CN108166281A - A kind of glass fibre of ecology coloring - Google Patents

A kind of glass fibre of ecology coloring Download PDF

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Publication number
CN108166281A
CN108166281A CN201810120082.1A CN201810120082A CN108166281A CN 108166281 A CN108166281 A CN 108166281A CN 201810120082 A CN201810120082 A CN 201810120082A CN 108166281 A CN108166281 A CN 108166281A
Authority
CN
China
Prior art keywords
glass fibre
vacuum degree
maintained
coloring
ecology
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810120082.1A
Other languages
Chinese (zh)
Inventor
王银川
余荣沾
刘琼溪
张欣
尹华平
梁媛
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
GUANGDONG XINFENG TECHNOLOGY CO., LTD.
Original Assignee
Beijing Nano Chromophore Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Beijing Nano Chromophore Technology Co Ltd filed Critical Beijing Nano Chromophore Technology Co Ltd
Priority to CN201810120082.1A priority Critical patent/CN108166281A/en
Publication of CN108166281A publication Critical patent/CN108166281A/en
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
    • C23C14/14—Metallic material, boron or silicon
    • C23C14/18—Metallic material, boron or silicon on other inorganic substrates
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
    • C23C14/14—Metallic material, boron or silicon
    • C23C14/18—Metallic material, boron or silicon on other inorganic substrates
    • C23C14/185—Metallic material, boron or silicon on other inorganic substrates by cathodic sputtering
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/22—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
    • C23C14/24—Vacuum evaporation
    • C23C14/28—Vacuum evaporation by wave energy or particle radiation
    • C23C14/30—Vacuum evaporation by wave energy or particle radiation by electron bombardment
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/22—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
    • C23C14/24—Vacuum evaporation
    • C23C14/32—Vacuum evaporation by explosion; by evaporation and subsequent ionisation of the vapours, e.g. ion-plating
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/22—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
    • C23C14/34—Sputtering
    • C23C14/35—Sputtering by application of a magnetic field, e.g. magnetron sputtering
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/80—Inorganic fibres

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Metallurgy (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Textile Engineering (AREA)
  • Laminated Bodies (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)

Abstract

A kind of glass fibre of ecology coloring, it includes base fabric and color film layer, it is characterized in that, the color film layer is formed using evaporating deposition technique, target includes one or more of Ti, Fe, Al, Zn, Cu, W, Mg, Au, Ag, Cr, Ni, V, Co, C, N, O, Si, Pt elements.The product utilization vacuum deposition method forms plurality of color film layer in fiberglass surfacing, colours fiberglass surfacing.

Description

A kind of glass fibre of ecology coloring
Technical field
The invention belongs to textile field more particularly to a kind of glass fibres of ecology coloring.
Background technology
At present, staining technique cannot colour on the glass fibers, reason mainly due to the architectural characteristic of glass fibre, Chemical inertness is presented in its surface, lacks with the chemical group compared with high reaction activity, the low chemical bond cooperation between dye molecule With making its extremely difficult dyeing, this significantly limits the application field of glass fibre.
In order to be coloured in fiberglass surfacing, there is an urgent need to a kind of new coloring principle and methods by the mankind.
Invention content
In order to solve the above technical problem, the present invention provides a kind of glass fibre of ecology coloring, the product utilization vacuum Sedimentation forms plurality of color film layer in fiberglass surfacing, colours fiberglass surfacing.
The present invention technical solution be：
A kind of glass fibre of ecology coloring, including base fabric and color film layer, the color film layer uses evaporating deposition technique It is formed, target includes one or more of Ti, Fe, Al, Zn, Cu, W, Mg, Au, Ag, Cr, Ni, V, Co, C, N, O, Si, Pt members Element.
Preferably, the color film layer is single-layer or multi-layer.
Preferably, the evaporating deposition technique is splashed including vacuum thermal evaporation deposition, electron beam deposition, ion film plating, magnetic control It penetrates.
A kind of preparation method of the glass fibre of above-mentioned ecology coloring, including：
Pre-treatment is carried out to glass fibre, removes surface blot；
It is involved on glass fibre and unreels room, guarantee unreels room vacuum degree and is maintained at 0.5-1E-9Pa sections；
Glass fibre makes glass fibre temperature rise to 2-180 DEG C, heating room vacuum degree is maintained at 0.5- into heating room 1E-9Pa sections；
Glass fibre is maintained at 0.5-1E into prechamber, house vacuum degree-9Pa；
When coating chamber vacuum degree reaches 1E-3During more than Pa, base fabric makes to be formed in base fabric into coating chamber using vacuum deposition method Color film layer, target include one or more of Ti, Fe, Al, Zn, Cu, Mg, Au, W, Ag, Cr, Ni, V, Co, C, N, O, Si, Pt Element, power 50-38000W；
Glass fibre ensures that winding room vacuum degree is maintained at 0.5-1E into winding room-9Pa sections；
Take out finished fabric, sampling detection；
Whole process is pipelined operation, and the cloth speed of service is 0.3m/min to 100m/min.
Beneficial effects of the present invention are：
A kind of colouring method compared with prior art, method that can colour glass fibre of the present invention, can be in glass Fiber surface forms plurality of color film layer, makes glass fibre that multiple color be presented, so as to meet the standard of GB/T 2660-2017.
Description of the drawings
Fig. 1 is present invention process flow chart.
Fig. 2 is fabric construction schematic diagram of the present invention.
Reference numeral：1- color film layers, 2- glass fibres.
Specific embodiment
Embodiment is described in detail below in conjunction with attached drawing.
Embodiment 1
As shown in Figure 1, a kind of method that can colour glass fibre, including：
Pre-treatment is carried out to glass fibre, removes surface blot；
It is involved on glass fibre and unreels room, guarantee unreels room vacuum degree and is maintained at 1-1.8E-1Pa sections；
Glass fibre makes glass fibre temperature rise to 45 DEG C, heating room vacuum degree is maintained at 1-1.8E into heating room-1Pa Section；
Glass fibre is maintained at 4-5E into prechamber, house vacuum degree-2Pa；
When coating chamber vacuum degree reaches 1E-3During more than Pa, glass fibre is into coating chamber, target Ti, power 800w, Fiberglass surfacing sputters outstanding film layer, and during which vacuum degree maintains 1-1.8E-1Pa sections, glass fibre can present red orange green The multiple color of ultramarine purple；
Glass fibre ensures that winding room vacuum degree is maintained at 0.5-2.5E into winding room-1Pa sections；
Take out finished fabric, sampling detection；
Whole process is pipelined operation, and the cloth speed of service is 45m/min to 50m/min.
Embodiment 2
As shown in Figure 1, a kind of method that can colour glass fibre, including：
Pre-treatment is carried out to glass fibre, removes surface blot；
It is involved on glass fibre and unreels room, guarantee unreels room vacuum degree and is maintained at 0.5E-1Pa sections；
Glass fibre makes glass fibre temperature rise to 23 DEG C, heating room vacuum degree is maintained at 0.5E into heating room-1Pa areas Between；
Glass fibre is maintained at 3E into prechamber, house vacuum degree-2Pa；
When coating chamber vacuum degree reaches 1E-3During more than Pa, glass fibre is into coating chamber, and target is respectively Cu, ZnO, power Respectively 1500w, 4000w sputter outstanding film layer in fiberglass surfacing, and during which vacuum degree maintains 0.5E-1Pa sections, glass The multiple color of red, orange, yellow, green, indigo, azure, purple can be presented in fiber；
Glass fibre ensures that winding room vacuum degree is maintained at 0.5E into winding room-1Pa sections；
Take out finished fabric, sampling detection；
Whole process is pipelined operation, and the cloth speed of service is 67m/min to 72m/min.
Embodiment 3
As shown in Figure 1, a kind of method that can colour glass fibre, including：
Pre-treatment is carried out to glass fibre, removes surface blot；
It is involved on glass fibre and unreels room, guarantee unreels room vacuum degree and is maintained at 2.5E-1Pa sections；
Glass fibre makes glass fibre temperature rise to 34 DEG C, heating room vacuum degree is maintained at 2.5E into heating room-1Pa areas Between；
Glass fibre is maintained at 8E into prechamber, house vacuum degree-2Pa；
When coating chamber vacuum degree reaches 1E-3During more than Pa, glass fibre into coating chamber, target be respectively stainless steel, CuO, TiCN, power are respectively 11000w, 5500w, 4000w, sputter outstanding film layer in fiberglass surfacing, during which vacuum degree maintains 2.5E-1The multiple color of red, orange, yellow, green, indigo, azure, purple can be presented in Pa, glass fibre；
Glass fibre ensures that winding room vacuum degree is maintained at 2.5E into winding room-1Pa sections；
Take out finished fabric, sampling detection；
Whole process is pipelined operation, and the cloth speed of service is 89m/min to 94m/min.
Embodiment 4
As shown in Figure 1, a kind of method that can colour glass fibre, including：
Pre-treatment is carried out to glass fibre, removes surface blot；
It is involved on glass fibre and unreels room, guarantee unreels room vacuum degree and is maintained at 2E-1Pa sections；
Glass fibre makes glass fibre temperature rise to 34 DEG C, heating room vacuum degree is maintained at 2E into heating room-1Pa areas Between；
Glass fibre is maintained at 5E into prechamber, house vacuum degree-2Pa；
When coating chamber vacuum degree reaches 1E-3During more than Pa, for glass fibre into coating chamber, target is respectively TiO2、Zn、CuO、 AlTiN, power are respectively 1000w, 3000w, 2500w, 8800w, sputter outstanding film layer in fiberglass surfacing, during which vacuum degree Maintain 2E-1The multiple color of red, orange, yellow, green, indigo, azure, purple can be presented in Pa, glass fibre；
Glass fibre ensures that winding room vacuum degree is maintained at 2.5E into winding room-1Pa sections；
Take out finished fabric, sampling detection；
Whole process is pipelined operation, and the cloth speed of service is 14m/min to 20m/min.
Coloring experiment
According to GB/T 2660-2017, glass fibre of the present invention is in color fastness to water, colour fastness to perspiration, antifriction Wipe the standard that color fastness, fastness to soaping, colour fasteness to dry cleaning, color fastness to light meet GB/T 2660-2017.
Target described in embodiment 1-4 includes Ti, Cu, ZnO, stainless steel, CuO, TiCN, TiO2, Zn, CuO, AlTiN, but not It is limited to target described in embodiment 1-4, target described in embodiment 1-4 is used to prove the tinctorial property of fabric of the present invention；Ability Field technique personnel are it will be appreciated that target is included in Ti, Fe, Al, Zn, Cu, W, Mg, Au, Ag, Cr, Ni, V, Co, C, N, O, Si, Pt One or more of elements.
The present invention elaborates and has been cited embodiment, but those skilled in the art made according to above-described embodiment it is aobvious And be clear to various schemes, modification, change, these schemes, modification, change should all belong to the present invention claim protection Range.

Claims (4)

1. a kind of glass fibre of ecology coloring, including base fabric and color film layer, which is characterized in that the color film layer uses vacuum Deposition technique is formed, and target includes one kind in Ti, Fe, Al, Zn, Cu, W, Mg, Au, Ag, Cr, Ni, V, Co, C, N, O, Si, Pt Or several elements.
2. a kind of glass fibre of ecology coloring as described in claim 1, which is characterized in that the color film layer is individual layer or more Layer.
3. a kind of glass fibre of ecology coloring as described in claim 1, which is characterized in that the evaporating deposition technique includes true Empty thermal evaporation deposition, electron beam deposition, ion film plating, magnetron sputtering.
4. a kind of preparation method of the glass fibre of ecology coloring as described in claim 1, including：
Pre-treatment is carried out to glass fibre, removes surface blot；
It is involved on glass fibre and unreels room, guarantee unreels room vacuum degree and is maintained at 0.5-1E-9Pa sections；
Glass fibre makes glass fibre temperature rise to 2-180 DEG C, heating room vacuum degree is maintained at 0.5-1E into heating room-9Pa Section；
Glass fibre is maintained at 0.5-1E into prechamber, house vacuum degree-9Pa；
When coating chamber vacuum degree reaches 1E-3During more than Pa, base fabric makes to form color film in base fabric using vacuum deposition method into coating chamber Layer, target include one or more of Ti, Fe, Al, Zn, Cu, Mg, Au, W, Ag, Cr, Ni, V, Co, C, N, O, Si, Pt members Element, power interval 50-38000W；
Glass fibre ensures that winding room vacuum degree is maintained at 0.5-1E into winding room-9Pa sections；
Take out finished fabric, sampling detection；
Whole process is pipelined operation, and the cloth speed of service is 0.3m/min to 100m/min.
CN201810120082.1A 2018-02-05 2018-02-05 A kind of glass fibre of ecology coloring Pending CN108166281A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810120082.1A CN108166281A (en) 2018-02-05 2018-02-05 A kind of glass fibre of ecology coloring

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810120082.1A CN108166281A (en) 2018-02-05 2018-02-05 A kind of glass fibre of ecology coloring

Publications (1)

Publication Number Publication Date
CN108166281A true CN108166281A (en) 2018-06-15

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201810120082.1A Pending CN108166281A (en) 2018-02-05 2018-02-05 A kind of glass fibre of ecology coloring

Country Status (1)

Country Link
CN (1) CN108166281A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2019242594A1 (en) * 2018-06-22 2019-12-26 广东欣丰科技有限公司 Fabric coloring method and colored fabric

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2019242594A1 (en) * 2018-06-22 2019-12-26 广东欣丰科技有限公司 Fabric coloring method and colored fabric
US11505860B2 (en) 2018-06-22 2022-11-22 Guangdong Rising Well Science & Technology Co., Ltd. Fabric coloring method and colored fabric

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PB01 Publication
PB01 Publication
TA01 Transfer of patent application right

Effective date of registration: 20181211

Address after: 529000 First Floor of No.6 Jinzhang Avenue, Changsha District, Kaiping City, Guangdong Province

Applicant after: GUANGDONG XINFENG TECHNOLOGY CO., LTD.

Address before: 100080 Tianchuang Science and Technology Building, 8th Caihefang Road, Haidian District, Beijing, 12th floor 211B

Applicant before: Beijing nano chromophore Technology Co., Ltd.

TA01 Transfer of patent application right
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20180615

WD01 Invention patent application deemed withdrawn after publication