CN108129911A - It meets water developing ink and preparation method thereof, meet water optically variable films - Google Patents
It meets water developing ink and preparation method thereof, meet water optically variable films Download PDFInfo
- Publication number
- CN108129911A CN108129911A CN201711188816.1A CN201711188816A CN108129911A CN 108129911 A CN108129911 A CN 108129911A CN 201711188816 A CN201711188816 A CN 201711188816A CN 108129911 A CN108129911 A CN 108129911A
- Authority
- CN
- China
- Prior art keywords
- water
- parts
- ink
- acrylic resin
- resin liquid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 91
- 238000002360 preparation method Methods 0.000 title claims description 8
- 239000007788 liquid Substances 0.000 claims abstract description 21
- 229920000178 Acrylic resin Polymers 0.000 claims abstract description 20
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 20
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000002270 dispersing agent Substances 0.000 claims abstract description 13
- 235000019441 ethanol Nutrition 0.000 claims abstract description 11
- 239000000049 pigment Substances 0.000 claims abstract description 11
- 239000000843 powder Substances 0.000 claims abstract description 11
- IDQBJILTOGBZCR-UHFFFAOYSA-N 1-butoxypropan-1-ol Chemical compound CCCCOC(O)CC IDQBJILTOGBZCR-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000002518 antifoaming agent Substances 0.000 claims abstract description 10
- 239000008367 deionised water Substances 0.000 claims abstract description 10
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 10
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 9
- 239000000463 material Substances 0.000 claims abstract description 8
- 210000002469 basement membrane Anatomy 0.000 claims description 13
- 239000000080 wetting agent Substances 0.000 claims description 6
- 229920002125 Sokalan® Polymers 0.000 claims description 3
- 150000003863 ammonium salts Chemical class 0.000 claims description 3
- 210000004276 hyalin Anatomy 0.000 claims description 3
- 210000004379 membrane Anatomy 0.000 claims description 3
- 239000012528 membrane Substances 0.000 claims description 3
- 239000004584 polyacrylic acid Substances 0.000 claims description 3
- 159000000000 sodium salts Chemical class 0.000 claims description 3
- 230000003213 activating effect Effects 0.000 claims 1
- 238000003756 stirring Methods 0.000 claims 1
- 239000002904 solvent Substances 0.000 abstract description 6
- 239000007844 bleaching agent Substances 0.000 abstract description 2
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 239000010410 layer Substances 0.000 description 10
- 238000002845 discoloration Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 2
- 108010010803 Gelatin Proteins 0.000 description 1
- 206010040849 Skin fissures Diseases 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 230000011132 hemopoiesis Effects 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 210000000653 nervous system Anatomy 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 210000004003 subcutaneous fat Anatomy 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/50—Sympathetic, colour changing or similar inks
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
- C09D11/033—Printing inks characterised by features other than the chemical nature of the binder characterised by the solvent
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The present invention relates to technical field of ink, disclose a kind of chance water developing ink, include following material by mass fraction：36~56 parts of water-based acrylic resin liquid, 2~6 parts of pigment powder, 16~20 parts of deionized water, 6~8 parts of ethyl alcohol, 4~6 parts of propandiol butyl ether, 0.6~1 part of film forming agent, 0.8~1.2 part of dispersant, 0.4~0.6 part of antifoaming agent, the water-based acrylic resin liquid softness number be 10~15 DEG C.It also discloses a kind of chance water developing ink production method and meets water optically variable films.The chance water developing ink solvent of the present invention is mainly water, more environmentally-friendly, and the water-based acrylic resin liquid sheet as its main component is as Transparent color, the characteristic to bleach with chance water, therefore it is transparent under the ink normality, is meeting water time-varying white, water restores transparent after doing.
Description
Technical field
The present invention relates to technical field of ink, more particularly to a kind of chance water developing ink and preparation method thereof meets water discoloration
Film.
Background technology
The material of chance water discoloration at present (surface layer is transparent, and pattern is showed after meeting water) is widely used in soft painting and calligraphy and practices, is anti-
Pseudo- pattern and furnishing fields.It is to meet the ink of water colour developing, but traditional solvent type to meet the main component in the material of water discoloration
The organic solvent of ink is usually harmful ethers or ketone, and Long Term Contact can damage subcutaneous fat, make chapped skin,
It penetrates into human body and seriously affects hematopoiesis function, and be chronically exposed in the environment of solvent volatilization, pole can be caused to nervous system
Big damage.The solvent of water-based ink is mainly pure water and a small amount of alcohols, harmless, meets instantly environmentally friendly master
Topic.Do not occur the chance water developing ink based on water-based ink also at present.
Invention content
The present invention proposes a kind of chance water developing ink and preparation method thereof, meets water optically variable films, solves in the prior art
The problem of meeting water color shifting ink not environmentally.
A kind of chance water developing ink of the present invention includes following material by mass fraction：
36~56 parts of water-based acrylic resin liquid；
2~6 parts of pigment powder；
16~20 parts of deionized water；
6~8 parts of ethyl alcohol；
4~6 parts of propandiol butyl ether；
0.6~1 part of film forming agent；
0.8~1.2 part of dispersant；
0.4~0.6 part of antifoaming agent；
The softness number of the water-based acrylic resin liquid is -10~-15 DEG C.
Wherein, include following material by mass fraction：
50 parts of water-based acrylic resin liquid；
4 parts of pigment powder；
18 parts of deionized water；
8 parts of ethyl alcohol；
5 parts of propandiol butyl ether；
0.8 part of film forming agent；
1 part of dispersant；
0.6 part of antifoaming agent；
The softness number of the water-based acrylic resin liquid is -15 DEG C.
Wherein, the dispersant is polyacrylic acid sodium salt or ammonium salt.
Wherein, the wetting agent is long chain ethoxylates class surfactant.
The present invention also provides the preparation method that a kind of any of the above-described meets water developing ink, including step：
S1：Water-based acrylic resin liquid, ethyl alcohol, deionized water and propandiol butyl ether are put into Scattered Kettle by formula,
It is sufficiently stirred and is uniformly dispersed；
S2：Dispersant and pigment powder are added in the Scattered Kettle and be uniformly dispersed；
S3：Antifoaming agent and wetting agent are added in the Scattered Kettle and be uniformly dispersed.
Water optically variable films is met the present invention also provides a kind of, including：It basement membrane and is covered on the basement membrane by above-mentioned
The ink design layer met water developing ink and formed described in one.
Wherein, the substratum transparent between ink design layer and basement membrane is further included.
Wherein, the basement membrane is hyaline membrane.
The chance water developing ink solvent of the present invention is mainly water, more environmentally-friendly, and as aqueous the third of its main component
Olefin(e) acid resin liquid sheet has as Transparent color and meets the characteristic that water bleaches, therefore be transparent under the ink normality, bleach when meeting water
Color, water restore transparent after doing.
Description of the drawings
In order to illustrate more clearly about the embodiment of the present invention or technical scheme of the prior art, to embodiment or will show below
There is attached drawing needed in technology description to be briefly described, it should be apparent that, the accompanying drawings in the following description is only this
Some embodiments of invention, for those of ordinary skill in the art, without having to pay creative labor, may be used also
To obtain other attached drawings according to these attached drawings.
Fig. 1 is a kind of chance water optically variable films structure diagram of the present invention.
Specific embodiment
Below in conjunction with the attached drawing in the embodiment of the present invention, the technical solution in the embodiment of the present invention is carried out clear, complete
Site preparation describes, it is clear that described embodiment is only part of the embodiment of the present invention, instead of all the embodiments.It is based on
Embodiment in the present invention, those of ordinary skill in the art are obtained every other without creative efforts
Embodiment shall fall within the protection scope of the present invention.
The chance water developing ink of the first embodiment of the present invention includes following material by mass fraction：
36~56 parts of water-based acrylic resin liquid；
2~6 parts of pigment powder；
16~20 parts of deionized water；
6~8 parts of ethyl alcohol；
4~6 parts of propandiol butyl ether；
0.6~1 part of film forming agent；
0.8~1.2 part of dispersant；
0.4~0.6 part of antifoaming agent；
The softness number of the water-based acrylic resin liquid is -10~-15 DEG C.
The water-based acrylic resin liquid that softness number is -10~-15 DEG C, which has, meets the characteristic that water bleaches, therefore the ink normality
It is transparent down, is meeting water time-varying white, water restores transparent after doing.And it is mainly water to meet water developing ink solvent, and it is more environmentally-friendly.
A small amount of pigment powder causes the ink under normality to show transparent color, when meeting water and bleaching since white is by color reflective, also may be used
Develop the color desired color.
Preferably, it prepares in the following proportions and meets water colour developing faster, water is quickly replied after doing.
50 parts of water-based acrylic resin liquid；
4 parts of pigment powder；
18 parts of deionized water；
8 parts of ethyl alcohol；
5 parts of propandiol butyl ether；
0.8 part of film forming agent；
1 part of dispersant；
0.6 part of antifoaming agent；
The softness number of the water-based acrylic resin liquid is -15 DEG C.
In the present embodiment, dispersant is polyacrylic acid sodium salt or ammonium salt, and wetting agent is lived for long chain ethoxylates class surface
Property agent.
Second embodiment of the invention provides a kind of preparation method for meeting water developing ink, including：
Water-based acrylic resin liquid, ethyl alcohol, deionized water and propandiol butyl ether are put into Scattered Kettle by step S1 by formula
It is interior, it is sufficiently stirred and is uniformly dispersed；
Dispersant and pigment powder are added in the Scattered Kettle and are uniformly dispersed by step S2；
Antifoaming agent and wetting agent are added in the Scattered Kettle and are uniformly dispersed by step S3.
Third embodiment of the invention provides a kind of chance water optically variable films, as shown in Figure 1, including：Basement membrane 1 and it is covered in base
The ink design layer 2 formed on film 1 by above-mentioned chance water developing ink.Ink design layer 2 is transparent under normal condition, due to
Water-based acrylic resin liquid, which has, meets the characteristic that water bleaches, and ink design layer 2 becomes white after meeting water, so as to show ink logo
Layer 2 printing pattern, water do rear pattern revert to it is transparent.
The chance water optically variable films of the present embodiment further includes the substratum transparent 3 between ink design layer 2 and basement membrane 1, thoroughly
Gelatin layer 3 can make basement membrane 1 and 2 combination of ink design layer closer, avoid water frequent between basement membrane 1 and ink design layer 2
It is impregnated with, is detached from the two.
In the present embodiment, basement membrane 1 is hyaline membrane, and so in the dry state, entire film is transparence.
The foregoing is merely presently preferred embodiments of the present invention, is not intended to limit the invention, it is all the present invention spirit and
Within principle, any modification, equivalent replacement, improvement and so on should all be included in the protection scope of the present invention.
Claims (8)
1. a kind of chance water developing ink, which is characterized in that include following material by mass fraction：
36~56 parts of water-based acrylic resin liquid；
2~6 parts of pigment powder；
16~20 parts of deionized water；
6~8 parts of ethyl alcohol；
4~6 parts of propandiol butyl ether；
0.6~1 part of film forming agent；
0.8~1.2 part of dispersant；
0.4~0.6 part of antifoaming agent；
The softness number of the water-based acrylic resin liquid is -10~-15 DEG C.
2. water developing ink is met as described in claim 1, which is characterized in that include following material by mass fraction：
50 parts of water-based acrylic resin liquid；
4 parts of pigment powder；
18 parts of deionized water；
8 parts of ethyl alcohol；
5 parts of propandiol butyl ether；
0.8 part of film forming agent；
1 part of dispersant；
0.6 part of antifoaming agent；
The softness number of the water-based acrylic resin liquid is -15 DEG C.
3. water developing ink is met as described in claim 1, which is characterized in that the dispersant is polyacrylic acid sodium salt or ammonium
Salt.
4. water developing ink is met as described in claim 1, which is characterized in that the wetting agent is long chain ethoxylates class table
Face activating agent.
5. a kind of any one of Claims 1 to 4 meets the preparation method of water developing ink, which is characterized in that including step：
S1：Water-based acrylic resin liquid, ethyl alcohol, deionized water and propandiol butyl ether are put into Scattered Kettle by formula, fully
It is dispersed with stirring uniformly；
S2：Dispersant and pigment powder are added in the Scattered Kettle and be uniformly dispersed；
S3：Antifoaming agent and wetting agent are added in the Scattered Kettle and be uniformly dispersed.
6. a kind of chance water optically variable films, which is characterized in that including：It basement membrane and is covered on the basement membrane by Claims 1 to 4
Any one of described in the ink design layer met water developing ink and formed.
7. water optically variable films is met as claimed in claim 6, which is characterized in that further include between ink design layer and basement membrane
Substratum transparent.
8. the chance water optically variable films as described in claim 6 and 7, which is characterized in that the basement membrane is hyaline membrane.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711188816.1A CN108129911A (en) | 2017-11-24 | 2017-11-24 | It meets water developing ink and preparation method thereof, meet water optically variable films |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711188816.1A CN108129911A (en) | 2017-11-24 | 2017-11-24 | It meets water developing ink and preparation method thereof, meet water optically variable films |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108129911A true CN108129911A (en) | 2018-06-08 |
Family
ID=62388897
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711188816.1A Pending CN108129911A (en) | 2017-11-24 | 2017-11-24 | It meets water developing ink and preparation method thereof, meet water optically variable films |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108129911A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111995906A (en) * | 2020-09-01 | 2020-11-27 | 福建琦峰科技有限公司 | Printing ventilated membrane that urine wet discolours |
| CN112878052A (en) * | 2021-01-15 | 2021-06-01 | 惠州市启恒科技有限公司 | Fluorescent canvas and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102108222A (en) * | 2011-04-01 | 2011-06-29 | 中山永辉化工有限公司 | Humidity sensing ink as well as preparation method and application thereof |
| CN103946337A (en) * | 2011-11-11 | 2014-07-23 | 株式会社樱花彩色笔 | Hygrochromic/thermochromic composition and hygrochromic/thermochromic indicator |
| CN107286752A (en) * | 2017-07-04 | 2017-10-24 | 厦门麓山新材料科技有限公司 | A kind of vapor sensitive color shifting ink and wet sensitive antifalsification label |
-
2017
- 2017-11-24 CN CN201711188816.1A patent/CN108129911A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102108222A (en) * | 2011-04-01 | 2011-06-29 | 中山永辉化工有限公司 | Humidity sensing ink as well as preparation method and application thereof |
| CN103946337A (en) * | 2011-11-11 | 2014-07-23 | 株式会社樱花彩色笔 | Hygrochromic/thermochromic composition and hygrochromic/thermochromic indicator |
| CN107286752A (en) * | 2017-07-04 | 2017-10-24 | 厦门麓山新材料科技有限公司 | A kind of vapor sensitive color shifting ink and wet sensitive antifalsification label |
Non-Patent Citations (1)
| Title |
|---|
| 朱万强: "《涂料基础教程》", 30 June 2012, 西南交通大学出版社 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111995906A (en) * | 2020-09-01 | 2020-11-27 | 福建琦峰科技有限公司 | Printing ventilated membrane that urine wet discolours |
| CN112878052A (en) * | 2021-01-15 | 2021-06-01 | 惠州市启恒科技有限公司 | Fluorescent canvas and preparation method thereof |
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| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180608 |