CN102382514B - Ink for replacing aluminum foil lining paper and preparation method thereof - Google Patents
Ink for replacing aluminum foil lining paper and preparation method thereof Download PDFInfo
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- CN102382514B CN102382514B CN201110345412.5A CN201110345412A CN102382514B CN 102382514 B CN102382514 B CN 102382514B CN 201110345412 A CN201110345412 A CN 201110345412A CN 102382514 B CN102382514 B CN 102382514B
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Abstract
The invention relates to an ink for replacing aluminum foil lining paper, which is characterized by being prepared from the following raw materials in parts by weight: 20-65 parts of resin, 35-65 parts of reactive diluent, 0.5-2 parts of dispersant, 0.2-2 parts of leveling agent, 0.1-1 part of defoaming agent, 10-25 parts of pigment, 0.1-1 part of antifriction agent, 2-7 parts of initiator A, 1-5 parts of initiator B and 5-15 parts of organic amine assistant. The invention also discloses a preparation method of the ink for replacing aluminum foil lining paper. The ink for replacing aluminum foil lining paper has a reasonable composition, and can be printed on paper to replace aluminum foil lining paper. The ink for replacing aluminum foil lining paper is convenient to use and operate, and low in cost.
Description
Technical field
The present invention relates to a kind of ink, particularly a kind of ink that replaces aluminum foil lining paper; The invention still further relates to the preparation method of the ink of aforementioned replacement aluminum foil lining paper.
Background technology
Aluminum foil lining paper of the prior art is prepared by following technique, vacuum aluminum-coated on polyester film, coat and separate after solvent, on specific complex machine, carry out pressing with cigarette with aluminum casting paper, then polyester film is peeled off, clad aluminum foil internal lining paper makes finished product after cutting.Vacuum aluminum-coated operation is had relatively high expectations to Working environment, and this processing requirement is equipped with specific complex machine, and comprehensive cost is higher.In prior art, also there is no to replace the ink of aluminum foil lining paper.
Summary of the invention
Technical problem to be solved by this invention is for the deficiencies in the prior art, and a kind of ink of replacement aluminum foil lining paper newly, reasonable recipe is provided.
Another technical problem to be solved by this invention has been to provide a kind of preparation method of ink of replacement aluminum foil lining paper as above.
Technical problem to be solved by this invention is to realize by following technical scheme.The present invention is a kind of ink that replaces aluminum foil lining paper, is characterized in, it is to be made up of the raw material of following weight proportion:
Resin 20-65; Reactive thinner 35-65;
Dispersion agent 0.5-2; Flow agent 0.2-2;
Defoamer 0.1-1; Pigment 10-25;
Antifriction liniment 0.1-1; Initiator A 2-7;
Initiator B 1-5; Organic amine auxiliary agent 5-15;
Described resin is selected from the composition of any two kinds of compositions in epoxy acrylate, urethane acrylate, polyester acrylate, polyether acrylate, polyacrylic acid acrylate, Vinylite; In the time being used in combination, the portfolio ratio of the two can be arbitrarily, also can select as required.
Described reactive thinner is the mixture of any and Viscoat 295 composition in two diacrylates of Poly-propylene glycols, tripropylene glycol diacrylate, hexanediyl ester, neopentylglycol diacrylate; While being used in combination, the portfolio ratio of the two can be arbitrarily, also can select as required.
Described dispersion agent be disclosed in prior art can be for the one in the anionic of ink, non-ionic type or polymer;
Described flow agent be disclosed in prior art can be for the one in the silicone based of ink or fluorine carbon flow agent;
Described defoamer is selected from the one in polysiloxane, dimethyl silicone oil, silicone emulsion, polyoxyethylene polyoxypropylene tetramethylolmethane ether, polyoxyethylene polyoxy propyl alcohol amidogen ether;
Described pigment for have disclosed in technology can be for the transparent pigment of ink; Can be one or more in transparent yellow, transparent red, transparent blue pigment.
Described antifriction liniment is selected from the one in PE wax, PP wax, polyamide wax, White Carbon black;
Initiator A is selected from benzophenone or 4-phenyl benzophenone;
Initiator B is selected from 2-hydroxy-2-methyl-1-phenyl-acetone, 1-hydroxy-cyclohexyl phenyl ketone or 2-methyl-2-(4-morpholinyl)-1-[4-(methylthio group) phenyl]-1-acetone;
Described organic amine auxiliary agent is selected from N, N-dipropyl-1-propylamine, DMA or Dodecyl Dimethyl Amine.
In the ink technology scheme of above-described replacement aluminum foil lining paper: described dispersion agent is selected from carboxylate salt, sulfuric acid, polyethylene glycol type polyvalent alcohol, polyethylenimine derivates, how joins the reactant of polyvalent alcohol-many ethyleneimines segmented copolymer or many caprolactones and triethylene tetramine in.Many caprolactones refer to by many caprolactones, triethylene tetramine and react any reactant generating with the reactant of triethylene tetramine.
In the ink technology scheme of above-described replacement aluminum foil lining paper: described flow agent is selected from polydimethylsiloxane, PSI, organic radical modified polyorganosiloxane, polyfluoro polyene hydrocarbon or fluorin modified crylic acid.
In the ink technology scheme of above-described replacement aluminum foil lining paper: the weight proportion of each raw material is preferably:
Resin 40; Reactive thinner 50;
Dispersion agent 1.2; Flow agent 1.2;
Defoamer 0.5; Pigment 17;
Antifriction liniment 0.5; Initiator A 4.5;
Initiator B 3; Organic amine auxiliary agent 10.
Ink of the present invention can adopt ordinary method preparation, preferred following method preparation.
A kind of preparation method who the invention also discloses the ink of above-described replacement aluminum foil lining paper, is characterized in, its step is as follows:
(1) take by weight ratio raw material, choosing, by the resin of the whole and 40-60% of dispersion agent, defoamer, reactive thinner and flow agent blending dispersion, obtains pre-dispersed liquid;
(2) pigment and antifriction liniment are dropped in pre-dispersed liquid, be ground to fineness through three-roller and be less than 10 microns, obtain mill base;
(3) by remaining resin, reactive thinner and flow agent, and mix with mill base in initiator A, initiator B and organic amine auxiliary agent input mill base, under normal temperature, be uniformly dispersed, obtain finished product.
Compared with prior art, the present invention replaces the ink reasonable recipe of aluminum foil lining paper, is imprinted on paper with it, can replace aluminum foil lining paper.Its use, easy to operate, cost is low.
Embodiment
Below further describe concrete technical scheme of the present invention, so that those skilled in the art understands the present invention further, and do not form the restriction to its right.
Embodiment 1, a kind of ink that replaces aluminum foil lining paper, it is to be made up of the raw material of following weight proportion:
Resin 20; Reactive thinner 35;
Dispersion agent 0.5; Flow agent 0.2;
Defoamer 0.1; Pigment 10;
Antifriction liniment 0.1; Initiator A 2;
Initiator B 1; Organic amine auxiliary agent 5;
Described resin is selected from the composition of any two kinds of compositions in epoxy acrylate, urethane acrylate, polyester acrylate, polyether acrylate, polyacrylic acid acrylate, Vinylite;
Described reactive thinner is the mixture of any and Viscoat 295 composition in two diacrylates of Poly-propylene glycols, tripropylene glycol diacrylate, hexanediyl ester, neopentylglycol diacrylate;
Described dispersion agent is the one in anionic, non-ionic type or polymer;
Described flow agent is the one in silicone based or fluorine carbon;
Described defoamer is selected from the one in polysiloxane, dimethyl silicone oil, silicone emulsion, polyoxyethylene polyoxypropylene tetramethylolmethane ether, polyoxyethylene polyoxy propyl alcohol amidogen ether;
Described pigment is transparent pigment;
Described antifriction liniment is selected from the one in PE wax, PP wax, polyamide wax, White Carbon black;
Initiator A is selected from benzophenone or 4-phenyl benzophenone;
Initiator B is selected from 2-hydroxy-2-methyl-1-phenyl-acetone, 1-hydroxy-cyclohexyl phenyl ketone or 2-methyl-2-(4-morpholinyl)-1-[4-(methylthio group) phenyl]-1-acetone;
Described organic amine auxiliary agent is selected from N, N-dipropyl-1-propylamine, DMA or Dodecyl Dimethyl Amine.
Preparation according to a conventional method.
Embodiment 2, a kind of ink that replaces aluminum foil lining paper, it is to be made up of the raw material of following weight proportion:
Resin 65; Reactive thinner 65;
Dispersion agent 2; Flow agent 2;
Defoamer 1; Pigment 25;
Antifriction liniment 1; Initiator A 7;
Initiator B 5; Organic amine auxiliary agent 15;
Selecting of each raw material is identical with embodiment 1.
Its preparation method is:
(1) take by weight ratio raw material, choosing, by the resin of the whole of dispersion agent, defoamer and 60%, reactive thinner and flow agent blending dispersion, obtains pre-dispersed liquid;
(2) pigment and antifriction liniment are dropped in pre-dispersed liquid, be ground to fineness through three-roller and be less than 10 microns, obtain mill base;
(3) by remaining resin, reactive thinner and flow agent, and mix with mill base in initiator A, initiator B and organic amine auxiliary agent input mill base, under normal temperature, be uniformly dispersed, obtain finished product.
Embodiment 3, a kind of ink that replaces aluminum foil lining paper, it is to be made up of the raw material of following weight proportion:
Resin 40; Reactive thinner 50;
Dispersion agent 1.2; Flow agent 1.2;
Defoamer 0.5; Pigment 17;
Antifriction liniment 0.5; Initiator A 4.5;
Initiator B 3; Organic amine auxiliary agent 10.
Selecting of each raw material is identical with embodiment 1.
Its preparation method is:
(1) take by weight ratio raw material, choosing, by the resin of the whole of dispersion agent, defoamer and 40%, reactive thinner and flow agent blending dispersion, obtains pre-dispersed liquid;
(2) pigment and antifriction liniment are dropped in pre-dispersed liquid, be ground to fineness through three-roller and be less than 10 microns, obtain mill base;
(3) by remaining resin, reactive thinner and flow agent, and mix with mill base in initiator A, initiator B and organic amine auxiliary agent input mill base, under normal temperature, be uniformly dispersed, obtain finished product.
Embodiment 4, the ink of the replacement aluminum foil lining paper described in embodiment 1 or 2 or 3: described dispersion agent is selected from carboxylate salt, sulfuric acid, polyethylene glycol type polyvalent alcohol, polyethylenimine derivates, how joins the reactant of polyvalent alcohol-many ethyleneimines segmented copolymer or many caprolactones and triethylene tetramine in.
Embodiment 5, the ink of the replacement aluminum foil lining paper described in embodiment 1 or 2 or 3: described flow agent is selected from polydimethylsiloxane, PSI, organic radical modified polyorganosiloxane, polyfluoro polyene hydrocarbon or fluorin modified crylic acid.
Embodiment 6, the ink of the replacement aluminum foil lining paper described in embodiment 1 or 2 or 3: one or more in described pigment transparent yellow, transparent red, transparent basket.
Embodiment 7, a kind of ink that replaces aluminum foil lining paper, it is to be made up of the raw material of following weight proportion:
Resin 40; Reactive thinner 50;
Dispersion agent 1.2; Flow agent 1.2;
Defoamer 0.5; Pigment 17;
Antifriction liniment 0.5; Initiator A 4.5;
Initiator B 3; Organic amine auxiliary agent 10.
Described resin is the composition of epoxy acrylate and Vinylite composition;
Described reactive thinner is the mixture of two diacrylates of Poly-propylene glycols and Viscoat 295 composition;
Described defoamer is polysiloxane;
Described pigment is transparent yellow;
Described antifriction liniment is PE wax;
Initiator A is benzophenone;
Initiator B is 2-hydroxy-2-methyl-1-phenyl-acetone;
Described organic amine auxiliary agent is N, N-dipropyl-1-propylamine;
Described dispersion agent is carboxylate salt;
Described flow agent is polydimethylsiloxane;
Its preparation methods steps is as follows:
(1) take by weight ratio raw material, choosing, by the resin of the whole of dispersion agent, defoamer and 50%, reactive thinner and flow agent blending dispersion, obtains pre-dispersed liquid;
(2) pigment and antifriction liniment are dropped in pre-dispersed liquid, be ground to fineness through three-roller and be less than 10 microns, obtain mill base;
(3) by remaining resin, reactive thinner and flow agent, and mix with mill base in initiator A, initiator B and organic amine auxiliary agent input mill base, under normal temperature, be uniformly dispersed, obtain finished product.
The technical indicator of gained finished product ink is as follows, and what index of correlation detected employing is prior art ordinary method and instrument:
| Index | Content |
| Solid content (%) | 25-50 |
| Fineness (um) | ≤10 |
| Attachment fastness (%) | 100 |
| Glossiness (60 degree) | ＞70 |
Claims (3)
1. an ink that replaces aluminum foil lining paper, is characterized in that, it is to be made up of the raw material of following weight proportion:
Resin 40; Reactive thinner 50;
Dispersion agent 1.2; Flow agent 1.2;
Defoamer 0.5; Pigment 17;
Antifriction liniment 0.5; Initiator A 4.5;
Initiator B 3; Organic amine auxiliary agent 10;
Described resin is selected from the composition of any two kinds of compositions in polyester acrylate, polyether acrylate, polyacrylic acid acrylate, Vinylite;
Described reactive thinner is the mixture of any and Viscoat 295 composition in tripropylene glycol diacrylate, hexanediyl ester, neopentylglycol diacrylate;
Described dispersion agent is selected from carboxylate salt, sulfuric acid, polyethylene glycol type polyvalent alcohol, polyethylenimine derivates, how joins the reactant of polyvalent alcohol-many ethyleneimines segmented copolymer or many caprolactones and triethylene tetramine in;
Described flow agent is selected from PSI, organic radical modified polyorganosiloxane, polyfluoro polyene hydrocarbon or fluorin modified crylic acid;
Described defoamer is selected from the one in dimethyl silicone oil, silicone emulsion, polyoxyethylene polyoxypropylene tetramethylolmethane ether, polyoxyethylene polyoxy propyl alcohol amidogen ether;
Described pigment is transparent pigment;
Described antifriction liniment is selected from the one in PE wax, PP wax, polyamide wax, White Carbon black;
Initiator A is benzophenone;
Initiator B is selected from 2-hydroxy-2-methyl-1-phenyl-acetone or 2-methyl-2-(4-morpholinyl)-1-[4-(methylthio group) phenyl]-1-acetone;
Described organic amine auxiliary agent is selected from N, N-dipropyl-1-propylamine, DMA or Dodecyl Dimethyl Amine.
2. the ink of replacement aluminum foil lining paper according to claim 1, is characterized in that: described pigment is one or more in transparent yellow, transparent red, transparent basket.
3. a preparation method for the ink of replacement aluminum foil lining paper as claimed in claim 1 or 2, is characterized in that, its step is as follows:
(1) take by weight ratio raw material, choosing, by the resin of the whole and 40-60% of dispersion agent, defoamer, reactive thinner and flow agent blending dispersion, obtains pre-dispersed liquid;
(2) pigment and antifriction liniment are dropped in pre-dispersed liquid, be ground to fineness through three-roller and be less than 10 microns, obtain mill base;
(3) by remaining resin, reactive thinner and flow agent, and mix with mill base in initiator A, initiator B and organic amine auxiliary agent input mill base, under normal temperature, be uniformly dispersed, obtain finished product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110345412.5A CN102382514B (en) | 2011-11-04 | 2011-11-04 | Ink for replacing aluminum foil lining paper and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110345412.5A CN102382514B (en) | 2011-11-04 | 2011-11-04 | Ink for replacing aluminum foil lining paper and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102382514A CN102382514A (en) | 2012-03-21 |
| CN102382514B true CN102382514B (en) | 2014-06-25 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201110345412.5A Active CN102382514B (en) | 2011-11-04 | 2011-11-04 | Ink for replacing aluminum foil lining paper and preparation method thereof |
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Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103666097A (en) * | 2013-11-25 | 2014-03-26 | 铜陵方正塑业科技有限公司 | UV printing ink for silk-screen printing and preparation method thereof |
| CN103666058A (en) * | 2013-11-25 | 2014-03-26 | 铜陵方正塑业科技有限公司 | UV curing offset printing ink and preparation method thereof |
| CN103666066A (en) * | 2013-11-25 | 2014-03-26 | 铜陵方正塑业科技有限公司 | High-performance high-production-efficiency UV-cured printing ink and preparation method thereof |
| CN107266968A (en) * | 2017-08-15 | 2017-10-20 | 南宁东印时代广告有限公司 | A kind of indoor wallpaper ink and preparation method thereof |
| CN107780295A (en) * | 2017-09-12 | 2018-03-09 | 昆明理工大学 | It is a kind of to be used to allocate water paint of cigarette liner paper and coating and preparation method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102093782A (en) * | 2011-03-30 | 2011-06-15 | 北京神彩优维喷墨材料科技有限公司 | Ultraviolet-cured digital painting ink and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101665643A (en) * | 2009-09-18 | 2010-03-10 | 林国顺 | Ultraviolet curing pearl ink |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102093782A (en) * | 2011-03-30 | 2011-06-15 | 北京神彩优维喷墨材料科技有限公司 | Ultraviolet-cured digital painting ink and preparation method thereof |
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