CN108239472A - A kind of artistic coating - Google Patents

A kind of artistic coating Download PDF

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Publication number
CN108239472A
CN108239472A CN201810030793.XA CN201810030793A CN108239472A CN 108239472 A CN108239472 A CN 108239472A CN 201810030793 A CN201810030793 A CN 201810030793A CN 108239472 A CN108239472 A CN 108239472A
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CN
China
Prior art keywords
parts
artistic coating
coating
artistic
raw material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810030793.XA
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Chinese (zh)
Inventor
郑世华
陈亚南
祁芬芬
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henan Institute of Science and Technology
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Henan Institute of Science and Technology
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henan Institute of Science and Technology filed Critical Henan Institute of Science and Technology
Priority to CN201810030793.XA priority Critical patent/CN108239472A/en
Publication of CN108239472A publication Critical patent/CN108239472A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D167/00Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
    • C09D167/08Polyesters modified with higher fatty oils or their acids, or with natural resins or resin acids
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/06Artists' paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • C09D5/10Anti-corrosive paints containing metal dust
    • C09D5/103Anti-corrosive paints containing metal dust containing Al
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18Fireproof paints including high temperature resistant paints
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/08Metals
    • C08K2003/0812Aluminium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

Abstract

The invention discloses a kind of artistic coatings, belong to technical field of coatings.The artistic coating is made of the raw material of following parts by weight:70 100 parts of alkyd resin, glass fibre:25 40 parts, melamine:22 38 parts, titanium dioxide:30 45 parts, polyoxyethylene polyoxy propyl alcohol amidogen ether:10 18 parts, aluminium powder:15 30 parts, phenolsulfonic acid:10 15 parts, acrylic resin polyurethane copolymerization resin:20 28 parts, color stuffing:40 55 parts, solvent:30 45 parts.The glossiness of the artistic coating film of the present invention is good, and firm coloration, corrosion resistance, high temperature resistance are good, extend the service life of film.

Description

A kind of artistic coating
Technical field
The present invention relates to technical field of coatings, and in particular to a kind of artistic coating.
Background technology
Artistic coating is one of kind of coating, and artistic coating is called novelty finish, fine arts paint;Artistic coating is by special type The coating variety with special efficiency that coating is formed, is a kind of industrial finish, as other coating, this coating is coated in Body surface can play the protective effect to various objects, the difference is that after its coating film forming, coating surface can self-assembling formation and appearance Naturally various beautiful patterns, such as mallear stria, wrinkle, tangerine line, stone pattern, speckle, crystallized, crackle, wood grain;As society is sent out Exhibition, the raising of people's environmental consciousness, environment-friendly type artistic coating becomes development trend, in addition, existing artistic coating is corrosion-resistant Property, high temperature resistance, the service life of coating etc. needs further to improve.
Invention content
The purpose of the invention is to overcome the problems of the prior art, a kind of artistic coating is provided.
The present invention provides a kind of artistic coatings, are made of the raw material of following parts by weight:70-100 parts of alkyd resin, glass Fiber:25-40 parts, melamine:22-38 parts, titanium dioxide:30-45 parts, polyoxyethylene polyoxy propyl alcohol amidogen ether:10-18 parts, aluminium Powder:15-30 parts, phenolsulfonic acid:10-15 parts, acrylic resin polyurethane copolymerization resin:20-28 parts, color stuffing:40-55 parts, Solvent:30-45 parts.
Preferably, a kind of artistic coating, is made of the raw material of following parts by weight:78 parts of alkyd resin, glass fibre:36 Part, melamine:22 parts, titanium dioxide:35 parts, polyoxyethylene polyoxy propyl alcohol amidogen ether:17 parts, aluminium powder:23 parts, phenolsulfonic acid:12 Part, acrylic resin polyurethane copolymerization resin:24 parts, color stuffing:48 parts, solvent:40 parts.
Preferably, color stuffing is medium chrome yellow or barba hispanica.
Preferably, further include 10-12 parts of preservative in the raw material composition of artistic coating.
Preferably, solvent is ethyl alcohol or ethylene glycol.
Preferably, further include fragrance in the raw material composition of artistic coating.
Preferably, the granularity of titanium dioxide is 30-45um.
Compared with prior art, the beneficial effects of the invention are as follows:The artistic coating of present invention raw material in raw material selection comes Source is extensive, economic and environment-friendly, added in coating composition it is levigate after glass fibre, enhance the toughness of coating, reduce the receipts of coating Shrinkage, suitable melamine can increase the wearability and heat resistance of artistic coating, and melamine is also used as inhaling aldehyde agent The formaldehyde discharged in absorption resin, it is economic and environment-friendly;Aluminium powder is used to increase the brightness of artistic coating, and titanium dioxide has excellent covering Power and color fastness so that the glossiness of artistic coating film is good, firm coloration;After tested:The painting of the artistic coating of the present invention Layer adhesive force is 0 grade, and corrosion resistance, high temperature resistance are good, extend the service life of film.
Specific embodiment
The specific embodiment of the present invention is described in detail below, it is to be understood that protection scope of the present invention is not It is restricted by specific implementation.Based on the embodiments of the present invention, those of ordinary skill in the art are not making creativeness All other embodiments obtained under the premise of labour, shall fall within the protection scope of the present invention.
Embodiment 1:
A kind of artistic coating is made of the raw material of following parts by weight:78 parts of alkyd resin, glass fibre:36 parts, melamine Amine:22 parts, titanium dioxide:35 parts, polyoxyethylene polyoxy propyl alcohol amidogen ether:17 parts, aluminium powder:23 parts, phenolsulfonic acid:12 parts, acrylic acid Resin polyurethane copolymerization resin:24 parts, barba hispanica:48 parts, ethyl alcohol:40 parts.
Preparation method is as follows:The glass fibre of the present invention is to be ground short glass fiber by hammer-mill or ball mill It arrives, mixed solution is stirred evenly to obtain after mixing alkyd resin, ethyl alcohol under room temperature;Titanium dioxide and aluminium powder are ground by ball mill Carefully, 100 DEG C are heated to after titanium dioxide, aluminium powder, glass fibre, melamine, barba hispanica being sequentially added mixed solution, stirring 30min;Then polyoxyethylene polyoxy propyl alcohol amidogen ether, phenolsulfonic acid and acrylic resin polyurethane copolymerization resin, stirring are added in 40min obtains the slurry of above-mentioned artistic coating.
Embodiment 2:
A kind of artistic coating is made of the raw material of following parts by weight:85 parts of alkyd resin, glass fibre:36 parts, melamine Amine:27 parts, titanium dioxide:32 parts, polyoxyethylene polyoxy propyl alcohol amidogen ether:17 parts, aluminium powder:22 parts, phenolsulfonic acid:13 parts, acrylic acid Resin polyurethane copolymerization resin:22 parts, chrome yellow:46 parts, ethyl alcohol:40 parts, 10 parts of preservative.
Preparation method is as follows:The glass fibre of the present invention is to be ground short glass fiber by hammer-mill or ball mill It arrives, mixed solution is stirred evenly to obtain after mixing alkyd resin, ethyl alcohol under room temperature;Titanium dioxide and aluminium powder are ground by ball mill Carefully, 80 DEG C are heated to after titanium dioxide, aluminium powder, glass fibre, melamine, barba hispanica being sequentially added mixed solution, stirring 30min;Then polyoxyethylene polyoxy propyl alcohol amidogen ether, phenolsulfonic acid, acrylic resin polyurethane copolymerization resin and preservative are added in, 40min is stirred, obtains the slurry of above-mentioned artistic coating.
Embodiment 3:
A kind of artistic coating is made of the raw material of following parts by weight:88 parts of alkyd resin, glass fibre:30 parts, melamine Amine:35 parts, titanium dioxide:32 parts, polyoxyethylene polyoxy propyl alcohol amidogen ether:15 parts, aluminium powder:18 parts, phenolsulfonic acid:12 parts, acrylic acid Resin polyurethane copolymerization resin:25 parts, barba hispanica:50 parts, ethylene glycol:35 parts.
Preparation method is as follows:The glass fibre of the present invention is to be ground short glass fiber by hammer-mill or ball mill It arrives, mixed solution is stirred evenly to obtain after mixing alkyd resin, ethylene glycol under room temperature;Titanium dioxide and aluminium powder are ground by ball mill Carefully, 100 DEG C are heated to after titanium dioxide, aluminium powder, glass fibre, melamine, barba hispanica being sequentially added mixed solution, stirring 30min;Then polyoxyethylene polyoxy propyl alcohol amidogen ether, phenolsulfonic acid and acrylic resin polyurethane copolymerization resin, stirring are added in 40min obtains the slurry of above-mentioned artistic coating.
Embodiment 4:
A kind of artistic coating is made of the raw material of following parts by weight:78 parts of alkyd resin, glass fibre:27 parts, melamine Amine:31 parts, titanium dioxide:40 parts, polyoxyethylene polyoxy propyl alcohol amidogen ether:15 parts, aluminium powder:20 parts, phenolsulfonic acid:11 parts, acrylic acid Resin polyurethane copolymerization resin:27 parts, barba hispanica:53 parts, ethyl alcohol:40 parts, 10 parts of fragrance.
Preparation method is as follows:The glass fibre of the present invention is to be ground short glass fiber by hammer-mill or ball mill It arrives, mixed solution is stirred evenly to obtain after mixing alkyd resin, ethyl alcohol under room temperature;Titanium dioxide and aluminium powder are ground by ball mill Carefully, 100 DEG C are heated to after titanium dioxide, aluminium powder, glass fibre, melamine, barba hispanica being sequentially added mixed solution, stirring 30min;Then polyoxyethylene polyoxy propyl alcohol amidogen ether, phenolsulfonic acid, fragrance and acrylic resin polyurethane copolymerization resin are added in, is stirred 40min is mixed, obtains the slurry of above-mentioned artistic coating.
Performance test:
1) the artistic coating slurry being prepared according to the raw material components of embodiment 1-4 and proportioning is respectively coated on experiment sample The surface of piece;
If the coating property of comparative example and the present invention is compared:Artistic coating in comparative example, by following parts by weight Raw material forms:85 parts of alkyd resin, glass fibre:36 parts, titanium dioxide:32 parts, polyoxyethylene polyoxy propyl alcohol amidogen ether:17 parts, aluminium Powder:22 parts, phenolsulfonic acid:13 parts, acrylic resin polyurethane copolymerization resin:22 parts, chrome yellow:46 parts, ethyl alcohol:40 parts, anti-corrosion 10 parts of agent.Preparation method is identical with the preparation method of the embodiment of the present invention 2, and difference lies in the addition steps for saving melamine.
The embodiment of the present invention is tested for the property with comparative example in laboratory, it is as a result as follows:
1.1) the artistic coating items detection performance of embodiment 1 is qualified, and high temperature resistance is preferable, and test result is shown in Table 1.
Table 1:1 artistic coating performance test table of embodiment
1.2) the artistic coating items detection performance of embodiment 2 is qualified, and high temperature resistance is notable, and test result is shown in Table 2.
Table 2:2 artistic coating performance test table of embodiment
Detection project Coating performance Examination criteria
Appearance of film Well Range estimation
Pencil hardness H GB/T1743-1993
Impact resistance 50 pass through GB/T1730-1993
High temperature resistant 400 DEG C pass through GB/T1735-2009
Corrosion-resistant (salt spray test) 200h passes through GB/T1771-91
Cupping >6mm GB/T6742-86
Coating adhesion 0 GB/T1720-1989
1.3) the artistic coating items detection performance of embodiment 3 is qualified, and high temperature resistance is notable, and test result is shown in Table 3.
Table 3:3 artistic coating performance test table of embodiment
1.4) the artistic coating items detection performance of embodiment 4 is qualified, and high temperature resistance is notable, and test result is shown in Table 4.
Table 4:4 artistic coating performance test table of embodiment
Detection project Coating performance Examination criteria
Appearance of film Well Range estimation
Pencil hardness H GB/T1743-1993
Impact resistance 50 pass through GB/T1730-1993
High temperature resistant 400 DEG C pass through GB/T1735-2009
Corrosion-resistant (salt spray test) 200h passes through GB/T1771-91
Cupping >6mm GB/T6742-86
Coating adhesion 0 GB/T1720-1989
1.5) the artistic coating items detection performance of comparative example is qualified, but high temperature resistant and resistance to film property are relatively poor, test It the results are shown in Table 5.
Table 5:Comparative example artistic coating performance test table
It although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with Understanding without departing from the principles and spirit of the present invention can carry out these embodiments a variety of variations, modification, replace And modification, the scope of the present invention is defined by the appended.

Claims (7)

1. a kind of artistic coating, which is characterized in that be made of the raw material of following parts by weight:70-100 parts of alkyd resin, glass fibers Dimension:25-40 parts, melamine:22-38 parts, titanium dioxide:30-45 parts, polyoxyethylene polyoxy propyl alcohol amidogen ether:10-18 parts, aluminium powder: 15-30 parts, phenolsulfonic acid:10-15 parts, acrylic resin polyurethane copolymerization resin:20-28 parts, color stuffing:It is 40-55 parts, molten Agent:30-45 parts.
2. a kind of artistic coating as described in claim 1, which is characterized in that be made of the raw material of following parts by weight:Alkyd tree 78 parts of fat, glass fibre:36 parts, melamine:22 parts, titanium dioxide:35 parts, polyoxyethylene polyoxy propyl alcohol amidogen ether:17 parts, aluminium Powder:23 parts, phenolsulfonic acid:12 parts, acrylic resin polyurethane copolymerization resin:24 parts, color stuffing:48 parts, solvent:40 parts.
3. a kind of artistic coating as claimed in claim 1 or 2, which is characterized in that the color stuffing is medium chrome yellow or barba hispanica.
4. a kind of artistic coating as claimed in claim 1 or 2, which is characterized in that in the raw material composition of the artistic coating also Including 10-12 parts of preservative.
5. a kind of artistic coating as claimed in claim 1 or 2, which is characterized in that the solvent is ethyl alcohol or ethylene glycol.
6. a kind of artistic coating as claimed in claim 1 or 2, which is characterized in that in the raw material composition of the artistic coating also Including fragrance.
7. a kind of artistic coating as claimed in claim 1 or 2, which is characterized in that the granularity of the titanium dioxide is 30-45um.
CN201810030793.XA 2018-01-12 2018-01-12 A kind of artistic coating Pending CN108239472A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810030793.XA CN108239472A (en) 2018-01-12 2018-01-12 A kind of artistic coating

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810030793.XA CN108239472A (en) 2018-01-12 2018-01-12 A kind of artistic coating

Publications (1)

Publication Number Publication Date
CN108239472A true CN108239472A (en) 2018-07-03

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Country Status (1)

Country Link
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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104263209A (en) * 2014-08-27 2015-01-07 南京市荣达树脂有限公司 Impact-resistant metal paint and preparation method thereof
CN106833316A (en) * 2017-02-27 2017-06-13 霍碧滢 A kind of glass paint

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104263209A (en) * 2014-08-27 2015-01-07 南京市荣达树脂有限公司 Impact-resistant metal paint and preparation method thereof
CN106833316A (en) * 2017-02-27 2017-06-13 霍碧滢 A kind of glass paint

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
袁曙宏: "《新食品安全法200问》", 31 December 2015 *
陈云: "《食品中有毒有害物质检测》", 31 January 2013 *

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Application publication date: 20180703

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