CN105524537A - Environment-friendly high wear-resistant water-based polishing oil and preparation method thereof - Google Patents
Environment-friendly high wear-resistant water-based polishing oil and preparation method thereof Download PDFInfo
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- CN105524537A CN105524537A CN201610032777.5A CN201610032777A CN105524537A CN 105524537 A CN105524537 A CN 105524537A CN 201610032777 A CN201610032777 A CN 201610032777A CN 105524537 A CN105524537 A CN 105524537A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
- C09D125/08—Copolymers of styrene
- C09D125/14—Copolymers of styrene with unsaturated esters
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
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- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
Environment-friendly high wear-resistant water-based polishing oil is prepared from the following components in parts by weight: an organosilicone modified acrylic film forming emulsion, an organosilicone modified acrylic non-film-forming emulsion, waterborne polyurethane resin, a waterborne wear-resistant agent, a waterborne cross-linking agent, a PH modifier, a waterborne film forming aid, a waterborne slipping agent, a waterborne defoaming agent, a waterborne leveling and wetting agent and a solvent. The environment-friendly high wear-resistant water-based polishing oil has a good wear-resistant property and is environment-friendly and free of toxins, pollution and emission of harmful gases; the polishing oil has good printability and leveling property, can be used on a sheet-fed gravure press, a continuous-fed gravure press and an offset print varnishing machine and is capable of thoroughly solving the problems of residues of organic matters in presswork and the problem of emission of volatile organic compounds in a printing process and reducing the harms of the volatile organic compounds to operation personnel and the harms of harmful residues to users.
Description
Technical field
The present invention relates to the starting material processing and fabricating technical field in printing industry, be specifically related to a kind of environmental protection high wearable water-based gloss oil for intaglio printing and preparation method thereof.
Background technology
The surface of a lot of Packaging Printing Product all has one deck to protect gloss oil, to protect product injury-free.At present conventional protection gloss oil has: 1, solvent-borne type gloss oil, 2, UV gloss oil, 3, water-based gloss oil, solvent-borne type gloss oil contains 50 ~ 80% organic solvents, noxious gas emission serious environment pollutions a large amount of in printing process, and harm workman's is healthy; And easily produce fire.UV gloss oil has non-renewable characteristic and serious lingering taste, and price is higher, and therefore people are more ready the environment-friendly type aqueous gloss oil of choice for use, but water-based gloss oil wear resistance conventional is in the market general, can only meet the wear-resisting requirement of usual production; Gap is larger compared with UV gloss oil; Require that on higher product, water-based gloss oil cannot meet its performance requriements at wear resisting property.
Summary of the invention
The present invention is directed to above-mentioned the deficiencies in the prior art and provide that a kind of wear resisting property is good, environmental protection, nontoxic, pollution-free, without the environmental protection high wearable water-based gloss oil and preparation method thereof of noxious gas emission.
The present invention for the adopted technical scheme that solves the problem is:
A kind of environmental protection high wearable water-based gloss oil is made up of following component and weight part:
Organosilicon-modified acrylic filming emulsion 0 ~ 80%;
Organosilicon-modified acrylic is filming emulsion 0 ~ 70% not;
Waterborne polyurethane resin 5 ~ 80%,
Aqueous wear-resistant agent 2 ~ 10,
Water cross-linking agent 1 ~ 5%,
PH conditioning agent 0 ~ 5%,
Waterborne film-forming auxiliary agent 0 ~ 5%,
Water-based slipping agent 0 ~ 2%,
Water-based defoamer 0.1 ~ 1%,
Water-based levelling wetting agent 0 ~ 3%,
Solvent 0 ~ 40%.
Further, described organosilicon-modified acrylic filming emulsion is the combination of a kind of in organic-silicon-modified pure acrylic acid filming emulsion or waterborne organic silicon modifying cinepazid olefin(e) acid filming emulsion or two kinds;
Described organosilicon-modified acrylic not filming emulsion is the combination of a kind of not in filming emulsion of organic-silicon-modified pure acrylic latex or organosilicon-modified styrene-acrylic olefin(e) acid or two kinds;
Described waterborne polyurethane resin is aliphatic polyurethane dispersion.
Described aqueous wear-resistant agent is one or more combinations in high density polyethylene waxes, Fischer-Tropsch wax or fluorine richness polyethylene wax;
Described water cross-linking agent is one or more conjunction of polymine, carbodiimide or aziridine;
Described waterborne film-forming auxiliary agent is one or more the combination in ester alcohol 12 or dipropylene, ether solvent;
Described water-based slipping agent is one in dimethyl polysiloxane or Siloxane-Oxyalkylene Copolymers or two kinds of combinations;
Described water-based defoamer is aqueous mineral oils defoamer, containing silicone based polymer-type defoamer or containing one or more combinations in silicone based polymer-type defoamer;
Described water-based moistening flatting agent is one or more combinations in waterborne general type non-silicon class degree material wetting agent, polyether-modified polydimethylsiloxane class water-based moistening flatting agent, negatively charged ion perfluorocarbon surface promoting agent or diisooctyl amber semi-annular jade pendant acid sodium solution;
Described solvent is the combination of one or more in water solvent, deionized water solvent or alcoholic solvent, and described alcoholic solvent is one or more combinations in ethanol, Virahol, propylene glycol or glycerol.
A preparation method for environmental protection high wearable water-based gloss oil, it is as follows that the method comprising the steps of:
(1) in opening cylinder, add waterborne organic silicon modified acroleic acid not filming emulsion, waterborne organic silicon modified acroleic acid filming emulsion, and adopt the dispersion machine with disc type stirring rake to carry out stirring to make it be uniformly dispersed, the rotating speed of agitator of described dispersion machine is 300 ~ 1000rpm/min, jitter time 2 ~ 5 minutes;
(2) in described opening cylinder, add waterborne polyurethane resin more while stirring, continue stir and make it be uniformly dispersed, the rotating speed of agitator of described dispersion machine is 500 ~ 1500rpm/min, jitter time 5 ~ 10 minutes;
(3) in described opening cylinder, add anti-wear agent while stirring more successively, water-based slipping agent, water-based moistening flatting agent, water-based defoamer adopt disc type stirring rake to be uniformly dispersed, the rotating speed of agitator of described dispersion machine is 500 ~ 1500rpm/min, jitter time 5 ~ 30 minutes;
(4) in described opening cylinder, add water, alcoholic solvent, waterborne film-forming auxiliary agent more successively while stirring, and make it be uniformly dispersed, the rotating speed of agitator of described dispersion machine is 500 ~ 1500rpm/min, jitter time 2 ~ 10 minutes;
(5) limit water, alcohol, waterborne film-forming auxiliary agent mixed solution again in described opening cylinder while stirring, adopt disc type stirring rake to be uniformly dispersed, the rotating speed of agitator of described dispersion machine is 500 ~ 1500rpm/min, jitter time 8 ~ 30 minutes;
(6) in described opening cylinder, add described water cross-linking agent while stirring, and utilize the stirring rake of described dispersion machine to be uniformly dispersed;
(7) gloss oil pH value is regulated with PH conditioning agent;
(8) check viscosity, outward appearance, the fastness to rubbing of product, qualified rear filtration is finished product.
Further, described gloss oil PH=8 ~ 9.
Beneficial effect of the present invention is:
A kind of environmental protection high wearable water-based gloss oil provided by the present invention and manufacture method thereof, this gloss oil wear resisting property is good, can reach the antiwear characteristic of UV gloss oil, abrasion-resistant degree >=500 time/4 pounds; Static friction system≤0.2, dyanainic friction system≤0.2; Reach the requirement of UV gloss oil scratch-resistant performance; And environmental protection, nontoxic, pollution-free, without noxious gas emission, this gloss oil printing is good, good leveling property, can use on single recessed machine, even recessed machine, offset printing seasoning machine, volatile organic compounds emission problem in the residue problem of thorough solution organism in printed matter and printing process, reduce volatile organic compounds to the harm of operator and the Harmful Residue confrontation user harm.
Embodiment
Below in conjunction with specifically illustrating embodiments of the present invention, only for reference and explanation uses, and does not form the restriction to scope of patent protection of the present invention.
Embodiment one:
A kind of environmental protection high wearable water-based gloss oil that the present embodiment provides is made up of following component and weight part: organic-silicon-modified pure acrylic acid filming emulsion (YE3211) 5%; Organic-silicon-modified pure acrylic acid is filming emulsion (YE3212) 5% not; Water-based aliphatic polyurethane resin dispersion (AD393) 80%; Fluorine richness polyethylene wax anti-wear agent (LANCOSM1778) 3%; Water cross-linking agent (polymine) 3%; Conditioning agent (APM-95PH) 0.1%; Waterborne film-forming auxiliary agent (ester alcohol 12) 1%, Siloxane-Oxyalkylene Copolymers slipping agent (DC51) 0.2%; Containing silicone based polymer-type water-based defoamer (TEGO-1488) 0.1%; Universal non-silicon class degree material water-based levelling wetting agent (surfynol104E) 2.4%.
The preparation method of this environment-friendly type aqueous wear-resistant gloss oil comprises the steps:
(1) in the stirred opening cylinder of a constant volume, drop into not filming emulsion (YE3212), 5kg waterborne organic silicon modification pure acrylic acid filming emulsion (YE3212) of the organic-silicon-modified pure acrylic acid of water-based 5kg, adopt the dispersion of disc type stirring rake, rate of dispersion: 300rpm/min, time 2min;
(2) drop into 80kg water-based aliphatic polyurethane resin dispersion (AD393) while stirring, adopt the dispersion of disc type stirring rake, rate of dispersion 500rpm/min, jitter time 5min;
(3) 2kg fluorine richness polyethylene wax anti-wear agent polyethylene wax anti-wear agent (LANCOSM1778), 0.2kg Siloxane-Oxyalkylene Copolymers slipping agent (DC51), 2.4kg universal non-silicon class degree material water-based levelling wetting agent (surfynol104E), 0.1kg is dropped into while stirring successively containing silicone based polymer-type water-based defoamer (TEGO-1488), the dispersion of employing disc type stirring rake, rate of dispersion 1500rpm/min, jitter time 8min;
(4) drop into 1kg waterborne film-forming auxiliary agent (ester alcohol 12) while stirring, adopt the dispersion of disc type stirring rake, rate of dispersion 1500rpm/min, jitter time 8min;
(5) drop into 3kg water cross-linking agent (polymine) while stirring, adopt the dispersion of disc type stirring rake, rate of dispersion 1500rpm/min, jitter time 20min;
(6) pH value is regulated to be 8 ~ 9 with 0.1kgPH conditioning agent (APM-95);
(7) viscosity of product is checked: 35 seconds/25 DEG C Zahn2
#; Outward appearance: milky white liquid; Abrasion-resistant>=500 time/4 pounds, qualified rear use 250 order net filtration is finished product.
Embodiment two:
A kind of environmental protection high wearable water-based gloss oil that the present embodiment provides is made up of following component and weight part: organosilicon-modified styrene-acrylic filming emulsion (YE3223) 75%; Water-based aliphatic polyurethane resin dispersion (R-600) 10%; High density polyethylene waxes anti-wear agent (FL-1021) 4%; Water cross-linking agent carbodiimide 2%; Conditioning agent Monoethanolamine MEA BASF 0.2%; Waterborne film-forming auxiliary agent dipropylene 5%, dimethyl polysiloxane slipping agent (BORCHIGOLM51) 0.4%; Not containing silicone based polymer-type water-based defoamer (BORCHIAF1373-03) 0.2%; Diisooctyl amber sulfonate water-based levelling wetting agent (OT75) 1%; Water 2.2%.
The preparation method's the method for a kind of environment-friendly type aqueous wear-resistant gloss oil that the present embodiment provides comprises the steps:
(1) in the stirred opening cylinder of a constant volume, 75kg waterborne organic silicon modification propyl benzene third not film forming liquid (YE3223) is dropped into;
(2) drop into 10kg water-based aliphatic polyurethane resin dispersion (R-600) while stirring, adopt the dispersion of disc type stirring rake, rate of dispersion 900rpm/min, jitter time 10 minutes;
(3) 4kg high density polyethylene waxes anti-wear agent (FL-1021), 0.4kg dimethyl polysiloxane slipping agent (BORCHIGOLM51), 1kg diisooctyl amber sulfonate water-based levelling wetting agent (OT75), 0.2kg is dropped into while stirring successively not containing silicone based polymer-type water-based defoamer (BORCHIAF1373-03), the dispersion of employing disc type stirring rake, rate of dispersion 1200rpm/min, jitter time 15 minutes;
(4) in the stirred opening cylinder of a constant volume, drop into 2.2kg water, 5kg waterborne film-forming auxiliary agent (dipropylene), adopt disc type stirring rake to be uniformly dispersed.Rate of dispersion 500rpm/min, jitter time 2 minutes;
(5) drop into the mixed solvent of water and waterborne film-forming auxiliary agent (dipropylene) while stirring, adopt the dispersion of disc type stirring rake, rate of dispersion 600rpm/min, jitter time 5 minutes;
(6) drop into 3kg water cross-linking agent (carbodiimide) while stirring, adopt the dispersion of disc type stirring rake, rate of dispersion 1000rpm/min, jitter time 25 minutes;
(7) (Monoethanolamine MEA BASF) is regulated to regulate pH value=8-9 with 0.2kgPH;
(8) viscosity of product is checked: 32 seconds/25 DEG C ZNHA2
#; Outward appearance: milky white liquid; Abrasion-resistant>=500 time/4 pounds, qualified rear use 250 order net filtration is finished product.
Embodiment three:
A kind of environmental protection high wearable water-based gloss oil that the present embodiment provides is made up of following component and weight part: 40% organic-silicon-modified pure acrylic acid filming emulsion (YE3235); 15% organosilicon-modified styrene-acrylic is filming emulsion (YE3245) not; 12.5% water-based aliphatic polyurethane resin dispersion (825); 6% high density polyethylene waxes anti-wear agent (FL-1021); 0.3%PH conditioning agent (APM-95); 4% water cross-linking agent (aziridine), 0.5% Siloxane-Oxyalkylene Copolymers slipping agent (DC51); 0.3% silicone based polymer-type defoamer water-based defoamer (DC65); 0.4% negatively charged ion perfluorocarbon surface promoting agent (silok100); 10% water; 10% ethanol.
The preparation method's the method for a kind of environment-friendly type aqueous wear-resistant gloss oil that the present embodiment provides comprises the steps:
(1) in the stirred opening cylinder of a constant volume, 40kg waterborne organic silicon modification pure acrylic acid not filming emulsion (YE3223) is dropped into; 15% organosilicon-modified styrene-acrylic is filming emulsion (YE3245) not, adopts the dispersion of disc type stirring rake, rate of dispersion 600rpm/min, jitter time 6 minutes;
(2) drop into 12.5kg waterborne polyurethane resin (825) while stirring, adopt the dispersion of disc type stirring rake, rate of dispersion 1000rpm/min, jitter time 8 minutes;
(3) 6kg high density polyethylene waxes anti-wear agent (FL-1021) is dropped into successively while stirring; 0.5kg Siloxane-Oxyalkylene Copolymers slipping agent (DC51); 0.4kg negatively charged ion perfluorocarbon surface promoting agent (silok100); Polymer-type defoamer water-based defoamer (DC65) that 0.3kg is silicone based; Adopt the dispersion of disc type stirring rake, rate of dispersion 1000rpm/min, jitter time 13 minutes;
(4) in the stirred opening cylinder of a constant volume, 10kg water is dropped into; 10kg ethanol, adopts disc type stirring rake to be uniformly dispersed.Rate of dispersion 500rpm/min, jitter time 2 minutes;
(5) drop into the mixed solvent of water and ethanol while stirring, adopt the dispersion of disc type stirring rake, rate of dispersion 600rpm/min, jitter time 5 minutes;
(6) drop into 4kg water cross-linking agent (aziridine) while stirring, adopt the dispersion of disc type stirring rake, rate of dispersion 1200rpm/min, jitter time 30 minutes;
(7) pH value is regulated to be 8-9 with 0.3kgPH conditioning agent (APM-95);
(8) viscosity of product is checked: 30 seconds/25 DEG C ZNHA2
#; Outward appearance: milky white liquid; Abrasion-resistant>=500 time/4 pounds, qualified rear use 250 order net filtration is finished product.
In above-described embodiment, all raw material is technical grade.
The performance physical and chemical index of above embodiment gained water-based gloss oil is as following table:
Above-described embodiment is the present invention's preferably embodiment; but embodiments of the present invention are not restricted to the described embodiments; change, the modification done under other any does not deviate from spirit of the present invention and principle, substitute, combine, simplify; all should be the substitute mode of equivalence, be included within protection scope of the present invention.
Claims (4)
1. an environmental protection high wearable water-based gloss oil, is characterized in that being made up of following component and weight part:
Organosilicon-modified acrylic filming emulsion 0 ~ 80%;
Organosilicon-modified acrylic is filming emulsion 0 ~ 70% not;
Waterborne polyurethane resin 5 ~ 80%,
Aqueous wear-resistant agent 2 ~ 10,
Water cross-linking agent 1 ~ 5%,
PH conditioning agent 0 ~ 5%,
Waterborne film-forming auxiliary agent 0 ~ 5%,
Water-based slipping agent 0 ~ 2%,
Water-based defoamer 0.1 ~ 1%,
Water-based levelling wetting agent 0 ~ 3%,
Solvent 0 ~ 40%.
2. a kind of environmental protection high wearable water-based gloss oil according to claim 1, is characterized in that:
Described organosilicon-modified acrylic filming emulsion is the combination of a kind of in organic-silicon-modified pure acrylic acid filming emulsion or waterborne organic silicon modifying cinepazid olefin(e) acid filming emulsion or two kinds;
Described organosilicon-modified acrylic not filming emulsion is the combination of a kind of not in filming emulsion of organic-silicon-modified pure acrylic latex or organosilicon-modified styrene-acrylic olefin(e) acid or two kinds;
Described waterborne polyurethane resin is aliphatic polyurethane dispersion.
Described aqueous wear-resistant agent is one or more combinations in high density polyethylene waxes, Fischer-Tropsch wax or fluorine richness polyethylene wax;
Described water cross-linking agent is one or more conjunction of polymine, carbodiimide or aziridine;
Described waterborne film-forming auxiliary agent is one or more the combination in ester alcohol 12 or dipropylene, ether solvent;
Described water-based slipping agent is one in dimethyl polysiloxane or Siloxane-Oxyalkylene Copolymers or two kinds of combinations;
Described water-based defoamer is aqueous mineral oils defoamer, containing silicone based polymer-type defoamer or containing one or more combinations in silicone based polymer-type defoamer;
Described water-based moistening flatting agent is one or more combinations in waterborne general type non-silicon class degree material wetting agent, polyether-modified polydimethylsiloxane class water-based moistening flatting agent, negatively charged ion perfluorocarbon surface promoting agent or diisooctyl amber semi-annular jade pendant acid sodium solution;
Described solvent is the combination of one or more in water solvent, deionized water solvent or alcoholic solvent, and described alcoholic solvent is one or more combinations in ethanol, Virahol, propylene glycol or glycerol.
3. a preparation method for environmental protection high wearable water-based gloss oil, is characterized in that: comprise the steps:
(1) in opening cylinder, add waterborne organic silicon modified acroleic acid not filming emulsion, waterborne organic silicon modified acroleic acid filming emulsion, and adopt the dispersion machine with disc type stirring rake to carry out stirring to make it be uniformly dispersed, the rotating speed of agitator of described dispersion machine is 300 ~ 1000rpm/min, jitter time 2 ~ 5 minutes;
(2) in described opening cylinder, add waterborne polyurethane resin more while stirring, continue stir and make it be uniformly dispersed, the rotating speed of agitator of described dispersion machine is 500 ~ 1500rpm/min, jitter time 5 ~ 10 minutes;
(3) in described opening cylinder, add anti-wear agent while stirring more successively, water-based slipping agent, water-based moistening flatting agent, water-based defoamer adopt disc type stirring rake to be uniformly dispersed, the rotating speed of agitator of described dispersion machine is 500 ~ 1500rpm/min, jitter time 5 ~ 30 minutes;
(4) in described opening cylinder, add water, alcoholic solvent, waterborne film-forming auxiliary agent more successively while stirring, and make it be uniformly dispersed, the rotating speed of agitator of described dispersion machine is 500 ~ 1500rpm/min, jitter time 2 ~ 10 minutes;
(5) limit water, alcohol, waterborne film-forming auxiliary agent mixed solution again in described opening cylinder while stirring, adopt disc type stirring rake to be uniformly dispersed, the rotating speed of agitator of described dispersion machine is 500 ~ 1500rpm/min, jitter time 8 ~ 30 minutes;
(6) in described opening cylinder, add described water cross-linking agent while stirring, and utilize the stirring rake of described dispersion machine to be uniformly dispersed;
(7) gloss oil pH value is regulated with PH conditioning agent;
(8) check viscosity, outward appearance, the fastness to rubbing of product, qualified rear filtration is finished product.
4. a kind of environmental protection high wearable water-based gloss oil according to claim 3, is characterized in that: described gloss oil PH=8 ~ 9.
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| CN109651551A (en) * | 2018-12-25 | 2019-04-19 | 成都巴德富科技有限公司 | A kind of dope for inner wall of architecture acrylic acid ester emulsion and preparation method thereof and coating |
| CN109762399A (en) * | 2018-08-29 | 2019-05-17 | 东莞市浩彩油墨科技有限公司 | A kind of aqueous anti-scratch ink and its production technology for plastic film |
| CN110157263A (en) * | 2019-04-24 | 2019-08-23 | 杭州天龙油墨有限公司 | A kind of environment-friendly type high abrasion high glaze water-based gloss oil and its preparation process |
| CN110183957A (en) * | 2019-07-08 | 2019-08-30 | 东莞职业技术学院 | A kind of environmental protection high abrasion water-based gloss oil and preparation method thereof |
| CN112409907A (en) * | 2020-12-24 | 2021-02-26 | 安徽安大华泰新材料有限公司 | Waterborne polyurethane environment-friendly coating for automobile windshield wiper adhesive tape and preparation method thereof |
| CN112662228A (en) * | 2021-02-05 | 2021-04-16 | 漯河樱花包装材料有限公司 | Water-soluble environment-friendly gravure ink and preparation method thereof |
| CN113817376A (en) * | 2021-10-12 | 2021-12-21 | 江苏乐离新材料科技有限公司 | Water-soluble equipment protective film solution and preparation method thereof |
| CN113999608A (en) * | 2021-11-30 | 2022-02-01 | 中山市中益油墨涂料有限公司 | Water-based degradable plastic-replacing gloss oil and preparation method thereof |
| CN116254720A (en) * | 2023-03-27 | 2023-06-13 | 绿天鹅新材料(北京)有限公司 | Functional coating capable of replacing BOPP film and preparation method thereof |
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| CN107325706A (en) * | 2017-08-16 | 2017-11-07 | 河北惠驰装饰材料有限公司 | A kind of UV gloss oil and preparation method thereof and a kind of water-based UV gloss oil |
| CN109762399A (en) * | 2018-08-29 | 2019-05-17 | 东莞市浩彩油墨科技有限公司 | A kind of aqueous anti-scratch ink and its production technology for plastic film |
| CN109651551A (en) * | 2018-12-25 | 2019-04-19 | 成都巴德富科技有限公司 | A kind of dope for inner wall of architecture acrylic acid ester emulsion and preparation method thereof and coating |
| CN109651551B (en) * | 2018-12-25 | 2021-06-25 | 成都巴德富科技有限公司 | Acrylate emulsion for building interior wall coating, preparation method thereof and coating |
| CN110157263A (en) * | 2019-04-24 | 2019-08-23 | 杭州天龙油墨有限公司 | A kind of environment-friendly type high abrasion high glaze water-based gloss oil and its preparation process |
| CN110183957A (en) * | 2019-07-08 | 2019-08-30 | 东莞职业技术学院 | A kind of environmental protection high abrasion water-based gloss oil and preparation method thereof |
| CN112409907A (en) * | 2020-12-24 | 2021-02-26 | 安徽安大华泰新材料有限公司 | Waterborne polyurethane environment-friendly coating for automobile windshield wiper adhesive tape and preparation method thereof |
| CN112409907B (en) * | 2020-12-24 | 2022-04-19 | 安徽安大华泰新材料有限公司 | Waterborne polyurethane environment-friendly coating for automobile windshield wiper adhesive tape and preparation method thereof |
| CN112662228A (en) * | 2021-02-05 | 2021-04-16 | 漯河樱花包装材料有限公司 | Water-soluble environment-friendly gravure ink and preparation method thereof |
| CN113817376A (en) * | 2021-10-12 | 2021-12-21 | 江苏乐离新材料科技有限公司 | Water-soluble equipment protective film solution and preparation method thereof |
| CN113999608A (en) * | 2021-11-30 | 2022-02-01 | 中山市中益油墨涂料有限公司 | Water-based degradable plastic-replacing gloss oil and preparation method thereof |
| CN116254720A (en) * | 2023-03-27 | 2023-06-13 | 绿天鹅新材料(北京)有限公司 | Functional coating capable of replacing BOPP film and preparation method thereof |
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