room temperature multiple self crosslinking nano acrylate copolymer lotion, its preparation method and water-borne wood paint based on the lotion Effective date of registration: 20230713 Granted publication date: 20190416 Pledgee: Renmin sub branch of Hengshui Bank Co.,Ltd. Pledgor: HENGSHUI XINGUANG NEW MATERIAL TECHNOLOGY CO.,LTD. Registration number: Y2023980048488 |