CN102382514A - Ink for replacing aluminum foil lining paper and preparation method thereof - Google Patents
Ink for replacing aluminum foil lining paper and preparation method thereof Download PDFInfo
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- CN102382514A CN102382514A CN2011103454125A CN201110345412A CN102382514A CN 102382514 A CN102382514 A CN 102382514A CN 2011103454125 A CN2011103454125 A CN 2011103454125A CN 201110345412 A CN201110345412 A CN 201110345412A CN 102382514 A CN102382514 A CN 102382514A
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Abstract
The invention relates to an ink for replacing aluminum foil lining paper, which is characterized by being prepared from the following raw materials in parts by weight: 20-65 parts of resin, 35-65 parts of reactive diluent, 0.5-2 parts of dispersant, 0.2-2 parts of leveling agent, 0.1-1 part of defoaming agent, 10-25 parts of pigment, 0.1-1 part of antifriction agent, 2-7 parts of initiator A, 1-5 parts of initiator B and 5-15 parts of organic amine assistant. The invention also discloses a preparation method of the ink for replacing aluminum foil lining paper. The ink for replacing aluminum foil lining paper has a reasonable composition, and can be printed on paper to replace aluminum foil lining paper. The ink for replacing aluminum foil lining paper is convenient to use and operate, and low in cost.
Description
Technical field
The present invention relates to a kind of printing ink, particularly a kind of printing ink that replaces lining paper in the aluminium foil; The invention still further relates to the preparation method of the printing ink of lining paper in the aforementioned replacement aluminium foil.
Background technology
Lining paper is by following prepared in the aluminium foil of the prior art; Vacuum aluminum-coated on the polyester film, coat separate solvent after; On the specific complex machine, carry out pressing with aluminum casting paper, again polyester film is peeled off, make finished product after lining paper is cut in the clad aluminum foil with cigarette.Vacuum aluminum-coated operation is had relatively high expectations to Working environment, and this processing requirement is equipped with the specific complex machine, and comprehensive cost is higher.Also there is not to replace the printing ink of lining paper in the aluminium foil in the prior art.
Summary of the invention
Technical problem to be solved by this invention is the deficiency to prior art, and the printing ink of lining paper in a kind of replacement aluminium foil new, reasonable recipe is provided.
Another technical problem to be solved by this invention has provided the preparation method of the printing ink of lining paper in a kind of aforesaid replacement aluminium foil.
Technical problem to be solved by this invention is to realize through following technical scheme.The present invention is a kind of printing ink that replaces lining paper in the aluminium foil, is characterized in that it is to be processed by following materials of weight proportions:
Resin 20-65; Reactive thinner 35-65;
Dispersion agent 0.5-2; Flow agent 0.2-2;
Skimmer 0.1-1; Pigment 10-25;
Antifriction liniment 0.1-1; Initiator A 2-7;
Initiator B 1-5; Organic amine auxiliary agent 5-15;
Described resin is selected from the compsn of any two kinds of compositions in epoxy acrylate, urethane acrylate, polyester acrylate, polyether acrylate, ROHM propenoate, the Vinylite; When combination was used, the portfolio ratio of the two can be arbitrarily, also can select as required.
Described reactive thinner is two mixtures that any and Viscoat 295 in propylene glycol diacrylate, tripropylene glycol diacrylate, hexanediyl ester, the neopentylglycol diacrylate forms that contract; When combination was used, the portfolio ratio of the two can be arbitrarily, also can select as required.
Described dispersion agent is a kind of of disclosed anionic, non-ionic type or the polymer that can be used for printing ink in the prior art;
Described flow agent is disclosedly in the prior art can be used for a kind of of the silicone based of printing ink or fluorine carbon flow agent;
Described skimmer is selected from a kind of in ZGK 5, dimethyl silicone oil, silicone emulsion, polyoxyethylene polyoxypropylene tetramethylolmethane ether, the T 46155 polyoxy propyl alcohol amidogen ether;
Described pigment is for there being the disclosed transparent pigment that can be used for printing ink in the technology; Can be in transparent yellow, transparent red, the transparent blue pigment one or more.
Described antifriction liniment is selected from a kind of in PE wax, PP wax, polyamide wax, the white carbon black;
Initiator A is selected from UVNUL MS-40 or 4-phenyl benzophenone;
Initiator B is selected from 2-hydroxy-2-methyl-1-phenyl-acetone, 1-hydroxy-cyclohexyl phenyl ketone or 2-methyl-2-(4-morpholinyl)-1-[4-(methylthio group) phenyl]-1-acetone;
Described organic amine auxiliary agent is selected from N, N-dipropyl-1-propylamine, N, accelerine or dodecyl dimethyl tertiary amine.
In the above-described replacement aluminium foil in the ink technology scheme of lining paper: described dispersion agent is selected from carboxylate salt, sulfuric acid, polyethylene glycol type polyvalent alcohol, polyethylenimine derivates, how joins the reactant of polyvalent alcohol-many ethyleneimines segmented copolymer or many caprolactones and triethylene tetramine in.The reactant of many caprolactones and triethylene tetramine is meant any reactant that is reacted generation by many caprolactones, triethylene tetramine.
In the ink technology scheme of the interior lining paper of above-described replacement aluminium foil: described flow agent is selected from YSR 3286, PSI, organic radical modified polyorganosiloxane, polyfluoro polyene hydrocarbon or fluorin modified crylic acid.
In the ink technology scheme of the interior lining paper of above-described replacement aluminium foil: the weight proportion of each raw material is preferably:
Resin 40; Reactive thinner 50;
Dispersion agent 1.2; Flow agent 1.2;
Skimmer 0.5; Pigment 17;
Antifriction liniment 0.5; Initiator A 4.5;
Initiator B 3; Organic amine auxiliary agent 10.
Printing ink of the present invention can adopt the ordinary method preparation, preferred following method preparation.
The invention also discloses a kind of preparation method of the printing ink of lining paper in the above-described replacement aluminium foil, be characterized in that its step is following:
(1) take by weighing raw material by weight ratio, choosing gets pre-dispersed liquid with resin, reactive thinner and the flow agent blending dispersion of the whole and 40-60% of dispersion agent, skimmer;
(2) pigment and antifriction liniment are dropped in the pre-dispersed liquid, be ground to fineness less than 10 microns, get mill base through three-roller;
(3) with remaining resin, reactive thinner and flow agent, and mix with mill base in initiator A, initiator B and the organic amine auxiliary agent input mill base, be uniformly dispersed under the normal temperature, get finished product.
Compared with prior art, the present invention replaces the printing ink reasonable recipe of lining paper in the aluminium foil, is imprinted on the paper with it, can replace lining paper in the aluminium foil.Its use, easy to operate, cost is low.
Embodiment
Below further describe concrete technical scheme of the present invention,, and do not constitute restriction its right so that those skilled in the art understands the present invention further.
Embodiment 1, a kind of printing ink that replaces lining paper in the aluminium foil, and it is to be processed by following materials of weight proportions:
Resin 20; Reactive thinner 35;
Dispersion agent 0.5; Flow agent 0.2;
Skimmer 0.1; Pigment 10;
Antifriction liniment 0.1; Initiator A 2;
Initiator B 1; Organic amine auxiliary agent 5;
Described resin is selected from the compsn of any two kinds of compositions in epoxy acrylate, urethane acrylate, polyester acrylate, polyether acrylate, ROHM propenoate, the Vinylite;
Described reactive thinner is two mixtures that any and Viscoat 295 in propylene glycol diacrylate, tripropylene glycol diacrylate, hexanediyl ester, the neopentylglycol diacrylate forms that contract;
Described dispersion agent is a kind of in anionic, non-ionic type or the polymer;
Described flow agent is a kind of in silicone based or the fluorine carbon;
Described skimmer is selected from a kind of in ZGK 5, dimethyl silicone oil, silicone emulsion, polyoxyethylene polyoxypropylene tetramethylolmethane ether, the T 46155 polyoxy propyl alcohol amidogen ether;
Described pigment is transparent pigment;
Described antifriction liniment is selected from a kind of in PE wax, PP wax, polyamide wax, the white carbon black;
Initiator A is selected from UVNUL MS-40 or 4-phenyl benzophenone;
Initiator B is selected from 2-hydroxy-2-methyl-1-phenyl-acetone, 1-hydroxy-cyclohexyl phenyl ketone or 2-methyl-2-(4-morpholinyl)-1-[4-(methylthio group) phenyl]-1-acetone;
Described organic amine auxiliary agent is selected from N, N-dipropyl-1-propylamine, N, accelerine or dodecyl dimethyl tertiary amine.
By the ordinary method preparation.
Embodiment 2, a kind of printing ink that replaces lining paper in the aluminium foil, and it is to be processed by following materials of weight proportions:
Resin 65; Reactive thinner 65;
Dispersion agent 2; Flow agent 2;
Skimmer 1; Pigment 25;
Antifriction liniment 1; Initiator A 7;
Initiator B 5; Organic amine auxiliary agent 15;
Selecting for use of each raw material is identical with embodiment 1.
Its preparation method is:
(1) take by weighing raw material by weight ratio, choosing gets pre-dispersed liquid with resin, reactive thinner and the flow agent blending dispersion of the whole of dispersion agent, skimmer and 60%;
(2) pigment and antifriction liniment are dropped in the pre-dispersed liquid, be ground to fineness less than 10 microns, get mill base through three-roller;
(3) with remaining resin, reactive thinner and flow agent, and mix with mill base in initiator A, initiator B and the organic amine auxiliary agent input mill base, be uniformly dispersed under the normal temperature, get finished product.
Embodiment 3, a kind of printing ink that replaces lining paper in the aluminium foil, and it is to be processed by following materials of weight proportions:
Resin 40; Reactive thinner 50;
Dispersion agent 1.2; Flow agent 1.2;
Skimmer 0.5; Pigment 17;
Antifriction liniment 0.5; Initiator A 4.5;
Initiator B 3; Organic amine auxiliary agent 10.
Selecting for use of each raw material is identical with embodiment 1.
Its preparation method is:
(1) take by weighing raw material by weight ratio, choosing gets pre-dispersed liquid with resin, reactive thinner and the flow agent blending dispersion of the whole of dispersion agent, skimmer and 40%;
(2) pigment and antifriction liniment are dropped in the pre-dispersed liquid, be ground to fineness less than 10 microns, get mill base through three-roller;
(3) with remaining resin, reactive thinner and flow agent, and mix with mill base in initiator A, initiator B and the organic amine auxiliary agent input mill base, be uniformly dispersed under the normal temperature, get finished product.
Embodiment 4, the printing ink of lining paper in embodiment 1 or the 2 or 3 described replacement aluminium foils: described dispersion agent is selected from carboxylate salt, sulfuric acid, polyethylene glycol type polyvalent alcohol, polyethylenimine derivates, how joins the reactant of polyvalent alcohol-many ethyleneimines segmented copolymer or many caprolactones and triethylene tetramine in.
Embodiment 5, and the printing ink of lining paper in embodiment 1 or the 2 or 3 described replacement aluminium foils: described flow agent is selected from YSR 3286, PSI, organic radical modified polyorganosiloxane, polyfluoro polyene hydrocarbon or fluorin modified crylic acid.
Embodiment 6, the printing ink of lining paper in embodiment 1 or the 2 or 3 described replacement aluminium foils: one or more in described pigment transparent yellow, transparent red, the transparent basket.
Embodiment 7, a kind of printing ink that replaces lining paper in the aluminium foil, and it is to be processed by following materials of weight proportions:
Resin 40; Reactive thinner 50;
Dispersion agent 1.2; Flow agent 1.2;
Skimmer 0.5; Pigment 17;
Antifriction liniment 0.5; Initiator A 4.5;
Initiator B 3; Organic amine auxiliary agent 10.
Described resin is the compsn that epoxy acrylate and Vinylite are formed;
Described reactive thinner is two mixtures that propylene glycol diacrylate and Viscoat 295 form that contract;
Described skimmer is a ZGK 5;
Described pigment is transparent yellow;
Described antifriction liniment is a PE wax;
Initiator A is a UVNUL MS-40;
Initiator B is 2-hydroxy-2-methyl-1-phenyl-acetone;
Described organic amine auxiliary agent is N, N-dipropyl-1-propylamine;
Described dispersion agent is a carboxylate salt;
Described flow agent is a YSR 3286;
Its preparation methods steps is following:
(1) take by weighing raw material by weight ratio, choosing gets pre-dispersed liquid with resin, reactive thinner and the flow agent blending dispersion of the whole of dispersion agent, skimmer and 50%;
(2) pigment and antifriction liniment are dropped in the pre-dispersed liquid, be ground to fineness less than 10 microns, get mill base through three-roller;
(3) with remaining resin, reactive thinner and flow agent, and mix with mill base in initiator A, initiator B and the organic amine auxiliary agent input mill base, be uniformly dispersed under the normal temperature, get finished product.
The technical indicator of gained finished product printing ink is following, and what index of correlation detected employing is prior art ordinary method and instrument:
| Index | Content |
| Solid content (%) | 25-50 |
| Fineness (um) | ≤10 |
| Attachment fastness (%) | 100 |
| Glossiness (60 degree) | ＞70 |
Claims (6)
1. printing ink that replaces lining paper in the aluminium foil is characterized in that it is to be processed by following materials of weight proportions:
Resin 20-65; Reactive thinner 35-65;
Dispersion agent 0.5-2; Flow agent 0.2-2;
Skimmer 0.1-1; Pigment 10-25;
Antifriction liniment 0.1-1; Initiator A 2-7;
Initiator B 1-5; Organic amine auxiliary agent 5-15;
Described resin is selected from the compsn of any two kinds of compositions in epoxy acrylate, urethane acrylate, polyester acrylate, polyether acrylate, ROHM propenoate, the Vinylite;
Described reactive thinner is two mixtures that any and Viscoat 295 in propylene glycol diacrylate, tripropylene glycol diacrylate, hexanediyl ester, the neopentylglycol diacrylate forms that contract;
Described dispersion agent is a kind of in anionic, non-ionic type or the polymer;
Described flow agent is a kind of in silicone based or the fluorine carbon;
Described skimmer is selected from a kind of in ZGK 5, dimethyl silicone oil, silicone emulsion, polyoxyethylene polyoxypropylene tetramethylolmethane ether, the T 46155 polyoxy propyl alcohol amidogen ether;
Described pigment is transparent pigment;
Described antifriction liniment is selected from a kind of in PE wax, PP wax, polyamide wax, the white carbon black;
Initiator A is selected from UVNUL MS-40 or 4-phenyl benzophenone;
Initiator B is selected from 2-hydroxy-2-methyl-1-phenyl-acetone, 1-hydroxy-cyclohexyl phenyl ketone or 2-methyl-2-(4-morpholinyl)-1-[4-(methylthio group) phenyl]-1-acetone;
Described organic amine auxiliary agent is selected from N, N-dipropyl-1-propylamine, N, accelerine or dodecyl dimethyl tertiary amine.
2. the printing ink of lining paper in the replacement aluminium foil according to claim 1 is characterized in that: described dispersion agent is selected from carboxylate salt, sulfuric acid, polyethylene glycol type polyvalent alcohol, polyethylenimine derivates, how joins the reactant of polyvalent alcohol-many ethyleneimines segmented copolymer or many caprolactones and triethylene tetramine in.
3. the printing ink of lining paper in the replacement aluminium foil according to claim 1, it is characterized in that: described flow agent is selected from YSR 3286, PSI, organic radical modified polyorganosiloxane, polyfluoro polyene hydrocarbon or fluorin modified crylic acid.
4. the printing ink of lining paper is characterized in that: one or more in described pigment transparent yellow, transparent red, the transparent basket in the replacement aluminium foil according to claim 1.
5. the printing ink of lining paper in the replacement aluminium foil according to claim 1, it is characterized in that: the weight proportion of each raw material is:
Resin 40; Reactive thinner 50;
Dispersion agent 1.2; Flow agent 1.2;
Skimmer 0.5; Pigment 17;
Antifriction liniment 0.5; Initiator A 4.5;
Initiator B 3; Organic amine auxiliary agent 10.
6. preparation method like the printing ink of lining paper in any one described replacement aluminium foil of claim 1-5 is characterized in that its step is following:
(1) take by weighing raw material by weight ratio, choosing gets pre-dispersed liquid with resin, reactive thinner and the flow agent blending dispersion of the whole and 40-60% of dispersion agent, skimmer;
(2) pigment and antifriction liniment are dropped in the pre-dispersed liquid, be ground to fineness less than 10 microns, get mill base through three-roller;
(3) with remaining resin, reactive thinner and flow agent, and mix with mill base in initiator A, initiator B and the organic amine auxiliary agent input mill base, be uniformly dispersed under the normal temperature, get finished product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110345412.5A CN102382514B (en) | 2011-11-04 | 2011-11-04 | Ink for replacing aluminum foil lining paper and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110345412.5A CN102382514B (en) | 2011-11-04 | 2011-11-04 | Ink for replacing aluminum foil lining paper and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102382514A true CN102382514A (en) | 2012-03-21 |
| CN102382514B CN102382514B (en) | 2014-06-25 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201110345412.5A Active CN102382514B (en) | 2011-11-04 | 2011-11-04 | Ink for replacing aluminum foil lining paper and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102382514B (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103666066A (en) * | 2013-11-25 | 2014-03-26 | 铜陵方正塑业科技有限公司 | High-performance high-production-efficiency UV-cured printing ink and preparation method thereof |
| CN103666097A (en) * | 2013-11-25 | 2014-03-26 | 铜陵方正塑业科技有限公司 | UV printing ink for silk-screen printing and preparation method thereof |
| CN103666058A (en) * | 2013-11-25 | 2014-03-26 | 铜陵方正塑业科技有限公司 | UV curing offset printing ink and preparation method thereof |
| CN107266968A (en) * | 2017-08-15 | 2017-10-20 | 南宁东印时代广告有限公司 | A kind of indoor wallpaper ink and preparation method thereof |
| CN107780295A (en) * | 2017-09-12 | 2018-03-09 | 昆明理工大学 | It is a kind of to be used to allocate water paint of cigarette liner paper and coating and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101665643A (en) * | 2009-09-18 | 2010-03-10 | 林国顺 | Ultraviolet curing pearl ink |
| CN102093782A (en) * | 2011-03-30 | 2011-06-15 | 北京神彩优维喷墨材料科技有限公司 | Ultraviolet-cured digital painting ink and preparation method thereof |
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2011
- 2011-11-04 CN CN201110345412.5A patent/CN102382514B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101665643A (en) * | 2009-09-18 | 2010-03-10 | 林国顺 | Ultraviolet curing pearl ink |
| CN102093782A (en) * | 2011-03-30 | 2011-06-15 | 北京神彩优维喷墨材料科技有限公司 | Ultraviolet-cured digital painting ink and preparation method thereof |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103666066A (en) * | 2013-11-25 | 2014-03-26 | 铜陵方正塑业科技有限公司 | High-performance high-production-efficiency UV-cured printing ink and preparation method thereof |
| CN103666097A (en) * | 2013-11-25 | 2014-03-26 | 铜陵方正塑业科技有限公司 | UV printing ink for silk-screen printing and preparation method thereof |
| CN103666058A (en) * | 2013-11-25 | 2014-03-26 | 铜陵方正塑业科技有限公司 | UV curing offset printing ink and preparation method thereof |
| CN107266968A (en) * | 2017-08-15 | 2017-10-20 | 南宁东印时代广告有限公司 | A kind of indoor wallpaper ink and preparation method thereof |
| CN107780295A (en) * | 2017-09-12 | 2018-03-09 | 昆明理工大学 | It is a kind of to be used to allocate water paint of cigarette liner paper and coating and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102382514B (en) | 2014-06-25 |
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