CN101153105A - ABS modified prescription - Google Patents
ABS modified prescription Download PDFInfo
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- CN101153105A CN101153105A CNA200610122384XA CN200610122384A CN101153105A CN 101153105 A CN101153105 A CN 101153105A CN A200610122384X A CNA200610122384X A CN A200610122384XA CN 200610122384 A CN200610122384 A CN 200610122384A CN 101153105 A CN101153105 A CN 101153105A
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- Prior art keywords
- abs
- portions
- modified formula
- mah
- oxidation inhibitor
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Abstract
The present invention provides an ABS modified formula. The formula mainly comprises the following components: 75 portions to 90 portions of ABS, 5 portions to 10 portions of compatible agent, 3 portions to 10 portions of toughener, 0.1 portions to 0.3 portions of antioxidant and 2 portions to 5 portions of nano-filler, according to the weight portions. The nano-filler can be SiO2 and CaCO3. The present invention uses the method of adding nano-filler, effectively improves the MI value of ABS, improves the processing fluidity of ABS, and slightly improves the mechanical strength.
Description
Technical field
The present invention relates to technical field of polymer materials, particularly a kind of ABS modified formula.
Background technology
ABS is meant vinyl cyanide, divinyl, cinnamic terpolymer, because it is superior that it has over-all properties, the advantage that price is low and easy-formation is processed, become current sales volume maximum, range of application is thermoplastic engineering plastic the most widely, and be widely used in automotive industry, electric industry, industries such as household electrical appliances.
The ABS chemical resistance is good, higher thermotolerance, toughness, impact property and rigidity are arranged.But the processing fluidity of the ABS of some trade mark is still lower, for example strange beautiful PA757, and its MI value has only 8.8g/10min, and processing fluidity is lower, is difficult for injection when injection molding.
Summary of the invention
In view of the above problems, the invention provides a kind of ABS modified formula, adopt the method for adding Nano filling, improve its MI value, further improve the processing fluidity of this type of ABS.
In order to achieve the above object, the present invention has adopted following technical scheme: a kind of ABS modified formula, and it mainly comprises following component and content (representing with parts by weight):
ABS 75～90；
Compatilizer 5～10;
Toughner 3～10;
Oxidation inhibitor 0.1～0.3;
Nano filling 2～5.
Wherein, described compatilizer can be PP-g-MAH, ABS-g-MAH, and described toughner can be MBS, SBS and SEBS, and described Nano filling can be SiO
2, CaCO
3, described oxidation inhibitor can be 2921.
Compared to prior art, the invention provides a kind of ABS modified formula, adopt to add the method for Nano filling, the MI value of ABS (PA757) is being shown improve, further improved the ABS processing fluidity, and mechanical strength also there is raising slightly.
Embodiment
Below in conjunction with specific embodiment a kind of magnesium alloy chemical nickel plating solution and nickel plating technology thereof proposed by the invention are described in further detail.
Embodiment 1:
Earlier by the following raw material (representing) of getting with parts by weight:
ABS 90；
PP-g-MAH 5；
MBS 3；
Oxidation inhibitor 2,921 0.3;
Nanometer SiO
22.
With above-mentioned raw materials put into stirrer for mixing evenly after, join melt blending in the forcing machine, be cut into pellet through plastic grain cutting machine again, to make the ABS modifying material.
Then above-mentioned ABS modifying material is made the test batten with injection moulding machine, and this batten is carried out the test of notched Izod impact strength, tensile strength, flexural strength and MI value, and ABS and the ABS (PA757) that makes behind the interpolation Nano filling made comparisons, test result is as shown in the table:
| ABS(PA757) | Nano-filled ABS | |
| Notched Izod impact strength (kJ/m 2) | 10.1 | 9.4 |
| Tensile strength (MPa) | 50.3 | 54.7 |
| Flexural strength (MPa) | 79.3 | 80.5 |
| MI(g/10min，260 ℃，2.16kg) | 8.8 | 14.4 |
Embodiment 2:
Earlier by the following raw material (representing) of getting with parts by weight:
ABS 85；
PP-g-MAH 6；
MBS 5；
Oxidation inhibitor 2,921 0.3;
Nanometer SiO
24.
With above-mentioned raw materials join stirrer for mixing evenly after, join melt blending in the forcing machine, be cut into pellet through plastic grain cutting machine again, to make the ABS modifying material.
Then above-mentioned ABS modifying material is made the test batten with injection moulding machine, and this batten is carried out the test of notched Izod impact strength, tensile strength, flexural strength and MI value, and ABS and the ABS (PA757) that makes behind the interpolation Nano filling made comparisons, test result is as shown in the table:
| ABS(PA757) | Nano-filled ABS | |
| Notched Izod impact strength (kJ/m 2) | 10.1 | 8.3 |
| Tensile strength (MPa) | 50.3 | 56.6 |
| Flexural strength (MPa) | 79.3 | 78.1 |
| MI(g/10min，260 ℃，2.16kg) | 8.8 | 19.7 |
Embodiment 3:
Earlier by the following raw material (representing) of getting with parts by weight:
ABS 75；
PP-g-MAH 10；
MBS 10；
Oxidation inhibitor 2,921 0.3;
Nanometer SiO
25.
With above-mentioned raw materials join stirrer for mixing evenly after, join melt blending in the forcing machine, be cut into pellet through plastic grain cutting machine again, to make the ABS modifying material.
Then above-mentioned ABS modifying material is made the test batten with injection moulding machine, and this batten is carried out the test of notched Izod impact strength, tensile strength, flexural strength and MI value, and ABS and the ABS (PA757) that makes behind the interpolation Nano filling made comparisons, test result is as shown in the table:
| ABS(PA757) | Nano-filled ABS | |
| Notched Izod impact strength (kJ/m 2) | 10.1 | 7.8 |
| Tensile strength (MPa) | 50.3 | 54.2 |
| Flexural strength (MPa) | 79.3 | 77.4 |
| MI(g/10min，260 ℃，2.16kg) | 8.8 | 23.1 |
Claims (8)
1. ABS modified formula, it comprises following component and content thereof:
ABS 75～90；
Compatilizer 5～10;
Toughner 3～10;
Oxidation inhibitor 0.1～0.3;
Nano filling 2～5.
2. ABS modified formula according to claim 1 is characterized in that described compatilizer can be PP-g-MAH, ABS-g-MAH.
3. ABS modified formula according to claim 1 is characterized in that described toughner can be MBS, SBS, SEBS.
4. ABS modified formula according to claim 1 is characterized in that described Nano filling can be SiO
2, CaCO
3
5. ABS modified formula according to claim 1 is characterized in that described oxidation inhibitor can be 2921.
6. according to any described ABS modified formula of claim 1 to 5, it is characterized in that its optimum formula is:
ABS 90；
PP-g-MAH 5；
MBS 3；
Oxidation inhibitor 2,921 0.3;
Nanometer SiO
22.
7. according to any described ABS modified formula of claim 1 to 5, it is characterized in that its optimization of C is:
ABS 85；
PP-g-MAH 6；
MBS 5；
Oxidation inhibitor 2,921 0.3;
Nanometer SiO
24.
8. according to any described ABS modified formula of claim 1 to 5, it is characterized in that its optimization of C is:
ABS 75；
PP-g-MAH 10；
MBS 10；
Oxidation inhibitor 2,921 0.3;
Nanometer SiO
25.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA200610122384XA CN101153105A (en) | 2006-09-25 | 2006-09-25 | ABS modified prescription |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA200610122384XA CN101153105A (en) | 2006-09-25 | 2006-09-25 | ABS modified prescription |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101153105A true CN101153105A (en) | 2008-04-02 |
Family
ID=39255000
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA200610122384XA Pending CN101153105A (en) | 2006-09-25 | 2006-09-25 | ABS modified prescription |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101153105A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101798434A (en) * | 2010-03-20 | 2010-08-11 | 东莞市华立实业股份有限公司 | Furniture ABS resin sealing strip |
| CN102675810A (en) * | 2012-05-11 | 2012-09-19 | 江苏安格特科技发展有限公司 | High-impact extrusion grade ABS (Acrylonitrile Butadiene Styrene) nanocomposite material |
| CN102675809A (en) * | 2012-04-10 | 2012-09-19 | 江苏启蓝新材料有限公司 | Extinction styrene copolymer composition and preparation method thereof |
| CN103333455A (en) * | 2013-07-19 | 2013-10-02 | 上海锦湖日丽塑料有限公司 | High-temperature creep resisting ABS resin composite and preparation method thereof |
| CN105694338A (en) * | 2016-03-14 | 2016-06-22 | 苏州莱特复合材料有限公司 | Preparation method of weather-resistant composite material for car bumpers |
| CN109135162A (en) * | 2018-08-28 | 2019-01-04 | 安徽江淮汽车集团股份有限公司 | Good ABS composite material of a kind of oil-resistant weather-resistant energy and preparation method thereof |
-
2006
- 2006-09-25 CN CNA200610122384XA patent/CN101153105A/en active Pending
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101798434A (en) * | 2010-03-20 | 2010-08-11 | 东莞市华立实业股份有限公司 | Furniture ABS resin sealing strip |
| CN101798434B (en) * | 2010-03-20 | 2011-09-14 | 东莞市华立实业股份有限公司 | Furniture ABS resin sealing strip |
| CN102675809A (en) * | 2012-04-10 | 2012-09-19 | 江苏启蓝新材料有限公司 | Extinction styrene copolymer composition and preparation method thereof |
| CN102675810A (en) * | 2012-05-11 | 2012-09-19 | 江苏安格特科技发展有限公司 | High-impact extrusion grade ABS (Acrylonitrile Butadiene Styrene) nanocomposite material |
| CN102675810B (en) * | 2012-05-11 | 2014-05-07 | 江苏安格特科技发展有限公司 | High-impact extrusion grade ABS (Acrylonitrile Butadiene Styrene) nanocomposite material |
| CN103333455A (en) * | 2013-07-19 | 2013-10-02 | 上海锦湖日丽塑料有限公司 | High-temperature creep resisting ABS resin composite and preparation method thereof |
| CN103333455B (en) * | 2013-07-19 | 2016-05-18 | 上海锦湖日丽塑料有限公司 | A kind of ABS resin composition and method of making the same of high temperature resistant creep |
| CN105694338A (en) * | 2016-03-14 | 2016-06-22 | 苏州莱特复合材料有限公司 | Preparation method of weather-resistant composite material for car bumpers |
| CN109135162A (en) * | 2018-08-28 | 2019-01-04 | 安徽江淮汽车集团股份有限公司 | Good ABS composite material of a kind of oil-resistant weather-resistant energy and preparation method thereof |
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Legal Events
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|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C12 | Rejection of a patent application after its publication | ||
| RJ01 | Rejection of invention patent application after publication |
Open date: 20080402 |