CN102392387A - Water-based gravure polishing oil and preparing method thereof - Google Patents

Water-based gravure polishing oil and preparing method thereof Download PDF

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Publication number
CN102392387A
CN102392387A CN2011103454159A CN201110345415A CN102392387A CN 102392387 A CN102392387 A CN 102392387A CN 2011103454159 A CN2011103454159 A CN 2011103454159A CN 201110345415 A CN201110345415 A CN 201110345415A CN 102392387 A CN102392387 A CN 102392387A
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China
Prior art keywords
emulsion
water
agent
coalescents
intaglio printing
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CN2011103454159A
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Chinese (zh)
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CN102392387B (en
Inventor
周贤永
朱丽纯
丁立刚
张凤丽
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JIANGSU TIGER INK CO Ltd
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JIANGSU TIGER INK CO Ltd
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Abstract

The invention provides water-based gravure polishing oil and is characterized in that the water-based gravure polishing oil is prepared with the following raw materials in percentage by weight: water: 10-25; alcohols solvent: 5-20; emulsion: 20-45; solid resin: 5-25; amine assistant: 5-15; foam killer: 0.1-0.5; anti-wear additive: 0.5-5; flatting agent: 0.1-3; and film forming assistant: 1-5. The invention further discloses a polishing oil preparing method. Compared with the traditional gravure polishing oil, through the adoption of more reasonable raw materials, the water-based gravure polishing oil has the advantages of stable quality, innocuity, zero environment pollution, no solvent volatilization, high glossiness, strong abrasion resistance, low probability of yellowing and good adhesive attraction, can improve production environment, and is favorable for the health of operating staff; and the attenuant can be water and also can be the mixture of alcohols solvent and water with the ratio of 1 to 1 according to specific circumstances, so that the use cost of attenuant is greatly reduced.

Description

Aqueous intaglio printing oil polish and preparation method thereof
Technical field
The present invention relates to a kind of oil polish, particularly a kind of aqueous intaglio printing oil polish; The invention still further relates to a kind of preparation method of aforementioned oil polish.
Background technology
The intaglio printing oil polish is applicable to the surperficial glazing of various wine marks, cigarette-brand and various high-grade paper (like art paper, paperboard, composite sheet etc.) printed matter.Can play the effect of protection and decoration printed matter.At present, the intaglio printing oil polish that uses is the solvent-borne type oil polish, and printing gloss is low, and abrasion resistance is poor, contains VOC, and health of operators and production environment are had destruction.
Summary of the invention
Technical problem to be solved by this invention is the deficiency to prior art, provides that a kind of new prescription is more reasonable, glossiness is high, ABRASION RESISTANCE is strong, the aqueous intaglio printing oil polish of safety and stability.
Another technical problem to be solved by this invention has provided a kind of preparation method of aforesaid oil polish.
Technical problem to be solved by this invention is to realize through following technical scheme.The present invention is a kind of aqueous intaglio printing oil polish, is characterized in, it is processed by following materials of weight proportions,
Water 10-25; Alcohols solvent 5-20;
Emulsion 20-45; Hard resin 5-25;
Amine auxiliary agent 5-15; Antifoaming agent 0.1-0.5;
Antiwear additive 0.5-5; Levelling agent 0.1-3;
Coalescents 1-5;
Described hard resin is (methyl) acrylic acid ester and styrol copolymer, its acid number 200-240mgKOH/g; Described (methyl) acrylic acid ester is a methacrylate, is the acrylic acid ester of 1-10% and the mixture that 90-99% methacrylate is formed by percentage by weight perhaps;
Described emulsion is selected from a kind of in pure-acrylic emulsion, benzene emulsion, uncle's acrylic emulsion, vinyl acetate emulsion or the Silicone acrylic emulsion;
Described alcohols solvent is selected from a kind of in ethanol, isopropyl alcohol, the normal propyl alcohol;
Described amine auxiliary agent is selected from ammoniacal liquor, 2-amino-2-methyl-1-propanol, N, a kind of in the N-dimethylethanolamine;
Described antifoaming agent is selected from a kind of in polysiloxanes, dimethicone, silicone emulsion, polyoxyethylene polyoxypropylene pentaerythrite ether, the polyoxyethylene polyoxy propyl alcohol amidogen ether;
Described antiwear additive is selected from a kind of in PE wax, PP wax, polyamide wax, the white carbon black;
Described levelling agent is silicone based or the fluorine carbon levelling agent;
Described coalescents is a propylene glycol ethers slow curing solvent.
In the above-described aqueous intaglio printing oil polish technical scheme, further optimized technical scheme or characteristic are:
1, a kind of in the preferred dimethyl silicone polymer of described levelling agent, PSI, organic group modified polyorganosiloxane, polyfluoro polyene, the fluorin modified crylic acid.
2, a kind of among the preferred propylene glycol butyl ether of described coalescents, propylene glycol monomethyl ether PM, the 1-Methoxy-2-propyl acetate PMA.
3, the weight proportion of each raw material is preferably:
Water 18; Alcohols solvent 12;
Emulsion 32; Hard resin 12;
Amine auxiliary agent 10; Antifoaming agent 0.3;
Antiwear additive 2.8; Levelling agent 1.5;
Coalescents 2.5.
Oil polish of the present invention can adopt the conventional method preparation, preferred following method preparation.
The invention also discloses a kind of preparation method of as the described aqueous intaglio printing oil polish of above technical scheme, be characterized in that its step is following:
(1) with hard resin, water, part ethanol mixed and dispersed, add the amine auxiliary agent while disperseing, regulating the pH value is 8.5-9, gets resin liquid;
(2) with ready-made resin liquid, emulsion, remaining ethanol mixed and dispersed, add antifoaming agent, antiwear additive, levelling agent, coalescents while disperseing; Dispersing speed is controlled in the 600rpm, and it is uniformly dispersed fully;
(3) add the amine auxiliary agent while disperseing, regulate p H value to 8.5-9, it is uniformly dispersed fully, promptly get.
Compared with prior art, the present invention has been owing to selected more reasonable raw material for use, and more traditional intaglio printing oil polish steady quality is nontoxic, non-environmental-pollution, and solvent-free volatilization can improve production environment, helps operating personnel's health; Glossiness is high, and ABRASION RESISTANCE is strong, and is inhibited from yellowing, and adhesive force is good; Diluent can adopt water, also can do diluent to the mixture of alcohols solvent and water 1:1 as the case may be, greatly reduces the use cost of diluent.
The specific embodiment
Below further describe concrete technical scheme of the present invention,, and do not constitute restriction its right so that those skilled in the art understands the present invention further.
Embodiment 1, a kind of aqueous intaglio printing oil polish, and it is processed by following materials of weight proportions,
Water 10; Alcohols solvent 5;
Emulsion 20; Hard resin 5;
Amine auxiliary agent 5; Antifoaming agent 0.1;
Antiwear additive 0.5; Levelling agent 0.1;
Coalescents 1;
Described hard resin is (methyl) acrylic acid ester and styrol copolymer, its acid number 200mgKOH/g; Described (methyl) acrylic acid ester is a methacrylate;
Described emulsion is selected from a kind of in pure-acrylic emulsion, benzene emulsion, uncle's acrylic emulsion, vinyl acetate emulsion or the Silicone acrylic emulsion;
Described alcohols solvent is selected from a kind of in ethanol, isopropyl alcohol, the normal propyl alcohol;
Described amine auxiliary agent is selected from ammoniacal liquor, 2-amino-2-methyl-1-propanol, N, a kind of in the N-dimethylethanolamine;
Described antifoaming agent is selected from a kind of in polysiloxanes, dimethicone, silicone emulsion, polyoxyethylene polyoxypropylene pentaerythrite ether, the polyoxyethylene polyoxy propyl alcohol amidogen ether;
Described antiwear additive is selected from a kind of in PE wax, PP wax, polyamide wax, the white carbon black;
Described levelling agent is silicone based or the fluorine carbon levelling agent;
Described coalescents is a propylene glycol ethers slow curing solvent;
The preparation of employing conventional method.
Embodiment 2, a kind of aqueous intaglio printing oil polish, and it is processed by following materials of weight proportions,
Water 25; Alcohols solvent 20;
Emulsion 45; Hard resin 25;
Amine auxiliary agent 15; Antifoaming agent 0.5;
Antiwear additive 5; Levelling agent 3;
Coalescents 5;
Described hard resin is (methyl) acrylic acid ester and styrol copolymer, its acid number 240mgKOH/g; Described (methyl) acrylic acid ester is the mixture that the methacrylate of 10% acrylic acid ester and 90% is formed by percentage by weight;
Described emulsion is selected from a kind of in pure-acrylic emulsion, benzene emulsion, uncle's acrylic emulsion, vinyl acetate emulsion or the Silicone acrylic emulsion;
Described alcohols solvent is selected from a kind of in ethanol, isopropyl alcohol, the normal propyl alcohol;
Described amine auxiliary agent is selected from ammoniacal liquor, 2-amino-2-methyl-1-propanol, N, a kind of in the N-dimethylethanolamine;
Described antifoaming agent is selected from a kind of in polysiloxanes, dimethicone, silicone emulsion, polyoxyethylene polyoxypropylene pentaerythrite ether, the polyoxyethylene polyoxy propyl alcohol amidogen ether;
Described antiwear additive is selected from a kind of in PE wax, PP wax, polyamide wax, the white carbon black;
Described levelling agent is silicone based or the fluorine carbon levelling agent;
Described coalescents is a propylene glycol ethers slow curing solvent;
Its preparation methods steps is following:
(1) with hard resin, water, part ethanol mixed and dispersed, add the amine auxiliary agent while disperseing, regulating the pH value is 8.5, gets resin liquid;
(2) with ready-made resin liquid, emulsion, remaining ethanol mixed and dispersed, add antifoaming agent, antiwear additive, levelling agent, coalescents while disperseing; Dispersing speed is controlled in the 600rpm, and it is uniformly dispersed fully;
(3) add the amine auxiliary agent while disperseing, regulate p H value to 8.5, it is uniformly dispersed fully, promptly get.
Embodiment 3, a kind of aqueous intaglio printing oil polish, and it is processed by following materials of weight proportions,
Water 18; Alcohols solvent 12;
Emulsion 32; Hard resin 12;
Amine auxiliary agent 10; Antifoaming agent 0.3;
Antiwear additive 2.8; Levelling agent 1.5;
Coalescents 2.5.
Described hard resin is (methyl) acrylic acid ester and styrol copolymer, its acid number 220mgKOH/g; Described (methyl) acrylic acid ester is the mixture that the methacrylate of 1% acrylic acid ester and 99% is formed by percentage by weight;
Described emulsion is selected from a kind of in pure-acrylic emulsion, benzene emulsion, uncle's acrylic emulsion, vinyl acetate emulsion or the Silicone acrylic emulsion;
Described alcohols solvent is selected from a kind of in ethanol, isopropyl alcohol, the normal propyl alcohol;
Described amine auxiliary agent is selected from ammoniacal liquor, 2-amino-2-methyl-1-propanol, N, a kind of in the N-dimethylethanolamine;
Described antifoaming agent is selected from a kind of in polysiloxanes, dimethicone, silicone emulsion, polyoxyethylene polyoxypropylene pentaerythrite ether, the polyoxyethylene polyoxy propyl alcohol amidogen ether;
Described antiwear additive is selected from a kind of in PE wax, PP wax, polyamide wax, the white carbon black;
Described levelling agent is selected from a kind of in dimethyl silicone polymer, PSI, organic group modified polyorganosiloxane, polyfluoro polyene, the fluorin modified crylic acid;
Described coalescents is selected from a kind of among propylene glycol butyl ether, propylene glycol monomethyl ether PM, the 1-Methoxy-2-propyl acetate PMA.
Its preparation methods steps is following:
(1) with hard resin, water, part ethanol mixed and dispersed, add the amine auxiliary agent while disperseing, regulating the pH value is 9, gets resin liquid;
(2) with ready-made resin liquid, emulsion, remaining ethanol mixed and dispersed, add antifoaming agent, antiwear additive, levelling agent, coalescents while disperseing; Dispersing speed is controlled in the 600rpm, and it is uniformly dispersed fully;
(3) add the amine auxiliary agent while disperseing, regulate p H value to 9, it is uniformly dispersed fully, promptly get.
The performance indications of the not gloss oil that present embodiment makes see the following form (disclosed conventional method and instrument in the prior art are all adopted in the test of each index):
Index Content
Solid content (%) 15-45
Glossiness (60 degree) >70
Viscosity (s, 25 ℃) 30-40

Claims (5)

1. an aqueous intaglio printing oil polish is characterized in that, it is processed by following materials of weight proportions,
Water 10-25; Alcohols solvent 5-20;
Emulsion 20-45; Hard resin 5-25;
Amine auxiliary agent 5-15; Antifoaming agent 0.1-0.5;
Antiwear additive 0.5-5; Levelling agent 0.1-3;
Coalescents 1-5;
Described hard resin is (methyl) acrylic acid ester and styrol copolymer, its acid number 200-240mgKOH/g; Described (methyl) acrylic acid ester is a methacrylate, is the acrylic acid ester of 1-10% and the mixture that 90-99% methacrylate is formed by percentage by weight perhaps;
Described emulsion is selected from a kind of in pure-acrylic emulsion, benzene emulsion, uncle's acrylic emulsion, vinyl acetate emulsion or the Silicone acrylic emulsion;
Described alcohols solvent is selected from a kind of in ethanol, isopropyl alcohol, the normal propyl alcohol;
Described amine auxiliary agent is selected from ammoniacal liquor, 2-amino-2-methyl-1-propanol, N, a kind of in the N-dimethylethanolamine;
Described antifoaming agent is selected from a kind of in polysiloxanes, dimethicone, silicone emulsion, polyoxyethylene polyoxypropylene pentaerythrite ether, the polyoxyethylene polyoxy propyl alcohol amidogen ether;
Described antiwear additive is selected from a kind of in PE wax, PP wax, polyamide wax, the white carbon black;
Described levelling agent is silicone based or the fluorine carbon levelling agent;
Described coalescents is a propylene glycol ethers slow curing solvent.
2. aqueous intaglio printing oil polish according to claim 1 is characterized in that: described levelling agent is selected from a kind of in dimethyl silicone polymer, PSI, organic group modified polyorganosiloxane, polyfluoro polyene, the fluorin modified crylic acid.
3. aqueous intaglio printing oil polish according to claim 1 is characterized in that: described coalescents is selected from a kind of among propylene glycol butyl ether, propylene glycol monomethyl ether PM, the 1-Methoxy-2-propyl acetate PMA.
4. aqueous intaglio printing oil polish according to claim 1 is characterized in that: the weight proportion of each raw material is,
Water 18; Alcohols solvent 12;
Emulsion 32; Hard resin 12;
Amine auxiliary agent 10; Antifoaming agent 0.3;
Antiwear additive 2.8; Levelling agent 1.5;
Coalescents 2.5.
5. the preparation method like any one described aqueous intaglio printing oil polish of claim 1-4 is characterized in that, its step is following:
(1) with hard resin, water, part ethanol mixed and dispersed, add the amine auxiliary agent while disperseing, regulating the pH value is 8.5-9, gets resin liquid;
(2) with ready-made resin liquid, emulsion, remaining ethanol mixed and dispersed, add antifoaming agent, antiwear additive, levelling agent, coalescents while disperseing; Dispersing speed is controlled in the 600rpm, and it is uniformly dispersed fully;
(3) add the amine auxiliary agent while disperseing, regulate p H value to 8.5-9, it is uniformly dispersed fully, promptly get.
CN 201110345415 2011-11-04 2011-11-04 Water-based gravure polishing oil and preparing method thereof Active CN102392387B (en)

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Application Number Priority Date Filing Date Title
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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102943412A (en) * 2012-11-14 2013-02-27 海南必凯水性涂料有限公司 Wear-resistant high-gloss waterborne glazing oil and preparation method thereof
CN104005262A (en) * 2014-06-03 2014-08-27 山西金博雅油墨科技有限责任公司 Water-based lotus-leaf-structured hydrophobic over-printing varnish for wallpaper and preparation method of over-printing varnish
CN106351074A (en) * 2016-09-09 2017-01-25 湖北中烟工业有限责任公司 Water-based polishing oil for treating tipping paper and preventing aromatic bead oil from leaking
CN106351073A (en) * 2016-09-09 2017-01-25 湖北中烟工业有限责任公司 Treatment method of tipping paper used for preventing leakage of bead oil from bead blasting
CN106638128A (en) * 2016-10-12 2017-05-10 安徽集友纸业包装有限公司 Oleophobic and hydrophilic coating for tipping paper for cigarettes and preparation method thereof
CN108300066A (en) * 2018-02-07 2018-07-20 温州深奥科技有限公司 Printed matter protection layer formula
CN109266155A (en) * 2018-09-20 2019-01-25 赵建平 A kind of printing gloss oil and preparation method thereof
CN110105831A (en) * 2019-05-30 2019-08-09 江苏美乔科技有限公司 A kind of fast-drying aqueous oil polish of high glaze and preparation method thereof

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CN1341689A (en) * 2000-09-07 2002-03-27 广州擎天新材料研究开发有限公司 Preparation method of water lustering oil for paper
CN1887986A (en) * 2006-06-10 2007-01-03 惠州市华阳化工有限公司 Water thinned polishing oil for offset line and its prepn
CN101402818A (en) * 2008-11-14 2009-04-08 上海维凯化学品有限公司 Environment-friendly watersoluble tintage paint, preparation and uses thereof
CN101407655A (en) * 2008-11-14 2009-04-15 上海维凯化学品有限公司 Environment-friendly type aqueous aluminum foil protecting agent and preparation thereof

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JPH111535A (en) * 1997-06-13 1999-01-06 Mitsui Chem Inc Amino resin alkyl-etherified with isopropyl group
CN1341689A (en) * 2000-09-07 2002-03-27 广州擎天新材料研究开发有限公司 Preparation method of water lustering oil for paper
CN1887986A (en) * 2006-06-10 2007-01-03 惠州市华阳化工有限公司 Water thinned polishing oil for offset line and its prepn
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CN101407655A (en) * 2008-11-14 2009-04-15 上海维凯化学品有限公司 Environment-friendly type aqueous aluminum foil protecting agent and preparation thereof

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102943412A (en) * 2012-11-14 2013-02-27 海南必凯水性涂料有限公司 Wear-resistant high-gloss waterborne glazing oil and preparation method thereof
CN104005262A (en) * 2014-06-03 2014-08-27 山西金博雅油墨科技有限责任公司 Water-based lotus-leaf-structured hydrophobic over-printing varnish for wallpaper and preparation method of over-printing varnish
CN104005262B (en) * 2014-06-03 2016-03-02 山西金博雅油墨科技有限责任公司 Hydrophobic finishing oil of a kind of wallpaper waterborne lotus leaf and preparation method thereof
CN106351074A (en) * 2016-09-09 2017-01-25 湖北中烟工业有限责任公司 Water-based polishing oil for treating tipping paper and preventing aromatic bead oil from leaking
CN106351073A (en) * 2016-09-09 2017-01-25 湖北中烟工业有限责任公司 Treatment method of tipping paper used for preventing leakage of bead oil from bead blasting
CN106351074B (en) * 2016-09-09 2018-07-20 湖北中烟工业有限责任公司 It is a kind of to prevent the quick-fried outer water-based gloss oil invaded of pearl pearl oil for handling tipping paper
CN106638128A (en) * 2016-10-12 2017-05-10 安徽集友纸业包装有限公司 Oleophobic and hydrophilic coating for tipping paper for cigarettes and preparation method thereof
CN106638128B (en) * 2016-10-12 2018-12-04 安徽集友纸业包装有限公司 Oleophobic hydrophilic coating and preparation method thereof for cigarette tipping paper
CN108300066A (en) * 2018-02-07 2018-07-20 温州深奥科技有限公司 Printed matter protection layer formula
CN109266155A (en) * 2018-09-20 2019-01-25 赵建平 A kind of printing gloss oil and preparation method thereof
CN110105831A (en) * 2019-05-30 2019-08-09 江苏美乔科技有限公司 A kind of fast-drying aqueous oil polish of high glaze and preparation method thereof

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Denomination of invention: Waterborne gravure printing varnish and its preparation method

Granted publication date: 20130821

Pledgee: Industrial and Commercial Bank of China Limited Lianyungang Haizhou sub branch

Pledgor: JIANGSU TAIGE INK CO.,LTD.

Registration number: Y2024980000213