CN108208915B - Preparation method of tobacco tar thorn-reducing softener and tobacco tar thorn-reducing softener prepared by same - Google Patents
Preparation method of tobacco tar thorn-reducing softener and tobacco tar thorn-reducing softener prepared by same Download PDFInfo
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- CN108208915B CN108208915B CN201711484432.4A CN201711484432A CN108208915B CN 108208915 B CN108208915 B CN 108208915B CN 201711484432 A CN201711484432 A CN 201711484432A CN 108208915 B CN108208915 B CN 108208915B
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- China
- Prior art keywords
- tobacco tar
- mixed solution
- softener
- stirring
- acid
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Links
- 241000208125 Nicotiana Species 0.000 title claims abstract description 59
- 235000002637 Nicotiana tabacum Nutrition 0.000 title claims abstract description 59
- 238000002360 preparation method Methods 0.000 title claims abstract description 23
- SNICXCGAKADSCV-JTQLQIEISA-N (-)-Nicotine Chemical class CN1CCC[C@H]1C1=CC=CN=C1 SNICXCGAKADSCV-JTQLQIEISA-N 0.000 claims abstract description 27
- 229960002715 nicotine Drugs 0.000 claims abstract description 21
- SNICXCGAKADSCV-UHFFFAOYSA-N nicotine Natural products CN1CCCC1C1=CC=CN=C1 SNICXCGAKADSCV-UHFFFAOYSA-N 0.000 claims abstract description 21
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims description 55
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 54
- 239000011259 mixed solution Substances 0.000 claims description 38
- 238000003756 stirring Methods 0.000 claims description 29
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 27
- 239000005711 Benzoic acid Substances 0.000 claims description 27
- 235000010233 benzoic acid Nutrition 0.000 claims description 27
- 239000000243 solution Substances 0.000 claims description 19
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 claims description 18
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 claims description 18
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 claims description 18
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 9
- 235000019260 propionic acid Nutrition 0.000 claims description 9
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 claims description 9
- 238000007789 sealing Methods 0.000 claims description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
- 238000000034 method Methods 0.000 claims description 7
- 230000003255 anti-acne Effects 0.000 claims description 6
- 235000019504 cigarettes Nutrition 0.000 abstract description 9
- 239000003205 fragrance Substances 0.000 abstract description 8
- 230000000391 smoking effect Effects 0.000 abstract description 5
- 150000007524 organic acids Chemical class 0.000 abstract description 4
- 230000000638 stimulation Effects 0.000 abstract description 4
- 239000002253 acid Substances 0.000 abstract description 3
- 239000002994 raw material Substances 0.000 abstract description 2
- 206010043521 Throat irritation Diseases 0.000 abstract 1
- 150000007513 acids Chemical class 0.000 abstract 1
- 235000005985 organic acids Nutrition 0.000 abstract 1
- 239000003571 electronic cigarette Substances 0.000 description 2
- 150000001413 amino acids Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- CNLSPQQMAJCIFB-UHFFFAOYSA-N benzoic acid;ethanol Chemical compound CCO.OC(=O)C1=CC=CC=C1 CNLSPQQMAJCIFB-UHFFFAOYSA-N 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 239000002085 irritant Substances 0.000 description 1
- 230000007794 irritation Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
- A24B15/10—Chemical features of tobacco products or tobacco substitutes
- A24B15/16—Chemical features of tobacco products or tobacco substitutes of tobacco substitutes
- A24B15/167—Chemical features of tobacco products or tobacco substitutes of tobacco substitutes in liquid or vaporisable form, e.g. liquid compositions for electronic cigarettes
-
- A24F47/008—
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacture Of Tobacco Products (AREA)
Abstract
The invention provides a preparation method of a tobacco tar anti-irritation softener, which is characterized in that nicotine salt is prepared by adopting a combination mode of multiple organic acids, so that stimulation of nicotine to the throat is balanced, comfort is increased, influence of added acid on original fragrance and taste of tobacco tar is reduced, throat irritation and impact feeling brought by smoking electronic tobacco tar can be effectively reduced, original fragrance is kept to the maximum extent, experience feeling of substituting tobacco for smokers is remarkably increased, the maximum adding amount of the nicotine salt is higher than that of nicotine salt prepared by other single acids, sufficient nicotine can be effectively ingested, and smoking experience feeling similar to that of cigarettes and better throat comfort feeling can be obtained. The preparation method of the tobacco tar stab-reducing softener provided by the invention has the advantages of rich raw material sources, simple steps, easily controlled conditions, strong repeatability and good industrial prospect.
Description
Technical Field
The invention belongs to the field of chemical materials, and particularly relates to a preparation method of a tobacco tar thorn-reducing softener and the tobacco tar thorn-reducing softener prepared by the method.
Background
The existing tobacco tar with low nicotine concentration can not meet the requirement of smokers for replacing the nicotine, and the nicotine addition amount of the existing tobacco tar can overcome the defects of strong strength and strong stimulation in the same electronic cigarette tobacco tar which meets the requirement of absorbing the nicotine in the cigarettes, so that the smoking experience of the smokers who want to replace the cigarette is reduced, and the tobacco tar with good smoking experience is provided, so that the technical problem to be solved in the field is solved.
At present, there are some related patents at home and abroad, most of the single organic acid is added into the tobacco tar, and the single organic acid has certain fragrance, so that the original fragrance of the tobacco tar is necessarily greatly influenced to achieve the effect of reducing the thorn. Cabernet pustulata, Zhang Zhong Hu, is added into tobacco tar with benzoic acid ethanol solution to reduce nicotine irritation. JerryW.Lawson and the like add different aromatic acid and nicotine combined products into cigarettes to increase the tobacco fragrance of the cigarettes so as to make up for the loss of the tobacco fragrance caused by reducing cigarette tar. S.B. Anderson, etc. can reduce the dependence of smoking-quitting smokers on tobacco nicotine by adding different amino acid and nicotine combination products into oral smoking-quitting medicines.
Disclosure of Invention
The invention aims to solve the technical problem of providing a preparation method of a tobacco tar thorn-reducing softener and the tobacco tar thorn-reducing softener prepared by the method.
The technical scheme adopted by the invention for solving the technical problems is as follows: the preparation method of tobacco flavor tobacco tar is characterized by comprising the following steps:
a preparation method of a tobacco tar thorn-reducing softener comprises the following steps:
respectively taking 3-9 g of benzoic acid and 6-14 g of alcohol, mixing and stirring to obtain a benzoic acid solution;
sequentially adding 4-12 g of caproic acid, 6-18 g of butyric acid, 5-15 g of propionic acid, 12-28 g of acetic acid and 25-45 g of propylene glycol into the benzoic acid solution, and stirring to obtain a mixed solution 1;
adding 60-100 g of nicotine into the mixed solution 1, sealing, and stirring in a water bath at 50-80 ℃ for 12-24 hours to obtain a mixed solution 2;
and adding 1000-2000 g of propylene glycol into the mixed solution 2, and storing in a dark place to obtain the tobacco tar thorn-reducing softener. Preferably, the stirring time of the mixed solution 1 is 10 to 30 minutes.
A tobacco tar thorn-reducing softener prepared by the preparation method is provided.
The invention has the beneficial effects that: the tobacco tar of this patent method preparation falls thorn softener is through the mode preparation nicotine salt that adopts multiple organic acid combination, come the stimulation of balanced nicotine to the throat, when increasing comfortable, reduce the influence of additional acid to original fragrance of tobacco tar and taste, can effectively reduce the throat stimulation and the impact that the electronic cigarette oil of suction brought and feel, original fragrance is kept to the at utmost simultaneously, the experience that shows the increase smoker replaced the cigarette is felt, the maximum addition of nicotine salt is also higher than the nicotine salt that other single acidies were prepared, can effectually absorb sufficient nicotine, can obtain simultaneously have with the cigarette close smoking experience of cigarette feel and better throat comfort. The preparation method of the tobacco tar stab-reducing softener provided by the invention has the advantages of rich raw material sources, simple steps, easily controlled conditions, strong repeatability and good industrial prospect.
Detailed Description
The present invention is described in further detail below. The embodiment of the invention provides a preparation method of a tobacco tar thorn-reducing softener, which comprises the following steps:
respectively taking 3-9 g of benzoic acid and 6-14 g of alcohol, mixing and stirring to obtain a benzoic acid solution;
sequentially adding 4-12 g of caproic acid, 6-18 g of butyric acid, 5-15 g of propionic acid, 12-28 g of acetic acid and 25-45 g of propylene glycol into the benzoic acid solution, and stirring to obtain a mixed solution 1;
adding 60-100 g of nicotine into the mixed solution 1, sealing, and stirring in a water bath at 50-80 ℃ for 12-24 hours to obtain a mixed solution 2;
and adding 1000-2000 g of propylene glycol into the mixed solution 2, and storing in a dark place to obtain the tobacco tar thorn-reducing softener.
A tobacco tar thorn-reducing softener prepared by the preparation method is provided.
According to different requirements of the tobacco tar on reducing the thorn, the tobacco tar thorn reducing softener with different weight parts can be added into the tobacco tar mixture, for example, 3mg of tobacco tar is prepared, and the proportion of the tobacco tar thorn reducing softener can be selected to be 5.2%.
Specifically, the following describes in detail the preparation method of the tobacco tar anti-irritant softener.
Example 1
The embodiment provides a preparation method of a tobacco tar thorn-reducing softener, which comprises the following steps:
respectively taking 3 g of benzoic acid and 6 g of alcohol, mixing and stirring for 10 minutes to obtain a benzoic acid solution;
sequentially adding 4 g of caproic acid, 6 g of butyric acid, 5 g of propionic acid, 12 g of acetic acid and 25 g of propylene glycol into the benzoic acid solution, and stirring to obtain a mixed solution 1;
adding 60 g of nicotine into the mixed solution 1, sealing, and stirring in a water bath at 50 ℃ for 12-24 hours to obtain a mixed solution 2;
and adding 1000 g of propylene glycol into the mixed solution 2, and storing in a dark place to obtain the tobacco tar anti-acne softener.
The embodiment also provides the tobacco tar stab-reducing softener prepared by the method.
Example 2
The embodiment provides a preparation method of a tobacco tar thorn-reducing softener, which comprises the following steps:
respectively taking 9 g of benzoic acid and 14 g of alcohol, mixing and stirring for 20 minutes to obtain a benzoic acid solution;
adding 12 g of caproic acid, 18 g of butyric acid, 15 g of propionic acid, 28 g of acetic acid and 45 g of propylene glycol into the benzoic acid solution in sequence, and stirring to obtain a mixed solution 1;
adding 100 g of nicotine into the mixed solution 1, sealing, and stirring in a water bath at 80 ℃ for 12-24 hours to obtain a mixed solution 2;
adding 2000 g of propylene glycol into the mixed solution 2, and storing in a dark place to obtain the tobacco tar anti-acne softener.
The embodiment also provides the tobacco tar stab-reducing softener prepared by the method.
Example 3
The embodiment provides a preparation method of a tobacco tar thorn-reducing softener, which comprises the following steps:
respectively taking 6 g of benzoic acid and 10 g of alcohol, mixing, and stirring for 30 minutes to obtain a benzoic acid solution;
sequentially adding 8 g of caproic acid, 12 g of butyric acid, 10 g of propionic acid, 19 g of acetic acid and 35 g of propylene glycol into the benzoic acid solution, and stirring to obtain a mixed solution 1;
adding 80 g of nicotine into the mixed solution 1, sealing, and stirring in a water bath at 65 ℃ for 12-24 hours to obtain a mixed solution 2;
and (3) adding 1420 g of propylene glycol into the mixed solution 2, and storing in a dark place to obtain the tobacco tar anti-acne softener.
The embodiment also provides the tobacco tar stab-reducing softener prepared by the method.
The invention is not limited to the embodiments described above, and all modifications of the invention within the scope of the known principles are within the scope of the invention.
Claims (6)
1. A preparation method of a tobacco tar thorn-reducing softener is characterized by comprising the following steps:
respectively taking 3-9 g of benzoic acid and 6-14 g of alcohol, mixing and stirring to obtain a benzoic acid solution;
sequentially adding 4-12 g of caproic acid, 6-18 g of butyric acid, 5-15 g of propionic acid, 12-28 g of acetic acid and 25-45 g of propylene glycol into the benzoic acid solution, and stirring to obtain a mixed solution 1;
adding 60-100 g of nicotine into the mixed solution 1, sealing, and stirring in a water bath at 50-80 ℃ for 12-24 hours to obtain a mixed solution 2;
and adding 1000-2000 g of propylene glycol into the mixed solution 2, and storing in a dark place to obtain the tobacco tar thorn-reducing softener.
2. The preparation method of the tobacco tar stab-reducing softener according to claim 1, characterized by comprising the following steps:
respectively taking 3 g of benzoic acid and 6 g of alcohol, mixing and stirring to obtain a benzoic acid solution;
sequentially adding 4 g of caproic acid, 6 g of butyric acid, 5 g of propionic acid, 12 g of acetic acid and 25 g of propylene glycol into the benzoic acid solution, and stirring to obtain a mixed solution 1;
adding 60 g of nicotine into the mixed solution 1, sealing, and stirring in a water bath at 50 ℃ for 12-24 hours to obtain a mixed solution 2;
and adding 1000 g of propylene glycol into the mixed solution 2, and storing in a dark place to obtain the tobacco tar anti-acne softener.
3. The preparation method of the tobacco tar stab-reducing softener according to claim 1, characterized by comprising the following steps:
respectively taking 9 g of benzoic acid and 14 g of alcohol, mixing and stirring to obtain a benzoic acid solution;
adding 12 g of caproic acid, 18 g of butyric acid, 15 g of propionic acid, 28 g of acetic acid and 45 g of propylene glycol into the benzoic acid solution in sequence, and stirring to obtain a mixed solution 1;
adding 100 g of nicotine into the mixed solution 1, sealing, and stirring in a water bath at 80 ℃ for 12-24 hours to obtain a mixed solution 2;
adding 2000 g of propylene glycol into the mixed solution 2, and storing in a dark place to obtain the tobacco tar anti-acne softener.
4. The preparation method of the tobacco tar stab-reducing softener according to claim 1, characterized by comprising the following steps:
respectively taking 6 g of benzoic acid and 10 g of alcohol, mixing and stirring to obtain a benzoic acid solution;
sequentially adding 8 g of caproic acid, 12 g of butyric acid, 10 g of propionic acid, 19 g of acetic acid and 35 g of propylene glycol into the benzoic acid solution, and stirring to obtain a mixed solution 1;
adding 80 g of nicotine into the mixed solution 1, sealing, and stirring in a water bath at 65 ℃ for 12-24 hours to obtain a mixed solution 2;
and (3) adding 1420 g of propylene glycol into the mixed solution 2, and storing in a dark place to obtain the tobacco tar anti-acne softener.
5. The method for preparing tobacco tar stab-reducing softener according to any one of claims 1 to 4, wherein the stirring time of the mixed solution 1 is 10 to 30 minutes.
6. A tobacco tar stimulation-reducing softener prepared by the preparation method of claim 1.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711484432.4A CN108208915B (en) | 2017-12-29 | 2017-12-29 | Preparation method of tobacco tar thorn-reducing softener and tobacco tar thorn-reducing softener prepared by same |
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| CN201711484432.4A CN108208915B (en) | 2017-12-29 | 2017-12-29 | Preparation method of tobacco tar thorn-reducing softener and tobacco tar thorn-reducing softener prepared by same |
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| Publication Number | Publication Date |
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| CN108208915A CN108208915A (en) | 2018-06-29 |
| CN108208915B true CN108208915B (en) | 2021-06-08 |
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| CN201711484432.4A Expired - Fee Related CN108208915B (en) | 2017-12-29 | 2017-12-29 | Preparation method of tobacco tar thorn-reducing softener and tobacco tar thorn-reducing softener prepared by same |
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Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108887731A (en) * | 2018-08-21 | 2018-11-27 | 深圳瀚星翔科技有限公司 | Nicotine salt, electronics tobacco tar and preparation method thereof |
| CN109171010A (en) * | 2018-09-10 | 2019-01-11 | 深圳市新宜康科技股份有限公司 | Liquid nicotine salt and preparation method thereof |
| CN109288115A (en) * | 2018-10-16 | 2019-02-01 | 云南拓宝科技有限公司 | A kind of nicotine salt and preparation method thereof of solventless method preparation |
| CN111449270B (en) * | 2020-03-12 | 2022-04-26 | 深圳瀚星翔科技有限公司 | Smoke softener, electronic cigarette tobacco tar and preparation method thereof |
| CN114468337A (en) * | 2022-03-23 | 2022-05-13 | 云南巴菰生物科技股份有限公司 | Electronic cigarette atomized liquid |
| CN117058670B (en) * | 2023-10-12 | 2024-01-02 | 深圳市华加生物科技有限公司 | Electronic tobacco tar flexibility evaluation method |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2006004646A1 (en) * | 2004-06-28 | 2006-01-12 | Nektar Therapeutics | Aerosol formulation comprising nicotine salt |
| CN104473322A (en) * | 2014-12-02 | 2015-04-01 | 河南中烟工业有限责任公司 | Electronic-cigarette liquid tobacco containing nicotine and organic acid |
| CN105263345A (en) * | 2013-05-06 | 2016-01-20 | 派克斯实验公司 | Nicotine salt formulations for aerosol devices and methods thereof |
| CN106063583A (en) * | 2016-07-14 | 2016-11-02 | 深圳昱朋科技有限公司 | The preparation method of ree-oil additive and ree-oil |
| CN106714589A (en) * | 2014-04-30 | 2017-05-24 | 奥驰亚客户服务有限责任公司 | Liquid aerosol formulation of an electronic smoking article |
| CN107105756A (en) * | 2014-11-07 | 2017-08-29 | 尼科创业控股有限公司 | The solution of nicotine containing non-protonated form and protonated form |
-
2017
- 2017-12-29 CN CN201711484432.4A patent/CN108208915B/en not_active Expired - Fee Related
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2006004646A1 (en) * | 2004-06-28 | 2006-01-12 | Nektar Therapeutics | Aerosol formulation comprising nicotine salt |
| CN105263345A (en) * | 2013-05-06 | 2016-01-20 | 派克斯实验公司 | Nicotine salt formulations for aerosol devices and methods thereof |
| CN106714589A (en) * | 2014-04-30 | 2017-05-24 | 奥驰亚客户服务有限责任公司 | Liquid aerosol formulation of an electronic smoking article |
| CN107105756A (en) * | 2014-11-07 | 2017-08-29 | 尼科创业控股有限公司 | The solution of nicotine containing non-protonated form and protonated form |
| CN104473322A (en) * | 2014-12-02 | 2015-04-01 | 河南中烟工业有限责任公司 | Electronic-cigarette liquid tobacco containing nicotine and organic acid |
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