CN108129789A - A kind of ABS composite material of 3D printing and preparation method thereof - Google Patents
A kind of ABS composite material of 3D printing and preparation method thereof Download PDFInfo
- Publication number
- CN108129789A CN108129789A CN201711237715.9A CN201711237715A CN108129789A CN 108129789 A CN108129789 A CN 108129789A CN 201711237715 A CN201711237715 A CN 201711237715A CN 108129789 A CN108129789 A CN 108129789A
- Authority
- CN
- China
- Prior art keywords
- parts
- composite material
- antioxidant
- abs
- maleic anhydride
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y70/00—Materials specially adapted for additive manufacturing
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of ABS composite materials of 3D printing and preparation method thereof, are related to 3D printing technique field, are made of the raw material of following parts by weight：70 80 parts of ABS resin, 7 15 parts of maleic anhydride grafting toughening agent, 10 20 parts of anacardol, 13 parts of lubricant, 13 parts of toner, 0.2 1 parts of antioxidant, the present invention carries out activeness and quietness using maleic anhydride grafting toughening agent and anacardol mating reaction to ABS resin, the processing fluidity of ABS can also be improved, by extruding pelletization after these three material mixings, so that it is uniformly mixed, again with lubricant, toner, the rational proportion of the other ingredients of antioxidant, temperature in reasonably optimizing technique, carry out extrusion wire drawing, 3D printing consumable product performance obtained is good, toughening effect is apparent.
Description
Technical field
The present invention relates to the ABS composite materials and its preparation side of 3D printing technique field more particularly to a kind of 3D printing
Method.
Background technology
3D printing is one of rapid prototyping manufacturing (RPM) technology, is born in the late 1980s, it is with macromolecule
And metal be consumptive material, using its can adhesion characteristic, digital model file is printed as by entity by successively accumulation molding mode
Forming technique.The technology can simplify product manufacturing program, shorten product development cycle, improve efficiency, reduce cost, can be extensive
Applied to national defence, space flight, automobile and metal manufacture etc. industries, it is considered to be in recent years an important technical of manufacturing field into
Fruit.3D printing rapid shaping technique based on fusion sediment rapid shaping (RPM) principle is most vital quick at present
One of forming technique, the consumptive material used are generally thermoplastic macromolecule material, are heated above silk material using Electric heating
Its melting temperature, under control of the computer, nozzle make x-y plane movement, by the material coating of melting on the table, successively
Accumulation forms 3 D workpiece.
At present, available for the molding macromolecule silk materials of FDM have acrylonitrile-butadiene-polyglass (ABS), polylactic acid,
Nylon, makrolon and polyphenylsulfone etc..Wherein, ABS is current production rate maximum, most widely used general engineering plastic, it will
Acrylonitrile, butadiene, styrene various performances organically unite, there is higher toughness, hardness and rigidity, but when using
When the product of higher level, certain mechanical properties are not met by its requirement, especially impact strength, it is therefore desirable to develop
With mechanical property more excellent 3D printing ABS consumptive materials.
Invention content
Technical problems based on background technology, the present invention propose a kind of ABS composite material of 3D printing, impact
Intensity is high, good toughness, and comprehensive mechanical property is excellent.
A kind of ABS composite material of 3D printing proposed by the present invention, technical method are as follows：
A kind of ABS composite material of 3D printing, is made of the raw material of following parts by weight：70-80 parts of ABS resin, Malaysia
7-15 parts of acid anhydrides grafting toughening agent, 10-20 parts of anacardol, 1-3 parts of lubricant, 1-3 parts of toner, 0.2-1 parts of antioxidant.
Preferably, the maleic anhydride grafting toughening agent for maleic anhydride-g-SBS, in Maleic anhydride-containg polyethylene extremely
Few one kind.
Preferably, the antioxidant is according to 1-4 by antioxidant 1010 and antioxidant 300：2 mass ratio compounding composition
's.
Preferably, the lubricant is polyethylene wax, in bi-tristearin, oleamide, stearic acid, magnesium stearate
It is at least one.
A kind of preparation method of the ABS composite material of 3D printing, step are as follows：
S1, mixing will be carried out in ABS resin, maleic anhydride grafting toughening agent, anacardol addition mixer, obtains mixing material；
S2, mixing material is added in double screw extruder, melting extrusion is granulated, and obtains pellet；
S3, pellet is added in single screw extrusion machine, it is cold adds in lubricant, toner and antioxidant, melting extrusion wire drawing
But be molded, wind to get.
Preferably, mixing temperature is 180-200 DEG C in the step S1, mixing time 5-10min.
Preferably, melting temperature is 200-230 DEG C in the step S2.
Preferably, melting temperature is 200-230 DEG C in the step S3.
Beneficial effects of the present invention are as follows：The present invention is using maleic anhydride grafting toughening agent and anacardol cooperation to ABS trees
Fat carries out activeness and quietness, and ABS resin, maleic anhydride grafting toughening agent, anacardol are in 70-80：7-15：The weight ratio of 10-20
In the range of, activeness and quietness is with obvious effects, and improves the processing fluidity of ABS, and anacardol point is can be seen that from the structure of anacardol
Containing phenyl ring and flexible long linear in son, wherein, phenyl ring provides rigidity and high temperature resistance, C=C double bonds and C- on long linear
C singly-bounds assign compliance and toughness, use it for ABS modifications, can be good at improving the notch impact strength and toughness of ABS；
Using maleic anhydride grafting toughening agent, make it that there is better compatibility with ABS substrate, efficient for flexibilizing ABS, can improve
The shock resistance and toughness of ABS；By extruding pelletization after these three material mixings so that be uniformly mixed, then with lubricant, color
The rational proportion of the other ingredients of powder, antioxidant, the temperature in reasonably optimizing technique carry out extrusion wire drawing, 3D printing consumption obtained
Material good product performance, toughening effect are apparent.
Specific embodiment
In the following, technical scheme of the present invention is described in detail by specific embodiment.
Embodiment 1
A kind of ABS composite material of 3D printing, is made of the raw material of following parts by weight：70 parts of ABS resin, maleic anhydride
15 parts of grafting toughening agent, 10 parts of anacardol, 3 parts of lubricant, 1 part of toner, 0.2 part of antioxidant.
A kind of preparation method of the ABS composite material of 3D printing, step are as follows：
S1, mixing will be carried out in ABS resin, maleic anhydride grafting toughening agent, anacardol addition mixer, obtains mixing material；
S2, mixing material is added in double screw extruder, melting extrusion is granulated, and obtains pellet；
S3, pellet is added in single screw extrusion machine, it is cold adds in lubricant, toner and antioxidant, melting extrusion wire drawing
But be molded, wind to get.
Embodiment 2
A kind of ABS composite material of 3D printing, is made of the raw material of following parts by weight：72 parts of ABS resin, maleic anhydride
9 parts of Maleated SEBS, 13 parts of anacardol, 1.5 parts of polyethylene wax, 2 parts of toner, 0.5 part of antioxidant.Wherein, antioxidant is by antioxygen
Agent 1010 and antioxidant 300 are according to 1：2 mass ratio compounding composition.
A kind of preparation method of the ABS composite material of 3D printing, step are as follows：
S1, ABS resin, maleic anhydride-g-SBS, anacardol are added in mixer, under 180 DEG C of mixing temperature
Mixing 5min obtains mixing material；
S2, mixing material is added in double screw extruder, each process section temperature be 210 DEG C, 215 DEG C, 220 DEG C, 225
DEG C, 230 DEG C, 230 DEG C, 230 DEG C, 230 DEG C, 200 DEG C, 200 DEG C, extruding pelletization obtains pellet；
S3, pellet is added in single screw extrusion machine, adding in stearic acid, toner and antioxidant, each process section temperature is
210 DEG C, 215 DEG C, 220 DEG C, 225 DEG C, 230 DEG C, 230 DEG C, 230 DEG C, 230 DEG C, 200 DEG C, 200 DEG C, wire drawing is squeezed out, is cooled to
Type, wind to get.
Embodiment 3
A kind of ABS composite material of 3D printing, is made of the raw material of following parts by weight：75 parts of ABS resin, maleic anhydride
10 parts of Maleated SEBS, 15 parts of anacardol, 2 parts of stearic acid, 2 parts of toner, 0.6 part of antioxidant.Wherein, antioxidant is by antioxidant
1010 and antioxidant 300 according to 1：1 mass ratio compounding composition.
A kind of preparation method of the ABS composite material of 3D printing, step are as follows：
S1, ABS resin, maleic anhydride-g-SBS, anacardol are added in mixer, under 190 DEG C of mixing temperature
Mixing 8min obtains mixing material；
S2, mixing material is added in double screw extruder, each process section temperature be 205 DEG C, 210 DEG C, 215 DEG C, 220
DEG C, 225 DEG C, 225 DEG C, 225 DEG C, 225 DEG C, 200 DEG C, 200 DEG C, extruding pelletization obtains pellet；
S3, pellet is added in single screw extrusion machine, adding in stearic acid, toner and antioxidant, each process section temperature is
210 DEG C, 215 DEG C, 220 DEG C, 225 DEG C, 230 DEG C, 230 DEG C, 230 DEG C, 230 DEG C, 200 DEG C, 200 DEG C, wire drawing is squeezed out, is cooled to
Type, wind to get.
Embodiment 4
A kind of ABS composite material of 3D printing, is made of the raw material of following parts by weight：78 parts of ABS resin, maleic anhydride
It is grafted 12 parts of SBS, 18 parts of anacardol, 2 parts of oleamide, 2.5 parts of toner, 0.5 part of antioxidant.Wherein, antioxidant is by antioxidant
1010 and antioxidant 300 according to 3：2 mass ratio compounding composition.
A kind of preparation method of the ABS composite material of 3D printing, step are as follows：
S1, ABS resin, Maleic anhydride-containg polyethylene, anacardol are added in mixer, it is close under 195 DEG C of mixing temperature
10min is refined, obtains mixing material；
S2, mixing material is added in double screw extruder, each process section temperature be 200 DEG C, 205 DEG C, 210 DEG C, 215
DEG C, 220 DEG C, 220 DEG C, 220 DEG C, 220 DEG C, 200 DEG C, 200 DEG C, extruding pelletization obtains pellet；
S3, pellet is added in single screw extrusion machine, adding in stearic acid, toner and antioxidant, each process section temperature is
205 DEG C, 210 DEG C, 215 DEG C, 220 DEG C, 225 DEG C, 225 DEG C, 225 DEG C, 225 DEG C, 200 DEG C, 200 DEG C, wire drawing is squeezed out, is cooled to
Type, wind to get.
Embodiment 5
A kind of ABS composite material of 3D printing, is made of the raw material of following parts by weight：80 parts of ABS resin, maleic anhydride
7 parts of grafting toughening agent, 20 parts of anacardol, 1 part of bi-tristearin, 3 parts of toner, 0.2 part of antioxidant.Wherein, antioxidant is
By antioxidant 1010 and antioxidant 300 according to 2：1 mass ratio compounding composition；Maleic anhydride grafting toughening agent is by maleic acid
Acid anhydride Maleated SEBS and Maleic anhydride-containg polyethylene are according to 1：1 mass ratio compounding composition.
A kind of preparation method of the ABS composite material of 3D printing, step are as follows：
S1, ABS resin, maleic anhydride grafting toughening agent, anacardol are added in mixer, in 200 DEG C of mixing temperature
Lower mixing 10min, obtains mixing material；
S2, mixing material is added in double screw extruder, each process section temperature be 210 DEG C, 215 DEG C, 220 DEG C, 225
DEG C, 230 DEG C, 230 DEG C, 230 DEG C, 230 DEG C, 200 DEG C, 200 DEG C, extruding pelletization obtains pellet；
S3, pellet is added in single screw extrusion machine, adding in stearic acid, toner and antioxidant, each process section temperature is
210 DEG C, 215 DEG C, 220 DEG C, 225 DEG C, 230 DEG C, 230 DEG C, 230 DEG C, 230 DEG C, 200 DEG C, 200 DEG C, wire drawing is squeezed out, is cooled to
Type, wind to get.
Comparative example 1
A kind of ABS composite material of 3D printing, is made of the raw material of following parts by weight：75 parts of ABS resin, maleic anhydride
10 parts of Maleated SEBS, 2 parts of stearic acid, 2 parts of toner, 0.6 part of antioxidant.Wherein, antioxidant is by antioxidant 1010 and antioxidant
300 according to 1：1 mass ratio compounding composition.
A kind of preparation method of the ABS composite material of 3D printing, step are as follows：
S1, ABS resin, maleic anhydride-g-SBS are added in mixer, the mixing under 190 DEG C of mixing temperature
8min obtains mixing material；
S2, mixing material is added in double screw extruder, each process section temperature be 205 DEG C, 210 DEG C, 215 DEG C, 220
DEG C, 225 DEG C, 225 DEG C, 225 DEG C, 225 DEG C, 200 DEG C, 200 DEG C, extruding pelletization obtains pellet；
S3, pellet is added in single screw extrusion machine, adding in stearic acid, toner and antioxidant, each process section temperature is
210 DEG C, 215 DEG C, 220 DEG C, 225 DEG C, 230 DEG C, 230 DEG C, 230 DEG C, 230 DEG C, 200 DEG C, 200 DEG C, wire drawing is squeezed out, is cooled to
Type, wind to get.
Notch impact strength, elongation at break properties in 2-5 of the embodiment of the present invention and comparative example 1 is detected, is examined
Result is surveyed to see the table below.
1 notch impact strength of table, elongation at break properties detection
The notch impact strength of ABS composite material for preparing of the present invention, elongation at break are good it can be seen from upper table,
Compared with being only added with the ABS composite material of maleic anhydride grafting toughening agent, anacardol system is also added in the embodiment of the present invention
The activeness and quietness effect of standby ABS composite material is more preferable.
The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited thereto,
Any one skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its
Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.
Claims (8)
1. a kind of ABS composite material of 3D printing, which is characterized in that be made of the raw material of following parts by weight：ABS resin 70-
80 parts, 7-15 parts of maleic anhydride grafting toughening agent, 10-20 parts of anacardol, 1-3 parts of lubricant, 1-3 parts of toner, antioxidant 0.2-1
Part.
2. the ABS composite material of 3D printing according to claim 1, which is characterized in that the maleic anhydride grafting increases
Tough dose is at least one of maleic anhydride-g-SBS, Maleic anhydride-containg polyethylene.
3. the ABS composite material of 3D printing according to claim 1, which is characterized in that the antioxidant is by antioxygen
Agent 1010 and antioxidant 300 are according to 1-4：2 mass ratio compounding composition.
4. the ABS composite material of 3D printing according to claim 1, which is characterized in that the lubricant is polyethylene
At least one of wax, bi-tristearin, oleamide, stearic acid, magnesium stearate.
5. a kind of preparation method of the ABS composite material based on any 3D printings of claim 1-4, feature exist
In step is as follows：
S1, mixing will be carried out in ABS resin, maleic anhydride grafting toughening agent, anacardol addition mixer, obtains mixing material；
S2, mixing material is added in double screw extruder, melting extrusion is granulated, and obtains pellet；
S3, pellet is added in single screw extrusion machine, adds in lubricant, toner and antioxidant, melting extrusion wire drawing and be cooled to
Type, wind to get.
6. the preparation method of the ABS composite material of 3D printing according to claim 5, which is characterized in that the step
Mixing temperature is 180-200 DEG C in S1, mixing time 5-10min.
7. the preparation method of the ABS composite material of 3D printing according to claim 5, which is characterized in that the step
Melting temperature is 200-230 DEG C in S2.
8. the preparation method of the ABS composite material of 3D printing according to claim 5, which is characterized in that the step
Melting temperature is 200-230 DEG C in S3.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711237715.9A CN108129789A (en) | 2017-11-30 | 2017-11-30 | A kind of ABS composite material of 3D printing and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711237715.9A CN108129789A (en) | 2017-11-30 | 2017-11-30 | A kind of ABS composite material of 3D printing and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108129789A true CN108129789A (en) | 2018-06-08 |
Family
ID=62388985
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711237715.9A Withdrawn CN108129789A (en) | 2017-11-30 | 2017-11-30 | A kind of ABS composite material of 3D printing and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108129789A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108912585A (en) * | 2018-06-29 | 2018-11-30 | 三叠打印线材有限公司 | FDM3D printing new A BS material and preparation method thereof |
| CN116769270A (en) * | 2023-06-25 | 2023-09-19 | 广东丙辛新材料有限公司 | Low-density high-pressure polyethylene closed-cell foam plastic plate and production process thereof |
-
2017
- 2017-11-30 CN CN201711237715.9A patent/CN108129789A/en not_active Withdrawn
Non-Patent Citations (1)
| Title |
|---|
| 乔雯钰等: ""3D打印用ABS丝材性能研究"", 《工程塑料应用》 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108912585A (en) * | 2018-06-29 | 2018-11-30 | 三叠打印线材有限公司 | FDM3D printing new A BS material and preparation method thereof |
| CN116769270A (en) * | 2023-06-25 | 2023-09-19 | 广东丙辛新材料有限公司 | Low-density high-pressure polyethylene closed-cell foam plastic plate and production process thereof |
| CN116769270B (en) * | 2023-06-25 | 2024-03-08 | 广东丙辛新材料有限公司 | Low-density high-pressure polyethylene closed-cell foam plastic plate and production process thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN110835442B (en) | Polypropylene/polyamide/polyketone composite material and preparation method thereof | |
| CN103087456A (en) | Heat resistance ABS material and preparation method thereof | |
| CN103059537B (en) | High-rigidity high-fluidity PC/ABS (polycarbonate/acrylonitrile-butadiene-styrene) alloy and preparation method thereof | |
| CN102134369A (en) | ABS (acrylonitrile butadiene styrene) /PET (polyethylene terephthalate) /copolyester ternary alloy and preparation method thereof | |
| CN105348724A (en) | High-gloss high-hardness scratching-resisting modified PC/ABS alloy material and preparation method thereof | |
| CN107523001A (en) | A kind of ABS/PC 3D consumptive material PP Pipe Compounds and preparation method thereof | |
| CN108129789A (en) | A kind of ABS composite material of 3D printing and preparation method thereof | |
| CN104592730A (en) | Polylactic acid/polyester alloy and preparation method thereof | |
| CN102690463A (en) | Ethylene-vinyl acetate rubber thermoplastic elastomer and preparation method thereof | |
| CN108690315A (en) | A kind of Heat resistance ABS material of matt and preparation method thereof | |
| CN105504759A (en) | ABS composite material used for 3D printing and preparation method of ABS composite material | |
| CN105602098B (en) | It is a kind of for modified polypropylene composite material of 3D printing and preparation method thereof | |
| CN107603170B (en) | High-performance PBT/ABS alloy material and preparation method thereof | |
| CN108164941A (en) | A kind of PLA composite materials of 3D printing and preparation method thereof | |
| CN101153105A (en) | ABS modified prescription | |
| CN105385067A (en) | Folding-whitening-free high-weather-resistance hard PVC extrusion profile black pellet and preparation method thereof | |
| CN107118421A (en) | A kind of high temperature resistant wood plastic composite and preparation method thereof | |
| CN106939112B (en) | High-gloss HIPS/recycled PET bottle flake composite material and preparation method thereof | |
| CN107523002A (en) | A kind of special high oil resistant high-performance ABS alloy material of battery cell case | |
| CN105949625A (en) | Polypropylene composite material with spraying-free and high-rigidity metal texture effect and preparation method thereof | |
| CN101870797B (en) | Polyacrylonitrile-butadiene-styrene modified compound and preparation method thereof | |
| CN108239393A (en) | A kind of lightweight daiamid composition and preparation method thereof | |
| CN107353568A (en) | A kind of high-light ABS material of metallic luster and preparation method thereof | |
| CN105713336A (en) | High-performance electroplating ABS (acrylonitrile butadiene styrene) alloy material and preparation method thereof | |
| CN104672747A (en) | Heat-resisting ABS (Acrylonitrile Butadiene StyreneAcrylonitrile Butadiene Styrene) material and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WW01 | Invention patent application withdrawn after publication | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20180608 |