CN108115872A - A kind of preparation method of lasting lasting household rubber gloves - Google Patents
A kind of preparation method of lasting lasting household rubber gloves Download PDFInfo
- Publication number
- CN108115872A CN108115872A CN201711411693.3A CN201711411693A CN108115872A CN 108115872 A CN108115872 A CN 108115872A CN 201711411693 A CN201711411693 A CN 201711411693A CN 108115872 A CN108115872 A CN 108115872A
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- Prior art keywords
- lasting
- gloves
- fingerprint
- preparation
- glued membrane
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C41/00—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor
- B29C41/003—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor characterised by the choice of material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C41/00—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor
- B29C41/02—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor for making articles of definite length, i.e. discrete articles
- B29C41/14—Dipping a core
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L21/00—Compositions of unspecified rubbers
- C08L21/02—Latex
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2031/00—Other particular articles
- B29L2031/48—Wearing apparel
- B29L2031/4842—Outerwear
- B29L2031/4864—Gloves
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Gloves (AREA)
Abstract
The present invention relates to a kind of preparation methods of lasting lasting household rubber gloves, include the following steps：Prepare the vulcanized latex slurry containing flavouring agent, prepare villus rubber cement material, clean fingerprint, and the fingerprint dipping calcium chloride solution after cleaning is handled, drying process is carried out after fingerprint is impregnated coagulator, fingerprint is impregnated into the vulcanized latex slurry containing flavouring agent, gloves glued membrane is carried out to leaching and crimping processing successively, will be dry after gloves glued membrane dipping villus rubber cement material, gloves glued membrane is carried out to crimping, the demoulding, water vulcanization, surface treatment, drying process successively.The preparation method of the lasting lasting household rubber gloves of the present invention, using the oiliness flavouring agent that proper ratio is added in the filler-calcium carbonate of vulcanized latex slurry so that fragrance agent molecule combines more stable in film structure, realizes the effect of lasting lasting.
Description
Technical field
The present invention relates to a kind of manufacturing method of rubber gloves, especially a kind of preparation of lasting lasting household rubber gloves
Method.
Background technology
At present, household rubber gloves are widely used in daily life, are mainly used for isolating pollution, protection pair
Hand.Rubber gloves main raw material(s) is natural emulsion, and natural emulsion is preserving and needing various auxiliary agents to be added in process,
So that rubber gloves carries one rubber taste or auxiliary agent taste, " the smelly glue taste " being exactly commonly called as.With the development in market, in order to full
The sufficient more individual character words demands of people, partial glove manufacturer develop odor type gloves.One kind is by entering packaging in gloves
The method of essence fragrant on gloves before bag；Another is that water-soluble flavouring agent is directly added in latex formulations, due to glue
Breast is water-based system, and water-soluble flavouring agent can be directly appended in latex formulations.
Existing two methods can make gloves fragrant, but the equal existing defects of this two methods, i.e., the method for fragrant essence
So that fragrance is uneven, and packaging bag open after fragrance volatilize quickly disappearance；Although water-soluble flavouring agent is than more uniform point
Film surface is dispersed in, but due to being water-soluble, processes the water sulfurating stage in later stage in gloves and post-processing stages again can be a large amount of
Flavouring agent is lost in, fragrance is not lasting.Therefore, it is necessary to develop a kind of preparation method of lasting lasting household rubber gloves.
The content of the invention
For overcome the deficiencies in the prior art, the present invention provides a kind of lasting is lasting, the uniform lasting lasting family expenses of fragrance
The preparation method of rubber gloves.
A kind of preparation method of lasting lasting household rubber gloves, which is characterized in that it includes the following steps：
Step S1：Prepare the vulcanized latex slurry containing flavouring agent；
Step S2：Prepare villus rubber cement material；
Step S3：Fingerprint is cleaned, and the fingerprint dipping calcium chloride solution after cleaning is handled；
Step S4：Drying process is carried out after fingerprint is impregnated coagulator；
Step S5：Fingerprint is impregnated into the vulcanized latex slurry containing flavouring agent so that gloves glued membrane is formed on fingerprint；
Step S6：Gloves glued membrane is carried out to leaching and crimping processing successively；
Step S7：It will be dry after gloves glued membrane dipping villus rubber cement material；
Step S8：Gloves glued membrane is carried out to crimping, the demoulding, water vulcanization, surface treatment, drying process successively.
Further, the vulcanized latex slurry containing flavouring agent in the step S1 is by raw latex 100.00g, mixing point
2.0~3.0g of granular media, 10.0~20.0g of flavoring calcium carbonate, 2.0~3.0g of titanium dioxide, 0.03~0.06g of pigment compositions.
Further, calculated with butt quality, the hybrid dispersions are by vulcanizing agent 15.00g, zinc oxide 7.50g, promotion
Agent 12.00g, antioxidant 5.25g, diffusant 1.20g, potassium hydroxide 0.80g, the ammonium hydroxide 0.50g and soft water of 18% concentration
100g is formed；It is calculated with butt quality, the flavoring calcium carbonate is by 35~40g of calcium carbonate, 2.0~3.0g of casein, diffusant 1.0
~3.0g, 0.1~0.2g of potassium hydroxide, oiliness essence (liquid) 0.5~3.5g and soft water 100g composition.
Further, the villus rubber cement material in the step S2 by 70.00~100.00g of soft water, potassium hydroxide 0.30~
0.60g, titanium dioxide 1.25g, 75.00~85.00g of white family's glue, 25.00~35.00g of villus and methylcellulose 1.50~
2.50g composition.Wherein, white family's glue is by raw latex 100g, 0~0.50g of casein, 0~0.50g of potassium hydroxide and hybrid dispersions
3.0g composition.
Further, first fingerprint is immersed in hydrochloric acid solution in the step S3 and cleaned, then hand is rinsed with clear water
Mould finally cleans fingerprint in alkaline solution；The concentration of the calcium chloride solution is 1~15%.
Further, fingerprint is immersed in the coagulator that concentration is 15~35% in the step S4, wherein, coagulator
It is made of 20~25g of calcium chloride, 0~1.5g of wetting agent and 73.5~80.0g of water.
Further, the temperature of the vulcanized latex slurry containing flavouring agent is 25~50 DEG C in the step S5.
Further, gloves glued membrane carries out leaching under circulating water in the step S6, and water temperature is 30~100 DEG C.
Further, the temperature of villus rubber cement material is 15~50 DEG C in the step S7.
Further, curing temperature is 85~95 DEG C in the step S8.
Beneficial effects of the present invention：
The preparation method of the lasting lasting household rubber gloves of the present invention is utilized in the filler carbonic acid of vulcanized latex slurry
The oiliness flavouring agent of proper ratio is added in calcium, oiliness flavouring agent is adsorbed using the cavernous structure of calcium carbonate, then with glue
Newborn molecule is combined together by chemical reaction, and fragrance agent molecule combines more stable in film structure.As gloves make
Progressively oxidation and the aging in, the rubber molecule on surface are lost in, and the molecule of calcium carbonate sprays surface, can still smell perfume (or spice)
Taste achievees the effect that lasting lasting, and aroma burst is uniform.
Specific embodiment
Technical scheme is further elaborated With reference to embodiment.
A kind of preparation method of lasting lasting household rubber gloves of the present invention, is as follows：Step S1：Preparation contains
Savory dose of vulcanized latex slurry.
Raw latex, hybrid dispersions, flavoring calcium carbonate, titanium dioxide, pigment are sequentially added in soft water, is stirred
Vulcanize 10~60 minutes at a temperature of 35~60 DEG C afterwards.The butt quality of more than raw material matches：Raw latex 100.00g, mix
Close 2.0~3.0g of dispersion, 10.0~20.0g of flavoring calcium carbonate, 2.0~3.0g of titanium dioxide, 0.03~0.06g of pigment.
Wherein, calculated with butt quality, hybrid dispersions are by vulcanizing agent 15.00g, zinc oxide 7.50g, accelerating agent
12.00g, antioxidant 5.25g, diffusant 1.20g, potassium hydroxide 0.80g, the ammonium hydroxide 0.50g of 18% concentration and soft water composition.
Calculated with butt quality, flavoring calcium carbonate by 35~40g of calcium carbonate, 2.0~3.0g of casein, diffusant 1.0~
3.0g, 0.1~0.2g of potassium hydroxide, oiliness essence (liquid) 0.5~3.5g and soft water composition.
Step S2：Prepare villus rubber cement material.It in turn includes the following steps：
(1) 0.01~0.50g of casein, 0~0.50g of potassium hydroxide are sequentially added in the raw latex of 100g, mixes and disperses
White family's glue (glue of villus) is made in body 3.0g after stirring.
(2) 0.30~0.60g of potassium hydroxide, titanium dioxide 1.25g, Bai Jia are sequentially added in the soft water of 70.00~100.00g
Glue (glue of villus) 75.00~85.00g, 25.00~35.00g of villus, 1.50~2.50g of methylcellulose, are sufficiently stirred
Villus rubber cement material is made after uniformly.
Step S3：Fingerprint is cleaned, and the fingerprint dipping calcium chloride solution after cleaning is handled.It includes following step successively
Suddenly：
(1) first fingerprint is immersed in hydrochloric acid solution and cleaned, then fingerprint is rinsed with clear water, finally in alkaline solution
Clean fingerprint.
(2) calcium chloride solution of the fingerprint after cleaning in 1~15% concentration is impregnated, and the temperature of calcium chloride solution is not low
In 40 DEG C.
Step S4：Drying process is carried out after fingerprint is impregnated coagulator.It in turn includes the following steps：
(1) fingerprint is immersed in the coagulator that concentration is 15~35%, coagulator temperature is 28~75 DEG C.Wherein, coagulate
Gu agent is made of 20~25g of calcium chloride, 0.01~1.5g of wetting agent and 73.5~80.0g of water.
(2) by impregnate coagulator after fingerprint processing is dried at a temperature of 60 DEG C or more, with coagulator parch for
It is accurate.
Step S5：Fingerprint is impregnated into the vulcanized latex slurry containing flavouring agent so that gloves glued membrane is formed on fingerprint
It will be in fingerprint dipping in step sl the vulcanized latex slurry obtained containing flavouring agent so that be formed on fingerprint
Gloves glued membrane, wherein the temperature of the vulcanized latex slurry containing flavouring agent is controlled at 25~50 DEG C.
Step S6：Gloves glued membrane on fingerprint is subjected to leaching and crimping processing successively.It in turn includes the following steps：
(1) gloves glued membrane is subjected to leaching with circulating water, water temperature is controlled at 30~100 DEG C；
(2) the gloves glued membrane after leaching is subjected to crimping processing again.
Step S7：Gloves glued membrane is impregnated into villus rubber cement material and drying process.It in turn includes the following steps：
(1) fingerprint that will be covered with gloves glued membrane is impregnated in villus rubber cement material obtained in step s 2, so that gloves
The temperature of uniform fold villous on glued membrane, wherein villus rubber cement material is controlled at 15~50 DEG C.
(2) the gloves glued membrane that will be covered with villus is dried in 60 DEG C or more of temperature, wherein drying is in hot wind
It is operated under the circulatory system.
Step S8：Gloves glued membrane is carried out to crimping, the demoulding, water vulcanization, surface treatment, drying process successively.It is wrapped successively
Include following steps：
(1) the gloves glued membrane that will be covered with villus carries out crimping, demoulding processing successively；
(2) the covering gloves glued membrane villous after the demoulding is subjected to water vulcanizing treatment, wherein curing temperature control is 85
~95 DEG C, vulcanization time is 40~60 minutes；
(3) the gloves glued membrane that first will be covered with villus impregnates 10~20 minutes in sodium hypochlorite handles treatment fluid, then uses
The hypo solution that concentration is 1~4% carries out reduction treatment, finally will be covered with the gloves glued membrane of villus at 40~60 DEG C
Hot water in impregnate 15~20 minutes.Wherein, sodium hypochlorite processing treatment fluid by 4~6kg of sodium hypochlorite, hydrochloric acid content 1.5~
2.5kg, 800~1200kg of water are formed；
(4) the gloves glued membrane that will be covered with villus is 20~120 minutes dry at a temperature of no more than 120 DEG C.
The foregoing is merely the better embodiments of the present invention, and the invention is not limited in the above embodiments, are implementing
In the process there may be local small structural modification, if the various changes or modifications of the present invention are not departed from the essence of the present invention
God and scope, and belong within the scope of the claim and equivalent technologies of the present invention, then the present invention is also intended to comprising these changes
And modification.
Claims (10)
1. a kind of preparation method of lasting lasting household rubber gloves, it is characterised in that include the following steps：
Step S1：Prepare the vulcanized latex slurry containing flavouring agent；
Step S2：Prepare villus rubber cement material；
Step S3：Fingerprint is cleaned, and the fingerprint dipping calcium chloride solution after cleaning is handled；
Step S4：Fingerprint is impregnated into coagulator, and carries out drying process；
Step S5：Fingerprint is impregnated into the vulcanized latex slurry containing flavouring agent so that gloves glued membrane is formed on fingerprint；
Step S6：Gloves glued membrane is carried out to leaching and crimping processing successively；
Step S7：Gloves glued membrane is impregnated into villus rubber cement material, and carries out drying process；
Step S8：Gloves glued membrane is carried out to crimping, the demoulding, water vulcanization, surface treatment, drying process successively.
A kind of 2. preparation method of lasting lasting household rubber gloves as described in claim 1, which is characterized in that the step
The vulcanized latex slurry containing flavouring agent in S1 is by raw latex 100.00g, 2.0~3.0g of hybrid dispersions, flavoring calcium carbonate
10.0~20.0g, 2.0~3.0g of titanium dioxide, 0.03~0.06g of pigment compositions.
3. a kind of preparation method of lasting lasting household rubber gloves as claimed in claim 2, which is characterized in that with butt matter
Amount calculates, and the hybrid dispersions are by vulcanizing agent 15.00g, zinc oxide 7.50g, accelerating agent 12.00g, antioxidant 5.25g, expansion
Powder 1.20g, potassium hydroxide 0.80g, the ammonium hydroxide 0.50g of 18% concentration and soft water 100g compositions；It is calculated with butt quality, it is described
Flavoring calcium carbonate is by 35~40g of calcium carbonate, 2.0~3.0g of casein, 1.0~3.0g of diffusant, 0.1~0.2g of potassium hydroxide, oil
Property essence (liquid) 0.5~3.5g and soft water 100g composition.
A kind of 4. preparation method of lasting lasting household rubber gloves as described in claim 1, which is characterized in that the step
Villus rubber cement material in S2 is by 70.00~100.00g of soft water, 0.30~0.60g of potassium hydroxide, titanium dioxide 1.25g, white family's glue
75.00~85.00g, 25.00~35.00g of villus and 1.50~2.50g of methylcellulose compositions；Wherein, white family's glue is by raw rubber
Newborn 100g, 0~0.50g of casein, 0.01~0.50g of potassium hydroxide and hybrid dispersions 3.0g compositions.
A kind of 5. preparation method of lasting lasting household rubber gloves as described in claim 1, which is characterized in that the step
First fingerprint is immersed in hydrochloric acid solution in S3 and is cleaned, then fingerprint is rinsed with clear water, hand is finally cleaned in alkaline solution
Mould；The concentration of the calcium chloride solution is 1~15%.
A kind of 6. preparation method of lasting lasting household rubber gloves as described in claim 1, which is characterized in that the step
Fingerprint is immersed in the coagulator that concentration is 15~35% in S4, wherein, coagulator is by 20~25g of calcium chloride, wetting agent
0.01~1.5g and 73.5~80.0g of water compositions.
A kind of 7. preparation method of lasting lasting household rubber gloves as described in claim 1, which is characterized in that the step
The temperature of the vulcanized latex slurry containing flavouring agent is 25~50 DEG C in S5.
A kind of 8. preparation method of lasting lasting household rubber gloves as described in claim 1, which is characterized in that the step
Gloves glued membrane carries out leaching under circulating water in S6, and water temperature is 30~100 DEG C.
A kind of 9. preparation method of lasting lasting household rubber gloves as described in claim 1, which is characterized in that the step
The temperature of villus rubber cement material is 15~50 DEG C in S7.
A kind of 10. preparation method of lasting lasting household rubber gloves as described in claim 1, which is characterized in that the step
Curing temperature is 85~95 DEG C in rapid S8.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711411693.3A CN108115872A (en) | 2017-12-23 | 2017-12-23 | A kind of preparation method of lasting lasting household rubber gloves |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711411693.3A CN108115872A (en) | 2017-12-23 | 2017-12-23 | A kind of preparation method of lasting lasting household rubber gloves |
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| Publication Number | Publication Date |
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| CN108115872A true CN108115872A (en) | 2018-06-05 |
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ID=62231428
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711411693.3A Pending CN108115872A (en) | 2017-12-23 | 2017-12-23 | A kind of preparation method of lasting lasting household rubber gloves |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1903545A (en) * | 2006-08-03 | 2007-01-31 | 天津市格林科特高分子材料技术有限公司 | Method for producing functional gloves made of nitrile butadiene rubber |
| CN101920541A (en) * | 2010-08-03 | 2010-12-22 | 邓琳 | Production method of rubber gloves dipped in cotton velvet |
| CN106514918A (en) * | 2016-10-27 | 2017-03-22 | 南京润京乳胶制品有限公司 | Production method of latex gloves |
| CN106995539A (en) * | 2017-04-17 | 2017-08-01 | 中国热带农业科学院农产品加工研究所 | Distribute latex product of fragrance and preparation method thereof |
-
2017
- 2017-12-23 CN CN201711411693.3A patent/CN108115872A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1903545A (en) * | 2006-08-03 | 2007-01-31 | 天津市格林科特高分子材料技术有限公司 | Method for producing functional gloves made of nitrile butadiene rubber |
| CN101920541A (en) * | 2010-08-03 | 2010-12-22 | 邓琳 | Production method of rubber gloves dipped in cotton velvet |
| CN106514918A (en) * | 2016-10-27 | 2017-03-22 | 南京润京乳胶制品有限公司 | Production method of latex gloves |
| CN106995539A (en) * | 2017-04-17 | 2017-08-01 | 中国热带农业科学院农产品加工研究所 | Distribute latex product of fragrance and preparation method thereof |
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Application publication date: 20180605 |
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