CN108236133A - Ox-hide collagen multifunction health-preserving socks and its preparation method and application - Google Patents
Ox-hide collagen multifunction health-preserving socks and its preparation method and application Download PDFInfo
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- CN108236133A CN108236133A CN201810056912.9A CN201810056912A CN108236133A CN 108236133 A CN108236133 A CN 108236133A CN 201810056912 A CN201810056912 A CN 201810056912A CN 108236133 A CN108236133 A CN 108236133A
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- socks
- hide collagen
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- health
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- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41B—SHIRTS; UNDERWEAR; BABY LINEN; HANDKERCHIEFS
- A41B11/00—Hosiery; Panti-hose
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41B—SHIRTS; UNDERWEAR; BABY LINEN; HANDKERCHIEFS
- A41B17/00—Selection of special materials for underwear
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04B—KNITTING
- D04B1/00—Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
- D04B1/14—Other fabrics or articles characterised primarily by the use of particular thread materials
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04B—KNITTING
- D04B1/00—Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
- D04B1/22—Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes specially adapted for knitting goods of particular configuration
- D04B1/24—Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes specially adapted for knitting goods of particular configuration wearing apparel
- D04B1/26—Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes specially adapted for knitting goods of particular configuration wearing apparel stockings
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41B—SHIRTS; UNDERWEAR; BABY LINEN; HANDKERCHIEFS
- A41B2400/00—Functions or special features of shirts, underwear, baby linen or handkerchiefs not provided for in other groups of this subclass
- A41B2400/32—Therapeutic use
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41B—SHIRTS; UNDERWEAR; BABY LINEN; HANDKERCHIEFS
- A41B2400/00—Functions or special features of shirts, underwear, baby linen or handkerchiefs not provided for in other groups of this subclass
- A41B2400/34—Functions or special features of shirts, underwear, baby linen or handkerchiefs not provided for in other groups of this subclass antimicrobial or antibacterial
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41B—SHIRTS; UNDERWEAR; BABY LINEN; HANDKERCHIEFS
- A41B2400/00—Functions or special features of shirts, underwear, baby linen or handkerchiefs not provided for in other groups of this subclass
- A41B2400/36—Deodorising or perfuming
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2211/00—Protein-based fibres, e.g. animal fibres
- D10B2211/01—Natural animal fibres, e.g. keratin fibres
- D10B2211/06—Collagen fibres
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Treatment And Processing Of Natural Fur Or Leather (AREA)
- Socks And Pantyhose (AREA)
Abstract
The present invention provides a kind of ox-hide collagen multifunction health-preserving socks and its preparation method and application, are related to the woven technical field of socks.The health socks have antibacterial deodourizing, moisture retention crack prevention, heat-insulation breathable, the multiple efficacies for nourishing skin using cattle-hide collagen fibers as functional components.The preparation method of above-mentioned ox-hide collagen multifunction health-preserving socks, the step of including by cattle-hide collagen fibers mixed yarn through weaving obtained health socks, this method makes the health-preserving function of health socks obtained have durability by the way that cattle-hide collagen fibers to be not only used as to raw material yarn as functional components.When the ox-hide collagen multifunction health-preserving socks are split applied to alleviation tinea pedis, antibacterial deodourizing and prevention foot, there is durability, its effect will not be lost with the multiple washing of socks.Solves the technical issues of lacking a kind of natural multi-functional endurable health socks and preparation method thereof in the prior art.
Description
Technical field
The present invention relates to socks weaving technology field, more particularly, to a kind of ox-hide collagen multifunction health-preserving socks and its preparation
Methods and applications.
Background technology
Functional hosiery especially has the function of antibacterial deodourizing, moisture retention crack prevention, comfortable ventilating, nourishes skin etc.
Hosiery products are increasingly praised highly by market, are also paid close attention to by many scholars, are proposed the socks of numerous anti-bacterial anti-foul functions
Sub- finishing technique.At present, the antibacterial deodourizing processing technology of hosiery mainly has following a few major class：(1) chemical antiseptic arranges
Technology：Such as the aromatic halogens compounds such as 2,4,4- tri- chloro- 2 dihydroxy diphenyl ethers, the DC-5700 organosilicons of Dow corning company
Organic oxygen compounds such as doped quaternary ammonium salt class compound, polyoxygenated Asia hydroxyl trialkyl ammonium salts etc.；(2) plant extract antibiotic finish skill
Art；(3) metal material antibiotic finish technology：Such as using nano-silver thread, nano-silver ionic, silver fiber, fine silver fiber, silver plated fiber
Yarn, copper ion arrange yarn or zinc ion finishing fiber etc. as socks raw material is knitted and carry out antibacterial processing；(4) functionalityization is used
It learns fibrous material and carries out antibacterial processing：Such as nano-glass pearl powder is added in viscose fiber, adds nanoscale graphite alkene material
Antibacterial deodourizing is obtained into nylon fiber knits the processing technologies such as socks material；(5) using natural antibacterial fiber as anti-biotic material
It is processed：Such as using flaxen fiber, bamboo fiber, acid fiber by polylactic there is the natural fiber of certain antibacterial action to be used as and knit socks
Raw material carries out antibacterial processing.
The antibacterial deodourizing technology of existing socks is more to achieve the effect that antibacterial deodourizing using metal materials such as silver, copper, zinc, though
Right effect is preferable, but silver, copper, zinc are the metal material for having certain toxicity, and to human body, there are potential with human body Long Term Contact
Harm, especially nanoscale metal material has the potential threat being absorbed by the body after being dissolved out from socks.
There is dissolution infiltration in the chemical antibacterial finishing agent of the prior art, the antibacterial material penetrated is inhaled by foot mostly
To human body there are larger genotoxic potential threat after receipts, and such socks anti-microbial property after washing substantially reduces, repeatedly
Antiseptic, which comes off, after washing causes anti-bacterial anti-foul function to completely disappear.
The plant extract antiseptic of the prior art is although environmentally protective, there is preferable affinity and safe to use to human body
Property, but the antibacterial efficacy of socks and persistence is caused to cannot be guaranteed due to the problems such as its easily denaturation, washing loss.
Therefore, the functional processing technology of existing socks is reached by certain anti-biotic material or integrated structure design mostly
To certain antibacterial deodourizing effect, there are yielding, scrub stream is become estranged, and to human body, there are potential hazards with human body Long Term Contact
Technical problem.
In view of this, it is special to propose the present invention.
Invention content
The first object of the present invention is to provide a kind of ox-hide collagen multifunction health-preserving socks, solves and lack in the prior art
A kind of the technical issues of multi-functional endurable health socks.
The second object of the present invention is to provide a kind of preparation method of above-mentioned ox-hide collagen multifunction health-preserving socks, solve
The technical issues of lacking a kind of method of multi-functional endurable health socks of weaving in the prior art.
The third object of the present invention is the provision of a kind of above-mentioned ox-hide collagen multifunction health-preserving socks and is alleviating tinea pedis, antibacterial
Deodorization and prevention foot split in application, solve it is in the prior art lack it is a kind of endurable and without side-effects can be anti-
The problem of alleviating the health socks of tinea pedis while smelly.
In order to solve the above technical problems, it adopts the following technical scheme that：
A kind of ox-hide collagen multifunction health-preserving socks, the functional components of the ox-hide collagen multifunction health-preserving socks include ox-hide
Collagenous fibres.
Further, the raw material of the ox-hide collagen multifunction health-preserving socks includes cattle-hide collagen fibers mixed yarn；
Preferably, the mass fraction of the cattle-hide collagen fibers mixed yarn heifer collagenous fibres is 5%-60%；
Preferably, the cattle-hide collagen fibers mixed yarn is wrap yarn；
Preferably, the line density of the cattle-hide collagen fibers mixed yarn is 20-60 public affairs branch.
Further, the raw material of the health socks includes veil and inner yarn, and it is blended that the veil includes cattle-hide collagen fibers
Yarn；
Preferably, the mass ratio of the veil and inner yarn is 3:2-4:1；
Preferably, the inner yarn includes cladding wire；
It is further preferred that the cladding wire includes terylene cladding wire, polyamide fibre cladding wire, acrylic fibers cladding wire or silk cladding
Silk.
A kind of preparation method of above-mentioned ox-hide collagen multifunction health-preserving socks, the preparation method are included cattle-hide collagen fibers
Mixed yarn is through weaving the step of ox-hide collagen multifunction health-preserving socks are made.
Further, the cattle-hide collagen fibers mixed yarn includes the cattle-hide collagen fibers of 5%-60%；
Preferably, the cattle-hide collagen fibers mixed yarn is wrap yarn；
Preferably, the line density of the cattle-hide collagen fibers mixed yarn is 20-60 public affairs branch.
Further, the woven raw material includes veil and inner yarn, and the veil includes cattle-hide collagen fibers mixed yarn；
Preferably, the mass ratio of the veil and inner yarn is 3:2-4:1；
Preferably, the inner yarn includes cladding wire and elastic material；
It is further preferred that the cladding wire includes terylene cladding wire, polyamide fibre cladding wire, acrylic fibers cladding wire or silk cladding
Silk；
It is further preferred that the elastic material includes shirr.
Further, the step of weaving includes veil and inner yarn carrying out double-deck plain weave；
Preferably, in stocking blank part yarn use shirr, socks body, undertoe and socks root position in yarn use cladding wire.
Further, the preparation method further include by through ox-hide collagen multifunction health-preserving socks made from weaving first through washing
The step of handling, then processing be dried, finally carrying out sizing treatment；
Preferably, the washing process is included under conditions of 20-65 DEG C, first soaps 10-30 minutes, then clear water washes 10-
30 minutes the step of；
Preferably, described to be dried the step for including that heating is dry paragraph by paragraph, the piecewise heating drying includes elder generation 30-65
DEG C dry 10-30 minutes, then 65-80 DEG C 10-30 minutes dry, last 80-100 DEG C dry 10-30 minutes the step of；
Preferably, the step of sizing treatment is baked including high temperature and pressure, the high temperature and pressure, which bakes, is included in temperature
It is 2-5kgf/cm in pressure under conditions of 100-160 DEG C2Compressed air in bake sizing 1-20s the step of.
Further, the preparation method further includes the step of soft treatment before the drying process；
Preferably, the soft treatment is included under conditions of 20-65 DEG C, and the step of 10-60 minutes is handled using softening agent
Suddenly.
Application of the above-mentioned ox-hide collagen multifunction health-preserving socks in alleviating tinea pedis, antibacterial deodourizing and prevention foot and splitting.
Compared with prior art, the present invention has the advantages that：
Ox-hide collagen multifunction health-preserving socks provided by the invention, using natural Kraft collagenous fibres as functional components, ox
Materials with hide glue fibril has the function of the bacterium, the fungi that inhibit foot, to staphylococcus aureus, Escherichia coli, Candida albicans
There is bacteriostasis, realize the functions such as its anti-treating bad smell of feet, tinea pedis；By the excellent moisture retention crack prevention of cattle-hide collagen fibers, warming
Ventilative wait nourishes characteristic, has certain repair to foot disorders skin.Disease etc. is also split to athlete's foot, foot by bacterium, true
Skin disease caused by the factors such as bacterium, drying has certain prevention, alleviation with repairing effect.Cattle-hide collagen fibers have excellent
Moisture adsorption and releasing regulating power, when foot and perspiring, can absorb moisture moisturizing, and when foot dryness can be played slow with moisture releasing with moisture retention crack prevention
The effect that solution foot is split.And due to the special multi-dimentional scale construction feature of cattle-hide collagen fibers, make it have prominent warming
Gas performance.Cattle-hide collagen fibers main component is Type I collagen albumen, has natural affinity, comfortable docile, peace with the skin of people
Full health.Therefore, the health socks using natural Kraft collagenous fibres as primary raw material have antibacterial deodourizing, moisture retention crack prevention, warming
Gas nourishes the effect of skin.
The preparation method of above-mentioned ox-hide collagen multifunction health-preserving socks provided by the invention, is mixed by weaving cattle-hide collagen fibers
Health socks are prepared in spinning, and this method is woven as health socks again by regarding natural Kraft collagenous fibres as raw material spinning, and
It is not arranged using antibacterial finishing agent or is obtained using metal antibacterial material from outside, both avoided chemical finishing agent, gold
Antibacterial effect caused by metal nanometer material is lost in due to washing is not durable, in turn avoids potential danger caused by it is absorbed by the body
Evil, the effect of making the antibacterial deodourizing, moisture retention crack prevention, heat-insulation breathable that above-mentioned health socks have and the prevention that disease is split to athlete's foot, foot
Etc. functions have permanent durability.
Ox-hide collagen multifunction health-preserving socks provided by the invention are in use, since cattle-hide collagen fibers are both health socks
The raw material of functional components and health socks, therefore the health socks are applied to the work(for alleviating tinea pedis, antibacterial deodourizing and prevention foot are split
During energy, there is durability, its effect will not be lost with the multiple washing of socks.
Specific embodiment
Technical scheme of the present invention is clearly and completely described below in conjunction with embodiment, it is clear that described reality
It is part of the embodiment of the present invention to apply example, instead of all the embodiments.Based on the embodiments of the present invention, the common skill in this field
Art personnel all other embodiments obtained without making creative work belong to the model that the present invention protects
It encloses.
The present invention provides a kind of ox-hide collagen multifunction health-preserving socks, the functionality of the ox-hide collagen multifunction health-preserving socks
Ingredient includes natural Kraft collagenous fibres.
The functional components of ox-hide collagen multifunction health-preserving socks provided by the invention include natural Kraft collagenous fibres, ox-hide
Collagenous fibres have the function of the bacterium, the fungi proliferation that inhibit foot, to staphylococcus aureus, Escherichia coli, Candida albicans
Bacterium has bacteriostasis, realizes the functions such as its anti-treating bad smell of feet, tinea pedis；By the excellent moisture retention crack prevention of cattle-hide collagen fibers, protect
Warm ventilative wait nourishes characteristic, has certain repair to foot disorders skin.Also athlete's foot, foot are split disease etc. by bacterium,
Skin disease caused by the factors such as fungi, drying has certain prevention, alleviation with repairing effect.
Regain is up to 22% under the standard state of cattle-hide collagen fibers, is 2-3 times of general natural fiber, has excellent
Moisture adsorption and releasing regulating power, when foot and perspiring can absorb moisture moisturizing, and when foot dryness can be played with moisture releasing with moisture retention crack prevention
Alleviate the effect split of foot, and due to the special multi-dimentional scale construction feature of cattle-hide collagen fibers, make it have prominent warming
Permeability, and since the 70-80% of application on human skin dry weight is Type I collagen albumen, and cattle-hide collagen fibers main component is also I
Collagen type has natural affinity with the skin of people, and comfortable docile is safe and healthy.
Above-mentioned function based on cattle-hide collagen fibers, health socks provided by the invention have antibacterial deodourizing, alleviate tinea pedis, protect
The effect of wet anticracking and heat-insulation breathable.
In one optionally embodiment, the raw material of the ox-hide collagen multifunction health-preserving socks includes cattle-hide collagen fibers
Mixed yarn；Optionally, the mass fraction of the cattle-hide collagen fibers mixed yarn heifer collagenous fibres is 5%-60%, such as can
Think but be not limited to 5%, 10%, 20%, 30%, 35%, 40%, 50% or 60%, preferably 40%-50%.
In one preferred embodiment, the cattle-hide collagen fibers mixed yarn is wrap yarn；Wrap yarn is also known as looping
Yarn is a kind of yarn of new structure, it is outsourcing another kind long filament or staple fiber sliver using long filament or staple fiber as yarn core,
Outsourcing yarn in a screw fashion coats heart yarn.Its feature for item does that uniform, bulk plentiful, yarn is smooth and filoplume
Less, strength is high, little breakage, and the outsourcing yarn includes natural fiber or chemical fibre, such as can be but be not limited to bamboo fibre
Dimension, zein fiber, wool, nylon fibre, acrylic fiber or polyester fiber, the present invention do not limit the type of outsourcing yarn, can be with
Understand, as long as the material of outsourcing yarn can be played the role of, profit outside cattle-hide collagen fibers mixed yarn of the present invention
The cattle-hide collagen fibers mixed yarn as core is coated by the use of outsourcing yarn, cattle-hide collagen fibers can be effectively prevent in socks
It comes off in wearing process, enhances its wearability.Optionally, the line density of the cattle-hide collagen fibers mixed yarn is 20-60 public affairs branch,
Such as can be but be not limited to 20 public branch, 30 public branch, 40 public branch, preferably 50 public or 60 public branch, 35-50 public affairs branch, it can make
Cattle-hide collagen fibers in cattle-hide collagen fibers mixed yarn fully and skin contact, so as to play the role of health.
In one optionally embodiment, the raw material of the ox-hide collagen multifunction health-preserving socks includes veil and inner yarn,
The veil includes cattle-hide collagen fibers mixed yarn；Optionally, the mass ratio of the veil and inner yarn is 3:2-4:1, such as can
Think but be not limited to 3:2、2:1、5:2、3:1、7:2 or 4:1, preferably 5:2-3:1, by advanced optimize veil with it is inner
The mass ratio of yarn can advanced optimize the health effect of health socks.
In one optionally embodiment, the inner yarn includes cladding wire, and the cladding wire for example can be but unlimited
In for terylene cladding wire, polyamide fibre cladding wire, acrylic fibers cladding wire or silk cladding wire, preferably polyamide fibre cladding wire；Preferably, it is described
In yarn further include elastic thread, the elastic thread is preferably shirr, more preferable, and yarn uses in the stocking blank part of the health socks
Shirr, socks body, undertoe and socks root position in yarn use cladding wire.By advanced optimizing the performance of inner yarn, inner yarn can be made
While the good comfort level of socks and physical property is assigned, and the abundant of outer yarn heifer collagenous fibres and skin is not hindered
Contact.
The preparation method of above-mentioned ox-hide collagen multifunction health-preserving socks provided by the invention, the raw material used include ox-hide collagen
Fiber blend yarn, optionally, the mass fractions of the cattle-hide collagen fibers mixed yarn heifer collagenous fibres is 5%-60%, example
It such as can be but be not limited to 5%, 10%, 20%, 30%, 35%, 40%, 50% or 60%, preferably 40%-50%.
In one preferred embodiment, the cattle-hide collagen fibers mixed yarn is wrap yarn, and the wrap yarn is with ox
Materials with hide glue fibril is yarn core, and outsourcing yarn in a screw fashion coats heart yarn, the outsourcing yarn include natural fiber or
Person's chemical fibre, such as can be but be not limited to bamboo fibre, zein fiber, wool, nylon fibre, acrylic fiber or terylene
Fiber, the present invention do not limit the type of outsourcing yarn, it is to be understood that as long as the material of outsourcing yarn can be played the role of,
The line density of the cattle-hide collagen fibers mixed yarn is 20-60 public affairs branch, for example, can be but be not limited to 20 public branch, 30 public branch,
40 public branch, preferably 50 public or 60 public branch, 35-50 public affairs branch.
In one optionally embodiment, the raw material that is used in the preparation method of the health socks includes veil and inner
Yarn, the veil include cattle-hide collagen fibers mixed yarn；Optionally, the mass ratio of the veil and inner yarn is 3:2-4:1, such as
It can be but be not limited to 3:2、2:1、5:2、3:1、7:2 or 4:1, preferably 5:2-3:1.
In one optionally embodiment, the inner yarn includes cladding wire, and the cladding wire for example can be but unlimited
In for terylene cladding wire, polyamide fibre cladding wire, acrylic fibers cladding wire or silk cladding wire, preferably polyamide fibre cladding wire；Preferably, it is described
In yarn further include elastic thread, the elastic thread is preferably the shirr of 90#-120#, more preferable, the sock edge part of the health socks
Yarn is using shirr in point, and yarn uses cladding wire in socks body, undertoe and socks root position.
The selection of raw material and aforementioned health socks are invented based on same design in the preparation method, are prepared using the raw material
Institute of the obtained health socks with aforementioned health socks is effective, and details are not described herein.
The preparation method of ox-hide collagen multifunction health-preserving socks provided by the invention, including above-mentioned cattle-hide collagen fibers are blended
Yarn is through weaving the step of health socks are made.
In one optionally embodiment, the preparation method includes carrying out on above-mentioned veil and above-mentioned inner yarn double-deck flat
The step of line is weaved.In the present embodiment, outer layer veil uses thicker cattle-hide collagen fibers mixed yarn, and yarn uses in internal layer
The plain weave weave of thinner cladding wire, the veil collocation design different with inner yarn thickness and socks so that the ectonexine table of socks
Face is distributed with cattle-hide collagen fibers, the effect of can giving full play to cattle-hide collagen fibers.Preferably, yarn uses in stocking blank part
Shirr, socks body, undertoe and socks root position in yarn use cladding wire.
In one optionally embodiment, the preparation method further include by through health socks made from weaving first through washing
The step of handling, then processing be dried, finally carrying out sizing treatment；
In an optional embodiment, the washing process is included under conditions of 20-65 DEG C, and first soap 10-30
Minute, then the step of clear water washes 10-30 minutes；
Optionally, the temperature condition of the washing process for example can be but be not limited to 20 DEG C, 25 DEG C, 30 DEG C, 35 DEG C,
40 DEG C, 45 DEG C, 55 DEG C or 65 DEG C；Optionally, the time soaped for example can be but be not limited to 10 minutes, 20 minutes or
30 minutes；Optionally, the wash time in clear water for example can be but be not limited to 10 minutes, 20 minutes or 30 minutes.
The washing process uses 20-65 DEG C of water at low temperature treatment conditions, is, purpose specially designed according to the property of cattle-hide collagen fibers
It is to avoid cattle-hide collagen fibers contraction distortion in aqueous solution.
It is described to be dried the step of including heating paragraph by paragraph, the piecewise heating packet in an optional embodiment
Include first dry 10-30 minutes under conditions of 30-65 DEG C, for example, can be but be not limited to 30 DEG C, 35 DEG C, 40 DEG C, 50 DEG C, 60
DEG C or 65 DEG C；Again dry 10-30 minutes under the conditions of 65-80 DEG C, such as it can be but be not limited to 65 DEG C, 70 DEG C, 75 DEG C
Or 80 DEG C；Finally dry 10-30 minutes under conditions of 80-100 DEG C, for example, can be but be not limited to 80 DEG C, 85 DEG C, 90
DEG C, 98 DEG C or 100 DEG C；Optionally, the time of above-mentioned stage drying for example can be but being not limited to 10 points independently
Clock, 15 minutes, 20 minutes, 25 minutes or 30 minutes." heating paragraph by paragraph " seasoning is the property spy according to cattle-hide collagen fibers
It does not design, it is therefore an objective to direct high temperature drying be avoided to cause cattle-hide collagen fibers contraction distortion.
In an optional embodiment, the step of sizing treatment is baked including high temperature and pressure, the high temperature is high
Pressure, which bakes, is included in temperature to be 2-5kgf/cm in pressure under conditions of 100-160 DEG C2Compressed air in bake sizing 1-
The step of 20s；Optionally, the above-mentioned temperature baked for example can be but be not limited to 100 DEG C, 110 DEG C, 120 DEG C, 130 DEG C,
140 DEG C, 150 DEG C or 160 DEG C；Optionally, the pressure of above-mentioned compressed air for example can be but be not limited to 2kgf/cm2、
3kgf/cm2、3.5kgf/cm2、4kgf/cm2Or 5kgf/cm2；Optionally, the above-mentioned time for baking sizing for example can be but
It is not limited to 1s, 5s, 8s, 10s, 15s or 20s.Ox-hide collagen can be avoided by using the method for shaping of " high temperature and pressure bakes "
The non-uniform defect of apparent distribution caused by fiber is shunk by steam.
In an optional embodiment, the step of preparation method further includes soft treatment before the drying process；
Optionally, the softening agent for example can be but be not limited to organic silicon softening agent, film class softening agent or ester group quaternary ammonium
Salt softening agent, it should be noted that do not limit the type of softening agent in preparation method of the invention, commercially available softening agent can all make
With；Optionally, the soft treatment is included under conditions of 20-65 DEG C, for example, can be but be not limited to 20 DEG C, 25 DEG C, 30
DEG C, 35 DEG C, 40 DEG C, 45 DEG C, 55 DEG C or 65 DEG C, handled 10-60 minutes using softening agent, such as can be but be not limited to 10
Minute, 20 minutes, 30 minutes, 40 minutes, 50 minutes or 60 minutes.
The soft treatment uses 20-65 DEG C of water at low temperature treatment conditions, is especially set according to the property of cattle-hide collagen fibers
Meter, it is therefore an objective to avoid cattle-hide collagen fibers contraction distortion in aqueous solution.
The technological parameter in preparation method by advanced optimizing ox-hide collagen multifunction health-preserving socks, can further improve
The comfort level of health socks and health effect.
Antibacterial deodourizing that the ox-hide collagen multifunction health-preserving socks that above-mentioned preparation method is prepared have, moisture retention crack prevention, guarantor
Warm the effect of breathing freely and the prevention that disease is split to athlete's foot, foot etc., functions were with permanent durability.Because these functions are animal glues
The function that fibrinogen has in itself is not arranged using antibacterial finishing agent or is obtained using metal antibacterial material from outside,
Both it is not durable to have avoided antibacterial effect caused by chemical finishing agent or metal nano material are lost in due to washing, has in turn avoided its quilt
Potential hazard caused by absorption of human body.
The present invention also provides above-mentioned ox-hide collagen multifunction health-preserving socks in alleviating tinea pedis, antibacterial deodourizing and prevention foot and splitting
Application.
The health socks have the function of the bacterium, the fungi that inhibit foot using natural Kraft collagenous fibres as functional components,
There is bacteriostasis to staphylococcus aureus, Escherichia coli, Candida albicans.And cattle-hide collagen fibers have excellent guarantor
Wet anticracking, heat-insulation breathable etc. nourish characteristic, have certain repair to foot disorders skin.The standard of cattle-hide collagen fibers
Regain is up to 22% under state, is 2-3 times of general natural fiber, has excellent moisture adsorption and releasing regulating power.During foot and perspiring
Moisture moisturizing can be absorbed, when foot dryness can reach with moisture releasing and alleviate the effect of foot is split, therefore the health socks can be applied to alleviate
Tinea pedis, antibacterial deodourizing and alleviation foot are split.And since cattle-hide collagen fibers are both the functional components of health socks and health socks
Raw material, therefore when the ox-hide collagen multifunction health-preserving socks are applied to alleviate the function that tinea pedis, antibacterial deodourizing and prevention foot are split, tool
There is durability, its effect will not be lost with the multiple washing of socks.
The advantageous effect further illustrated the present invention with reference to preferred embodiment.
Embodiment 1
It present embodiments provides a kind of preparation method of ox-hide collagen multifunction health-preserving socks and is supported using made from this method
Raw socks.
Ox-hide collagen multifunction health-preserving socks provided in this embodiment include veil and inner yarn, and veil is cattle-hide collagen fibers matter
The blended wrap yarn of cattle-hide collagen fibers that score is 40% is measured, wrap yarn is acrylic fiber, and the line density of veil is 35 public branch；In
Yarn is acrylic fibers cladding wire and the shirr of 110#；The mass ratio of wherein veil and inner yarn is 5:2；
Ox-hide collagen multifunction health-preserving socks provided in this embodiment are prepared with the following method：
(a) above-mentioned veil and inner yarn are woven as socks, wherein yarn in stocking blank part using the method for double-deck plain weave manufacture
Using shirr, yarn uses cladding wire in socks body, undertoe and socks root position；
(b) socks being manufactured are soaped 20 minutes under conditions of 35 DEG C, then clear water is washed 25 minutes again；
(c) socks after washing are handled 45 minutes under conditions of 35 DEG C using silicone oil softener；
(d) socks after soft treatment are dried by the way of heating up paragraph by paragraph, condition is as follows：First 40 DEG C of 20 points of dryings
Clock, then 70 DEG C of dryings 25 minutes, last 85 DEG C of dryings 20 minutes
(e) dried socks are being passed through pressure as 4kgf/cm2Compressed air sock molding case in, temperature is
It shapes 20 minutes under conditions of 120 DEG C, finished product ox-hide collagen multifunction health-preserving socks.
Embodiment 2
It present embodiments provides a kind of preparation method of ox-hide collagen multifunction health-preserving socks and is supported using made from this method
Raw socks.
Ox-hide collagen multifunction health-preserving socks provided in this embodiment include veil and inner yarn, and veil is cattle-hide collagen fibers matter
The blended wrap yarn of cattle-hide collagen fibers that score is 50% is measured, wrap yarn is polyester fiber, and the line density of veil is 50 public branch；In
Yarn is silk cladding wire and the shirr of 120#；The mass ratio of wherein veil and inner yarn is 3:1；
Ox-hide collagen multifunction health-preserving socks provided in this embodiment are prepared with the following method：
(a) above-mentioned veil and inner yarn are woven as socks, wherein yarn in stocking blank part using the method for double-deck plain weave manufacture
Using shirr, yarn uses cladding wire in socks body, undertoe and socks root position；
(b) socks being manufactured are soaped 15 minutes under conditions of 45 DEG C, then clear water is washed 15 minutes again；
(c) socks after washing are handled 25 minutes under conditions of 45 DEG C using silicone oil softener；
(d) socks after soft treatment are dried by the way of heating up paragraph by paragraph, condition is as follows：First 50 DEG C of 15 points of dryings
Clock, then 75 DEG C of dryings 15 minutes, last 90 DEG C of dryings 15 minutes；
(e) dried socks are being passed through pressure as 5kgf/cm2Compressed air sock molding case in, temperature is
It shapes 5 minutes under conditions of 100 DEG C, finished product ox-hide collagen multifunction health-preserving socks.
Embodiment 3
It present embodiments provides a kind of preparation method of ox-hide collagen multifunction health-preserving socks and is supported using made from this method
Raw socks.
Ox-hide collagen multifunction health-preserving socks provided in this embodiment include veil and inner yarn, and veil is cattle-hide collagen fibers matter
The blended wrap yarn of cattle-hide collagen fibers that score is 5% is measured, wrap yarn is bamboo fibre, and the line density of veil is 60 public branch；In yarn
For terylene cladding wire and the shirr of 90#；The mass ratio of wherein veil and inner yarn is 4:1；
Ox-hide collagen multifunction health-preserving socks provided in this embodiment are prepared with the following method：
(a) above-mentioned veil and inner yarn are woven as socks, wherein yarn in stocking blank part using the method for double-deck plain weave manufacture
Using shirr, yarn uses cladding wire in socks body, undertoe and socks root position；
(b) socks being manufactured are soaped 30 minutes under conditions of 20 DEG C, then clear water is washed 30 minutes again；
(c) socks after washing are handled 60 minutes under conditions of 20 DEG C using silicone oil softener；
(d) socks after soft treatment are dried by the way of heating up paragraph by paragraph, condition is as follows：First 30 DEG C of 30 points of dryings
Clock, then 65 DEG C of dryings 30 minutes, last 80 DEG C of dryings 30 minutes
(e) dried socks are being passed through pressure as 2kgf/cm2Compressed air sock molding case in, temperature is
It shapes 10 minutes under conditions of 160 DEG C, finished product ox-hide collagen multifunction health-preserving socks.
Embodiment 4
It present embodiments provides a kind of preparation method of ox-hide collagen multifunction health-preserving socks and is supported using made from this method
Raw socks.
Ox-hide collagen multifunction health-preserving socks provided in this embodiment include veil and inner yarn, and veil is that mass fraction is 60%
The blended wrap yarn of cattle-hide collagen fibers, wrap yarn is nylon fibre, and the line density of veil public is propped up for 20；In yarn be polyamide fibre cladding
The shirr of silk and 100#；The mass ratio of wherein veil and inner yarn is 3:2；
Ox-hide collagen multifunction health-preserving socks provided in this embodiment are prepared with the following method：
(a) above-mentioned veil and inner yarn are woven as socks, wherein yarn in stocking blank part using the method for double-deck plain weave manufacture
Using shirr, yarn uses cladding wire in socks body, undertoe and socks root position；
(b) socks being manufactured are soaped 10 minutes under conditions of 65 DEG C, then clear water is washed 10 minutes again；
(c) socks after washing are handled 10 minutes under conditions of 65 DEG C using silicone oil softener；
(d) socks after soft treatment are dried by the way of heating up paragraph by paragraph, condition is as follows：First 65 DEG C of 10 points of dryings
Clock, then 80 DEG C of dryings 10 minutes, last 100 DEG C of dryings 10 minutes
(e) dried socks are being passed through pressure as 3kgf/cm2Compressed air sock molding case in, temperature is
It shapes 15 minutes under conditions of 140 DEG C, finished product ox-hide collagen multifunction health-preserving socks.
Embodiment 5
It present embodiments provides a kind of preparation method of ox-hide collagen multifunction health-preserving socks and is supported using made from this method
Raw socks difference lies in the mass fraction of the blended wrap yarn heifer collagenous fibres of cattle-hide collagen fibers are 80% with embodiment 1.
Comparative example 1
This comparative example provides a kind of preparation method of health socks and using health socks made from this method, with embodiment 1
Difference lies in veil is the bamboo fiber blended wrap yarn that mass fraction is 40%.
Comparative example 2
This comparative example provides a kind of preparation method of health socks and using health socks made from this method, with embodiment 1
Difference lies in veil is the blended cladding of cotton fiber that the cotton quality score that silver-ion antibiotic finishing agent arranges is 40%
Yarn.
Effect example 1
Health socks that embodiment and comparative example provides are detected to staphylococcus aureus, Escherichia coli, Candida albicans
Bacteriostasis rate (GB/T20944.3-2008, the test of concussion method), the results are shown in Table 1：
The bacteriostasis rate of 1 health socks of table
As can be seen from the above table, the health socks using cattle-hide collagen fibers as functional components have higher bacteriostasis rate,
Middle bacteriostasis rate is increased with the increase of the content of cattle-hide collagen fibers, illustrates antibacterial efficiency of the cattle-hide collagen fibers to health socks
Play crucial effect.
Effect example 2
The patient 160 with tinea pedis, wherein male 80, women 80 are collected, is divided into 8 groups, every group of male suffers from
Person 10, female patient 10, at 18~65 years old age, the age is randomly assigned.
Patient has following symptom：Foot hidrosis is impregnated between toe, coated with white skin, often with stench or vola pedis, foot edge cluster
The even entire vola pedis pachyderma of blister, dry furfur or heel, foot edge, drying, chap.Feel itching, summer is more so.
Therapy：1-7 groups are treatment group, and 1-5 groups wear the ox-hide collagen multifunction health-preserving of embodiment 1-5 offers respectively
Socks, 6-7 groups wear the health socks of comparative example 1-2 groups offer, and 8 groups are blank control, and dress does not have the quilted stockings of health-preserving function；And
And each patient changes clothes socks daily, and other drugs or treatment means is not used to treat tinea pedis, 1 month treatment time during experiment.
Curative effect determinate standard：It cures：Symptom and sign disappear, and skin restores normal；It improves：Symptom is substantially reduced, skin lesion
Subside more than 50%.Check fungi still has the positive；It is not cured：Symptom, sign are without change.
Table 2 treats tinea pedis effect verification
| It cures | It improves | It is not cured | Efficient (%) | |
| Embodiment 1 | 10 | 8 | 2 | 90 |
| Embodiment 2 | 8 | 9 | 3 | 85 |
| Embodiment 3 | 5 | 10 | 5 | 75 |
| Embodiment 4 | 9 | 8 | 3 | 85 |
| Embodiment 5 | 8 | 9 | 3 | 85 |
| Comparative example 1 | 3 | 7 | 10 | 50 |
| Comparative example 2 | 5 | 9 | 6 | 70 |
As seen from the results in Table 2, the ox-hide collagen multifunction health-preserving socks that embodiment 1- embodiments 5 provide are to the work of alleviation tinea pedis
With the health socks provided better than comparative example, by effect example 1 it is found that cattle-hide collagen fibers have good bacteriostasis, contribute to
Inhibit the growth for leading to generate the fungi of tinea pedis, therefore the health socks with higher cattle-hide collagen fibers content are with to tinea pedis
More preferably remission effect.The usual foot's amount of sweat of tinea pedis patient is larger, and the environment of skin surface wet is caused to be more conducive to fungi
Growth, so as to aggravate the extent of tinea pedis.Since cattle-hide collagen fibers have excellent moisture adsorption and releasing regulating power, during foot and perspiring
Moisture moisturizing can be absorbed, when foot dryness can make foot's skin be in a suitable humidity environment, it is therefore prevented that foot with moisture releasing
Excessive humidity causes fungi to grow, so as to further alleviate tinea pedis.
Although the antibacterial efficiency of health socks can be further improved by improving the content of cattle-hide collagen fibers, due to ox-hide
The mass ratio of wrap yarn is too small in the blended wrap yarn of collagenous fibres, insufficient to the coating function of cattle-hide collagen fibers core, causes
Cattle-hide collagen fibers mixed yarn does not wear well, and in the experiment of this effect example, since patient will clean health socks daily, having makes
It is represented with the patient of embodiment 5, health socks have that cattle-hide collagen fibers come off, therefore the suitable ox-hide collagen of health socks
Fiber content can enhance the wear of health socks, make the health effect that it is played more longlasting.
In the experiment of this effect example, do not represent that uncomfortable situation occurs in foot using the patient of embodiment 1-5, due to
Often there is breakage in patient feet's skin with tinea pedis, it is thus possible to there is the situation that cattle-hide collagen fibers are in direct contact wound,
100 patients for providing health socks using embodiment do not occur the reaction of foot's discomfort or allergy, card in this effect example
Bright health socks provided by the invention have no toxic side effect to the skin and body of patient, an example occur in the patient using comparative example 2
Malaise symptoms show as, using 3 days back foot part damaged part congestion and swelling pains, stopped use immediately.
Model case 1
Lee, man, 45 years old, with tinea pedis 5 years, symptom was foot hidrosis, is impregnated between toe, coated with white skin, with stench, and
And very itch unbearably often, normal life is seriously affected, wears one star of ox-hide collagen multifunction health-preserving socks provided in this embodiment
After phase, foot perspiration tends to be normal, and tinea pedis area reduces about 30%, and pruritis mitigates, and wears health provided in this embodiment
After socks one month, tinea pedis area reduces about 70%, and daytime, foot moisture conditions significantly weakened, and is reduced along with tinea pedis area
Pruritis is made to disappear.
Model case 2
Feng, female 55 years old, change tinea pedis 1 year, and symptom is vola pedis, foot edge cluster blister, dry furfur, and foot is dry and cracked, companion
There is itch, wear ox-hide collagen multifunction health-preserving socks provided in this embodiment 3 days, dry and cracked symptom is reduced, and foot starts to restore wet
Profit is soft, and wearing health socks provided in this embodiment, foot edge blister is reduced after two weeks, and pruritis mitigates, a month metapedes ringworm
Shape disappears substantially.
Effect example 3
Embodiment 1-5 and comparative example 1-2 according to the washing process in 1 step (b) of embodiment is washed repeatedly and is dried 30 times,
Then according to the method for effect example 1 detect health socks to staphylococcus aureus, Escherichia coli, Candida albicans bacteriostasis rate,
The results are shown in Table 3：
3 health socks of table wash repeatedly after bacteriostasis rate
Ox-hide collagen multifunction health-preserving socks provided in an embodiment of the present invention pass through it can be seen from embodiment and comparative example comparison
The fungistatic effect of health socks does not significantly reduce after washing repeatedly, it can be seen that, the health work(of health socks provided by the invention
The durability of energy is better than the health socks that comparative example provides, and health socks provided by the invention are water-fastness, user can be made to wear for a long time
And can also retain the health-preserving function of the health socks, this also further saves what people spent in alleviating tinea pedis and preventing foot from splitting
Cost is beneficial to consumers in general's use.
Finally it should be noted that：The above embodiments are only used to illustrate the technical solution of the present invention., rather than its limitations；To the greatest extent
Pipe is described in detail the present invention with reference to foregoing embodiments, it will be understood by those of ordinary skill in the art that：Its according to
Can so modify to the technical solution recorded in foregoing embodiments either to which part or all technical features into
Row equivalent replacement；And these modifications or replacement, various embodiments of the present invention technology that it does not separate the essence of the corresponding technical solution
The range of scheme.
Claims (10)
1. a kind of ox-hide collagen multifunction health-preserving socks, which is characterized in that the ox-hide collagen multifunction health-preserving socks it is functional into
Divide and include cattle-hide collagen fibers.
2. health socks according to claim 1, which is characterized in that the raw material of the ox-hide collagen multifunction health-preserving socks includes
Cattle-hide collagen fibers mixed yarn；
Preferably, the mass fraction of the cattle-hide collagen fibers mixed yarn heifer collagenous fibres is 5%-60%；
Preferably, the cattle-hide collagen fibers mixed yarn is wrap yarn；
Preferably, the line density of the cattle-hide collagen fibers mixed yarn is 20-60 public affairs branch.
3. health socks according to claim 2, which is characterized in that the raw material of the health socks includes veil and inner yarn, institute
It states veil and includes cattle-hide collagen fibers mixed yarn；
Preferably, the mass ratio of the veil and inner yarn is 3:2-4:1；
Preferably, the inner yarn includes cladding wire；
It is further preferred that the cladding wire includes terylene cladding wire, polyamide fibre cladding wire, acrylic fibers cladding wire or silk cladding wire.
4. the preparation method of the ox-hide collagen multifunction health-preserving socks described in a kind of any one of claim 1-3, which is characterized in that
The preparation method is included cattle-hide collagen fibers mixed yarn through weaving the step of ox-hide collagen multifunction health-preserving socks are made.
5. preparation method according to claim 4, which is characterized in that the cattle-hide collagen fibers mixed yarn includes 5%-
60% cattle-hide collagen fibers；
Preferably, the cattle-hide collagen fibers mixed yarn is wrap yarn；
Preferably, the line density of the cattle-hide collagen fibers mixed yarn is 20-60 public affairs branch.
6. preparation method according to claim 5, which is characterized in that the woven raw material includes veil and inner yarn, institute
It states veil and includes cattle-hide collagen fibers mixed yarn；
Preferably, the mass ratio of the veil and inner yarn is 3:2-4:1；
Preferably, the inner yarn includes cladding wire and elastic material；
It is further preferred that the cladding wire includes terylene cladding wire, polyamide fibre cladding wire, acrylic fibers cladding wire or silk cladding wire；
It is further preferred that the elastic material includes shirr.
7. preparation method according to claim 6, which is characterized in that the weaving includes carrying out on veil and inner yarn double-deck
The step of plain weave；
Preferably, in stocking blank part yarn use shirr, socks body, undertoe and socks root position in yarn use cladding wire.
8. preparation method according to claim 5, which is characterized in that the preparation method further includes will be through made from weaving
Ox-hide collagen multifunction health-preserving socks are first through washing process, then processing is dried, finally the step of progress sizing treatment；
Preferably, the washing process is included under conditions of 20-65 DEG C, first soaps 10-30 minutes, then clear water washes 10-30 points
The step of clock；
Preferably, described be dried includes the piecewise dry step that heats up, and dry 30-65 DEG C of the elder generation that includes of the piecewise heating does
It is 10-30 minutes dry, then 65-80 DEG C 10-30 minutes dry, the step of last 80-100 DEG C dry 10-30 minutes；
Preferably, the step of sizing treatment is baked including high temperature and pressure, the high temperature and pressure, which bakes, to be included in temperature and is
It is 2-5kgf/cm in pressure under conditions of 100-160 DEG C2Compressed air in bake sizing 1-20s the step of.
9. preparation method according to claim 8, which is characterized in that the preparation method further includes soft before the drying process
The step of supple-settlement；
Preferably, the soft treatment is included under conditions of 20-65 DEG C, the step of processing 10-60 minutes using softening agent.
10. as claim 1-3 any one of them ox-hide collagen multifunction health-preserving socks are alleviating tinea pedis, antibacterial deodourizing and prevention
Foot split in application.
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| CN201810056912.9A CN108236133B (en) | 2018-01-19 | 2018-01-19 | Multifunctional health-preserving socks with bovine skin collagen and preparation method and application thereof |
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| CN110664022A (en) * | 2019-10-29 | 2020-01-10 | 浙江诚信而已科技有限公司 | Antibacterial and deodorant sock |
| CN110897209A (en) * | 2020-01-10 | 2020-03-24 | 浙江宝善堂生物医疗科技有限公司 | Chinese herbal medicine-combined cowhide collagen fiber antibacterial socks and preparation method thereof |
| CN111020784A (en) * | 2019-05-27 | 2020-04-17 | 广州五源新材料集团有限公司 | Animal leather fiber bundle elastic fasciated yarn, elastic fabric and product |
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|---|---|
| CN108236133B (en) | 2021-03-30 |
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