CN108218613A - A kind of compound fertilizer and its preparation and application of long-acting type improvement acidified soil - Google Patents

A kind of compound fertilizer and its preparation and application of long-acting type improvement acidified soil Download PDF

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Publication number
CN108218613A
CN108218613A CN201711391958.8A CN201711391958A CN108218613A CN 108218613 A CN108218613 A CN 108218613A CN 201711391958 A CN201711391958 A CN 201711391958A CN 108218613 A CN108218613 A CN 108218613A
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CN
China
Prior art keywords
compound fertilizer
soil
long
acting type
attapulgite clay
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Pending
Application number
CN201711391958.8A
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Chinese (zh)
Inventor
罗小三
赵朕
蔡鸣
蔡一鸣
郑豫
季炜
张丹
陈燕
历红波
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Nanjing University of Information Science and Technology
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Nanjing University of Information Science and Technology
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Priority to CN201711391958.8A priority Critical patent/CN108218613A/en
Publication of CN108218613A publication Critical patent/CN108218613A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/80Soil conditioners
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05DINORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
    • C05D9/00Other inorganic fertilisers

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Soil Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Fertilizers (AREA)

Abstract

The invention discloses the compound fertilizer and its preparation and application of a kind of long-acting type improvement acidified soil, the mixture which forms for attapulgite clay and peat, wherein, the mass percent of the attapulgite clay is 40% 60%.It when ploughing before proportion of crop planting, spreads fertilizer over the fields in cultivated soil by compound fertilizer row replacement or comprehensively, the usage amount of the compound fertilizer is 1,000 2000 kilograms of compound fertilizers of using in farmland per acre.The present invention combines the advantages of attapulgite clay and peat, is a kind of organo-mineral complexing, long-term effect, multi-functional, natural fertilizers product that can effectively, persistently improve acidification agricultural land soil.

Description

A kind of compound fertilizer and its preparation and application of long-acting type improvement acidified soil
Technical field
The present invention relates to agricultural environmental protection technical field, the compound fertilizer of specifically a kind of long-acting type improvement acidified soil and Its preparation and application.
Background technology
In recent decades, due to the shadow of the high intensity human activities such as Acid Rain Pollution, chemical fertilizer excessively apply, booth vegetable continuous cropping It rings, the aggravation of Farmland Soil Acidification phenomenon, assessing index is serious, and significant damage is caused to ecological environment and agricultural production, special It is not the significant obstacle factor that plant growth is had become in subtropical and tropical zones, and is usually accompanied by heavy metal pollution feelings Condition threatens food security, therefore, adopts an effective measure and severe acidification agricultural land soil is improved and repaired, raw to protection agricultural State environment and guarantee crop production safety and agricultural sustainable development have important Significance for Environment and economic benefit.
Traditionally mainly acid soil, but the side effect of lime are improved using alkaline matters such as lime, gypsum both at home and abroad Excessive to be easy to cause soil hardening and multiple acidification phenomenon, the use of gypsum is then limited by factors such as the property of can be supplied to and prices.And These means are typically more single, and can not take into account improves soil pH, fixed-contamination object, promotes a variety of actual requirements such as fertility, because This urgently develops the Organic-inorganic composite that can effectively, persistently improve acidification agricultural land soil, long-term effect, multi-functional, natural fertilizers production Product.With attapulgite(The clay mineral of zeopan containing Shuifu County with layer chain structure)Natural clay as main component is then A kind of preferably selection is provided thus.
Invention content
The purpose of the present invention is the deficiencies in for the above-mentioned prior art, provide a kind of answering for long-acting type improvement acidified soil Hefei material and preparation method thereof and application method.
It is a further object of the present invention to provide a kind of preparation methods of the compound fertilizer of long-acting type improvement acidified soil.
Third object of the present invention is to provide a kind of application method of the compound fertilizer of long-acting type improvement acidified soil.
The purpose of the present invention is what is be achieved through the following technical solutions:
A kind of compound fertilizer of long-acting type improvement acidified soil, the mixing which forms for attapulgite clay and peat Object, wherein, the mass percent of the attapulgite clay is 40%-60%.Attapulgite clay is as the nature being widely present Resource, often containing the typical minerals such as attapulgite, montmorillonite, kaolinite, hydromica, opal, quartz, feldspar, dolomite into Point, peat is then representative organic materials, is all respectively provided with ideal adjusting acidity and fixed heavy metal and promotes fertility Function, the integrated complementary of both natural materials use, can be by adjusting soil pH, promoting fertility, passivation harmful heavy metal The effects that active, reaches the purpose of improving crop yield, improving vegetables and grain quality, ensure food safety.
In further designing scheme of the invention, the mass percent of above-mentioned attapulgite clay is 50%.
The preparation method of the compound fertilizer of long-acting type improvement acidified soil, step are:
Step 1, attapulgite clay and peat are carried out respectively to air-dry or not higher than 70 DEG C at a temperature of drying and processing, Ran Houjin Row crushes, and respectively obtains attapulgite clay powder and peat clast;
Step 2 carries out abundant after being matched attapulgite clay powder and peat clast by above-mentioned mass percent requirement It is uniformly mixed, obtains the compound fertilizer of long-acting type improvement acidified soil.
In further designing scheme of the invention, the attapulgite clay powder and peat obtained after being crushed in step 1 is broken Bits granularity requirements at least needed 5 mesh to sieve -10 mesh sieve.
The application method of the compound fertilizer of long-acting type improvement acidified soil, specifically used method are:Before proportion of crop planting It during arable land, spreads fertilizer over the fields in cultivated soil by the compound fertilizer row replacement or comprehensively, the usage amount of the compound fertilizer is per acre 1000-2000 kilograms of compound fertilizer of using in farmland.
The present invention has advantageous effect following prominent:
The present invention combines the advantages of attapulgite clay and peat, is that a kind of can effectively, persistently improve is acidified agricultural land soil Organic-inorganic composite, long-term effect, multi-functional, natural fertilizers product.The compound fertilizer of long-acting type improvement acidified soil passes through adjusting Soil aciditiy promotes fertility, is passivated the effects that harmful heavy metal is active, reaches and improves crop yield, improves vegetables and grain Quality, the purpose of ensuring food safety.
Description of the drawings
Fig. 1 is soil pH value result of the test compares figure in embodiment 1;
Fig. 2 is crop biomass result of the test compares figure in embodiment 1;
Fig. 3 is soil pH value result of the test compares figure in embodiment 2;
Fig. 4 is crop biomass result of the test compares figure in embodiment 2.
Specific embodiment
The invention will be further described with reference to the accompanying drawings and embodiments.
Embodiment 1
More batches of romaine lettuce are planted with compound fertilizer improvement severe acidification agricultural land soil.
The preparation of the compound fertilizer of long-acting type improvement acidified soil:Attapulgite clay is be derived from Xuyi Jiangsu natural recessed Convex stick stone clay, peat are the natural peat for being derived from northeast Jilin, attapulgite clay and peat are air-dried respectively, then It crushes, crosses 10 mesh and 5 mesh sieve respectively, respectively obtain attapulgite clay powder and peat clast;By attapulgite clay Powder and peat clast by mass percentage 1:1 ratio is matched, and is thoroughly mixed uniformly, and long-acting type improvement acid is made Change the compound fertilizer of soil.
The agricultural land soil of the severe acidification of experiment is collected in Hunan, and pH 4.43, acidification is serious, with the soil in greenhouse 2 batches of romaine lettuce potting verifications are carried out continuously, experiment includes not adding in the control group of any improved materials and application the present embodiment The soil improvement group of the compound fertilizer of preparation.The soil of soil improvement group is only by air-dried soil matter before first batch of romaine lettuce plantation The 4% of amount mixes application(It is equivalent to 1800 kgs/acre of amount of application), mixing in experiment grant production in row replacement or spread comprehensively It is identical to apply effect, every group sets 3 repetitions.
After romaine lettuce harvest, biomass, Analysis of Heavy Metals are carried out respectively to the romaine lettuce of control group and soil improvement group, and It acquires the soil liquid and carries out pH measure and heavy metal concentration analysis.Obtained result is averaged evidence, as a result sees 1 He of attached drawing 2.As seen from Figure 1, control group soil liquid pH<5, original agricultural land soil environmental quality is degenerated seriously, and acidizing degree is higher, romaine lettuce It is difficult to grow, and after the improvement of fertilizer of the soil of soil improvement group by the present invention, pH is significantly improved, soil liquid pH More than 7,2.5 units higher than control group, in order, and biomass greatly improves Growth of Lettuce, referring to attached drawing 2, phase Than 1 gram of control group, the romaine lettuce biomass of soil improvement group is promoted to 10 grams;The activity of heavy metal in soil reduces, such as soil Manganese concentration is reduced to 0.04 mg/L by 3.9 in solution, and safety is guaranteed for lettuce quality.
Embodiment 2
More batches of green vegetables are planted with compound fertilizer improvement severe acidification agricultural land soil.
The preparation of the compound fertilizer of long-acting type improvement acidified soil:Attapulgite clay, peat and the serious acid of experiment Preparing for the agricultural land soil source of change and compound fertilizer is in the same manner as in Example 1.
2 batches of green vegetables soil potting verifications are carried out continuously in greenhouse, experiment includes the control for not adding any improved materials The soil improvement group of compound fertilizer prepared in group and application the present embodiment.The soil of soil improvement group is only in first batch of green vegetables kind Application is mixed by the 4% of air-dried soil quality before planting, every group sets 3 repetitions.
After green vegetables harvest, biomass, Analysis of Heavy Metals are carried out respectively to the green vegetables of control group and soil improvement group, together When acquisition the soil liquid carry out pH measure and heavy metal concentration analysis.Obtained result is averaged evidence, as a result sees 1 He of attached drawing 2.As seen from Figure 1, control group soil liquid pH<4.5, original agricultural land soil environmental quality is degenerated seriously, and acidizing degree is higher, green Dish growing way is bad, and after the improvement of fertilizer of the soil of soil improvement group by the present invention, pH is significantly improved, the soil liquid PH is up to 7.4, and nearly 3 units higher than control group, green vegetables upgrowth situation is good, and biomass greatly improves, referring to attached drawing 2, phase Than 11.3 grams of control group, the green vegetables biomass of soil improvement group is promoted to 38.9 grams;The activity of heavy metal in soil reduces, such as Manganese concentration is reduced to 0.03 mg/L by 3.16 in the soil liquid, and green vegetables Quality Safety is protected.
The present invention is applicable not only to the Dry crop of green vegetables, romaine lettuce etc, and the paddy field adjusting for being equally applicable to rice etc is repaiied The effect of multiple soil aciditiy.
The present invention can effectively, persistently improve acidification agricultural land soil, and more unique advantage is the day as Organic-inorganic composite Right fertilizer product has long-term effect to adjust soil aciditiy, fixed harmful heavy metal, enhancing soil fertility, improves crop yield, changes Kind quality of agricultural product, the multi-functionals effect such as ensure food safety, and is with a wide range of applications in agriculture environmental protection field, And this method material is cheap, easy to operate, convenient to carry out and popularization.
The above are preferred embodiments of the present invention, all any changes made according to the technical solution of the present invention, and generated function is made During with range without departing from technical solution of the present invention, all belong to the scope of protection of the present invention.

Claims (5)

1. a kind of compound fertilizer of long-acting type improvement acidified soil, which is characterized in that the compound fertilizer for attapulgite clay and The mixture of peat composition, wherein, the mass percent of the attapulgite clay is 40%-60%.
2. the compound fertilizer of long-acting type improvement acidified soil according to claim 1, which is characterized in that the attapulgite The mass percent of clay is 50%.
3. the preparation method of the compound fertilizer of the long-acting type improvement acidified soil described in claims 1 or 2, step are:
Step 1, attapulgite clay and peat are carried out respectively to air-dry or not higher than 70 DEG C at a temperature of drying and processing, Ran Houjin Row crushes, and respectively obtains attapulgite clay powder and peat clast;
Step 2, by attapulgite clay powder and peat clast by mass percent requirement in claim 1 or claim 2 It carries out being sufficiently mixed the compound fertilizer for uniformly, obtaining long-acting type improvement acidified soil after being matched.
4. the preparation method of the compound fertilizer of long-acting type improvement acidified soil according to claim 3, which is characterized in that step The attapulgite clay powder and peat clast granularity requirements obtained after being crushed in rapid 1 at least needed 5 mesh to sieve -10 mesh sieve.
5. the application method of the compound fertilizer of the long-acting type improvement acidified soil described in claims 1 or 2, which is characterized in that When ploughing before proportion of crop planting, spread fertilizer over the fields in cultivated soil by the compound fertilizer row replacement or comprehensively, the compound fertilizer Usage amount is 1000-2000 kilograms of compound fertilizer of using in farmland per acre.
CN201711391958.8A 2017-12-21 2017-12-21 A kind of compound fertilizer and its preparation and application of long-acting type improvement acidified soil Pending CN108218613A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113528147A (en) * 2021-08-31 2021-10-22 云南和瑾科技有限公司 Callback agent for development depth of aluminum-rich soil, preparation method and callback method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105884427A (en) * 2016-04-21 2016-08-24 张楚沁 Improved acidified soil water-retention compound fertilizer and preparation method thereof
CN106717235A (en) * 2016-12-26 2017-05-31 南京林业大学 A kind of modification method of acidified soil
CN106888607A (en) * 2015-12-20 2017-06-27 衡阳智源农业科技有限公司 A kind of modification method of acidified soil
CN107032935A (en) * 2017-06-20 2017-08-11 兰州坤仑环保科技有限公司 Attapulgite-based trace element soil conditioner and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106888607A (en) * 2015-12-20 2017-06-27 衡阳智源农业科技有限公司 A kind of modification method of acidified soil
CN105884427A (en) * 2016-04-21 2016-08-24 张楚沁 Improved acidified soil water-retention compound fertilizer and preparation method thereof
CN106717235A (en) * 2016-12-26 2017-05-31 南京林业大学 A kind of modification method of acidified soil
CN107032935A (en) * 2017-06-20 2017-08-11 兰州坤仑环保科技有限公司 Attapulgite-based trace element soil conditioner and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113528147A (en) * 2021-08-31 2021-10-22 云南和瑾科技有限公司 Callback agent for development depth of aluminum-rich soil, preparation method and callback method thereof

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Application publication date: 20180629