CN108236133B - Multifunctional health-preserving socks with bovine skin collagen and preparation method and application thereof - Google Patents
Multifunctional health-preserving socks with bovine skin collagen and preparation method and application thereof Download PDFInfo
- Publication number
- CN108236133B CN108236133B CN201810056912.9A CN201810056912A CN108236133B CN 108236133 B CN108236133 B CN 108236133B CN 201810056912 A CN201810056912 A CN 201810056912A CN 108236133 B CN108236133 B CN 108236133B
- Authority
- CN
- China
- Prior art keywords
- yarns
- health
- preserving
- sock
- yarn
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41B—SHIRTS; UNDERWEAR; BABY LINEN; HANDKERCHIEFS
- A41B11/00—Hosiery; Panti-hose
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41B—SHIRTS; UNDERWEAR; BABY LINEN; HANDKERCHIEFS
- A41B17/00—Selection of special materials for underwear
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04B—KNITTING
- D04B1/00—Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
- D04B1/14—Other fabrics or articles characterised primarily by the use of particular thread materials
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04B—KNITTING
- D04B1/00—Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
- D04B1/22—Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes specially adapted for knitting goods of particular configuration
- D04B1/24—Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes specially adapted for knitting goods of particular configuration wearing apparel
- D04B1/26—Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes specially adapted for knitting goods of particular configuration wearing apparel stockings
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41B—SHIRTS; UNDERWEAR; BABY LINEN; HANDKERCHIEFS
- A41B2400/00—Functions or special features of shirts, underwear, baby linen or handkerchiefs not provided for in other groups of this subclass
- A41B2400/32—Therapeutic use
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41B—SHIRTS; UNDERWEAR; BABY LINEN; HANDKERCHIEFS
- A41B2400/00—Functions or special features of shirts, underwear, baby linen or handkerchiefs not provided for in other groups of this subclass
- A41B2400/34—Functions or special features of shirts, underwear, baby linen or handkerchiefs not provided for in other groups of this subclass antimicrobial or antibacterial
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41B—SHIRTS; UNDERWEAR; BABY LINEN; HANDKERCHIEFS
- A41B2400/00—Functions or special features of shirts, underwear, baby linen or handkerchiefs not provided for in other groups of this subclass
- A41B2400/36—Deodorising or perfuming
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2211/00—Protein-based fibres, e.g. animal fibres
- D10B2211/01—Natural animal fibres, e.g. keratin fibres
- D10B2211/06—Collagen fibres
Abstract
The invention provides a multifunctional health-preserving sock made of cow leather collagen and a preparation method and application thereof, and relates to the technical field of sock weaving. The health-preserving socks take the cow hide collagen fiber as a functional component, and have the effects of resisting bacteria, deodorizing, moisturizing, preventing cracking, keeping warm, ventilating and nourishing skin. The preparation method of the multifunctional health-preserving oxhide collagen sock comprises the step of weaving the oxhide collagen fiber blended yarn into the health-preserving sock, and the oxhide collagen fiber is used as the raw material yarn and the functional component, so that the health-preserving function of the prepared health-preserving sock has durability. The multifunctional health-preserving oxhide collagen sock is applied to relieving beriberi, resisting bacteria, deodorizing and preventing foot chap, has durability, and does not lose efficacy along with repeated washing of the sock. Solves the technical problem that the prior art lacks a natural multifunctional wearable health preserving sock and a preparation method thereof.
Description
Technical Field
The invention relates to the technical field of sock weaving, in particular to a multifunctional health-preserving sock made of cow leather collagen and a preparation method and application thereof.
Background
Functional socks products, especially socks products with the functions of resisting bacteria, deodorizing, moisturizing, preventing cracking, being comfortable, ventilating, nourishing skin and the like are increasingly popular in the market and are concerned by a plurality of scholars, and a plurality of sock finishing technologies with the functions of resisting bacteria and deodorizing are provided. At present, the antibacterial and deodorant processing technology of the sock products mainly comprises the following main categories: (1) chemical antibacterial agent finishing technology: aromatic halogen compounds such as 2,4, 4-trichloro-2-hydroxydiphenyl ether, DC-5700 organosilicon quaternary ammonium compounds of Dow Corning, and organic oxygen compounds such as polyoxyalkylenetrialkyl ammonium salts; (2) plant extract antibacterial finishing technology; (3) the metal material antibacterial finishing technology comprises the following steps: if nano silver wires, nano silver ions, silver fibers, pure silver fibers, silver-plated fiber yarns, copper ion finished yarns or zinc ion finished fibers and the like are adopted as raw materials of the hosiery, the antibacterial processing is carried out; (4) and (3) performing antibacterial processing by adopting a functional chemical fiber material: such as adding nanometer pearl powder into viscose fiber, adding nanometer graphene material into nylon fiber to obtain antibacterial deodorant sock knitting material, etc.; (5) the natural antibacterial fiber is adopted as an antibacterial material for processing: for example, natural fibers with a certain antibacterial effect, such as fibrilia, bamboo fiber, polylactic acid fiber and the like, are used as raw materials of the knitted socks for antibacterial processing.
The existing antibacterial and deodorant technology for socks mostly adopts metal materials such as silver, copper and zinc to achieve the antibacterial and deodorant effects, although the effect is good, the silver, copper and zinc are metal materials with certain toxicity, and have potential harm to human bodies after long-term contact with the human bodies, and especially the potential threat of being absorbed by the human bodies exists after the nanoscale metal materials are dissolved out of the socks.
Most of chemical antibacterial finishing agents in the prior art have the problem of dissolution and permeation, the permeated antibacterial substances have great potential toxicity threat to human bodies after being absorbed by feet, the antibacterial performance of the socks is greatly reduced after the socks are washed, and the antibacterial agent falls off after multiple times of washing to completely disappear the antibacterial and deodorant functions.
Although the plant extract antibacterial agent in the prior art is green and environment-friendly, has better affinity and use safety for human bodies, the antibacterial effect and durability of socks can not be ensured due to the problems of easy denaturation, washing loss and the like.
Therefore, the functional processing technology of the existing socks mostly depends on certain antibacterial materials or combined structure design to achieve certain antibacterial and deodorant effects, and has the technical problems of easy deformation, washing loss and potential harm to human bodies due to long-term contact with the human bodies.
In view of the above, the present invention is particularly proposed.
Disclosure of Invention
The invention aims to provide a multifunctional health-care cow leather collagen sock, and solves the technical problem that a multifunctional wearable health-care sock is lacked in the prior art.
The second purpose of the invention is to provide a preparation method of the multifunctional health preserving socks made of bovine skin collagen, and solve the technical problem that a method for weaving multifunctional wearable health preserving socks is lacked in the prior art.
The third purpose of the invention is to provide the application of the multifunctional health-preserving beef hide collagen sock in beriberi relieving, antibacterial, deodorization and foot crack prevention, and solve the problem that the health-preserving sock which is durable and has no side effect and can relieve beriberi while deodorizing exists in the prior art.
In order to solve the technical problems, the following technical scheme is adopted:
the functional components of the cow leather collagen multifunctional health preserving sock comprise cow leather collagen fibers.
Further, the raw materials of the multifunctional health-preserving oxhide collagen sock comprise oxhide collagen fiber blended yarns;
preferably, the mass fraction of the bovine collagen fibers in the bovine collagen fiber blended yarn is 5-60%;
preferably, the cowhide collagen fiber blended yarn is a covered yarn;
preferably, the linear density of the cowhide collagen fiber blended yarn is 20-60 metric counts.
Further, the raw materials of the health-preserving socks comprise face yarns and lining yarns, wherein the face yarns comprise cowhide collagen fiber blended yarns;
preferably, the mass ratio of the face yarn to the lining yarn is 3:2-4: 1;
preferably, the inner yarn comprises a covered filament;
further preferably, the coated yarn comprises polyester coated yarn, nylon coated yarn, acrylic coated yarn or silk coated yarn.
The preparation method of the multifunctional health-preserving oxhide collagen sock comprises the step of weaving the oxhide collagen fiber blended yarns to obtain the multifunctional health-preserving oxhide collagen sock.
Further, the bovine hide collagen fiber blended yarn comprises 5-60% of bovine hide collagen fibers;
preferably, the cowhide collagen fiber blended yarn is a covered yarn;
preferably, the linear density of the cowhide collagen fiber blended yarn is 20-60 metric counts.
Further, the weaving raw materials comprise a face yarn and a lining yarn, and the face yarn comprises a cowhide collagen fiber blended yarn;
preferably, the mass ratio of the face yarn to the lining yarn is 3:2-4: 1;
preferably, the inner yarn comprises a covering filament and an elastic material;
further preferably, the coated yarn comprises polyester coated yarn, chinlon coated yarn, acrylic coated yarn or silk coated yarn;
further preferably, the elastic material comprises elastic threads.
Further, the weaving comprises the step of carrying out double-layer plain weaving on the surface yarns and the lining yarns;
preferably, the inner yarn of the sock opening part is made of elastic yarns, and the inner yarn of the sock body, the sock head and the sock root part is made of wrap yarns.
Further, the preparation method also comprises the steps of washing the woven multifunctional health-preserving oxhide collagen socks with water, drying, and finally shaping;
preferably, the water washing treatment comprises the steps of firstly soaping for 10-30 minutes and then washing for 10-30 minutes by clean water at the temperature of 20-65 ℃;
preferably, the drying treatment comprises a step of heating and drying section by section, and the step of heating and drying section by section comprises a step of drying at 30-65 ℃ for 10-30 minutes, then drying at 65-80 ℃ for 10-30 minutes, and finally drying at 80-100 ℃ for 10-30 minutes;
preferably, the setting treatment includes a high-temperature high-pressure baking step including baking at a pressure of 2 to 5kgf/cm at a temperature of 100 ℃ and 160 ℃2The step of baking and shaping in the compressed air for 1 to 20 seconds.
Further, the preparation method also comprises the step of softening treatment before drying treatment;
preferably, the softening treatment comprises a step of treating with a softening agent at 20-65 ℃ for 10-60 minutes.
The multifunctional health-preserving beef hide collagen sock is applied to relieving beriberi, resisting bacteria, deodorizing and preventing foot chap.
Compared with the prior art, the invention has the following beneficial effects:
the multifunctional health-preserving bovine hide collagen sock provided by the invention takes natural bovine hide collagen fibers as functional components, the bovine hide collagen fibers have the functions of inhibiting bacteria and fungi on feet, have the bacteriostatic action on staphylococcus aureus, escherichia coli and candida albicans, and realize the functions of preventing and treating foot odor, beriberi and the like; the cowhide collagen fiber has the nourishing characteristics of excellent moisture retention, crack prevention, warm keeping, ventilation and the like, and has a certain repairing effect on the skin with pathological changes on feet. Also has certain effects of preventing, relieving and repairing dermatopathy caused by bacteria, fungi, dryness and other factors such as beriberi, split foot and the like. The bovine hide collagen fiber has excellent moisture absorption and release regulation capacity, can absorb moisture and preserve moisture when feet perspire, can release moisture when feet are dry, can preserve moisture and prevent cracking, and plays a role in relieving foot cracking. And because of the specific multi-dimensional scale structural characteristics of the bovine collagen fibers, the bovine collagen fibers have outstanding warm-keeping and air-permeable performances. The main component of the bovine skin collagen fiber is type I collagen, has natural affinity with human skin, is comfortable to be pasted, and is safe and healthy. Therefore, the health-care socks taking the natural cow leather collagen fiber as the main raw material have the effects of resisting bacteria and odor, moisturizing and preventing cracks, keeping warm and ventilating and nourishing skin.
According to the preparation method of the multifunctional health-care socks containing the oxhide collagen, provided by the invention, the health-care socks are prepared by weaving the oxhide collagen fiber blended yarns, natural oxhide collagen fibers are used as raw material yarns and then woven into the health-care socks instead of being finished by an antibacterial finishing agent or being obtained from the outside by a metal antibacterial material, so that the problems that the antibacterial effect is not durable due to washing loss of the chemical finishing agent and the metal nanometer material and the potential hazard is caused due to absorption of the chemical finishing agent and the metal nanometer material by a human body are avoided, and the health-care socks have the effects of resisting bacteria, deodorizing, moisturizing, preventing cracking, keeping warm and ventilating, and have permanent durability on the functions of preventing and treating beriberi, foot crack disease and the like.
When the multifunctional health-preserving socks provided by the invention are applied, because the oxhide collagen fibers are functional components of the health-preserving socks and are raw materials of the health-preserving socks, the health-preserving socks have durability when being applied to functions of relieving beriberi, resisting bacteria, deodorizing and preventing foot chap, and the efficacy of the socks cannot be lost along with repeated washing of the socks.
Detailed Description
The technical solutions of the present invention will be described clearly and completely with reference to the following embodiments, and it should be understood that the described embodiments are some, but not all, embodiments of the present invention. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
The invention provides a multifunctional health-care cow leather collagen sock, wherein the functional components of the multifunctional health-care cow leather collagen sock comprise natural cow leather collagen fibers.
The functional components of the multifunctional health-care bovine-hide collagen sock provided by the invention comprise natural bovine-hide collagen fibers, and the bovine-hide collagen fibers have the functions of inhibiting bacteria and fungi proliferation of feet, inhibiting staphylococcus aureus, escherichia coli and candida albicans, and realizing the functions of preventing and treating foot odor, beriberi and the like; the cowhide collagen fiber has the nourishing characteristics of excellent moisture retention, crack prevention, warm keeping, ventilation and the like, and has a certain repairing effect on the skin with pathological changes on feet. Also has certain effects of preventing, relieving and repairing dermatopathy caused by bacteria, fungi, dryness and other factors such as beriberi, split foot and the like.
The moisture regain of the bovine hide collagen fiber in a standard state is as high as 22%, the moisture regain is 2-3 times of that of common natural fibers, the bovine hide collagen fiber has excellent moisture absorption and release regulation capacity, moisture can be absorbed and preserved when feet perspire, moisture can be released when the feet are dry, moisture preservation and crack prevention can be realized, the effect of relieving foot crack is achieved, the bovine hide collagen fiber has outstanding warm keeping and air permeability due to the specific multi-dimensional scale structural characteristics of the bovine hide collagen fiber, 70-80% of dry weight of human skin is type I collagen, the main component of the bovine hide collagen fiber is type I collagen, the bovine hide collagen fiber has natural affinity with human skin, and the bovine hide collagen fiber is comfortable, safe and healthy.
Based on the functions of the cow leather collagen fibers, the health-preserving socks provided by the invention have the effects of resisting bacteria and odor, relieving beriberi, moisturizing and preventing cracking, and keeping warm and ventilating.
In an alternative embodiment, the raw material of the cowhide collagen multifunctional health preserving sock comprises cowhide collagen fiber blended yarn; optionally, the mass fraction of bovine collagen fibers in the bovine collagen fiber blended yarn is 5% to 60%, for example, but not limited to, 5%, 10%, 20%, 30%, 35%, 40%, 50% or 60%, preferably 40% to 50%.
In a preferred embodiment, the bovine hide collagen fiber blended yarn is a covered yarn; the covered yarn is also called wrapping yarn, and is a yarn with a novel structure, which takes filament or short fiber as a yarn core, is covered with another filament or short fiber yarn strip, and is covered with the core yarn in a spiral mode. The yarn is characterized by uniform evenness, bulkiness and fullness, smooth yarn with less hairiness, high strength and less broken ends, the covered yarn comprises natural fibers or chemical fibers, such as but not limited to bamboo fibers, corn fibers, wool, nylon fibers, acrylic fibers or polyester fibers, the type of the covered yarn is not limited, and the covered yarn can be understood as long as the covered yarn can be used as a material for covering the yarn. Optionally, the linear density of the bovine collagen fiber blended yarn is 20-60 cm, such as but not limited to 20 cm, 30 cm, 40 cm, 50 cm or 60 cm, preferably 35-50 cm, so that the bovine collagen fibers in the bovine collagen fiber blended yarn can be fully contacted with the skin to play a health-preserving role.
In an alternative embodiment, the raw materials of the cowhide collagen multifunctional health preserving sock comprise a face yarn and a lining yarn, wherein the face yarn comprises cowhide collagen fiber blended yarns; optionally, the mass ratio of the face yarns to the lining yarns is 3:2-4:1, for example, but not limited to, 3:2, 2:1, 5:2, 3:1, 7:2 or 4:1, preferably 5:2-3:1, and the health preserving effect of the health preserving sock can be further optimized by further optimizing the mass ratio of the face yarns to the lining yarns.
In an alternative embodiment, the inner yarn comprises a covered yarn, which may be, for example, but not limited to, a polyester covered yarn, a nylon covered yarn, an acrylic covered yarn, or a silk covered yarn, preferably a nylon covered yarn; preferably, the lining yarns further comprise elastic yarns, the elastic yarns are preferably elastic yarns, more preferably, the lining yarns at the welt part of the health preserving sock are made of elastic yarns, and the lining yarns at the sock body, the sock head and the sock root part are made of wrapping yarns. By further optimizing the performance of the inner yarn, the inner yarn can endow the sock with good comfort and physical performance, and meanwhile, the full contact between the oxhide gelatin fibrils and the skin in the outer yarn is not hindered.
In the method for preparing the multifunctional health-preserving bovine collagen sock, raw materials used in the method include a bovine collagen fiber blended yarn, and optionally, the mass fraction of bovine collagen fibers in the bovine collagen fiber blended yarn is 5% to 60%, for example, but not limited to, 5%, 10%, 20%, 30%, 35%, 40%, 50% or 60%, and preferably 40% to 50%.
In a preferred embodiment, the cowhide collagen fiber blended yarn is a covering yarn, the covering yarn takes the cowhide collagen fiber as a yarn core, the covering yarn covers the yarn core in a spiral manner, the covering yarn comprises natural fibers or chemical fibers, such as but not limited to bamboo fibers, corn fibers, wool, nylon fibers, acrylic fibers or polyester fibers, the invention is not limited to the kind of the covering yarn, and it is understood that the cowhide collagen fiber blended yarn has a linear density of 20-60 cm, such as but not limited to 20 cm, 30 cm, 40 cm, 50 cm or 60 cm, preferably 35-50 cm, as long as the material can function as the covering yarn.
In an alternative embodiment, the raw materials used in the method for preparing the health preserving socks comprise a face yarn and a lining yarn, wherein the face yarn comprises a cowhide collagen fiber blended yarn; optionally, the mass ratio of the face yarn to the inner yarn is 3:2 to 4:1, such as but not limited to 3:2, 2:1, 5:2, 3:1, 7:2, or 4:1, preferably 5:2 to 3: 1.
In an alternative embodiment, the inner yarn comprises a covered yarn, which may be, for example, but not limited to, a polyester covered yarn, a nylon covered yarn, an acrylic covered yarn, or a silk covered yarn, preferably a nylon covered yarn; preferably, the lining yarns further comprise elastic threads, the elastic threads are preferably 90# -120# elastic threads, more preferably, the lining yarns at the welt part of the health preserving sock are made of elastic threads, and the lining yarns at the sock body, sock head and sock root part are made of covered yarns.
The raw materials in the preparation method are selected based on the same conception as the health-preserving socks, and the health-preserving socks prepared from the raw materials have all effects of the health-preserving socks and are not described again.
The preparation method of the multifunctional health-preserving socks containing the oxhide collagen fibers comprises the step of weaving the oxhide collagen fiber blended yarns to prepare the health-preserving socks.
In an alternative embodiment, the method of making includes the step of double plain weaving the face yarn and the back yarn. In the embodiment, the outer-layer face yarn adopts thicker cowhide collagen fiber blended yarns, the inner-layer lining yarn adopts thinner coating yarns, the matching design of the face yarn and the lining yarn with different thicknesses and the plain weave method of the sock enable the inner and outer layers of the sock to be uniformly distributed with the cowhide collagen fibers, and the effect of the cowhide collagen fibers can be fully exerted. Preferably, the inner yarn of the sock opening part is made of elastic yarns, and the inner yarn of the sock body, the sock head and the sock root part is made of wrap yarns.
In an optional embodiment, the preparation method further comprises the steps of washing the woven health-preserving socks with water, drying, and finally shaping;
in an alternative embodiment, the water washing treatment comprises the steps of firstly soaping for 10-30 minutes and then washing for 10-30 minutes with clear water at the temperature of 20-65 ℃;
alternatively, the temperature condition of the water washing treatment may be, for example, but not limited to, 20 ℃, 25 ℃, 30 ℃, 35 ℃, 40 ℃, 45 ℃, 55 ℃ or 65 ℃; alternatively, the time of soaping may be, for example, but not limited to, 10 minutes, 20 minutes, or 30 minutes; alternatively, the washing time in clean water may be, for example, but not limited to, 10 minutes, 20 minutes, or 30 minutes. The washing treatment adopts the low-temperature water treatment condition of 20-65 ℃, is specially designed according to the property of the bovine hide collagen fiber and aims to avoid the shrinkage deformation of the bovine hide collagen fiber in aqueous solution.
In an alternative embodiment, the drying process comprises a step of increasing the temperature stepwise, wherein the stepwise increasing temperature comprises drying at 30-65 ℃ for 10-30 minutes, such as but not limited to 30 ℃, 35 ℃, 40 ℃, 50 ℃, 60 ℃ or 65 ℃; drying at 65-80 deg.C for 10-30 min, such as but not limited to 65 deg.C, 70 deg.C, 75 deg.C or 80 deg.C; finally drying at 80-100 deg.C for 10-30 min, such as but not limited to 80 deg.C, 85 deg.C, 90 deg.C, 98 deg.C or 100 deg.C; alternatively, the time of the above-mentioned sectional drying may be, but not limited to, 10 minutes, 15 minutes, 20 minutes, 25 minutes or 30 minutes, respectively. The 'section-by-section heating' drying method is specially designed according to the property of the cow leather collagen fiber, and aims to avoid shrinkage and deformation of the cow leather collagen fiber caused by direct high-temperature drying.
In an alternative embodiment, the setting treatment includes a high temperature and high pressure baking step, the high temperature and high pressure baking step includes baking at a temperature of 100 ℃ and 160 ℃ under a pressure of 2-5kgf/cm2Baking and shaping for 1-20s in compressed air; alternatively, the temperature of the baking may be, for example, but not limited to, 100 ℃, 110 ℃, 120 ℃, 130 ℃, 140 ℃, 150 ℃ or 160 ℃; alternatively, the pressure of the compressed air may be, for example, but not limited to, 2kgf/cm2、3kgf/cm2、3.5kgf/cm2、4kgf/cm2Or 5kgf/cm2(ii) a Alternatively, the baking time may be, but is not limited to, 1s, 5s, 8s, 10s, 15s, or 20 s. The shaping method of high-temperature high-pressure baking can avoid the defect of uneven appearance distribution caused by steam shrinkage of the cow leather collagen fiber.
In an alternative embodiment, the preparation method further comprises a step of softening treatment before drying treatment; alternatively, the softener may be, but not limited to, silicone softener, sheet softener, or ester quaternary ammonium salt softener, and it should be noted that the preparation method of the present invention is not limited to the type of softener, and commercially available softeners may be used; alternatively, the softening treatment comprises treatment with a softening agent at 20-65 ℃, such as but not limited to 20 ℃, 25 ℃, 30 ℃, 35 ℃, 40 ℃, 45 ℃, 55 ℃ or 65 ℃, for 10-60 minutes, such as but not limited to 10 minutes, 20 minutes, 30 minutes, 40 minutes, 50 minutes or 60 minutes.
The softening treatment adopts the water treatment condition at the low temperature of 20-65 ℃, is specially designed according to the property of the bovine hide collagen fiber and aims to avoid the shrinkage deformation of the bovine hide collagen fiber in aqueous solution.
By further optimizing the technological parameters in the preparation method of the oxhide collagen multifunctional health preserving socks, the comfort level and the health preserving effect of the health preserving socks can be further improved.
The multifunctional health-preserving oxhide collagen sock prepared by the preparation method has the effects of resisting bacteria, deodorizing, moisturizing, preventing cracking, keeping warm and ventilating, and has permanent durability for preventing and treating beriberi, foot crack disease and the like. Because the functions are the functions of the cow leather collagen fibers, the cow leather collagen fibers are not finished by the antibacterial finishing agent or are obtained from the outside by adopting the metal antibacterial material, the condition that the antibacterial effect of the chemical finishing agent or the metal nano material is not durable due to washing loss is avoided, and the potential harm caused by the absorption of the chemical finishing agent or the metal nano material by a human body is also avoided.
The invention also provides application of the multifunctional health-preserving beef hide collagen socks in relieving beriberi, resisting bacteria, deodorizing and preventing foot cracks.
The health socks take natural cow hide collagen fiber as functional component, have functions of inhibiting bacteria and fungi on foot, and have antibacterial effects on Staphylococcus aureus, Escherichia coli, and Candida albicans. And the cow hide collagen fiber has excellent nourishing characteristics of moisture retention, crack prevention, warm keeping, ventilation and the like, and has a certain repairing effect on the skin with foot pathological changes. The moisture regain of the cow hide collagen fiber in a standard state is as high as 22%, which is 2-3 times of that of common natural fiber, and the cow hide collagen fiber has excellent moisture absorption and desorption adjusting capacity. The foot can absorb moisture and keep moisture when perspiring, and can release moisture when the foot is dry, so as to achieve the effect of relieving the split foot, therefore, the health-care sock can be applied to relieving beriberi, resisting bacteria, deodorizing and relieving the split foot. And because the bovine hide collagen fiber is not only a functional component of the health-preserving socks, but also a raw material of the health-preserving socks, when the bovine hide collagen multifunctional health-preserving socks are applied to the functions of relieving beriberi, resisting bacteria, deodorizing and preventing foot chap, the bovine hide collagen multifunctional health-preserving socks have durability, and the efficacy of the bovine hide collagen multifunctional health-preserving socks cannot be lost along with repeated washing of the socks.
The advantageous effects of the present invention will be further described with reference to preferred embodiments.
Example 1
The embodiment provides a preparation method of multifunctional bovine skin collagen health-preserving socks and health-preserving socks prepared by the method.
The multifunctional health preserving cow leather collagen sock provided by the embodiment comprises surface yarns and lining yarns, wherein the surface yarns are cow leather collagen fiber blended coating yarns with the mass fraction of cow leather collagen fibers being 40%, the coating yarns are acrylic fibers, and the linear density of the surface yarns is 35 metric counts; the lining yarns are acrylic fiber coated yarns and 110# elastic yarns; wherein the mass ratio of the surface yarn to the lining yarn is 5: 2;
the multifunctional health preserving oxhide collagen sock provided by the embodiment is prepared by the following method:
(a) weaving the surface yarns and the lining yarns into socks by adopting a double-layer plain weaving method, wherein the lining yarns at the sock opening part adopt elastic yarns, and the lining yarns at the sock body, the sock head and the sock root part adopt covered yarns;
(b) soaping the formed socks for 20 minutes at 35 ℃, and then washing with clean water for 25 minutes;
(c) treating the washed socks with silicone oil softener at 35 deg.c for 45 min;
(d) drying the socks after the softening treatment in a way of heating up section by section, wherein the conditions are as follows: drying at 40 deg.C for 20 min, drying at 70 deg.C for 25 min, and drying at 85 deg.C for 20 min
(e) Introducing the dried sock under pressure of4kgf/cm2The sock is shaped for 20 minutes in a sock shaping box with compressed air at the temperature of 120 ℃ to obtain the finished multifunctional health-preserving oxhide collagen sock.
Example 2
The embodiment provides a preparation method of multifunctional bovine skin collagen health-preserving socks and health-preserving socks prepared by the method.
The multifunctional health preserving cow leather collagen sock provided by the embodiment comprises surface yarns and lining yarns, wherein the surface yarns are cow leather collagen fiber blended coating yarns with the mass fraction of the cow leather collagen fibers being 50%, the coating yarns are polyester fibers, and the linear density of the surface yarns is 50 metric counts; the lining yarn is silk covered yarn and No. 120 elastic yarn; wherein the mass ratio of the surface yarn to the lining yarn is 3: 1;
the multifunctional health preserving oxhide collagen sock provided by the embodiment is prepared by the following method:
(a) weaving the surface yarns and the lining yarns into socks by adopting a double-layer plain weaving method, wherein the lining yarns at the sock opening part adopt elastic yarns, and the lining yarns at the sock body, the sock head and the sock root part adopt covered yarns;
(b) soaping the molded socks at 45 ℃ for 15 minutes, and then washing the socks with clear water for 15 minutes;
(c) treating the washed socks with a silicone oil softener at 45 ℃ for 25 minutes;
(d) drying the socks after the softening treatment in a way of heating up section by section, wherein the conditions are as follows: drying at 50 ℃ for 15 minutes, drying at 75 ℃ for 15 minutes, and finally drying at 90 ℃ for 15 minutes;
(e) introducing dried sock under pressure of 5kgf/cm2The sock is shaped for 5 minutes in a sock shaping box with compressed air at the temperature of 100 ℃ to obtain the finished multifunctional health-preserving oxhide collagen sock.
Example 3
The embodiment provides a preparation method of multifunctional bovine skin collagen health-preserving socks and health-preserving socks prepared by the method.
The multifunctional health preserving cow leather collagen sock provided by the embodiment comprises surface yarns and lining yarns, wherein the surface yarns are cow leather collagen fiber blended coating yarns with the mass fraction of 5% of cow leather collagen fibers, the coating yarns are bamboo fibers, and the linear density of the surface yarns is 60 metric counts; the lining yarns are polyester covered yarns and 90# elastic yarns; wherein the mass ratio of the surface yarn to the lining yarn is 4: 1;
the multifunctional health preserving oxhide collagen sock provided by the embodiment is prepared by the following method:
(a) weaving the surface yarns and the lining yarns into socks by adopting a double-layer plain weaving method, wherein the lining yarns at the sock opening part adopt elastic yarns, and the lining yarns at the sock body, the sock head and the sock root part adopt covered yarns;
(b) soaping the molded socks for 30 minutes at the temperature of 20 ℃, and then washing the socks for 30 minutes by clear water;
(c) treating the washed socks with a silicone oil softener at 20 ℃ for 60 minutes;
(d) drying the socks after the softening treatment in a way of heating up section by section, wherein the conditions are as follows: drying at 30 deg.C for 30 min, drying at 65 deg.C for 30 min, and drying at 80 deg.C for 30 min
(e) Introducing dried sock under pressure of 2kgf/cm2The sock is shaped for 10 minutes in a sock shaping box with compressed air at the temperature of 160 ℃ to obtain the finished multifunctional health-preserving oxhide collagen sock.
Example 4
The embodiment provides a preparation method of multifunctional bovine skin collagen health-preserving socks and health-preserving socks prepared by the method.
The multifunctional health preserving cow leather collagen sock provided by the embodiment comprises surface yarns and lining yarns, wherein the surface yarns are blended and coated yarns of cow leather collagen fibers with the mass fraction of 60%, the coated yarns are nylon fibers, and the linear density of the surface yarns is 20 metric counts; the lining yarn is nylon covered yarn and 100# elastic yarn; wherein the mass ratio of the surface yarn to the lining yarn is 3: 2;
the multifunctional health preserving oxhide collagen sock provided by the embodiment is prepared by the following method:
(a) weaving the surface yarns and the lining yarns into socks by adopting a double-layer plain weaving method, wherein the lining yarns at the sock opening part adopt elastic yarns, and the lining yarns at the sock body, the sock head and the sock root part adopt covered yarns;
(b) soaping the molded socks at 65 ℃ for 10 minutes, and then washing with clean water for 10 minutes;
(c) treating the washed socks with a silicone oil softener at 65 ℃ for 10 minutes;
(d) drying the socks after the softening treatment in a way of heating up section by section, wherein the conditions are as follows: drying at 65 deg.C for 10 min, drying at 80 deg.C for 10 min, and drying at 100 deg.C for 10 min
(e) Introducing dried sock under pressure of 3kgf/cm2The sock is shaped for 15 minutes in a sock shaping box with compressed air at the temperature of 140 ℃ to obtain the finished multifunctional health-preserving oxhide collagen sock.
Example 5
The embodiment provides a preparation method of multifunctional bovine collagen health-preserving socks and health-preserving socks prepared by the method, and the difference from the embodiment 1 is that the mass fraction of bovine collagen fibers in the bovine collagen fiber blended and coated yarn is 80%.
Comparative example 1
The comparative example provides a preparation method of health-preserving socks and the health-preserving socks prepared by the method, and the difference from the example 1 is that the veil is bamboo fiber blended and coated yarn with the mass fraction of 40%.
Comparative example 2
The comparison example provides a preparation method of health-preserving socks and the health-preserving socks prepared by the method, and the difference from the example 1 is that the veil is cotton fiber blended and coated yarn with the mass fraction of 40% of cotton fiber finished by the silver ion antibacterial finishing agent.
Effect example 1
The results of testing the inhibition rates of the health socks provided in the examples and the comparative examples on staphylococcus aureus, escherichia coli and candida albicans (GB/T20944.3-2008, shake test) are shown in table 1:
TABLE 1 antibacterial rate of health socks
As can be seen from the above table, the health-preserving socks taking the bovine collagen fibers as the functional components have higher antibacterial rate, wherein the antibacterial rate is increased along with the increase of the content of the bovine collagen fibers, which indicates that the bovine collagen fibers play a key role in the antibacterial efficiency of the health-preserving socks.
Effect example 2
160 patients with tinea pedis were collected, wherein 80 men and 80 women were divided into 8 groups on average, and 10 male patients and 10 female patients in each group were aged 18-65 years and were randomly assigned.
The patient had the following symptoms: hyperhidrosis in the foot, impregnation between toes, and application of white skin often accompanied by malodor, or blisters on the plantar and marginal areas of the foot, dry desquamation, or a hypertrophic, dry, chapped skin on the heel, marginal areas of the foot, or even the entire plantar area of the foot. It is itchy in summer.
The treatment method comprises the following steps: 1-7 groups were treatment groups, 1-5 groups were respectively wearing the bovine hide collagen multifunctional health preserving socks provided in examples 1-5, 6-7 groups were wearing the health preserving socks provided in comparative examples 1-2, and 8 groups were blank controls were wearing cotton socks without health preserving function; and each patient changes and washes socks every day, does not adopt other medicines or treatment means to treat tinea pedis during the test period, and the treatment time is 1 month.
The therapeutic effect judgment standard is as follows: and (3) curing: the symptoms and physical signs disappear, and the skin returns to normal; improvement: the symptoms are obviously relieved, and the skin damage is resolved by more than 50 percent. Rechecking that the fungus still has positive; the disease is not cured: no change in symptoms and signs.
TABLE 2 verification of the action of treating tinea pedis
| Cure of disease | Improvement of life | Not cured | Effective rate (%) | |
| Example 1 | 10 | 8 | 2 | 90 |
| Example 2 | 8 | 9 | 3 | 85 |
| Example 3 | 5 | 10 | 5 | 75 |
| Example 4 | 9 | 8 | 3 | 85 |
| Example 5 | 8 | 9 | 3 | 85 |
| Comparative example 1 | 3 | 7 | 10 | 50 |
| Comparative example 2 | 5 | 9 | 6 | 70 |
As is apparent from the results of table 2, the effect of the multifunctional health socks of cow's skin collagen provided in examples 1 to 5 on relieving athlete's foot is superior to that of the health socks provided in comparative examples, and as is apparent from effect example 1, cow's skin collagen fibers have a good bacteriostatic effect and contribute to the inhibition of the growth of fungi that cause athlete's foot, so that the health socks having a higher content of cow's skin collagen fibers have a better relieving effect on athlete's foot. Patients with tinea pedis usually have a large foot perspiration volume, which leads to a moist environment on the skin surface to be more beneficial for the growth of fungi, thus aggravating the degree of tinea pedis. Because the cow leather collagen fiber has excellent moisture absorption and release regulation capacity, moisture can be absorbed and preserved when feet perspire, moisture can be released when the feet are dry, the skin of the feet is in a proper humidity environment, the fungi growth caused by the excessive moisture of the feet is prevented, and the tinea pedis is further relieved.
Although the antibacterial efficiency of the health-preserving socks can be further improved by improving the content of the bovine hide collagen fibers, the mass ratio of the coating yarns in the bovine hide collagen fiber blended coating yarns is too small, the coating effect on bovine hide collagen fiber cores is insufficient, and the bovine hide collagen fiber blended yarns cannot resist wearing.
In the experiment of this effect example, the patients using examples 1 to 5 did not show discomfort of the feet, and the skin of the feet of the patients with athlete's foot was damaged, so that bovine collagen fibers were likely to directly contact the wound, and in the effect example, none of 100 patients using the health socks provided in the examples had discomfort of the feet or allergic reaction, which proved that the health socks provided in the present invention had no toxic side effect on the skin and body of the patients, and that the patients using comparative example 2 had discomfort symptoms, which were manifested as swelling and pain of the damaged parts of the feet after 3 days of use, and immediately stopped using the socks.
Typical case 1
Plum, male and 45 years old, suffering from tinea pedis for 5 years, with symptoms of hyperhidrosis of feet, toe dip, covering white skin, accompanied by malodor, and often itching, hard to endure, seriously affecting normal life, after wearing the cow-hide collagen multifunctional health preserving sock provided by the embodiment for one week, the foot perspiration tends to be normal, the tinea pedis area is reduced by about 30%, the itching symptom is relieved, after wearing the health preserving sock provided by the embodiment for one month, the tinea pedis area is reduced by about 70%, the foot wetness condition in daytime is obviously weakened, and the itching symptom disappears along with the reduction of the tinea pedis area.
Typical case 2
The disease is characterized in that the disease is certain in von, women are 55 years old, and the tinea pedis is changed for 1 year, the symptoms are plantar and marginal blister clustering, dryness and desquamation, the feet are dry and cracked and accompanied with pruritus, when the multifunctional bovine hide collagen health-preserving sock provided by the embodiment is worn for 3 days, the cracking symptoms are reduced, the feet begin to recover moist and soft, the marginal blister is reduced after the health-preserving sock provided by the embodiment is worn for two weeks, the pruritus symptoms are relieved, and the tinea pedis symptoms basically disappear after one month.
Effect example 3
The examples 1 to 5 and the comparative examples 1 to 2 are repeatedly washed with water and dried for 30 times according to the washing process in the step (b) of the example 1, and then the inhibition rates of the health socks on staphylococcus aureus, escherichia coli and candida albicans are detected according to the method of the effect example 1, and the results are shown in table 3:
TABLE 3 antibacterial rate of the health socks after repeated washing
The embodiment and the comparative example are compared to each other, so that the antibacterial effect of the health-care socks provided by the embodiment of the invention is not obviously reduced after repeated water washing, and therefore, the durability of the health-care function of the health-care socks provided by the invention is superior to that of the health-care socks provided by the comparative example.
Finally, it should be noted that: the above embodiments are only used to illustrate the technical solution of the present invention, and not to limit the same; while the invention has been described in detail and with reference to the foregoing embodiments, it will be understood by those skilled in the art that: the technical solutions described in the foregoing embodiments may still be modified, or some or all of the technical features may be equivalently replaced; and the modifications or the substitutions do not make the essence of the corresponding technical solutions depart from the scope of the technical solutions of the embodiments of the present invention.
Claims (1)
1. The multifunctional health-preserving oxhide collagen socks are characterized in that raw materials of the health-preserving socks comprise face yarns and lining yarns, and the mass ratio of the face yarns to the lining yarns is 3:2-4: 1; the veil is a cowhide collagen fiber blended yarn, the cowhide collagen fiber blended yarn is a coating yarn with the cowhide collagen fiber in the mass fraction of 5% -60%, the coating yarn takes the cowhide collagen fiber as a yarn core, the yarn core is coated by an outer coating yarn in a spiral mode, and the outer coating yarn comprises natural fibers or chemical fibers; the linear density of the cowhide collagen fiber blended yarn is 20-60 metric counts; the lining yarns comprise covering yarns and elastic yarns, and the covering yarns are polyester covering yarns, polyamide covering yarns, acrylic covering yarns or silk covering yarns;
the inner yarn of the welt part of the health-preserving sock is made of elastic yarns, and the inner yarn of the sock body, the sock head and the sock root part is made of wrap yarns;
the preparation method of the health preserving socks comprises the steps of carrying out double-layer plain weaving on the surface yarns and the lining yarns; the preparation method of the health-preserving socks further comprises the steps of washing the woven multifunctional health-preserving socks made of the oxhide collagen by water, drying, and finally shaping;
the water washing treatment comprises the steps of firstly soaping for 10-30 minutes at the temperature of 20-65 ℃, and then washing for 10-30 minutes by clear water;
the drying treatment comprises the step of heating and drying section by section, and the step of heating and drying section by section comprises the steps of drying at 30-65 ℃ for 10-30 minutes, drying at 65-80 ℃ for 10-30 minutes, and finally drying at 80-100 ℃ for 10-30 minutes;
the shaping treatment comprises a high-temperature high-pressure baking step, wherein the high-temperature high-pressure baking step comprises baking at the temperature of 100-160 ℃ and under the pressure of 2-5kgf/cm2Baking and shaping for 1-20s in compressed air;
the preparation method also comprises a softening treatment step before the drying treatment, wherein the softening treatment comprises a step of treating for 10-60 minutes by using a softening agent at the temperature of 20-65 ℃.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810056912.9A CN108236133B (en) | 2018-01-19 | 2018-01-19 | Multifunctional health-preserving socks with bovine skin collagen and preparation method and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810056912.9A CN108236133B (en) | 2018-01-19 | 2018-01-19 | Multifunctional health-preserving socks with bovine skin collagen and preparation method and application thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN108236133A CN108236133A (en) | 2018-07-03 |
| CN108236133B true CN108236133B (en) | 2021-03-30 |
Family
ID=62698604
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810056912.9A Active CN108236133B (en) | 2018-01-19 | 2018-01-19 | Multifunctional health-preserving socks with bovine skin collagen and preparation method and application thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108236133B (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110664022A (en) * | 2019-10-29 | 2020-01-10 | 浙江诚信而已科技有限公司 | Antibacterial and deodorant sock |
| CN110897209A (en) * | 2020-01-10 | 2020-03-24 | 浙江宝善堂生物医疗科技有限公司 | Chinese herbal medicine-combined cowhide collagen fiber antibacterial socks and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN2498858Y (en) * | 2001-10-15 | 2002-07-10 | 捷盈实业股份有限公司 | Improved structure of socks |
| CN202112317U (en) * | 2011-06-01 | 2012-01-18 | 安丽集团有限公司 | Pure cotton fitting sock |
| CN103564663A (en) * | 2013-09-26 | 2014-02-12 | 浙江和也健康科技有限公司 | Socks and preparing method thereof |
| CN206043465U (en) * | 2016-08-30 | 2017-03-29 | 浪莎针织有限公司 | A kind of Graphene socks |
| CN107059142A (en) * | 2017-04-01 | 2017-08-18 | 顾勇杰 | A kind of overlength cattle-hide collagen fibers and its preparation method and application |
-
2018
- 2018-01-19 CN CN201810056912.9A patent/CN108236133B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN2498858Y (en) * | 2001-10-15 | 2002-07-10 | 捷盈实业股份有限公司 | Improved structure of socks |
| CN202112317U (en) * | 2011-06-01 | 2012-01-18 | 安丽集团有限公司 | Pure cotton fitting sock |
| CN103564663A (en) * | 2013-09-26 | 2014-02-12 | 浙江和也健康科技有限公司 | Socks and preparing method thereof |
| CN206043465U (en) * | 2016-08-30 | 2017-03-29 | 浪莎针织有限公司 | A kind of Graphene socks |
| CN107059142A (en) * | 2017-04-01 | 2017-08-18 | 顾勇杰 | A kind of overlength cattle-hide collagen fibers and its preparation method and application |
Also Published As
| Publication number | Publication date |
|---|---|
| CN108236133A (en) | 2018-07-03 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104178834B (en) | A kind of Chinese medicine viscose healthcare face fabric | |
| CN103668954B (en) | The antibiotic finishing method of antibacterial finishing agent, fabric and antibiotic fabric | |
| EP1703813A1 (en) | A functional compression socks | |
| CN108236133B (en) | Multifunctional health-preserving socks with bovine skin collagen and preparation method and application thereof | |
| CN202932044U (en) | Antibacterial deodorant stocking | |
| KR20040110966A (en) | A functional pressure socks and a manufacturing method thereof | |
| CN108741408B (en) | Insole with health care effect and preparation method thereof | |
| CN101613929A (en) | A kind of preparation method of inorganic nano antibiotic cotton fiber and the application in home textile product thereof | |
| CN109778373A (en) | A kind of bacteriostasis, and deodorization blend fibre and preparation method thereof and textile | |
| CN201663944U (en) | Antibacterial clothes | |
| CN105970604B (en) | A kind of safe antibacterial socks | |
| CN102940316A (en) | Antibacterial deodorization partial pressure decreasing type pressure socks | |
| KR101659963B1 (en) | Socks using copper fiber and korean paper fiber and manufacturing method | |
| CN207821122U (en) | A kind of antibacterial and deodorizing socks | |
| CN102767078A (en) | Special process finished chitosan antibacterial and deodorant health care sock | |
| CN104294579B (en) | A kind of healthcare face fabric for underpants for women | |
| CN106418743A (en) | Plant-derived antibacterial and odor-resistant sock and making method thereof | |
| CN109793288A (en) | A kind of compound bacteriostatic deodorizing socks and preparation method thereof | |
| CN112493617B (en) | Preparation method of breathable women's shoes | |
| CN202697730U (en) | Silver fiber socks | |
| CN102726842A (en) | Antibacterial and deodorant sock | |
| CN102742941A (en) | Silver fiber sock | |
| CN103668977A (en) | Chitosan antibacterial odor-resistant underpants finished through special process | |
| CN205052895U (en) | Anti -microbial sock | |
| CN110897263A (en) | Antibacterial and deodorant insole and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |