CN105713336A - High-performance electroplating ABS (acrylonitrile butadiene styrene) alloy material and preparation method thereof - Google Patents
High-performance electroplating ABS (acrylonitrile butadiene styrene) alloy material and preparation method thereof Download PDFInfo
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- CN105713336A CN105713336A CN201510996280.0A CN201510996280A CN105713336A CN 105713336 A CN105713336 A CN 105713336A CN 201510996280 A CN201510996280 A CN 201510996280A CN 105713336 A CN105713336 A CN 105713336A
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- styrene
- alloy material
- butadiene
- acrylonitrile
- performance
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/92—Measuring, controlling or regulating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/92704—Temperature
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/08—Polymer mixtures characterised by other features containing additives to improve the compatibility between two polymers
Abstract
The invention discloses a high-performance electroplating ABS (acrylonitrile butadiene styrene) alloy material and a preparation method thereof. The high-performance electroplating ABS alloy material is composed of, by weight, 65%-80% of acrylonitrile-butadiene-styrene copolymer, 10%-20% of styrene-acrylonitrile, 5%-10% of flexibilizer, 1%-5% of polarity modifier and 0.1%-1% of processing aid. The preparation method includes: weighing reaction materials according to the weight percentages; adding the materials into a high-speed mixer for high-speed mixing, feeding into a main feeder of an extruder, adding into a twin-screw extruder to perform primary pelletizing, subjecting extruded materials to water cooling and pelletizing, and drying pellets in a draught drying oven to obtain the high-performance electroplating ABS alloy material. The high-performance electroplating ABS alloy material is excellent in mechanical property, electroplating binding power, impact property and molding processability.
Description
Technical field
The invention belongs to chemical field, relate to a kind of alloy material, specifically a kind of high-performance plating ABS alloy material and preparation method thereof.
Background technology
Acrylonitrile-butadiene-styrene copolymer is by acrylonitrile, the terpolymer of butadiene and styrene composition, is called for short ABS.Plating ABS has beautiful outward appearance, good corrosion resistance and weatherability, simple adornment have evolved to the industrial circles such as the electronics of high request, bathroom, auto parts machinery.Along with the competition in market, the prescription of ABS plastic plated item is more and more higher, especially the binding force of cladding material in physical property measurement, and therefore more ABS plastic electroplates producer is that the adhesion ensured between plastic and electrodeposited coating adopts automatic electroplating production line operation.Briefly, B (butadiene) in ABS is chemically eroded by ABS plating exactly, product surface is made to present some loose pores, adhere to one layer of conductor (such as copper) again can conduct electricity, the mode referring again to metal plating subsequently is electroplated, at its plated surface last layer metallic film.But due to the impact on plastic coating adhesion of the plastic factor, cause that plated item qualification rate is too low.
It is said that in general, cause the reason of ABS plastic electrodeposited coating adhesion difference substantially to have 4 aspects:
(1) plastic substrate state is bad.
(2) injection molding parameter is not good enough, plastic stress concentration.
(3) pre-electroplating treatment is unreasonable.
(4) surface activity of adjacent coating is poor.
So it is significant to develop a kind of plating ABS material improving plastics and electrodeposited coating.
Summary of the invention
For above-mentioned technical problem of the prior art, the invention provides a kind of high-performance plating ABS alloy material and preparation method thereof, described this high-performance plating ABS alloy material and preparation method thereof solves the technical problem of ABS plastic electrodeposited coating adhesion of the prior art difference.
One high-performance of the present invention plating ABS alloy material, is made up of the component of following mass percent:
Wherein, described Acrylnitrile-Butadiene-Styrene is that emulsion method produces, and in described copolymer, the mass percent of described butadiene is 25-30% (such as ABSGP-22)；Described styrene-acrylonitrile is high flow stage, and in described styrene-acrylonitrile, its acrylonitrile content is 10～30wt%, and styrene-content is 70～90wt%；Described toughener is styrene butadiene thermoplasticelastomer, MMB methyl methacrylate butadiene styrene copolymer, polyester elastomer, polyolefin elastomer, or any one or the two or more combination in MBS, described polarity modifier is made up of polymer and the polyphenylene sulfide of substituted phenylethylene, wherein substituted phenylethylene is 2-methyl styrene, 4-butylstyrene, 2.5-disubstituted benzenes ethylene, α-methyl styrene, ethylene methacrylate (EMA), ethylene one ethyl propylene acid esters (EEA), or one or more the combination in ethylene monobutyl acrylate (EBA) copolymer.
Further, described processing aid is by any one in primary antioxidant, auxiliary antioxidant, in-lubricant or external lubricant or two or more combinations.
Described primary antioxidant is β-(3,5-di-tert-butyl-hydroxy phenyl) the positive octadecanol ester of propanoic acid, four [β-(3,5-di-tert-butyl-hydroxy phenyl) propanoic acid] pentaerythritol ester, double; two (2.4-di-tert-butyl-phenyl) tetramethylolmethane or 2,6-di-t-butyl-4-4 cresol；Described auxiliary antioxidant is the double; two stearic alcohol ester of three (2,4-di-tert-butyl-phenyl) phosphite ester, sulfo-three propanoic acid two lauryl or thio-2 acid.Described in-lubricant is E wax, calcium stearate or PE wax；Described external lubricant is silicone master batch or PETS.
The preparation method that present invention also offers above-mentioned a kind of high-performance plating ABS alloy material, comprises the steps:
1) Acrylnitrile-Butadiene-Styrene, styrene-acrylonitrile, toughener, polarity modifier, processing aid are weighed according to percentage by weight；
2) above-mentioned substance is added high mixer high-speed stirred 1～4 minute, join the main feeder of extruder, it is then added in double screw extruder and carries out basis pelletize, the distribution of this extruder temperature is as follows: be respectively as follows: 220 ± 10 DEG C, 240 ± 10 DEG C, 240 ± 10 DEG C, 240 ± 10 DEG C, 230 ± 10 DEG C, 230 ± 10 DEG C, 230 ± 10 DEG C, 220 ± 10 DEG C, 220 ± 10 DEG C by feed zone to head, die head: 240 ± 10 DEG C, through water-cooled, pelletizing after material extrusion, pellet dries at air dry oven, it is thus achieved that high-performance plating ABS alloy material.
The present invention compares with prior art, and its technological progress is significant.The present invention is that a kind of height is heat-resisting, high flowing, the material of plating ABS alloy material, has the mechanical performance of excellence, well electroplates the impact property of adhesion, excellence and good moulding processability.Can be applicable to the design of automobile interior exterior decorations, including heat dissipation grid, door handle, car mark and instrument board panel etc..
Detailed description of the invention
Below in conjunction with example, the invention will be further described.
Selecting ABSGP-22 (acrylonitrile-butadiene-styrene copolymer) as major ingredient, its butadiene phase content is higher, is suitable for plating.
Select AS117C (acrylonitritrile-styrene resin), improve the mobility of material, be beneficial to dispersion.
Select MBS-2620 (acrylate-butadiene-styrol copolymer), be possible not only to improve the butadiene phase of whole material, it is also possible to as compatilizer, improve the combination property of whole material.
Add polarity modifier and can properly increase the polarity improving material, strengthen electroplating effect and improve the thermal deformation of material.
Embodiment 1--5
ABS resin, fire retardant, fire retarding synergist and other various processing aids are added high mixer high-speed stirred 2 minutes, joins the main feeder of extruder, be then added in double screw extruder and carry out basis pelletize.The distribution of this extruder temperature is as follows: be respectively as follows: 220 DEG C, 240 DEG C, 240 DEG C, 240 DEG C, 230 DEG C, 230 DEG C, 230 DEG C, 220 DEG C, 220 DEG C by feed zone to head, die head: 240 DEG C, through water-cooled, pelletizing after material extrusion, then packs.Pellet is at air dry oven, and 90 DEG C dry 4 hours, then prepared test bars by injection machine.
Each raw material weight number is in Table 1.
The raw material weight percent proportioning of table 1 embodiment 1～5
Composition properties test result in table 2 embodiment and comparative example
Along with the increase of polarity modifier, the impact of material first improves and reduces afterwards, and Vicat softening point improves, and plating qualification rate also improves.The addition of polarity modifier, also can produce certain impact to the mobility of material, therefore, it has been found that when polarity modifier addition at 5 parts time, reached the optimum of material property and electroplating effect.
Claims (4)
1. a high-performance plating ABS alloy material, it is characterised in that be made up of the component of following mass percent:
Acrylnitrile-Butadiene-Styrene 65% ~ 80%；
Styrene-acrylonitrile 10% ~ 20%；
Toughener 5% ~ 10%；
Polarity modifier 1% ~ 5%；
Processing aid 0.1% ~ 1%；
Wherein, described Acrylnitrile-Butadiene-Styrene is that emulsion method produces, and in described copolymer, the mass percent of described butadiene is 25-30%；In described styrene-acrylonitrile, its acrylonitrile content is 10～30wt%, and styrene-content is 70～90wt%；Described toughener is any one or two or more combination in styrene butadiene thermoplasticelastomer, MBS terpolymer, polyester elastomer, polyolefin elastomer or MBS；Described polarity modifier is made up of polymer and the polyphenylene sulfide of substituted phenylethylene, and wherein substituted phenylethylene is one or more the combination in 2-methyl styrene, 4-butylstyrene, 2.5-disubstituted benzenes ethylene, α-methyl styrene, ethylene-methyl acrylate, ethylene-ethyl acrylate or ethylene-butylacrylic acid resin copolymer.
2. a kind of high-performance plating ABS alloy material according to claim 1, it is characterised in that: described processing aid is by any one in primary antioxidant, auxiliary antioxidant, in-lubricant or external lubricant or two or more combinations.
3. a kind of high-performance plating ABS alloy material according to claim 6, it is characterized in that: described primary antioxidant is β-(3,5-di-tert-butyl-hydroxy phenyl) the positive octadecanol ester of propanoic acid, four [β-(3,5-di-tert-butyl-hydroxy phenyl) propanoic acid] pentaerythritol ester, double; two (2.4-di-tert-butyl-phenyl) tetramethylolmethane or 2,6-di-t-butyl-4-4 cresol；Described auxiliary antioxidant is the double; two stearic alcohol ester of three (2,4-di-tert-butyl-phenyl) phosphite ester, sulfo-three propanoic acid two lauryl or thio-2 acid；Described in-lubricant is E wax, calcium stearate or PE wax；Described external lubricant is silicone master batch or PETS.
4. the preparation method of a kind of high-performance plating ABS alloy material described in claim 1, it is characterised in that: comprise the steps:
Acrylnitrile-Butadiene-Styrene, styrene-acrylonitrile, toughener, polarity modifier, processing aid is weighed according to percentage by weight；
Above-mentioned substance is added high mixer high-speed stirred 1 ~ 4 minute, join the main feeder of extruder, it is then added in double screw extruder and carries out basis pelletize, the distribution of this extruder temperature is as follows: be respectively as follows: 220 ± 10 DEG C, 240 ± 10 DEG C, 240 ± 10 DEG C, 240 ± 10 DEG C, 230 ± 10 DEG C, 230 ± 10 DEG C, 230 ± 10 DEG C, 220 ± 10 DEG C, 220 ± 10 DEG C by feed zone to head, die head: 240 ± 10 DEG C, through water-cooled, pelletizing after material extrusion, pellet dries at air dry oven, it is thus achieved that high-performance plating ABS alloy material.
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| CN201510996280.0A CN105713336A (en) | 2015-12-25 | 2015-12-25 | High-performance electroplating ABS (acrylonitrile butadiene styrene) alloy material and preparation method thereof |
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| CN201510996280.0A CN105713336A (en) | 2015-12-25 | 2015-12-25 | High-performance electroplating ABS (acrylonitrile butadiene styrene) alloy material and preparation method thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110643121A (en) * | 2019-10-31 | 2020-01-03 | 浩清先进新材料(嘉兴)有限公司 | High-heat-resistance metal silver spraying-free ASA material and preparation method thereof |
| CN111073316A (en) * | 2019-04-18 | 2020-04-28 | 重庆市智翔铺道技术工程有限公司 | Polymer alloy for paving steel bridge deck and preparation method thereof |
| WO2021078556A1 (en) * | 2019-10-21 | 2021-04-29 | Sabic Global Technologies B.V. | Polymeric composition for use in electroless plating, method of elecroless plating, and polymeric article made by electroless plating |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101768320A (en) * | 2008-12-31 | 2010-07-07 | 深圳市科聚新材料有限公司 | Heat-resisting ABS modified material and preparation method thereof for plating |
| CN103059547A (en) * | 2013-01-30 | 2013-04-24 | 上海俊尔新材料有限公司 | Electroplating PC/ABS (polycarbonate/acrylonitrile-butadiene-styrene) alloy material and preparation method thereof |
| US20130203909A1 (en) * | 2012-02-03 | 2013-08-08 | Amit S. Kulkarni | Polycarbonate blends having improved electroplate adhesion |
| CN103342874A (en) * | 2013-07-19 | 2013-10-09 | 上海锦湖日丽塑料有限公司 | Heat-resisting ABS (Acrylonitrile-Butadiene-Styrene) resin applicable to electroplating and preparation method thereof |
| CN104004343A (en) * | 2009-08-10 | 2014-08-27 | 联合碳化化学及塑料技术有限责任公司 | Thermoplastic elastomer compositions comprising intumescent flame retardants and non-phosphorous-based flame retardant synergists |
-
2015
- 2015-12-25 CN CN201510996280.0A patent/CN105713336A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101768320A (en) * | 2008-12-31 | 2010-07-07 | 深圳市科聚新材料有限公司 | Heat-resisting ABS modified material and preparation method thereof for plating |
| CN104004343A (en) * | 2009-08-10 | 2014-08-27 | 联合碳化化学及塑料技术有限责任公司 | Thermoplastic elastomer compositions comprising intumescent flame retardants and non-phosphorous-based flame retardant synergists |
| US20130203909A1 (en) * | 2012-02-03 | 2013-08-08 | Amit S. Kulkarni | Polycarbonate blends having improved electroplate adhesion |
| CN103059547A (en) * | 2013-01-30 | 2013-04-24 | 上海俊尔新材料有限公司 | Electroplating PC/ABS (polycarbonate/acrylonitrile-butadiene-styrene) alloy material and preparation method thereof |
| CN103342874A (en) * | 2013-07-19 | 2013-10-09 | 上海锦湖日丽塑料有限公司 | Heat-resisting ABS (Acrylonitrile-Butadiene-Styrene) resin applicable to electroplating and preparation method thereof |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111073316A (en) * | 2019-04-18 | 2020-04-28 | 重庆市智翔铺道技术工程有限公司 | Polymer alloy for paving steel bridge deck and preparation method thereof |
| WO2021078556A1 (en) * | 2019-10-21 | 2021-04-29 | Sabic Global Technologies B.V. | Polymeric composition for use in electroless plating, method of elecroless plating, and polymeric article made by electroless plating |
| CN114555701A (en) * | 2019-10-21 | 2022-05-27 | Sabic环球技术有限责任公司 | Polymer composition for use in electroless plating, method of electroless plating and polymer article made by electroless plating |
| CN110643121A (en) * | 2019-10-31 | 2020-01-03 | 浩清先进新材料(嘉兴)有限公司 | High-heat-resistance metal silver spraying-free ASA material and preparation method thereof |
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Application publication date: 20160629 |