CN102604479B - Ultraviolet radiation curing gravure freezing-point ink and preparation method thereof - Google Patents
Ultraviolet radiation curing gravure freezing-point ink and preparation method thereof Download PDFInfo
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Abstract
The invention relates to an ultraviolet radiation curing gravure freezing-point ink and a preparation method thereof. The ink comprises the following raw materials in parts by weight of: 15-25 parts of unsaturated acrylate resin, 15-25 parts of polyketone resin, 25-35 parts of acrylate monomer, 1-2 parts of matt powders, 5-8 parts of wax powders, 2-8 parts of inorganic filler, 0.4-0.8 parts of antifoaming agents, 0.6-1.0 part of wetting and leveling agents, 5-10 parts of photoinitiators, and 5-10 parts of promoters. The preparation method of the ultraviolet radiation curing gravure freezing-point ink comprises a step of pre-preparing resin liquid and a step of mixing, dispersing and tempering. The invention provides the ultraviolet radiation curing gravure freezing-point ink, which has the advantages of environmental friendless, no toxicity, no pollution, no emission of harmless gas, rapid printing speed and high production efficiency.
Description
Technical field
The present invention relates to a kind of technical field of tobacco bale surface printing printing ink, be specifically related to a kind of tobacco bale surface ultraviolet ray radiation curing gravure freezing point printing ink and preparation method thereof.
Background technology
Tobacco bale is as a kind of design and wrapped product of uniqueness, and it is the symbol of brand.Simultaneously, the variation of Material Cost, cost of labor also allows the tobacco bale design be faced with lot of challenges with printing.The pattern that it is dumb light that present tobacco bale printed decoration industry has a kind of surface, have the crystal lines, have the hand sense of touch to feel, in order to reach this kind of effect, printing-ink must be prepared especially.The printing-ink that can reach above-mentioned effect used now is all to adopt solvent ink for screen printing or UV ink for screen printing to be printed usually.But above-mentioned these two kinds of printing ink have its weak point: 1, the solvent ink for screen printing is used volatile solvent, and environment is caused to larger pollution; 2, UV ink for screen printing print speed is very slow, and production efficiency is low, can't meet the demand of a large amount of quick prints.Therefore, we are badly in need of a kind ofly can either reaching above-mentioned tobacco bale printing effect, can accomplish again environmental protection, the printing-ink that pollution-free, print speed is fast, production efficiency is high.
Summary of the invention
The objective of the invention is in order to overcome the defect of above-mentioned prior art, provide a kind of environmental protection, nontoxic, pollution-free, without noxious gas emission, print speed is fast, production efficiency is high solidified by ultraviolet ray radiation gravure freezing point printing ink.
Another goal of the invention of the present invention is to provide a kind of method for preparing above-mentioned solidified by ultraviolet ray radiation gravure freezing point printing ink.
Technical scheme of the present invention
The raw material that a kind of solidified by ultraviolet ray radiation gravure freezing point printing ink comprises following weight proportion:
15 ~ 25 parts of unsaturated acrylate resins; 15 ~ 25 parts of polyketone resins;
25 ~ 35 parts of acrylate monomers; 1 ~ 2 part, dumb light powder;
5 ~ 8 parts, wax powder; 2 ~ 8 parts of inorganic fillings;
0.4 ~ 0.8 part of defoamer; 0.6 ~ 1.0 part of moistening flatting agent;
5 ~ 10 parts of light triggers; 5 ~ 10 parts of aided initiatings.
The raw material that a kind of solidified by ultraviolet ray radiation gravure freezing point printing ink comprises following weight proportion:
16 parts of unsaturated acrylate resins; 16 parts of polyketone resins;
34 parts of acrylate monomers; 2 parts, dumb light powder;
7 parts, wax powder; 1 part of inorganic fillings;
0.7 part of defoamer; 0.6 part of moistening flatting agent;
6 parts of light triggers; 6 parts of aided initiatings.
The raw material that a kind of solidified by ultraviolet ray radiation gravure freezing point printing ink comprises following weight proportion:
20 parts of unsaturated acrylate resins; 20 parts of polyketone resins;
30 parts of acrylate monomers; 1.5 parts, dumb light powder;
7 parts, wax powder; 5 parts of inorganic fillings;
0.6 part of defoamer; 0.8 part of moistening flatting agent;
8 parts of light triggers; 8 parts of aided initiatings.
A kind of solidified by ultraviolet ray radiation gravure freezing point printing ink, the combination that described unsaturated acrylate resin is any one or any two in polyurethane acrylate resin or polyester acrylate resin or Epocryl; Polyketone resin is aldehyde ketone resin or polyketone resin; Acrylate monomer is the combination of any one or two kinds in 1,6-glycol diacrylate or tripropylene glycol diacrylate; The combination that the dumb light powder is the silicon-dioxide flatting silica processed through wax of surface or any one or two kinds in the general silica flatting silica; The combination that the wax powder is any one or any two in PP wax powder, PE wax powder or tetrafluoroethylene wax powder; The combination that inorganic fillings is any one or any two in talcum powder, Paris white or zinc white; Defoamer is silicone based defoamer; Moistening flatting agent is methyl polysilicone alkanes moistening flatting agent; Light trigger is isopropyl thioxanthone, aminoacetophenone, dimethyl benzil ketals, 2-hydroxy-2-methyl-to hydroxyethyl ether phenyl-acetone, 2-first class 1-4-methylthio group phenyl-2-morpholine acetone-1,2, the combination of any three kinds or any four kinds in these seven kinds of materials of 4,6-trimethylbenzoyl-oxyethyl group-phenyl phosphorus oxide; Aided initiating is any one in tertiary amine acrylate or thanomin acrylate.
Technical solution of the present invention also comprises that a kind of method concrete steps that prepare solidified by ultraviolet ray radiation gravure freezing point printing ink are as follows:
1. prewired resin liquid: in the stirred opening cylinder of a constant volume, at first add part propylene acid esters monomer to adopt the disc type stirring rake, rotating speed is 200 ~ 400 to turn and disperseed; Then dropping into while stirring polyketone resin rotating speed >=1200 turns and is disperseed 50 ~ 80 minutes;
2. blending dispersion is modified: first residual acrylic acid ester monomer is dropped in the opening cylinder, rotating speed is adjusted to 200 ~ 400 and turns stirring, then, in the solid photoinitiator input cylinder, is heated to while stirring 50 ~ 55 ℃, is dispersed to solid photoinitiator and all dissolves; Then prewired resin liquid, unsaturated acrylate resin, aided initiating are dropped in the opening cylinder, be cooled to while stirring below 45 ℃; Drop into successively again dumb light powder, wax powder, inorganic fillings, defoamer, levelling wetting agent, adopt disc type rotating speed of agitator >=1200 to turn and disperseed 30 ~ 50 minutes, be up to the standards and get final product.
Wherein, unsaturated acrylate resin is a kind of of polyurethane acrylate resin or polyester acrylate resin or Epocryl or two kinds.These three kinds of resins are that the preliminary election wettability is good, sticking power is good, snappiness good, good leveling property, product that light-cured performance is good.Molecular weight 1000-2000, the second-order transition temperature 45-85 ℃ of the unsaturated acrylate resin of preliminary election.
Polyketone resin is a kind of of aldehyde ketone resin and polyketone resin.The product that branching is good, taste is low, film forming is good that these two kinds of resins are preliminary elections.Molecular weight 3000-5000, the second-order transition temperature 35-45 ℃ of the polyketone resin of preliminary election.
Acrylic Acid Monomer is a kind of of 1,6 glycol diacrylate and tripropylene glycol diacrylate (being called for short TPGDA) or two kinds.These two kinds of Acrylic Acid Monomer dilution properties are good, non-volatile, the film forming rate of crosslinking is fast, smell is low, hypotoxicity and low skin irritability.The molecular weight 220-260 of the acrylate monomer of preliminary election, second-order transition temperature 40-65 ℃.
Preliminary election dumb light powder fineness 2-6um.Wax powder fineness 5-10um.Talcum powder is ultra-fine grain diameter, fineness 2000-5500 order.
Isopropyl thioxanthone Chinese another name: isopropyl thioxanthone (being divided into again two kinds of 2-isopropyl thioxanthone and 4-isopropyl thioxanthones), light initiator-ITX, be called for short IXT, as light trigger, cost performance is relatively better, is particularly suitable for the photocuring of titanium dioxide coloring system; Aminoacetophenone claims again ethanoyl aniline, and 3 kinds of isomer are arranged, o-aminoacetophenone, m-aminophenyl ethyl ketone, para-aminoacetophenone, and molecular formula is C8H9NO; Wax powder series comprises TF-1780, TF-1778, TF-1830, PE-1500F, PP-1362D; 2,4,6-trimethylbenzoyl-oxyethyl group-phenyl phosphorus oxide is called for short TPO.
Through experimental verification, the present invention has following advantage: 1, this kind of solidified by ultraviolet ray radiation gravure freezing point printing ink environmental protection, nontoxic, pollution-free, without noxious gas emission; 2, good, the good hand touch of scrath resistance; 3, the printing good stability, print trouble free for a long time; 4, print speed is fast, production efficiency is high; 5, the preparation method is easy.
Embodiment
The raw material that a kind of solidified by ultraviolet ray radiation gravure freezing point printing ink comprises following weight proportion: unsaturated acrylate resin 15-25 part; Polyketone resin 15-25 part; Acrylate monomer 25-35 part; Dumb light powder 1-2 part; Wax powder 5-8 part; Inorganic fillings 2-8 part; Defoamer 0.4-0.8 part; Moistening flatting agent 0.6-1.0 part; Light trigger 5-10 part; Aided initiating 5-10 part.
Embodiment 1
The raw material that a kind of solidified by ultraviolet ray radiation gravure freezing point printing ink comprises following weight proportion: 15 parts of polyurethane acrylate resins; 17 parts of aldehyde ketone resins; 26 parts of 1,6-glycol diacrylates; 1 part of general silica flatting silica; 6 parts, PP wax powder; Totally 6 parts of talcum powder and Paris whites; 0.4 part of silicone based defoamer; 0.8 part of methyl polysilicone alkanes moistening flatting agent; Totally 9 parts of isopropyl thioxanthone and aminoacetophenone and dimethyl benzil ketals; 5 parts of tertiary amine acrylate.
Embodiment 2
The raw material that a kind of solidified by ultraviolet ray radiation gravure freezing point printing ink comprises following weight proportion: totally 25 parts of polyester acrylate resin and Epocryls; 15 parts of polyketone resins; 30 parts of tripropylene glycol diacrylates; 2 parts of the silicon-dioxide flatting silicas that process through wax on surface; Totally 8 parts, PE wax powder and tetrafluoroethylene wax powder; 2 parts of zinc whites; 0.8 part of silicone based defoamer; 0.6 part of methyl polysilicone alkanes moistening flatting agent; Dimethyl benzil ketals and 2-hydroxy-2-methyl-to totally 10 parts of hydroxyethyl ether phenyl-acetone and 2-first class 1-4-methylthio group phenyl-2-morpholine acetone-1 and 2,4,6-trimethylbenzoyl-oxyethyl group-phenyl phosphorus oxide; 10 parts of thanomin acrylate.
Embodiment 3
The raw material that a kind of solidified by ultraviolet ray radiation gravure freezing point printing ink comprises following weight proportion: totally 20 parts of polyurethane acrylate resin and Epocryls; 20 parts of aldehyde ketone resins; Totally 35 parts of 1,6-glycol diacrylate and tripropylene glycol diacrylates; Totally 1.1 parts of the silicon-dioxide flatting silica that process through wax on surface and general silica flatting silicas; Totally 5 parts, PP wax powder and tetrafluoroethylene wax powder; Totally 8 parts of Paris white and zinc whites; 0.5 part of silicone based defoamer; 1 part of methyl polysilicone alkanes moistening flatting agent; Totally 5 parts of isopropyl thioxanthone and dimethyl benzil ketals and 2-first class 1-4-methylthio group phenyl-2-morpholine acetone-1 and 2,4,6-trimethylbenzoyl-oxyethyl group-phenyl phosphorus oxide; 8 parts of thanomin acrylate.
Embodiment 4
The raw material that a kind of solidified by ultraviolet ray radiation gravure freezing point printing ink comprises following weight proportion: 16 parts of polyester acrylate resins; 25 parts of aldehyde ketone resins; 25 parts of 1,6-glycol diacrylates; 1.5 parts of the silicon-dioxide flatting silicas that process through wax on surface; 7 parts, tetrafluoroethylene wax powder; 4 parts of Paris whites; 0.7 part of silicone based defoamer; 0.9 part of methyl polysilicone alkanes moistening flatting agent; Aminoacetophenone and 2-hydroxy-2-methyl-to hydroxyethyl ether phenyl-acetone and 2,4,6-trimethylbenzoyl-oxyethyl group-7 parts of phenyl phosphorus oxide; 6 parts of tertiary amine acrylate.
Embodiment 5
The raw material that a kind of solidified by ultraviolet ray radiation gravure freezing point printing ink comprises following weight proportion: totally 24 parts of polyurethane acrylate resin and Epocryls; 16 parts of aldehyde ketone resins; Totally 31 parts of 1,6-glycol diacrylate and tripropylene glycol diacrylates; Totally 1.9 parts of the silicon-dioxide flatting silica that process through wax on surface and general silica flatting silicas; Totally 5.5 parts, PP wax powder and tetrafluoroethylene wax powder; Totally 5 parts of Paris white and zinc whites; 0.5 part of silicone based defoamer; 1 part of methyl polysilicone alkanes moistening flatting agent; Totally 5 parts of isopropyl thioxanthone and dimethyl benzil ketals and 2-first class 1-4-methylthio group phenyl-2-morpholine acetone-1 and 2,4,6-trimethylbenzoyl-oxyethyl group-phenyl phosphorus oxide; 8 parts of thanomin acrylate.
Embodiment 6
The raw material that a kind of solidified by ultraviolet ray radiation gravure freezing point printing ink comprises following weight proportion: totally 18 parts of polyester acrylate resin and Epocryls; 24 parts of polyketone resins; 34 parts of tripropylene glycol diacrylates; 1.7 parts of the silicon-dioxide flatting silicas that process through wax on surface; Totally 7.8 parts, PE wax powder and tetrafluoroethylene wax powder; 7.5 parts of zinc whites; 0.8 part of silicone based defoamer; 0.6 part of methyl polysilicone alkanes moistening flatting agent; Dimethyl benzil ketals and 2-hydroxy-2-methyl-to totally 10 parts of hydroxyethyl ether phenyl-acetone and 2-first class 1-4-methylthio group phenyl-2-morpholine acetone-1 and 2,4,6-trimethylbenzoyl-oxyethyl group-phenyl phosphorus oxide; 10 parts of thanomin acrylate.
The concrete step of the preparation method of above-mentioned a kind of solidified by ultraviolet ray radiation gravure freezing point printing ink comprises:
1. prewired resin liquid: in the stirred opening cylinder of a constant volume, at first add part propylene acid esters monomer to adopt the disc type stirring rake, rotating speed is 200 ~ 400 to turn and disperseed; Then dropping into while stirring polyketone resin rotating speed >=1200 turns and is disperseed 50 ~ 80 minutes;
2. blending dispersion is modified: first residual acrylic acid ester monomer is dropped in the opening cylinder, rotating speed is adjusted to 200 ~ 400 and turns stirring, then, in the solid photoinitiator input cylinder, is heated to while stirring 50 ~ 55 ℃, is dispersed to solid photoinitiator and all dissolves; Then prewired resin liquid, unsaturated acrylate resin, aided initiating are dropped in the opening cylinder, be cooled to while stirring below 45 ℃; Drop into successively again dumb light powder, wax powder, inorganic fillings, defoamer, levelling wetting agent, adopt disc type rotating speed of agitator >=1200 to turn and disperseed 30 ~ 50 minutes, be up to the standards and get final product.
Embodiment 7
At first prewired resin liquid: in the stirred opening cylinder of a constant volume, at first add 6.25 parts of 6.25 parts of 1,6 glycol diacrylates and tripropylene glycol diacrylates to adopt the disc type rotating speed of agitator probably to be disperseed between turning 200 ~ 400; Then dropping into while stirring 12.5 parts of polyketone resins adopts 1200 to turn above and carry out high speed dispersion 50 ~ 80 minutes.
Next carry out the modified step of blending dispersion: first by 1,6 20 parts of glycol diacrylates drop in the opening cylinder, turn and carry out stirring at low speed with 200 ~ 400, solid photoinitiator ITX(sec.-propyl thia ketone) in 2 parts and 1 part of aminoacetophenone and 3 parts of input cylinders of dimethyl benzil ketals, be heated to while stirring 50 ~ 55 ℃,, be dispersed to solid photoinitiator and all dissolve; Then by prewired resin liquid, 20 parts of polyurethane acrylate resins, 10 parts of tripropylene glycol diacrylates, 8 parts of input opening cylinders of aided initiating, be cooled to while stirring below 45 ℃; Drop into successively again 1 part, dumb light powder, 6 parts, wax powder, 2.6 parts of talcum powder, 0.6 part of silicone antifoam agent, 0.8 part of levelling wetting agent, adopt the disc type stirring rake to turn above rotating speed with 1200 and carry out high speed dispersion 30 ~ 50 minutes, finally check fineness, viscosity, branching effect, drying regime, transparency, the feel of output qualified, be finished product.
Claims (4)
1. a solidified by ultraviolet ray radiation gravure freezing point printing ink is characterized in that the raw material that it comprises following weight proportion:
15 ~ 25 parts of unsaturated acrylate resins; 15 ~ 25 parts of polyketone resins;
25 ~ 35 parts of acrylate monomers; 1 ~ 2 part, dumb light powder;
5 ~ 8 parts, wax powder; 2 ~ 8 parts of inorganic fillings;
0.4 ~ 0.8 part of defoamer; 0.6 ~ 1.0 part of moistening flatting agent;
5 ~ 10 parts of light triggers; 5 ~ 10 parts of aided initiatings;
The combination that described unsaturated acrylate resin is any one or any two in polyurethane acrylate resin or polyester acrylate resin or Epocryl, molecular weight 1000-2000, the second-order transition temperature 45-85 ℃ of described unsaturated acrylate resin;
Molecular weight 3000-5000, the second-order transition temperature 35-45 ℃ of described polyketone resin;
Described acrylate monomer is the combination of any one or two kinds in 1,6 hexanediol diacrylate or tripropylene glycol diacrylate, the molecular weight 220-260 of described acrylate monomer, second-order transition temperature 40-65 ℃;
The combination that described dumb light powder is the silicon-dioxide flatting silica processed through wax of surface or any one or two kinds in the general silica flatting silica, dumb light powder fineness 2-6 μ m; The combination that the wax powder is any one or any two in PP wax powder, PE wax powder or tetrafluoroethylene wax powder, wax powder fineness 5-10 μ m; The combination that inorganic fillings is any one or any two in talcum powder, Paris white or zinc white;
Described defoamer is silicone based defoamer; Moistening flatting agent is methyl polysilicone alkanes moistening flatting agent; Light trigger is isopropyl thioxanthone, aminoacetophenone, dimethyl benzil ketals, 2-hydroxy-2-methyl-to hydroxyethyl ether phenyl-acetone, 2-methyl isophthalic acid-(4-methylthio group phenyl)-2-morpholinyl-1-acetone, 2, the combination of any three kinds or any four kinds in 4,6-trimethylbenzoyl-oxyethyl group-six kinds of phenyl phosphorus oxide material; Aided initiating is tertiary amine acrylate or thanomin acrylate;
The method for preparing above-mentioned solidified by ultraviolet ray radiation gravure freezing point printing ink comprises following steps: each raw material is ready to by aforementioned weight proportion,
1. prewired resin liquid: in can stirring the opening cylinder, at first add part propylene acid esters monomer to adopt the disc type stirring rake, rotating speed is 200 ~ 400 to turn and disperseed; Then dropping into while stirring polyketone resin rotating speed >=1200 turns and is disperseed 50 ~ 80 minutes;
2. blending dispersion is modified: first residual acrylic acid ester monomer is dropped in the opening cylinder, rotating speed is adjusted to 200 ~ 400 and turns stirring, then, in the solid photoinitiator input cylinder, is heated to while stirring 50 ~ 55 ℃, is dispersed to solid photoinitiator and all dissolves; Then prewired resin liquid, unsaturated acrylate resin, aided initiating are dropped in the opening cylinder, be cooled to while stirring below 45 ℃; Drop into successively again dumb light powder, wax powder, inorganic fillings, defoamer, moistening flatting agent, adopt disc type rotating speed of agitator >=1200 to turn and disperseed 30 ~ 50 minutes, be up to the standards and get final product.
2. solidified by ultraviolet ray radiation gravure freezing point printing ink according to claim 1 is characterized in that the raw material that it comprises following weight proportion:
16 parts of unsaturated acrylate resins; 16 parts of polyketone resins;
34 parts of acrylate monomers; 2 parts, dumb light powder;
7 parts, wax powder; 1 part of inorganic fillings;
0.7 part of defoamer; 0.6 part of moistening flatting agent;
6 parts of light triggers; 6 parts of aided initiatings.
3. solidified by ultraviolet ray radiation gravure freezing point printing ink according to claim 1 is characterized in that the raw material that it comprises following weight proportion:
20 parts of unsaturated acrylate resins; 20 parts of polyketone resins;
30 parts of acrylate monomers; 1.5 parts, dumb light powder;
7 parts, wax powder; 5 parts of inorganic fillings;
0.6 part of defoamer; 0.8 part of moistening flatting agent;
8 parts of light triggers; 8 parts of aided initiatings.
4. a method for preparing solidified by ultraviolet ray radiation gravure freezing point printing ink as described as claim 1～3 any one, it is characterized in that comprising following steps: each raw material is ready to by aforementioned weight proportion,
1. prewired resin liquid: in can stirring the opening cylinder, at first add part propylene acid esters monomer to adopt the disc type stirring rake, rotating speed is 200 ~ 400 to turn and disperseed; Then dropping into while stirring polyketone resin rotating speed >=1200 turns and is disperseed 50 ~ 80 minutes;
2. blending dispersion is modified: first residual acrylic acid ester monomer is dropped in the opening cylinder, rotating speed is adjusted to 200 ~ 400 and turns stirring, then, in the solid photoinitiator input cylinder, is heated to while stirring 50 ~ 55 ℃, is dispersed to solid photoinitiator and all dissolves; Then prewired resin liquid, unsaturated acrylate resin, aided initiating are dropped in the opening cylinder, be cooled to while stirring below 45 ℃; Drop into successively again dumb light powder, wax powder, inorganic fillings, defoamer, moistening flatting agent, adopt disc type rotating speed of agitator >=1200 to turn and disperseed 30 ~ 50 minutes, be up to the standards and get final product.
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| CN103642314A (en) * | 2013-12-11 | 2014-03-19 | 苏州谊恒印务有限公司 | Light curing flexographic printing ink |
| CN103709826B (en) * | 2013-12-30 | 2014-12-24 | 东莞智源彩印有限公司 | Gravure freezing point snowflake ink and preparation method thereof |
| JP6233143B2 (en) * | 2014-03-31 | 2017-11-22 | 東洋インキＳｃホールディングス株式会社 | Active energy ray curable ink and printed matter |
| CN106349807B (en) * | 2016-09-29 | 2017-06-30 | 东莞智源彩印有限公司 | A kind of UV offset printings freezing point ink and preparation method thereof |
| CN109082157B (en) * | 2018-07-23 | 2021-06-18 | 惠州市至上新材料有限公司 | Ultraviolet curing offset printing ink with ice flower effect and preparation method and application thereof |
| CN109749509B (en) * | 2018-12-10 | 2022-01-04 | 深圳市深赛尔股份有限公司 | LED-UV ink with snowflake special effect and preparation method thereof |
| CN109852131A (en) * | 2018-12-12 | 2019-06-07 | 杭州全为包装印刷有限公司 | A kind of flexible simulation gravure printing ink and preparation method thereof |
| CN110183899A (en) * | 2019-07-09 | 2019-08-30 | 湖南省浩彩新材料科技有限公司 | UV snowflake printing ink |
| CN112011214A (en) * | 2020-09-04 | 2020-12-01 | 苏州工业园区彩迪包装印刷有限公司 | Offset printing ultraviolet curing scratch-resistant oil and production process thereof |
| CN115558389B (en) * | 2022-02-25 | 2024-01-12 | 上海欧畅新材料科技有限公司 | Polyurethane-acrylate hand feeling coating and preparation method and application method thereof |
| CN115851083B (en) * | 2022-12-17 | 2023-11-10 | 鹤山市君子兰涂料有限公司 | Electrostatic spraying flame-retardant UV (ultraviolet) finish paint and preparation process thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102382508A (en) * | 2011-09-07 | 2012-03-21 | 张家港市威迪森油墨有限公司 | Printing ink for identifying electronic component by curing with ultraviolet light and preparation method thereof |
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| AU3210000A (en) * | 1999-02-19 | 2000-09-04 | Markem Corporation | Stable titanium dioxide containing ink jet ink composition |
-
2012
- 2012-04-09 CN CN2012101010711A patent/CN102604479B/en active Active
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102382508A (en) * | 2011-09-07 | 2012-03-21 | 张家港市威迪森油墨有限公司 | Printing ink for identifying electronic component by curing with ultraviolet light and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 凌云星等.实用油墨技术指南.《实用油墨技术指南》.印刷工业出版社,2007,(第1版),全文. * |
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