CN102392387A - Water-based gravure polishing oil and preparing method thereof - Google Patents
Water-based gravure polishing oil and preparing method thereof Download PDFInfo
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- CN102392387A CN102392387A CN2011103454159A CN201110345415A CN102392387A CN 102392387 A CN102392387 A CN 102392387A CN 2011103454159 A CN2011103454159 A CN 2011103454159A CN 201110345415 A CN201110345415 A CN 201110345415A CN 102392387 A CN102392387 A CN 102392387A
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- Prior art keywords
- emulsion
- water
- agent
- coalescents
- intaglio printing
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 20
- 238000000034 method Methods 0.000 title abstract description 3
- 238000005498 polishing Methods 0.000 title abstract 6
- 239000000839 emulsion Substances 0.000 claims abstract description 47
- 239000011347 resin Substances 0.000 claims abstract description 25
- 229920005989 resin Polymers 0.000 claims abstract description 25
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 23
- 150000001412 amines Chemical class 0.000 claims abstract description 21
- 239000002904 solvent Substances 0.000 claims abstract description 20
- 239000007866 anti-wear additive Substances 0.000 claims abstract description 17
- 150000001298 alcohols Chemical class 0.000 claims abstract description 15
- 239000000203 mixture Substances 0.000 claims abstract description 6
- 239000002994 raw material Substances 0.000 claims abstract description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 26
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 20
- CERQOIWHTDAKMF-UHFFFAOYSA-N alpha-methacrylic acid Natural products CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 20
- 239000012752 auxiliary agent Substances 0.000 claims description 20
- 229920001296 polysiloxane Polymers 0.000 claims description 19
- -1 polysiloxanes Polymers 0.000 claims description 19
- 239000002518 antifoaming agent Substances 0.000 claims description 16
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 15
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 15
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims description 15
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 10
- 238000002360 preparation method Methods 0.000 claims description 10
- 239000002253 acid Substances 0.000 claims description 8
- 239000007788 liquid Substances 0.000 claims description 8
- DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 8
- CERQOIWHTDAKMF-UHFFFAOYSA-M methacrylate group Chemical group C(C(=C)C)(=O)[O-] CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 claims description 7
- 229940058020 2-amino-2-methyl-1-propanol Drugs 0.000 claims description 5
- UEEJHVSXFDXPFK-UHFFFAOYSA-O N-dimethylethanolamine Chemical compound C[NH+](C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-O 0.000 claims description 5
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 5
- 239000004952 Polyamide Substances 0.000 claims description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 5
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 5
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 claims description 5
- MDFFNEOEWAXZRQ-UHFFFAOYSA-N aminyl Chemical compound [NH2] MDFFNEOEWAXZRQ-UHFFFAOYSA-N 0.000 claims description 5
- 235000011114 ammonium hydroxide Nutrition 0.000 claims description 5
- 239000006229 carbon black Substances 0.000 claims description 5
- 229920001577 copolymer Polymers 0.000 claims description 5
- 229940008099 dimethicone Drugs 0.000 claims description 5
- 235000013870 dimethyl polysiloxane Nutrition 0.000 claims description 5
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 5
- 239000000463 material Substances 0.000 claims description 5
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 5
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 5
- 229920002647 polyamide Polymers 0.000 claims description 5
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 claims description 5
- PRPAGESBURMWTI-UHFFFAOYSA-N [C].[F] Chemical compound [C].[F] PRPAGESBURMWTI-UHFFFAOYSA-N 0.000 claims description 4
- 125000005396 acrylic acid ester group Chemical group 0.000 claims description 4
- 230000001105 regulatory effect Effects 0.000 claims description 4
- RWNUSVWFHDHRCJ-UHFFFAOYSA-N 1-butoxypropan-2-ol Chemical compound CCCCOCC(C)O RWNUSVWFHDHRCJ-UHFFFAOYSA-N 0.000 claims description 3
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 claims description 3
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 claims description 3
- 125000000962 organic group Chemical group 0.000 claims description 3
- 150000004291 polyenes Chemical class 0.000 claims description 3
- LLHKCFNBLRBOGN-UHFFFAOYSA-N propylene glycol methyl ether acetate Chemical compound COCC(C)OC(C)=O LLHKCFNBLRBOGN-UHFFFAOYSA-N 0.000 claims description 3
- 229920005573 silicon-containing polymer Polymers 0.000 claims description 3
- 238000005299 abrasion Methods 0.000 abstract description 4
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 239000000853 adhesive Substances 0.000 abstract description 2
- 230000001070 adhesive effect Effects 0.000 abstract description 2
- 239000007787 solid Substances 0.000 abstract description 2
- 238000004383 yellowing Methods 0.000 abstract description 2
- 230000002349 favourable effect Effects 0.000 abstract 1
- 239000006260 foam Substances 0.000 abstract 1
- 238000007796 conventional method Methods 0.000 description 3
- 239000003085 diluting agent Substances 0.000 description 3
- 239000005022 packaging material Substances 0.000 description 2
- 239000000123 paper Substances 0.000 description 2
- 239000002131 composite material Substances 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000011087 paperboard Substances 0.000 description 1
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- Inks, Pencil-Leads, Or Crayons (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention provides water-based gravure polishing oil and is characterized in that the water-based gravure polishing oil is prepared with the following raw materials in percentage by weight: water: 10-25; alcohols solvent: 5-20; emulsion: 20-45; solid resin: 5-25; amine assistant: 5-15; foam killer: 0.1-0.5; anti-wear additive: 0.5-5; flatting agent: 0.1-3; and film forming assistant: 1-5. The invention further discloses a polishing oil preparing method. Compared with the traditional gravure polishing oil, through the adoption of more reasonable raw materials, the water-based gravure polishing oil has the advantages of stable quality, innocuity, zero environment pollution, no solvent volatilization, high glossiness, strong abrasion resistance, low probability of yellowing and good adhesive attraction, can improve production environment, and is favorable for the health of operating staff; and the attenuant can be water and also can be the mixture of alcohols solvent and water with the ratio of 1 to 1 according to specific circumstances, so that the use cost of attenuant is greatly reduced.
Description
Technical field
The present invention relates to a kind of oil polish, particularly a kind of aqueous intaglio printing oil polish; The invention still further relates to a kind of preparation method of aforementioned oil polish.
Background technology
The intaglio printing oil polish is applicable to the surperficial glazing of various wine marks, cigarette-brand and various high-grade paper (like art paper, paperboard, composite sheet etc.) printed matter.Can play the effect of protection and decoration printed matter.At present, the intaglio printing oil polish that uses is the solvent-borne type oil polish, and printing gloss is low, and abrasion resistance is poor, contains VOC, and health of operators and production environment are had destruction.
Summary of the invention
Technical problem to be solved by this invention is the deficiency to prior art, provides that a kind of new prescription is more reasonable, glossiness is high, ABRASION RESISTANCE is strong, the aqueous intaglio printing oil polish of safety and stability.
Another technical problem to be solved by this invention has provided a kind of preparation method of aforesaid oil polish.
Technical problem to be solved by this invention is to realize through following technical scheme.The present invention is a kind of aqueous intaglio printing oil polish, is characterized in, it is processed by following materials of weight proportions,
Water 10-25; Alcohols solvent 5-20;
Emulsion 20-45; Hard resin 5-25;
Amine auxiliary agent 5-15; Antifoaming agent 0.1-0.5;
Antiwear additive 0.5-5; Levelling agent 0.1-3;
Coalescents 1-5;
Described hard resin is (methyl) acrylic acid ester and styrol copolymer, its acid number 200-240mgKOH/g; Described (methyl) acrylic acid ester is a methacrylate, is the acrylic acid ester of 1-10% and the mixture that 90-99% methacrylate is formed by percentage by weight perhaps;
Described emulsion is selected from a kind of in pure-acrylic emulsion, benzene emulsion, uncle's acrylic emulsion, vinyl acetate emulsion or the Silicone acrylic emulsion;
Described alcohols solvent is selected from a kind of in ethanol, isopropyl alcohol, the normal propyl alcohol;
Described amine auxiliary agent is selected from ammoniacal liquor, 2-amino-2-methyl-1-propanol, N, a kind of in the N-dimethylethanolamine;
Described antifoaming agent is selected from a kind of in polysiloxanes, dimethicone, silicone emulsion, polyoxyethylene polyoxypropylene pentaerythrite ether, the polyoxyethylene polyoxy propyl alcohol amidogen ether;
Described antiwear additive is selected from a kind of in PE wax, PP wax, polyamide wax, the white carbon black;
Described levelling agent is silicone based or the fluorine carbon levelling agent;
Described coalescents is a propylene glycol ethers slow curing solvent.
In the above-described aqueous intaglio printing oil polish technical scheme, further optimized technical scheme or characteristic are:
1, a kind of in the preferred dimethyl silicone polymer of described levelling agent, PSI, organic group modified polyorganosiloxane, polyfluoro polyene, the fluorin modified crylic acid.
2, a kind of among the preferred propylene glycol butyl ether of described coalescents, propylene glycol monomethyl ether PM, the 1-Methoxy-2-propyl acetate PMA.
3, the weight proportion of each raw material is preferably:
Water 18; Alcohols solvent 12;
Emulsion 32; Hard resin 12;
Amine auxiliary agent 10; Antifoaming agent 0.3;
Antiwear additive 2.8; Levelling agent 1.5;
Coalescents 2.5.
Oil polish of the present invention can adopt the conventional method preparation, preferred following method preparation.
The invention also discloses a kind of preparation method of as the described aqueous intaglio printing oil polish of above technical scheme, be characterized in that its step is following:
(1) with hard resin, water, part ethanol mixed and dispersed, add the amine auxiliary agent while disperseing, regulating the pH value is 8.5-9, gets resin liquid;
(2) with ready-made resin liquid, emulsion, remaining ethanol mixed and dispersed, add antifoaming agent, antiwear additive, levelling agent, coalescents while disperseing; Dispersing speed is controlled in the 600rpm, and it is uniformly dispersed fully;
(3) add the amine auxiliary agent while disperseing, regulate p H value to 8.5-9, it is uniformly dispersed fully, promptly get.
Compared with prior art, the present invention has been owing to selected more reasonable raw material for use, and more traditional intaglio printing oil polish steady quality is nontoxic, non-environmental-pollution, and solvent-free volatilization can improve production environment, helps operating personnel's health; Glossiness is high, and ABRASION RESISTANCE is strong, and is inhibited from yellowing, and adhesive force is good; Diluent can adopt water, also can do diluent to the mixture of alcohols solvent and water 1:1 as the case may be, greatly reduces the use cost of diluent.
The specific embodiment
Below further describe concrete technical scheme of the present invention,, and do not constitute restriction its right so that those skilled in the art understands the present invention further.
Embodiment 1, a kind of aqueous intaglio printing oil polish, and it is processed by following materials of weight proportions,
Water 10; Alcohols solvent 5;
Emulsion 20; Hard resin 5;
Amine auxiliary agent 5; Antifoaming agent 0.1;
Antiwear additive 0.5; Levelling agent 0.1;
Coalescents 1;
Described hard resin is (methyl) acrylic acid ester and styrol copolymer, its acid number 200mgKOH/g; Described (methyl) acrylic acid ester is a methacrylate;
Described emulsion is selected from a kind of in pure-acrylic emulsion, benzene emulsion, uncle's acrylic emulsion, vinyl acetate emulsion or the Silicone acrylic emulsion;
Described alcohols solvent is selected from a kind of in ethanol, isopropyl alcohol, the normal propyl alcohol;
Described amine auxiliary agent is selected from ammoniacal liquor, 2-amino-2-methyl-1-propanol, N, a kind of in the N-dimethylethanolamine;
Described antifoaming agent is selected from a kind of in polysiloxanes, dimethicone, silicone emulsion, polyoxyethylene polyoxypropylene pentaerythrite ether, the polyoxyethylene polyoxy propyl alcohol amidogen ether;
Described antiwear additive is selected from a kind of in PE wax, PP wax, polyamide wax, the white carbon black;
Described levelling agent is silicone based or the fluorine carbon levelling agent;
Described coalescents is a propylene glycol ethers slow curing solvent;
The preparation of employing conventional method.
Embodiment 2, a kind of aqueous intaglio printing oil polish, and it is processed by following materials of weight proportions,
Water 25; Alcohols solvent 20;
Emulsion 45; Hard resin 25;
Amine auxiliary agent 15; Antifoaming agent 0.5;
Antiwear additive 5; Levelling agent 3;
Coalescents 5;
Described hard resin is (methyl) acrylic acid ester and styrol copolymer, its acid number 240mgKOH/g; Described (methyl) acrylic acid ester is the mixture that the methacrylate of 10% acrylic acid ester and 90% is formed by percentage by weight;
Described emulsion is selected from a kind of in pure-acrylic emulsion, benzene emulsion, uncle's acrylic emulsion, vinyl acetate emulsion or the Silicone acrylic emulsion;
Described alcohols solvent is selected from a kind of in ethanol, isopropyl alcohol, the normal propyl alcohol;
Described amine auxiliary agent is selected from ammoniacal liquor, 2-amino-2-methyl-1-propanol, N, a kind of in the N-dimethylethanolamine;
Described antifoaming agent is selected from a kind of in polysiloxanes, dimethicone, silicone emulsion, polyoxyethylene polyoxypropylene pentaerythrite ether, the polyoxyethylene polyoxy propyl alcohol amidogen ether;
Described antiwear additive is selected from a kind of in PE wax, PP wax, polyamide wax, the white carbon black;
Described levelling agent is silicone based or the fluorine carbon levelling agent;
Described coalescents is a propylene glycol ethers slow curing solvent;
Its preparation methods steps is following:
(1) with hard resin, water, part ethanol mixed and dispersed, add the amine auxiliary agent while disperseing, regulating the pH value is 8.5, gets resin liquid;
(2) with ready-made resin liquid, emulsion, remaining ethanol mixed and dispersed, add antifoaming agent, antiwear additive, levelling agent, coalescents while disperseing; Dispersing speed is controlled in the 600rpm, and it is uniformly dispersed fully;
(3) add the amine auxiliary agent while disperseing, regulate p H value to 8.5, it is uniformly dispersed fully, promptly get.
Embodiment 3, a kind of aqueous intaglio printing oil polish, and it is processed by following materials of weight proportions,
Water 18; Alcohols solvent 12;
Emulsion 32; Hard resin 12;
Amine auxiliary agent 10; Antifoaming agent 0.3;
Antiwear additive 2.8; Levelling agent 1.5;
Coalescents 2.5.
Described hard resin is (methyl) acrylic acid ester and styrol copolymer, its acid number 220mgKOH/g; Described (methyl) acrylic acid ester is the mixture that the methacrylate of 1% acrylic acid ester and 99% is formed by percentage by weight;
Described emulsion is selected from a kind of in pure-acrylic emulsion, benzene emulsion, uncle's acrylic emulsion, vinyl acetate emulsion or the Silicone acrylic emulsion;
Described alcohols solvent is selected from a kind of in ethanol, isopropyl alcohol, the normal propyl alcohol;
Described amine auxiliary agent is selected from ammoniacal liquor, 2-amino-2-methyl-1-propanol, N, a kind of in the N-dimethylethanolamine;
Described antifoaming agent is selected from a kind of in polysiloxanes, dimethicone, silicone emulsion, polyoxyethylene polyoxypropylene pentaerythrite ether, the polyoxyethylene polyoxy propyl alcohol amidogen ether;
Described antiwear additive is selected from a kind of in PE wax, PP wax, polyamide wax, the white carbon black;
Described levelling agent is selected from a kind of in dimethyl silicone polymer, PSI, organic group modified polyorganosiloxane, polyfluoro polyene, the fluorin modified crylic acid;
Described coalescents is selected from a kind of among propylene glycol butyl ether, propylene glycol monomethyl ether PM, the 1-Methoxy-2-propyl acetate PMA.
Its preparation methods steps is following:
(1) with hard resin, water, part ethanol mixed and dispersed, add the amine auxiliary agent while disperseing, regulating the pH value is 9, gets resin liquid;
(2) with ready-made resin liquid, emulsion, remaining ethanol mixed and dispersed, add antifoaming agent, antiwear additive, levelling agent, coalescents while disperseing; Dispersing speed is controlled in the 600rpm, and it is uniformly dispersed fully;
(3) add the amine auxiliary agent while disperseing, regulate p H value to 9, it is uniformly dispersed fully, promptly get.
The performance indications of the not gloss oil that present embodiment makes see the following form (disclosed conventional method and instrument in the prior art are all adopted in the test of each index):
Index | Content |
Solid content (%) | 15-45 |
Glossiness (60 degree) | >70 |
Viscosity (s, 25 ℃) | 30-40 |
Claims (5)
1. an aqueous intaglio printing oil polish is characterized in that, it is processed by following materials of weight proportions,
Water 10-25; Alcohols solvent 5-20;
Emulsion 20-45; Hard resin 5-25;
Amine auxiliary agent 5-15; Antifoaming agent 0.1-0.5;
Antiwear additive 0.5-5; Levelling agent 0.1-3;
Coalescents 1-5;
Described hard resin is (methyl) acrylic acid ester and styrol copolymer, its acid number 200-240mgKOH/g; Described (methyl) acrylic acid ester is a methacrylate, is the acrylic acid ester of 1-10% and the mixture that 90-99% methacrylate is formed by percentage by weight perhaps;
Described emulsion is selected from a kind of in pure-acrylic emulsion, benzene emulsion, uncle's acrylic emulsion, vinyl acetate emulsion or the Silicone acrylic emulsion;
Described alcohols solvent is selected from a kind of in ethanol, isopropyl alcohol, the normal propyl alcohol;
Described amine auxiliary agent is selected from ammoniacal liquor, 2-amino-2-methyl-1-propanol, N, a kind of in the N-dimethylethanolamine;
Described antifoaming agent is selected from a kind of in polysiloxanes, dimethicone, silicone emulsion, polyoxyethylene polyoxypropylene pentaerythrite ether, the polyoxyethylene polyoxy propyl alcohol amidogen ether;
Described antiwear additive is selected from a kind of in PE wax, PP wax, polyamide wax, the white carbon black;
Described levelling agent is silicone based or the fluorine carbon levelling agent;
Described coalescents is a propylene glycol ethers slow curing solvent.
2. aqueous intaglio printing oil polish according to claim 1 is characterized in that: described levelling agent is selected from a kind of in dimethyl silicone polymer, PSI, organic group modified polyorganosiloxane, polyfluoro polyene, the fluorin modified crylic acid.
3. aqueous intaglio printing oil polish according to claim 1 is characterized in that: described coalescents is selected from a kind of among propylene glycol butyl ether, propylene glycol monomethyl ether PM, the 1-Methoxy-2-propyl acetate PMA.
4. aqueous intaglio printing oil polish according to claim 1 is characterized in that: the weight proportion of each raw material is,
Water 18; Alcohols solvent 12;
Emulsion 32; Hard resin 12;
Amine auxiliary agent 10; Antifoaming agent 0.3;
Antiwear additive 2.8; Levelling agent 1.5;
Coalescents 2.5.
5. the preparation method like any one described aqueous intaglio printing oil polish of claim 1-4 is characterized in that, its step is following:
(1) with hard resin, water, part ethanol mixed and dispersed, add the amine auxiliary agent while disperseing, regulating the pH value is 8.5-9, gets resin liquid;
(2) with ready-made resin liquid, emulsion, remaining ethanol mixed and dispersed, add antifoaming agent, antiwear additive, levelling agent, coalescents while disperseing; Dispersing speed is controlled in the 600rpm, and it is uniformly dispersed fully;
(3) add the amine auxiliary agent while disperseing, regulate p H value to 8.5-9, it is uniformly dispersed fully, promptly get.
Priority Applications (1)
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CN 201110345415 CN102392387B (en) | 2011-11-04 | 2011-11-04 | Water-based gravure polishing oil and preparing method thereof |
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CN102392387B CN102392387B (en) | 2013-08-21 |
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Cited By (8)
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CN102943412A (en) * | 2012-11-14 | 2013-02-27 | 海南必凯水性涂料有限公司 | Wear-resistant high-gloss waterborne glazing oil and preparation method thereof |
CN104005262A (en) * | 2014-06-03 | 2014-08-27 | 山西金博雅油墨科技有限责任公司 | Water-based lotus-leaf-structured hydrophobic over-printing varnish for wallpaper and preparation method of over-printing varnish |
CN106351073A (en) * | 2016-09-09 | 2017-01-25 | 湖北中烟工业有限责任公司 | Treatment method of tipping paper used for preventing leakage of bead oil from bead blasting |
CN106351074A (en) * | 2016-09-09 | 2017-01-25 | 湖北中烟工业有限责任公司 | Water-based polishing oil for treating tipping paper and preventing aromatic bead oil from leaking |
CN106638128A (en) * | 2016-10-12 | 2017-05-10 | 安徽集友纸业包装有限公司 | Oleophobic and hydrophilic coating for tipping paper for cigarettes and preparation method thereof |
CN108300066A (en) * | 2018-02-07 | 2018-07-20 | 温州深奥科技有限公司 | Printed matter protection layer formula |
CN109266155A (en) * | 2018-09-20 | 2019-01-25 | 赵建平 | A kind of printing gloss oil and preparation method thereof |
CN110105831A (en) * | 2019-05-30 | 2019-08-09 | 江苏美乔科技有限公司 | A kind of fast-drying aqueous oil polish of high glaze and preparation method thereof |
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CN102943412A (en) * | 2012-11-14 | 2013-02-27 | 海南必凯水性涂料有限公司 | Wear-resistant high-gloss waterborne glazing oil and preparation method thereof |
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CN106351073A (en) * | 2016-09-09 | 2017-01-25 | 湖北中烟工业有限责任公司 | Treatment method of tipping paper used for preventing leakage of bead oil from bead blasting |
CN106351074A (en) * | 2016-09-09 | 2017-01-25 | 湖北中烟工业有限责任公司 | Water-based polishing oil for treating tipping paper and preventing aromatic bead oil from leaking |
CN106351074B (en) * | 2016-09-09 | 2018-07-20 | 湖北中烟工业有限责任公司 | It is a kind of to prevent the quick-fried outer water-based gloss oil invaded of pearl pearl oil for handling tipping paper |
CN106638128A (en) * | 2016-10-12 | 2017-05-10 | 安徽集友纸业包装有限公司 | Oleophobic and hydrophilic coating for tipping paper for cigarettes and preparation method thereof |
CN106638128B (en) * | 2016-10-12 | 2018-12-04 | 安徽集友纸业包装有限公司 | Oleophobic hydrophilic coating and preparation method thereof for cigarette tipping paper |
CN108300066A (en) * | 2018-02-07 | 2018-07-20 | 温州深奥科技有限公司 | Printed matter protection layer formula |
CN109266155A (en) * | 2018-09-20 | 2019-01-25 | 赵建平 | A kind of printing gloss oil and preparation method thereof |
CN110105831A (en) * | 2019-05-30 | 2019-08-09 | 江苏美乔科技有限公司 | A kind of fast-drying aqueous oil polish of high glaze and preparation method thereof |
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Denomination of invention: Waterborne gravure printing varnish and its preparation method Granted publication date: 20130821 Pledgee: Industrial and Commercial Bank of China Limited Lianyungang Haizhou sub branch Pledgor: JIANGSU TAIGE INK CO.,LTD. Registration number: Y2024980000213 |