CN108193488A - A kind of polyimides of ecology coloring - Google Patents

A kind of polyimides of ecology coloring Download PDF

Info

Publication number
CN108193488A
CN108193488A CN201810120301.6A CN201810120301A CN108193488A CN 108193488 A CN108193488 A CN 108193488A CN 201810120301 A CN201810120301 A CN 201810120301A CN 108193488 A CN108193488 A CN 108193488A
Authority
CN
China
Prior art keywords
polyimides
vacuum degree
coloring
ecology
maintained
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810120301.6A
Other languages
Chinese (zh)
Inventor
王银川
余荣沾
刘琼溪
张欣
尹华平
梁媛
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
GUANGDONG XINFENG TECHNOLOGY CO., LTD.
Original Assignee
Beijing Nano Chromophore Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Beijing Nano Chromophore Technology Co Ltd filed Critical Beijing Nano Chromophore Technology Co Ltd
Priority to CN201810120301.6A priority Critical patent/CN108193488A/en
Publication of CN108193488A publication Critical patent/CN108193488A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/06Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
    • C23C14/14Metallic material, boron or silicon
    • C23C14/20Metallic material, boron or silicon on organic substrates
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/38Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic Table
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/44Oxides or hydroxides of elements of Groups 2 or 12 of the Periodic Table; Zincates; Cadmates
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/58Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/83Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with metals; with metal-generating compounds, e.g. metal carbonyls; Reduction of metal compounds on textiles
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/02Material containing basic nitrogen
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16Synthetic fibres, other than mineral fibres
    • D06M2101/30Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Laminated Bodies (AREA)
  • Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)

Abstract

A kind of polyimides of ecology coloring, it includes base fabric and color film layer, the color film layer is formed using evaporating deposition technique, and target includes one or more of Ti, Fe, Al, Zn, Cu, W, Mg, Au, Ag, Cr, Ni, V, Co, C, N, O, Si, Pt elements.The product utilization vacuum deposition method forms plurality of color film layer in polyimide surface, colours polyimide surface.

Description

A kind of polyimides of ecology coloring
Technical field
The invention belongs to textile field more particularly to a kind of polyimides of ecology coloring.
Background technology
At present, staining technique cannot colour on polyimide, reason mainly due to the architectural characteristic of polyimides, Chemical inertness is presented in its surface, lacks with the chemical group compared with high reaction activity, the low chemical bond cooperation between dye molecule With making its extremely difficult dyeing, this significantly limits the application field of polyimides.
In order to be coloured in polyimide surface, there is an urgent need to a kind of new coloring principle and methods by the mankind.
Invention content
In order to solve the above technical problem, the present invention provides a kind of polyimides of ecology coloring, the product utilization vacuum Sedimentation forms plurality of color film layer in polyimide surface, colours polyimide surface.
The present invention technical solution be:
A kind of polyimides of ecology coloring, including base fabric and color film layer, the color film layer uses evaporating deposition technique It is formed, target includes one or more of Ti, Fe, Al, Zn, Cu, W, Mg, Au, Ag, Cr, Ni, V, Co, C, N, O, Si, Pt members Element.
Preferably, the color film layer is single-layer or multi-layer.
Preferably, the evaporating deposition technique is splashed including vacuum thermal evaporation deposition, electron beam deposition, ion film plating, magnetic control It penetrates.
A kind of preparation method of the polyimides of above-mentioned ecology coloring, including:
Pre-treatment is carried out to polyimides, removes surface blot;
It is involved on polyimides and unreels room, guarantee unreels room vacuum degree and is maintained at 0.5-1E-9Pa sections;
Polyimides makes polyimides temperature rise to 2-180 DEG C, heating room vacuum degree is maintained at 0.5- into heating room 1E-9Pa sections;
Polyimides is maintained at 0.5-1E into prechamber, house vacuum degree-9Pa;
When coating chamber vacuum degree reaches 1E-3During more than Pa, base fabric makes to be formed in base fabric into coating chamber using vacuum deposition method Color film layer, target include one or more of Ti, Fe, Al, Zn, Cu, Mg, Au, W, Ag, Cr, Ni, V, Co, C, N, O, Si, Pt Element, power 50-38000W;
Polyimides ensures that winding room vacuum degree is maintained at 0.5-1E into winding room-9Pa sections;
Take out finished fabric, sampling detection;
Whole process is pipelined operation, and the cloth speed of service is 0.3m/min to 100m/min.
Beneficial effects of the present invention are:
A kind of colouring method compared with prior art, method that can colour polyimides of the present invention, can be in polyamides Imines surface forms plurality of color film layer, makes polyimides that multiple color be presented, so as to meet the standard of GB/T 2660-2017.
Description of the drawings
Fig. 1 is present invention process flow chart.
Fig. 2 is fabric construction schematic diagram of the present invention.
Reference numeral:1- color film layers, 2- polyimides.
Specific embodiment
Embodiment is described in detail below in conjunction with attached drawing.
Embodiment 1
As shown in Figure 1, a kind of preparation method of the polyimides of ecology coloring, including:
Pre-treatment is carried out to polyimides, removes surface blot;
It is involved on polyimides and unreels room, guarantee unreels room vacuum degree and is maintained at 1-1.8E-1Pa sections;
Polyimides makes polyimides temperature rise to 45 DEG C, heating room vacuum degree is maintained at 1-1.8E into heating room-1Pa Section;
Polyimides is maintained at 4-5E into prechamber, house vacuum degree-2Pa;
When coating chamber vacuum degree reaches 1E-3During more than Pa, polyimides is into coating chamber, target Ti, power 800w, Polyimide surface sputters outstanding film layer, and during which vacuum degree maintains 1-1.8E-1Pa sections, polyimides can present red orange green The multiple color of ultramarine purple;
Polyimides ensures that winding room vacuum degree is maintained at 0.5-2.5E into winding room-1Pa sections;
Take out finished fabric, sampling detection;
Whole process is pipelined operation, and the cloth speed of service is 45m/min to 50m/min.
Embodiment 2
As shown in Figure 1, a kind of preparation method of the polyimides of ecology coloring, including:
Pre-treatment is carried out to polyimides, removes surface blot;
It is involved on polyimides and unreels room, guarantee unreels room vacuum degree and is maintained at 0.5E-1Pa sections;
Polyimides makes polyimides temperature rise to 23 DEG C, heating room vacuum degree is maintained at 0.5E into heating room-1Pa areas Between;
Polyimides is maintained at 3E into prechamber, house vacuum degree-2Pa;
When coating chamber vacuum degree reaches 1E-3During more than Pa, polyimides is into coating chamber, and target is respectively Cu, ZnO, power Respectively 1500w, 4000w sputter outstanding film layer in polyimide surface, and during which vacuum degree maintains 0.5E-1Pa sections, polyamides The multiple color of red, orange, yellow, green, indigo, azure, purple can be presented in imines;
Polyimides ensures that winding room vacuum degree is maintained at 0.5E into winding room-1Pa sections;
Take out finished fabric, sampling detection;
Whole process is pipelined operation, and the cloth speed of service is 67m/min to 72m/min.
Embodiment 3
As shown in Figure 1, a kind of preparation method of the polyimides of ecology coloring, including:
Pre-treatment is carried out to polyimides, removes surface blot;
It is involved on polyimides and unreels room, guarantee unreels room vacuum degree and is maintained at 2.5E-1Pa sections;
Polyimides makes polyimides temperature rise to 34 DEG C, heating room vacuum degree is maintained at 2.5E into heating room-1Pa areas Between;
Polyimides is maintained at 8E into prechamber, house vacuum degree-2Pa;
When coating chamber vacuum degree reaches 1E-3During more than Pa, polyimides into coating chamber, target be respectively stainless steel, CuO, TiCN, power are respectively 11000w, 5500w, 4000w, sputter outstanding film layer in polyimide surface, during which vacuum degree maintains 2.5E-1The multiple color of red, orange, yellow, green, indigo, azure, purple can be presented in Pa, polyimides;
Polyimides ensures that winding room vacuum degree is maintained at 2.5E into winding room-1Pa sections;
Take out finished fabric, sampling detection;
Whole process is pipelined operation, and the cloth speed of service is 89m/min to 94m/min.
Embodiment 4
As shown in Figure 1, a kind of preparation method of the polyimides of ecology coloring, including:
Pre-treatment is carried out to polyimides, removes surface blot;
It is involved on polyimides and unreels room, guarantee unreels room vacuum degree and is maintained at 2E-1Pa sections;
Polyimides makes polyimides temperature rise to 34 DEG C, heating room vacuum degree is maintained at 2E into heating room-1Pa areas Between;
Polyimides is maintained at 5E into prechamber, house vacuum degree-2Pa;
When coating chamber vacuum degree reaches 1E-3During more than Pa, for polyimides into coating chamber, target is respectively TiO2、Zn、CuO、 AlTiN, power are respectively 1000w, 3000w, 2500w, 8800w, sputter outstanding film layer in polyimide surface, during which vacuum degree Maintain 2E-1The multiple color of red, orange, yellow, green, indigo, azure, purple can be presented in Pa, polyimides;
Polyimides ensures that winding room vacuum degree is maintained at 2.5E into winding room-1Pa sections;
Take out finished fabric, sampling detection;
Whole process is pipelined operation, and the cloth speed of service is 14m/min to 20m/min.
Coloring experiment
According to GB/T 2660-2017, polyimides of the present invention is in color fastness to water, colour fastness to perspiration, antifriction Wipe the standard that color fastness, fastness to soaping, colour fasteness to dry cleaning, color fastness to light meet GB/T 2660-2017.
Target described in embodiment 1-4 includes Ti, Cu, ZnO, stainless steel, CuO, TiCN, TiO2, Zn, CuO, AlTiN, but not It is limited to target described in embodiment 1-4, target described in embodiment 1-4 is used to prove the tinctorial property of fabric of the present invention;Ability Field technique personnel are it will be appreciated that target is included in Ti, Fe, Al, Zn, Cu, W, Mg, Au, Ag, Cr, Ni, V, Co, C, N, O, Si, Pt One or more of elements.
The present invention elaborates and has been cited embodiment, but those skilled in the art made according to above-described embodiment it is aobvious And be clear to various schemes, modification, change, these schemes, modification, change should all belong to the present invention claim protection Range.

Claims (4)

1. a kind of polyimides of ecology coloring, including base fabric and color film layer, which is characterized in that the color film layer uses vacuum Deposition technique is formed, and target includes one kind in Ti, Fe, Al, Zn, Cu, W, Mg, Au, Ag, Cr, Ni, V, Co, C, N, O, Si, Pt Or several elements.
2. a kind of polyimides of ecology coloring as described in claim 1, which is characterized in that the color film layer is individual layer or more Layer.
3. a kind of polyimides of ecology coloring as described in claim 1, which is characterized in that the evaporating deposition technique includes true Empty thermal evaporation deposition, electron beam deposition, ion film plating, magnetron sputtering.
4. a kind of preparation method of the polyimides of ecology coloring as described in claim 1, which is characterized in that it includes:
Pre-treatment is carried out to polyimides, removes surface blot;
It is involved on polyimides and unreels room, guarantee unreels room vacuum degree and is maintained at 0.5-1E-9Pa sections;
Polyimides makes polyimides temperature rise to 2-180 DEG C, heating room vacuum degree is maintained at 0.5-1E into heating room-9Pa Section;
Polyimides is maintained at 0.5-1E into prechamber, house vacuum degree-9Pa;
When coating chamber vacuum degree reaches 1E-3During more than Pa, base fabric makes to form color film in base fabric using vacuum deposition method into coating chamber Layer, target include one or more of Ti, Fe, Al, Zn, Cu, Mg, Au, W, Ag, Cr, Ni, V, Co, C, N, O, Si, Pt members Element, power interval 50-38000W;
Polyimides ensures that winding room vacuum degree is maintained at 0.5-1E into winding room-9Pa sections;
Take out finished fabric, sampling detection;
Whole process is pipelined operation, and the cloth speed of service is 0.3m/min to 100m/min.
CN201810120301.6A 2018-02-05 2018-02-05 A kind of polyimides of ecology coloring Pending CN108193488A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810120301.6A CN108193488A (en) 2018-02-05 2018-02-05 A kind of polyimides of ecology coloring

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810120301.6A CN108193488A (en) 2018-02-05 2018-02-05 A kind of polyimides of ecology coloring

Publications (1)

Publication Number Publication Date
CN108193488A true CN108193488A (en) 2018-06-22

Family

ID=62593131

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201810120301.6A Pending CN108193488A (en) 2018-02-05 2018-02-05 A kind of polyimides of ecology coloring

Country Status (1)

Country Link
CN (1) CN108193488A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109825974A (en) * 2019-03-15 2019-05-31 北京纳米生色科技有限公司 The post-processing approach of fabric and tasteless fabric and preparation method thereof
CN116024535A (en) * 2023-03-28 2023-04-28 苏州浪潮智能科技有限公司 Method and equipment for preparing radiation film, radiation film and optical device

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109825974A (en) * 2019-03-15 2019-05-31 北京纳米生色科技有限公司 The post-processing approach of fabric and tasteless fabric and preparation method thereof
CN116024535A (en) * 2023-03-28 2023-04-28 苏州浪潮智能科技有限公司 Method and equipment for preparing radiation film, radiation film and optical device

Similar Documents

Publication Publication Date Title
CN108193488A (en) A kind of polyimides of ecology coloring
US11505860B2 (en) Fabric coloring method and colored fabric
CN105862000A (en) Method for preparing nano-films for realizing structural colors on fabric surfaces through magnetron sputtering technology
CN105603715B (en) A kind of preparation method of fabric construction color
CN106565113B (en) Colorful non-conductive metallic luster printing plated film ambetti of one kind and preparation method thereof
CN104831233B (en) One kind decoration blue ceramic coating and preparation method thereof
CN109722698B (en) Interference coloring method for double-layer microstructure film on surface of aluminum alloy
CN108130724A (en) A kind of aramid fiber of ecology coloring
CN108149471A (en) A kind of carbon fiber of ecology coloring
CN108166281A (en) A kind of glass fibre of ecology coloring
CN108914069A (en) RPVD green coating technique
CN105671513A (en) Novel vacuum color coating process
CN110396670A (en) A kind of colored fiber fabric and its production method
CN102744926B (en) Colored corrosion-resistanting decoration film of a kind of matrix surface color controllable and preparation method thereof
CN103302917A (en) Dual-absorption-layer TiON weather-resistant photothermal coating and preparation method thereof
Chen et al. Multifunctional Ti-O coatings on polyethylene terephthalate fabric produced by using roll-to-roll high power impulse magnetron sputtering system
CN104789964B (en) A kind of preparation method of high-temperature alloy surface high-temperature insulating coating
CN108117279A (en) A kind of method that can colour glass fibre
CN108130761A (en) A kind of method that can colour aramid fiber
CN108035176A (en) A kind of method that can colour carbon fiber
CN103014628B (en) Full-dry wire drawing surface treatment method for metal base material
CN109943107A (en) A kind of graphene oxide water paint and coating process
CN108048808A (en) A kind of method that can colour polyimides
CN204506030U (en) A kind of nano ceramics heat insulating membrane
CN207596950U (en) A kind of coating system based on the common sputtering technology of magnetic control

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
TA01 Transfer of patent application right

Effective date of registration: 20181211

Address after: 529000 First Floor of No.6 Jinzhang Avenue, Changsha District, Kaiping City, Guangdong Province

Applicant after: GUANGDONG XINFENG TECHNOLOGY CO., LTD.

Address before: 100080 Tianchuang Science and Technology Building, 8th Caihefang Road, Haidian District, Beijing, 12th floor 211B

Applicant before: Beijing nano chromophore Technology Co., Ltd.

TA01 Transfer of patent application right
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20180622

WD01 Invention patent application deemed withdrawn after publication