CN109793288A - A kind of compound bacteriostatic deodorizing socks and preparation method thereof - Google Patents
A kind of compound bacteriostatic deodorizing socks and preparation method thereof Download PDFInfo
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- CN109793288A CN109793288A CN201811522641.8A CN201811522641A CN109793288A CN 109793288 A CN109793288 A CN 109793288A CN 201811522641 A CN201811522641 A CN 201811522641A CN 109793288 A CN109793288 A CN 109793288A
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Abstract
The present invention provides a kind of compound bacteriostatic deodorizing socks, and the stink prevention hosiery is obtained by cotton fiber, chitin fiber, bamboo fibre, modal fiber blended, and composite metal ion is contained in the bamboo fibre, contains alumen in the cotton fiber.The present invention provides compound bacteriostatic deodorizing socks comprising containing composite metal ion, not only there is healthcare function, can the characteristics such as high-efficiency antimicrobial, quick antibacterial, broad-spectrum antiseptic, safe antibacterial, have broad application prospects.
Description
Technical field
The present invention relates to textile technology fields, in particular it relates to a kind of compound bacteriostatic deodorizing socks and its preparation side
Method.
Background technique
Socks are indispensable daily necessities in people's life, and socks production is an important set of China's hosiery industry
At part.Socks belong to the formed product of weft-knitted fabric.Comfortable due to requiring to wear, shape will meet foot shape, will not take off
It falls or overturns, and require good-extensibility, good permeability, in addition, also to have good hygroscopicity and wearability.The type of socks
Very much, can be classified according to raw material, institutional framework, leggings length and stocking blank structure, socks specification.Due to many people foots
With pedopathy, as the ringworm of the foot, foot are itched or tinea pedis, somebody are that sweaty feet or foot are split.As consciousness of the people to health care enhances, to foot
Health and health are more paid attention to, so that the antibacterial and deodoriging properties to socks propose very high requirement, derive in all societies
Many different types of socks, but existing socks are not able to satisfy the demand of people to a certain extent, produce thus
Some socks with health care function, such as five-toe socks, the friction reduced between toe and toe are perspired, and treatment tinea pedis can be played
Effect, there are also socks to make socks with healthcare function before factory by liquid medicine immersion, but the disadvantage is that: these socks
It will appear phenomena such as foot is done, foot is split or skin aging after wearing, be not able to satisfy the needs of people's daily life.
Summary of the invention
In consideration of it, applicant of the present invention provides a kind of compound bacteriostatic deodorizing socks, the stink prevention hosiery is to Escherichia coli, golden yellow
The bacteriums such as staphylococcus, Candida albicans, enterococcus faecalis, Friedlander's bacillus and mould all have good antibiotic property
Can, antibacterial that can not only be permanently effective, and can be avoided phenomena such as foot is dry, foot is split or skin aging.
In order to achieve the object of the present invention, the present invention adopts the following technical scheme:
One aspect of the present invention provides a kind of compound bacteriostatic deodorizing socks, and the stink prevention hosiery stink prevention hosiery is fine by cotton fiber, chitin
Dimension, bamboo fibre, modal fiber blended obtain, and composite metal ion is contained in the bamboo fibre, is contained in the cotton fiber withered
Alum.
Cotton fiber: the fiber being coated on the seed of Malvaceae cotton, also known as cotton, abbreviation cotton.It is textile industry
Important source material.Cotton Products moisture absorption and good permeability, it is soft and keep warm.
Bamboo fibre is that a kind of natural height being process by well known bamboo gathers as a kind of cellulose fibre
Object.
Bamboo fibre because its macromolecular special construction, and have it is good restrain the healthcare functions such as bacterial growth, absorption peculiar smell,
And moisture absorption is ventilative, biodegradable；Have the characteristics that simultaneously it is soft and smooth it is soft it is warm, moisture absorption is ventilative, environmentally protective, uvioresistant, praised
For the green fiber of new century.Special ultrafine micropore structure makes it have powerful adsorption capacity inside bamboo fibre, can inhale
Attached composite metal ion.And cross section deformation of unevenness, it has been covered with the hole for being similar to ellipse, capillary hollow in height
Effect is extremely strong, can be in transient absorption and evaporation water.Bamboo fibre Comfortable attractive function, unit G fineness is thin, and whiteness is good, fresh after dyeing
Gorgeous true, not fugitive color, gloss is beautiful, and plentiful very to scrape, drapability is good.
The distinctive antimicrobial factors of chitin fiber make it have excellent bacteriostasis, and deodorization function, can prevent bacterium, fungi
Procreation, eliminate peculiar smell, keep the cleaning of skin, distinctive structure has apparent nursing function to skin, can protect skin
It does not dry, prevent pruritus and has adjuvant treatment and prevention and treatment function to skin acne rash, eczema, erythema, allergic skin, due to first
Shell cellulose fiber on its macromolecular chain there are hydrophilic radicals such as a large amount of hydroxyl and amino, therefore fiber have good hydrophily and
Very high hygroscopicity, while chitin fiber has antistatic characteristic, this function, which can give, moistens soft comfort.When
So, the chitin fiber in the application also could alternatively be other organic fibers such as chitin fiber.
Modal fibre, abbreviation Modal fiber is a kind of high wet modulus regenerated celulose fibre, and the raw material of the fiber is adopted
With the beech in Europe, it is first made into wood pulp, then fiber is processed by special spinning technique.The entire production process of fiber
In there is no any pollution.It dry by force close to terylene, it is wet to improve many, gloss, flexibility, moisture absorption than common viscose glue by force
Property, dyeability, dyefastness are superior to Pure cotton Product；The fabric being made into it illustrates a kind of face gloss, has pleasant
Soft touch feel and pendency sense and fabulous endurable performance.Modal fibre fiber is made after wooden slurries by special
Spinning technique be made, be a kind of cellulose fibre, so belonging to cellulose fibre as cotton.Modal fibre product
With good flexibility and excellent hygroscopicity, and there is the gloss of silvery white, excellent stainability and bright color after being dyed
The characteristics of, it is used just to make coat.Modal fibre will not lack as its characteristic of the fabric of environmental protection in the pink of condition, not
Dai Er fiber has the characteristics that high-tenacity fiber is uniform, have good spinnability and textile, can with traditional method into
Row processing dyeing.Modal fiber fabric has water suction and permeability good, soft smooth, comfortable smooth feature.Modal
Fiber is primarily used in the personal clothing manufacture and household textiles of people, and the characteristic of soft smooth can allow people's dress non-
Normal health is comfortable, can also be blended together with the fabric of other materials, forms fabric with different feelings.
Alumen also known as alum is forged, take the alum for picking net, set heating in casserole and dissolve and be calcined to dried-up, take out, be irregular
Crystalline solid, not of uniform size, colourless, transparent or semitransparent, surface is slightly smooth or uneven, has fine and closely woven vertical rib, there is hyaloid
Gloss.Matter is hard and crisp, easily smashes, and gas is micro-, slightly sweet and puckery, white with color, transparent, matter is hard and crisp, free from admixture person is preferred.Function master
Control: dissolving phlegm, eliminating dampness, antidiarrheal are stopped blooding, removing toxic substances, desinsection.Epilepsy, sore throat are controlled, remorse saliva is stopped up very, and hepatitis, jaundice, Huang is swollen, stomach, and 12
Duodenalulcer, uterine prolapse, leukorrhea, dysentery, bleeding from five sense organs or subcutaneous tissue, aphthae, sore hemorrhoid scabies, water, fire, insect bite.
In the specific embodiment of the present invention, by being immersed in the cotton fiber containing 1%-5% alumen
It is prepared in aqueous solution.For example, being immersed in 100g cotton fiber in the aqueous solution containing 3% alumen.
In the specific embodiment of the present invention, the composite metal ion includes silver ion, copper ion, zinc ion
And tin ion.
The application selects one of silver ion, copper ion, zinc ion and tin ion or a variety of compound gold as antibacterial
Belong to ion, can not only efficiently antibacterial, quick antibacterial, and it is broad spectrum antimicrobial agent.
In the specific embodiment of the present invention, in bamboo fibre described in every 100g, it is added 2.5~8.5 × 10-4mol
Silver ion, 0.1~3.5 × 10-2Mol copper ion, 0.65~2.5 × 10-3Zinc ion, 3.5~9.9 × 10-3Tin ion.
The application selects the concentration range of above-mentioned silver ion, copper ion, zinc ion and tin ion, acceptable in human body
Safe concentration within the scope of, will not cause any harm to human body or side effect.
In the specific embodiment of the present invention, the cotton fiber further includes Chinese herbal medicine and surfactant.
In the specific embodiment of the present invention, the Chinese herbal medicine includes the root of Dahurain angelica, Chinese prickly ash, dandelion, asarum and Huang
A kind of reed mentioned in ancient books.
In the specific embodiment of the present invention, the Chinese herbal medicine is by the root of Dahurain angelica, Chinese prickly ash, dandelion, asarum and radix scutellariae
Composition.
The root of Dahurain angelica: warm-natured, acrid flavour, gas fragrance, slight bitter.Major function: wind-damp dispelling, apocenosis of invigorating blood circulation, myogenic pain relieving.For head
Bitterly, toothache, nasosinusitis, intestines wind anal fistula, leukorrhea with reddish discharge, ulcer sores, pruitus.Mainly using angelica anomala in the application.
Chinese prickly ash: (scientific name: Zanthoxylumbungeanum Maxim.) has warming spleen and stomach for dispelling cold, dehumidifies, analgesic, desinsection, solution
Effect of fish raw meat poison.It controls having indigestion to stop drinking, trusted subordinate's crymodynia, vomit, oh, cough with dyspnea, wind-cold-dampness arthralgia, diarrhea, dysentery, colic,
Dentalgia, roundworm disease, enterobiasis, pruritus vulvae, sore scabies.
Dandelion: (Classification system: Taraxacummongolicum Hand.-Mazz.), alias dandelion, grandmother
Fourth, Hua Hualang etc..Nature and flavor: bitter sweet is trembled with fear.Channel tropism: enter liver, stomach meridian.Major function: clearing heat and detoxicating, diuresis dissipating bind.Control acute mammary gland
Inflammation, adenolymphitis, scrofula, boil poisonous soreness, acute conjunctivitis, cold, fever, acute tonsillitis, acute bronchitis, gastritis,
Hepatitis, cholecystitis, urinary tract infections.
Asarum: alias: asarum sieboldii, basin grass asarum, Latin literary fame: AsarumsieboldiiMiq..This kind of all herbal medicine.
Major function: relieving exterior syndrome and dispelling cold, wind-expelling pain-stopping is sensible, warming lung and resolving fluid.For anemofrigid cold, have a headache, toothache, nasal congestion, nose
Have a stuffy nose, nasosinusitis, rheumatic arthralgia, sputum cough.Meridian distribution of property and flavor: acrid in flavour and warm in nature.Return heart, lung, kidney channel.HERBA ASARI from Liaoning of China root is thin, color sallow, leaf color
It is green, the peppery numb tongue of acrid flavour.It is warm-natured, it is slightly poisonous.Return heart, lung, kidney channel.There are wind-dispelling, cold dispelling, warm lung, Hang Shui, the effect having one's ideas straightened out.Control wind
Cold headache, nasosinusitis, dentalgia, sip and cough, rheumatic arthralgia.In addition, asarum also has anti inflammatory immunity, local anaesthesia, raising new old
Metabolism, antibacterial action, also can be used for the oligoleukocythemia of Chemotherapy of Tumor Patients and caused by radiation.The application uses HERBA ASARI from Liaoning of China,
Originate in Liaoning southeast.It is born in hayashishita and gully wetland.
Radix scutellariae: (Classification system: Scutellariabaicalensis Georgi), alias Radix Scutellariae, tsuchikane tea root are yellow
The root of a kind of reed mentioned in ancient books is used as medicine, bitter, cold in nature, there is heat-clearing and damp-drying drug, purging fire for removing toxin, hemostasis, miscarriage prevention and other effects.Cure mainly warm heat disease, the upper respiratory tract
The diseases such as infection, cough with lung heat, neonatal jaundice caused by dampness-heat, pneumonia, dysentery, hemoptysis, hot eyes, threatened abortion, hypertension, carbuncle swells furuncle sore.Radix scutellariae
Clinical antibiotic property it is better than the coptis, and do not develop drug resistance.
In the specific embodiment of the present invention, the Chinese herbal medicine include the 30-60 parts of roots of Dahurain angelica, 50-80 portions of Chinese prickly ashes,
40-60 portions of dandelions, 23-40 parts of asarums and 20-40 parts of radix scutellariaes.Such as the Chinese herbal medicine includes or by 50 parts of the root of Dahurain angelica；Chinese prickly ash 65
Part；53 parts of dandelion；32 parts of asarum；28 parts of radix scutellariae are prepared.
The preparation method of said herbal medicine, comprising the following steps:
(1) root of Dahurain angelica, Chinese prickly ash, dandelion, asarum and radix scutellariae are dried, is crushed；
(2) root of Dahurain angelica, Chinese prickly ash, dandelion, asarum and radix scutellariae are weighed according to parts by weight, and be uniformly mixed；
(3) 75% alcoholic extract is added, obtains extract liquor；
(4) extract liquor in step (3) is centrifuged, is concentrated under reduced pressure up to Chinese herbal medicine.
In the specific embodiment of the present invention, the surfactant is selected from polyoxyethanyl alkyl ether, fatty acid
Sorbitan ester, fatty acid polyoxyethanyl sorbitan ester, fatty glyceride, a kind in fatty acid cane sugar ester
The above compound.It has the function of water suction with the surfactant selected in the application, and property is stablized, and agglomeration etc. is not susceptible to
Phenomenon, and it is biodegradable, it is environmentally friendly.
Another aspect of the present invention provides the preparation method of above-mentioned compound bacteriostatic deodorizing socks comprising following steps:
(1) bamboo fibre is immersed in the solution containing silver ion, copper ion, zinc ion and tin ion and is prepared containing compound
The bamboo fibre of metal ion；
(2) cotton fiber is immersed in the aqueous solution containing 1%-5% alumen；And optionally, cotton fiber is immersed in
The cotton fiber containing Chinese herbal medicine is prepared in extracting solution containing the root of Dahurain angelica, Chinese prickly ash, dandelion, asarum and radix scutellariae；And optionally,
Cotton fiber containing Chinese herbal medicine is immersed in dissolubility of the preparation containing surfactant in the solution of surfactant
Fiber；
(3) by the cotton fiber containing surfactant and chitin fiber, bamboo fibre, Modal fibre in step (2)
Plying, and it is twisted into single cord, socks are then made by automatic air-jet loom.
Another aspect of the invention provides the compound bacteriostatic deodorizing socks and is inhibiting and/or killing Escherichia coli and/or withered grass
Application in bacillus and/or staphylococcus aureus and/or white grape bacterium and/or saccharomycete.
Illustratively, the present invention one of at least has the advantage that:
The present invention provides a kind of compound bacteriostatic deodorizing socks comprising containing composite metal ion, not only has health care function
Can, can the characteristics such as high-efficiency antimicrobial, quick antibacterial, broad-spectrum antiseptic, safe antibacterial, have broad application prospects.
Specific embodiment
Below in conjunction with specific embodiments of the present invention, technical solution of the present invention is clearly and completely described.It is aobvious
So, the described embodiment is only a part of the embodiment of the present invention, instead of all the embodiments.Based on the implementation in the present invention
Example, every other embodiment obtained by those of ordinary skill in the art without making creative efforts belong to
The scope of protection of the invention.
Bamboo fibre of the embodiment 1 containing composite metal ion
According in every 100g bamboo fibre contain 8.5 × 10-4Mol silver ion, 0.1 × 10-2Mol copper ion, 0.65 × 10-3
Zinc ion and 3.5 × 10-3The proportional arrangement composite metal ion solution of tin ion, bamboo fibre is immersed in containing silver ion, copper
In the compound ion solution of ion, zinc ion and tin ion overnight, the bamboo fibre containing composite metal ion is prepared.
The preparation of 2 cotton fiber of embodiment
Cotton fiber is immersed in the aqueous solution containing 1%-5% alumen, soaked overnight, it is fine to prepare the cotton containing alumen
Dimension.
Can choose the aqueous solution of 1%-5% alumen in the present embodiment, for example, 1%, 2%, 3%, 4% or 5% etc. it is withered
Alum aqueous solution, the present embodiment use 3% alumen aqueous solution.Cotton fiber is immersed in the aqueous solution containing 3% alumen, is impregnated
After overnight, drying.
By weight, Chinese herbal medicine includes: 50 parts of the root of Dahurain angelica；65 parts of Chinese prickly ash；53 parts of dandelion；32 parts of asarum；28 parts of radix scutellariae.
The preparation method of Chinese herbal medicine, comprising the following steps:
(1) root of Dahurain angelica, Chinese prickly ash, dandelion, asarum and radix scutellariae are dried, is crushed；
(2) root of Dahurain angelica, Chinese prickly ash, dandelion, asarum and radix scutellariae are weighed according to parts by weight, and be uniformly mixed；
(3) alcoholic extract for being added 75% obtains extract liquor；
(4) extract liquor in step (3) is centrifuged up to Chinese herbal medicine.
Cotton fiber containing alumen is immersed in the Chinese herbal medicine solution that mass fraction is 20%, overnight, is prepared in containing
The cotton fiber of herbal medicine.
Cotton fiber containing Chinese herbal medicine is immersed in after dry in the fatty glyceride that mass fraction is 10%, preparation contains
There is the cotton fiber of surfactant.
The preparation of the compound bacteriostatic deodorizing socks of embodiment 3
35% cotton fiber (is prepared) in embodiment 2,10% chitin fiber, 30% bamboo fibre (prepared by embodiment 1),
25% Modal fibre plying, and it is twisted into single cord, socks are then made by automatic air-jet loom.
The compound bacteriostatic deodorizing socks of embodiment 4
30% cotton fiber (is prepared) in embodiment 2,15% chitin fiber, 35% bamboo fibre (prepared by embodiment 1),
20% Modal fibre plying, and it is twisted into single cord, socks are then made by automatic air-jet loom.
The compound bacteriostatic deodorizing socks of embodiment 5
15% cotton fiber (is prepared) in embodiment 2,30% chitin fiber, 10% bamboo fibre (prepared by embodiment 1),
45% Modal fibre plying, and it is twisted into single cord, socks are then made by automatic air-jet loom.
The compound bacteriostatic deodorizing socks of embodiment 6
15% cotton fiber (is prepared) in embodiment 2,30% chitin fiber, 30% bamboo fibre (prepared by embodiment 1),
25% Modal fibre plying, and it is twisted into single cord, socks are then made by automatic air-jet loom.
The test of the compound bacteriostatic deodorizing socks bactericidal property of embodiment 7
Bactericidal property test is carried out with the compound bacteriostatic deodorizing socks in above-described embodiment 3-6.Anti-microbial property test presses QB/
T2591-2003 test.The results are shown in Table 1 for its experiment.
The anti-microbial property test of compound bacteriostatic deodorizing socks in 1 embodiment 3-6 of table
Anti-microbial property test is carried out to the compound bacteriostatic deodorizing socks provided in embodiment 3-6, the test strain selected is big
Enterobacteria ATCC25922, staphylococcus aureus ATCC6538, Candida albicans CMCC (F) 98001, enterococcus faecalis
ATCC29212, Friedlander's bacillus CMCC46117, aspergillus niger AS3.4463, Aureobasidium pullulans AS3.3984, test result
As shown in table 1.From table 1 it follows that the bactericidal effect of the compound bacteriostatic deodorizing socks in the present embodiment 3-6 is higher, it is seen then that
The compound bacteriostatic deodorizing socks that the present embodiment 3-6 is provided have efficient sterilizing, the effect of broad-spectrum sterilization.
The compound bacteriostatic deodorizing socks provided in the embodiment of the present application joined alumen, Chinese herbal medicine, surfactant and compound
Metal ion.Wherein,
Alumen has eliminating dampness, removing toxic substances, the functions such as desinsection；
1. Chinese herbal medicine has the function of bactericidal；2. having the function of deodorization；3. having the function of health care；
1. composite metal ion has the effect of antibacterial, antibacterial, mould proof, because composite metal ion will not ooze out, antibacterial
The effective content of matter can remain unchanged for a long time, and therefore, antibacterial effect remains unchanged with being also able to maintain；It is removed 2. having
Smelly function.
Surfactant: 1. can effective moisture absorption the effect of, can effectively absorb water moisture-proof, can further prevent thin
Bacterium breeds in the sweat of foot；2. the moisture of the absorption of surfactant provides solvent for the dissolution of Chinese herbal medicine, more added with
Its drug action is played conducive to Chinese herbal medicine.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all in essence of the invention
Within mind and principle, made any modification, equivalent replacement etc. be should all be included in the protection scope of the present invention.
Claims (8)
1. a kind of compound bacteriostatic deodorizing socks, which is characterized in that the stink prevention hosiery is by cotton fiber, chitin fiber, bamboo fibre, not generation
You obtain fiber blend, and composite metal ion is contained in the bamboo fibre, contains alumen in the cotton fiber.
2. compound bacteriostatic deodorizing socks as described in claim 1, which is characterized in that the composite metal ion include silver ion,
Copper ion, zinc ion and tin ion.
3. compound bacteriostatic deodorizing socks as claimed in claim 1 or 2, which is characterized in that the cotton fiber further include Chinese herbal medicine and
Surfactant.
4. compound bacteriostatic deodorizing socks as claimed in claim 3, which is characterized in that the Chinese herbal medicine includes the root of Dahurain angelica, Chinese prickly ash, Pu Gong
English, asarum and radix scutellariae.
5. compound bacteriostatic deodorizing socks as claimed in claim 3, which is characterized in that the surfactant is selected from polyoxyethanyl alkane
Base ether, sorbitan fatty esters, fatty acid polyoxyethanyl sorbitan ester, fatty glyceride, fatty acid sugarcane
One or more of sugar ester compound.
6. the preparation method of compound bacteriostatic deodorizing socks according to any one of claims 1 to 5, which is characterized in that including following
Step:
(1) bamboo fibre is immersed in preparation in the solution containing silver ion, copper ion, zinc ion and tin ion and contains composition metal
The bamboo fibre of ion；
(2) cotton fiber is immersed in the aqueous solution containing 1%-5% alumen；And optionally,
Cotton fiber is immersed in cotton of the preparation containing Chinese herbal medicine in the extracting solution containing the root of Dahurain angelica, Chinese prickly ash, dandelion, asarum and radix scutellariae
Fiber；And optionally,
Cotton fiber containing Chinese herbal medicine is immersed in cotton fiber of the preparation containing surfactant in the solution of surfactant；
(3) by the cotton fiber and chitin fiber, bamboo fibre, Modal fibre plying in step (2), and it is twisted into single cord,
Then socks are made by automatic air-jet loom.
7. preparation method as claimed in claim 6, which is characterized in that the extracting solution is the root of Dahurain angelica, Chinese prickly ash, Pu Gong that will be dried
After English, asarum and radix scutellariae crush, obtained by 75% alcoholic extract that utilizes.
8. compound bacteriostatic deodorizing socks according to any one of claims 1 to 5 are inhibiting and/or are killing Escherichia coli, and/or
In staphylococcus aureus and/or Candida albicans and/or enterococcus faecalis, and/or Friedlander's bacillus, and/or mould
Application.
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Application publication date: 20190524 |