CN108249720A - A kind of method that mechanical dehydration coupling desiccation pyrolysis prepares sludge carbon - Google Patents

A kind of method that mechanical dehydration coupling desiccation pyrolysis prepares sludge carbon Download PDF

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Publication number
CN108249720A
CN108249720A CN201810206001.XA CN201810206001A CN108249720A CN 108249720 A CN108249720 A CN 108249720A CN 201810206001 A CN201810206001 A CN 201810206001A CN 108249720 A CN108249720 A CN 108249720A
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Prior art keywords
sludge
sent
carbon
flue gas
pyrolysis
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CN201810206001.XA
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Chinese (zh)
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CN108249720B (en
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孟辉
景元琢
周学坤
肖培蒙
强宁
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Shandong Jinfu Environment Engineering Co Ltd
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Shandong Jinfu Environment Engineering Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/008Sludge treatment by fixation or solidification
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/10Treatment of sludge; Devices therefor by pyrolysis
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/12Treatment of sludge; Devices therefor by de-watering, drying or thickening
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/12Treatment of sludge; Devices therefor by de-watering, drying or thickening
    • C02F11/121Treatment of sludge; Devices therefor by de-watering, drying or thickening by mechanical de-watering
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10BDESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B53/00Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/20Heavy metals or heavy metal compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00Specific treatment goals
    • C02F2303/06Sludge reduction, e.g. by lysis
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/40Valorisation of by-products of wastewater, sewage or sludge processing

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Treatment Of Sludge (AREA)
  • Solid Fuels And Fuel-Associated Substances (AREA)

Abstract

The present invention relates to the methods that a kind of coupling desiccation pyrolysis of mechanical dehydration prepares sludge carbon, it receives and stores including sludge, mechanical presses are dehydrated, heating power breaks up desiccation, medium temperature pyrolysis charring, heavy metals immobilization, Carbon Materials cooling packing, the wet mud of high-moisture (80%~90%) is made to pass through depth machinery extrusion dehydration, heating power desiccation, pyrolysis charring, after the techniques such as heavy metals immobilization, it is prepared into Carbon Materials, the cost of Treatment of Sludge can be reduced, realize the thorough minimizing of sludge simultaneously, bioxin is not generated in the process, heavy metal in solidification sludge, retain the nutrients such as N P and K in sludge, product sludge carbon can be safely used for afforestation Nutrition Soil or fuel, recycling for sludge finds a new outlet, with important social benefit and environmental benefit.

Description

A kind of method that mechanical dehydration coupling desiccation pyrolysis prepares sludge carbon
Technical field
The present invention relates to sludge treatment field, and in particular to a kind of mechanical dehydration coupling desiccation pyrolysis prepares the side of sludge carbon Method.
Background technology
With the fast development of Chinese society economy and Development of China's Urbanization, the scale of municipal sewage plant constantly expands, Sludge yield also increases considerably.The disposal options of sludge are mainly with aerobic compost, landfill, burning etc. at present.
Sludge aerobic compost can utilize sludge in organic principle, but due to Heavy Metals in Sludge in composting process not It can cure, have the risk that can be discharged into environment, the Ministry of Agriculture forbids sludge manure to enter farmland, while needs to add in aerobic process A large amount of base-material, is not reduced not only, but also causes increment, therefore there are risks for this method.
Sludge incineration technology can realize the thorough minimizing of sludge, and there are two types of modes at present, and a kind of is 80% moisture content Sludge directly burns, and this method sludge calorific value is zero or negative value, and very big, 5% of mixed-fuel burning proportion no more than fuel is impacted to boiler, Treating capacity is limited.Another kind is burned after sludge drying, and which is solved to boiler combustion shock problem.But the mode burned Bioxin is easily generated, and when sludge mixes burning in existing boiler can generate bioxin, station boiler almost all is not provided with The treatment facility of bioxin, You dioxin emission risks.
Invention content
The purpose of the present invention is to provide the methods that a kind of coupling desiccation pyrolysis of mechanical dehydration prepares sludge carbon.
The technical solution adopted by the present invention to solve the technical problems is:A kind of mechanical dehydration coupling desiccation pyrolysis prepares dirty The method of peat receives storage including sludge, mechanical presses dehydration, heating power break up desiccation, medium temperature pyrolysis charring, heavy metal are solid Change, Carbon Materials cooling packing, be as follows:
(1) by sewage plant Automobile Transportation Lai moisture content 80% or so wet mud, after truck scale Weighing, send Enter sludge and receive storage warehouse, received and kept in;
(2) sludge pump of storage warehouse bottom is received by sludge, sludge is sent by pipeline to mechanical dehydration feed arrangement, After sludge is sent into mechanical dehydration device by mechanical dehydration feed arrangement, moisture percentage in sewage sludge is reduced to 60% or so from 80%, dirt Mud is reduced at least 50% in this link;
(3) semi-dry sludge of moisture content 60% or so is after the discharge of mechanical dehydration drawing mechanism, by feeding device of drier Be sent into sludge drier, copy plate is provided with inside sludge drier and breaks up mechanism, by sludge with flue gas drying process Middle to carry out violent heat and mass, moisture percentage in sewage sludge is reduced to 30~40% from 60%, is then discharged from drying machine end;It carries After cyclone collection, sludge summarizes the flue gas of dust after the drying with the discharge of drying machine end, is sent into Sludge carbonization furnace Feed arrangement;
(4) sludge of moisture content after drying 30~40% is sent into the center of Sludge carbonization furnace by Sludge carbonization furnace feed arrangement In cylinder, in carbonization process, inner cylinder slowly rotates, and sludge is heated to 500-700 DEG C in inner cylinder and is thermally decomposed, the dirt after pyrolysis Peat send to sludge carbon cooling device from the discharge of Sludge carbonization furnace end, is cooled to room temperature;
(5) sludge carbon after cooling promotes conveying device through sludge carbon, send to sludge carbon storage warehouse, sludge is sent by bottom Charcoal packing machine is transported outward after packaging.
Specifically, sludge in pyrolytic process, releases pyrolysis gas in Sludge carbonization furnace in the step 4), is pyrolyzed pneumatic transmission Burning generation high-temperature flue gas is carried out after entering pyrolysis gas combustion tower, when sludge calorific value is relatively low, supplements biomass fuel or natural gas Supply heat.
Specifically, in the step 4) pyrolysis gas combustion tower generate high-temperature flue gas after the adjustment after temperature 800~900 DEG C, multiple high-temperature flue gas air inlets of feeding sludge carbonization furnace bottom;After heat is released to sludge carbonization process, from barrel tip Sludge drier is sent into after discharge, carries out contact heat-exchanging with sludge, the flue-gas temperature after heat exchange is reduced to 100~130 DEG C, from dirt Mud drying machine outlet discharge is sent into washing deduster after cyclone dust collectors dedusting, through air-introduced machine, removes the dust in flue gas, removes Flue gas after dirt enters extracting tower, in this link after lye cycle washing, removes the sulfur dioxide sour gas in flue gas, takes off Flue gas after acid enters deodorization device, removes volatile organic matter therein, finally enters de- white device, in deep removal flue gas Moisture content after, qualified discharge to air.
The invention has the advantages that:The method that the present invention prepares sludge carbon makes the wet of high-moisture (80%~90%) Sludge is prepared into Carbon Materials, both after the techniques such as depth machinery extrusion dehydration, heating power desiccation, pyrolysis charring, heavy metals immobilization The cost of Treatment of Sludge can be reduced, while realizes the thorough minimizing of sludge, does not generate bioxin in the process, the weight in solidification sludge Metal, afforestation or fuel can be can be safely used for by retaining nutrients, the product sludge carbon such as N P and K in sludge, be sludge Recycling finds a new outlet, has important social benefit and environmental benefit.
Description of the drawings
Fig. 1 is the flow diagram that mechanical dehydration coupling desiccation pyrolysis of the present invention prepares sludge carbon.
1st, truck scale, 2, sludge receive storage warehouse, 3, sludge pump, 4, mechanical dehydration feed arrangement, 5, mechanical dehydration device, 6th, mechanical dehydration drawing mechanism, 7, feeding device of drier, 8, sludge drier, 9, cyclone dust collectors, 10, Sludge carbonization furnace into Expect device, 11, Sludge carbonization furnace, 12, high-temperature flue gas air inlet, 13, sludge carbon cooling device, 14, sludge carbon promote conveying dress It puts, 15, sludge carbon storage warehouse, 16, sludge carbon packing machine, 17, feeding device, 18, pyrolysis gas combustion tower, 19, air-introduced machine, 20, Wash deduster, 21, extracting tower, 22, deodorization device, 23, take off white device.
Specific embodiment
The following is specific embodiments of the present invention, and technical scheme of the present invention is described further, but the present invention Protection domain is not limited to these embodiments.It is every to be included in the present invention without departing substantially from the change of present inventive concept or equivalent substitute Protection domain within.
As shown in Figure 1, a kind of method that mechanical dehydration coupling desiccation pyrolysis prepares sludge carbon, stored including sludge reception, Mechanical presses dehydration, heating power break up desiccation, medium temperature pyrolysis charring, heavy metals immobilization, Carbon Materials cooling packing, and specific steps are such as Under:
(1) by sewage plant Automobile Transportation Lai moisture content 80% or so wet mud, after 1 Weighing of truck scale, It is sent into sludge and receives storage warehouse 2, received and kept in;
(2) sludge pump 3 of 2 bottom of storage warehouse is received by sludge, sludge is sent by pipeline to mechanical dehydration and feeds dress 4, after sludge is sent into mechanical dehydration device 5 by mechanical dehydration feed arrangement 4 are put, moisture percentage in sewage sludge is reduced to 60% left side from 80% The right side, sludge are reduced at least 50% in this link;
(3) semi-dry sludge of moisture content 60% or so is after the discharge of mechanical dehydration drawing mechanism 6, by feeding device of drier 7 are sent into sludge driers 8, and the inside of sludge drier 8 is provided with copy plate and breaks up mechanism, by sludge with flue gas drying mistake Violent heat and mass is carried out in journey, moisture percentage in sewage sludge is reduced to 30~40% from 60%, is then discharged from drying machine end;It takes After the collection of cyclone separator 9, sludge summarizes flue gas with dust after the drying with the discharge of drying machine end, is sent into sludge carbonization Stove feed arrangement 10;
(4) sludge of moisture content after drying 30~40% is sent into Sludge carbonization furnace 11 by Sludge carbonization furnace feed arrangement 10 In central tube, in carbonization process, inner cylinder slowly rotates, and sludge is heated to 500~700 DEG C in inner cylinder and is thermally decomposed, pyrolysis Sludge carbon afterwards send to sludge carbon cooling device 13 from the discharge of 11 end of Sludge carbonization furnace, is cooled to room temperature;
(5) sludge carbon after cooling promotes conveying device 14 through sludge carbon, send to sludge carbon storage warehouse 15, is sent by bottom Sludge carbon packing machine 16 is transported outward after packaging.
Sludge in pyrolytic process, releases pyrolysis gas in Sludge carbonization furnace 11 in the step 4), and pyrolysis gas is sent into heat It vents one's spleen and burning is carried out after combustion tower 18 generates high-temperature flue gas, when sludge calorific value is relatively low, biomass fuel is supplemented by feeding device 17 Material, which supplements biomass fuel or is passed directly into natural gas, supplies heat.
The high-temperature flue gas that pyrolysis gas combustion tower 18 generates in the step 4) after the adjustment at 800~900 DEG C, be sent by rear temperature Multiple high-temperature flue gas air inlets 12 of 11 bottom of Sludge carbonization furnace;After heat is released to sludge carbonization process, arranged from barrel tip Sludge drier 8 is sent into after going out, carries out contact heat-exchanging with sludge, the flue-gas temperature after heat exchange is reduced to 100~130 DEG C, from dirt The outlet of mud drying machine 8 discharge is sent into washing deduster 20 after 9 dedusting of cyclone dust collectors, through air-introduced machine 19, removes in flue gas Dust, the flue gas after dedusting enter extracting tower 21, in this link after lye cycle washing, remove the titanium dioxide sulfuric acid in flue gas Property gas, the flue gas after depickling enter deodorization device 22, remove volatile organic matter therein, finally enter de- white device 23, After moisture content in deep removal flue gas, qualified discharge to air.
The present invention is not limited to the above-described embodiments, anyone should learn that the structure made under the enlightenment of the present invention becomes Change, the technical schemes that are same or similar to the present invention are each fallen within protection scope of the present invention.
The present invention be not described in detail technology, shape, construction part be known technology.

Claims (3)

1. a kind of method that mechanical dehydration coupling desiccation pyrolysis prepares sludge carbon, which is characterized in that receive storage, machine including sludge Tool extrusion dehydration, heating power break up desiccation, medium temperature pyrolysis charring, heavy metals immobilization, Carbon Materials cooling packing, are as follows:
(1) by sewage plant Automobile Transportation Lai moisture content 80% or so wet mud, after truck scale Weighing, be sent into dirty Mud receives storage warehouse, is received and is kept in;
(2) sludge pump of storage warehouse bottom is received by sludge, sludge is sent by pipeline to mechanical dehydration feed arrangement, sludge After being sent into mechanical dehydration device by mechanical dehydration feed arrangement, moisture percentage in sewage sludge is reduced to 60% or so from 80%, sludge exists This link decrement at least 50%;
(3) semi-dry sludge of moisture content 60% or so is sent into after the discharge of mechanical dehydration drawing mechanism by feeding device of drier Copy plate is provided in sludge drier, inside sludge drier and breaks up mechanism, by sludge with flue gas drying during into The violent heat and mass of row, moisture percentage in sewage sludge are reduced to 30~40% from 60%, are then discharged from drying machine end;Carry dust Flue gas after cyclone collection, with drying machine end discharge drying after sludge summarize, be sent into Sludge carbonization furnace charging Device;
(4) sludge of moisture content after drying 30~40% is sent into the central tube of Sludge carbonization furnace by Sludge carbonization furnace feed arrangement In, in carbonization process, inner cylinder slowly rotates, and sludge is heated to 500~700 DEG C in inner cylinder and is thermally decomposed, the dirt after pyrolysis Peat send to sludge carbon cooling device from the discharge of Sludge carbonization furnace end, is cooled to room temperature;
(5) sludge carbon after cooling promotes conveying device through sludge carbon, send to sludge carbon storage warehouse, and sludge charcoal bag is sent by bottom It installs, is transported outward after packaging.
2. the method that mechanical dehydration coupling desiccation pyrolysis as described in claim 1 prepares sludge carbon, which is characterized in that the step It is rapid 4) in sludge in Sludge carbonization furnace in pyrolytic process, release pyrolysis gas, pyrolysis gas carries out after being sent into pyrolysis gas combustion tower Burning generates high-temperature flue gas, when sludge calorific value is relatively low, supplements biomass fuel by feeding device or direct supplemental natural gas is mended Sufficient heat.
3. the method that mechanical dehydration coupling desiccation pyrolysis as claimed in claim 2 prepares sludge carbon, which is characterized in that the step It is rapid 4) in the high-temperature flue gas that generates of pyrolysis gas combustion tower after the adjustment after temperature at 800~900 DEG C, be sent into sludge carbonization furnace bottom Multiple high-temperature flue gas air inlets;After heat is released to sludge carbonization process, sludge drier is sent into after barrel tip discharge, with Sludge carries out contact heat-exchanging, and the flue-gas temperature after heat exchange is reduced to 100~130 DEG C, from sludge drier outlet discharge through whirlwind After deduster dedusting, washing deduster to be sent into through air-introduced machine, removes the dust in flue gas, the flue gas after dedusting enters extracting tower, In this link after lye cycle washing, the sulfur dioxide sour gas in flue gas is removed, the flue gas after depickling enters deodorization dress It puts, removes volatile organic matter therein, finally enter de- white device, after the moisture content in deep removal flue gas, qualified discharge is extremely Air.
CN201810206001.XA 2018-03-13 2018-03-13 Method for preparing sewage peat by mechanical dehydration coupled drying pyrolysis Ceased CN108249720B (en)

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110304805A (en) * 2019-02-18 2019-10-08 联合瑞升(北京)科技有限公司 A kind of sludge heat drying and the energy conserving system that is carbonized
CN110746070A (en) * 2019-11-19 2020-02-04 江苏中顺节能科技有限公司 Biomass gas-carbon co-production coupling sludge deep treatment system and method
CN110759626A (en) * 2019-11-26 2020-02-07 山东金孚环境工程有限公司 Sludge conditioning dehydration coupling carbonization reduction treatment method and system
CN110759627A (en) * 2019-11-26 2020-02-07 山东金孚环境工程有限公司 Sludge indirect heat exchange evaporation dehydration coupling pyrolysis carbonization method and system
CN113526808A (en) * 2021-07-19 2021-10-22 天津大学 Preparation method of sludge-based biochar and sludge-based biochar
CN114106836A (en) * 2021-12-23 2022-03-01 青岛蓝博环境科技有限公司 Sludge carbonization product as soil conditioner
CN114195347A (en) * 2021-12-23 2022-03-18 青岛蓝博环境科技有限公司 Sludge pyrolysis carbonization process
CN114195356A (en) * 2021-12-23 2022-03-18 青岛蓝博环境科技有限公司 Sludge carbonization product as sludge dewatering promoter

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CN101805106A (en) * 2010-04-09 2010-08-18 扬州澄露环境工程有限公司 Partition wall heating drum type sludge carbonization integrated device
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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110304805A (en) * 2019-02-18 2019-10-08 联合瑞升(北京)科技有限公司 A kind of sludge heat drying and the energy conserving system that is carbonized
CN110304805B (en) * 2019-02-18 2023-04-21 北京智为蓝科技有限公司 Sludge heat drying and carbonization energy-saving system
CN110746070A (en) * 2019-11-19 2020-02-04 江苏中顺节能科技有限公司 Biomass gas-carbon co-production coupling sludge deep treatment system and method
CN110759626A (en) * 2019-11-26 2020-02-07 山东金孚环境工程有限公司 Sludge conditioning dehydration coupling carbonization reduction treatment method and system
CN110759627A (en) * 2019-11-26 2020-02-07 山东金孚环境工程有限公司 Sludge indirect heat exchange evaporation dehydration coupling pyrolysis carbonization method and system
CN113526808A (en) * 2021-07-19 2021-10-22 天津大学 Preparation method of sludge-based biochar and sludge-based biochar
CN114106836A (en) * 2021-12-23 2022-03-01 青岛蓝博环境科技有限公司 Sludge carbonization product as soil conditioner
CN114195347A (en) * 2021-12-23 2022-03-18 青岛蓝博环境科技有限公司 Sludge pyrolysis carbonization process
CN114195356A (en) * 2021-12-23 2022-03-18 青岛蓝博环境科技有限公司 Sludge carbonization product as sludge dewatering promoter

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