CN108114967A - A kind of method that environmental protective soap and sustained release fertilizer are produced using kitchen garbage - Google Patents

A kind of method that environmental protective soap and sustained release fertilizer are produced using kitchen garbage Download PDF

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Publication number
CN108114967A
CN108114967A CN201711388261.5A CN201711388261A CN108114967A CN 108114967 A CN108114967 A CN 108114967A CN 201711388261 A CN201711388261 A CN 201711388261A CN 108114967 A CN108114967 A CN 108114967A
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China
Prior art keywords
sustained release
soap
environmental protective
fertilizer
kitchen garbage
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Pending
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CN201711388261.5A
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Chinese (zh)
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吴豪
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Individual
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Priority to CN201711388261.5A priority Critical patent/CN108114967A/en
Publication of CN108114967A publication Critical patent/CN108114967A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09BDISPOSAL OF SOLID WASTE
    • B09B3/00Destroying solid waste or transforming solid waste into something useful or harmless
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05BPHOSPHATIC FERTILISERS
    • C05B7/00Fertilisers based essentially on alkali or ammonium orthophosphates
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05FORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
    • C05F17/00Preparation of fertilisers characterised by biological or biochemical treatment steps, e.g. composting or fermentation
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/80Soil conditioners
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00Compositions of detergents based essentially on soap
    • C11D9/02Compositions of detergents based essentially on soap on alkali or ammonium soaps
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00Compositions of detergents based essentially on soap
    • C11D9/04Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
    • C11D9/06Inorganic compounds
    • C11D9/08Water-soluble compounds
    • C11D9/10Salts
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00Compositions of detergents based essentially on soap
    • C11D9/04Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
    • C11D9/22Organic compounds, e.g. vitamins
    • C11D9/225Polymers
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00Compositions of detergents based essentially on soap
    • C11D9/04Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
    • C11D9/22Organic compounds, e.g. vitamins
    • C11D9/26Organic compounds, e.g. vitamins containing oxygen
    • C11D9/262Organic compounds, e.g. vitamins containing oxygen containing carbohydrates
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00Compositions of detergents based essentially on soap
    • C11D9/04Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
    • C11D9/42Per-compounds
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/40Bio-organic fraction processing; Production of fertilisers from the organic fraction of waste or refuse

Abstract

The present invention discloses a kind of method that environmental protective soap and sustained release fertilizer are produced using kitchen garbage, comprises the following steps:Step 1:Separation of solid and liquid, grease layering;Step 2:Decoloration;Step 3:Add lye, saponification;Step 4:At 40 50 DEG C, soap glue with curing agent, adhesion agent is uniformly mixed, precipitates, solidify, suppress, dry, that is, the environmental protective soap is made;Step 5:Comminuted solids residue and municipal refuse, plant ash;Step 6:1 3%YM bacterium and 11 15% sustained release agent are added in into fertilizer substrate, is fermented 46 days, that is, the sustained release fertilizer is made.The sustained release agent is made of sub- two urea of isobutyl, dicyandiamide, cyanogen elder brother and ammonium polyphosphate.The present invention realizes changing food waste into resources, high efficiency, energy-saving regeneration, produces that environmental protective soap emulsifying capacity is strong, clean effect is good, and it can be that plant be provided for a long term nutrient to produce sustained release fertilizer, and gas permeability and retention ability are good.

Description

A kind of method that environmental protective soap and sustained release fertilizer are produced using kitchen garbage
Technical field
The present invention relates to kitchen garbage processing technology fields, and in particular to it is a kind of using kitchen garbage production environmental protective soap and The method of sustained release fertilizer.
Background technology
Kitchen waste compost technology is a kind of more commonly used processing mode, but containing substantial amounts of useless in kitchen garbage Oil easily forms coating on soil particle surface, and the hydrophobic effect for causing soil is stronger, and poor air permeability causes root system of plant to rot, In the prior art, the means of separation of solid and liquid are often taken, the waste oil in kitchen garbage is removed, but waste oil is not made further to add Work utilizes, and causes the wasting of resources, in addition, it is not lasting using the fertilizer fertility that kitchen garbage produces, in a short time, it can release a large amount of Fertility and heat easily cause and burn root phenomenon.
The patent of Application No. CN201310545970.5 isolates the organic matter in kitchen garbage using classification, and Fermentation process is carried out to it, prepares liquid state organic fertilizer, this method is easy to operate, and flow is less, but isolates organic Containing substantial amounts of waste oil in object, microorganism is difficult to decompose using grease, and grease coating causes plant difficult in soil or plant root To absorb nutrient and butt rot problem.The patent of Application No. CN201410419088.0 using the means of separation of solid and liquid, makes Kitchen garbage is fully used, and the organic fertilizer energy water conservation produced is breathed freely, and with certain slow releasing function, but should Method equipment cost is high, it is difficult to realize large-scale production and application.It is of the invention efficiently to utilize kitchen garbage, produce environmental protective soap not Easily softening, the foam that dirt-removing power is strong, fine and smooth with abundant, make waste cooking oil realize recycling, turn waste into wealth, and produce Go out sustained release fertilizer and be easy to plant absorption utilization, fertility can be discharged steadily in the long term.
The content of the invention
In view of the deficiencies of the prior art, it is an object of the invention to provide a kind of environment-friendlyfertilizer fertilizer is produced using kitchen garbage The method of soap and sustained release fertilizer.
Technical scheme is summarized as follows:
A kind of method that environmental protective soap and sustained release fertilizer are produced using kitchen garbage, is comprised the following steps:
Step 1:Heat kitchen garbage to 100-110 DEG C, be stirred continuously to bubble-free generate when, kitchen is obtained by filtration and gives up Oil and solid residue add in the dense H of 5-10% into kitchen waste oil2SO4With 20-30% surfactants, react complete to oil, water layer When fully separating, water layer liquid is removed, is made and slightly carries grease;
Step 2:In the thick H for carrying addition 3-4% in grease of step 12O2With the atlapulgite of 3.5-6.5%, 60-70 20-30min is stirred at DEG C, obtains decoloration grease;
Step 3:Lye is added in decoloration grease into step 2, stirs saponification 2-3h, until PH stablizes in 7.5-7.8, The NaCl of 10-20% is added, obtains soap glue;
Step 4:At 40-50 DEG C, the soap glue in step 3 and 0.5-2% curing agents, 13-17% adhesion agents are uniformly mixed It closes, after staticly settling 1-2 days, solidification, compacting, dry, i.e., the obtained environmental protective soap;
Step 5:According to (1.5-2.5):(1-2):The weight ratio of (0.8-1.2) is residual by the solid after being filtered in step 1 Slag is uniformly mixed with municipal refuse, plant ash, crushed 30-80 mesh sieves, obtains fertilizer substrate;
Step 6:1-3%YM bacterium and the sustained release agent of 11-15% are added in fertilizer substrate into step 5, is stirred evenly, It treats that substrate temperature reaches 80-90 DEG C, carries out turning over fertilizer, ferment 4-6 days, that is, the sustained release fertilizer is made.
Wherein, the sustained release agent in parts by weight, including following components:
Preferably, dense H in step 12SO4Mass fraction is 75-85%.
Preferably, surfactant includes neopelex, sodium hexadecyl sulfate and fat in step 1 The one or more of alcohol polyethenoxy ether sodium sulfate.
Preferably, lye includes NaOH, Na in step 32CO3With the one or more of KOH.
Preferably, curing agent includes peroxide human relations methyl ethyl ketone and the one or more of peroxidating ring the sixth of the twelve Earthly Branches ketone in step 4.
Preferably, adhesion agent includes polyacrylic acid, methyl hydroxyethylcellulose and association type polyurethane in step 4 It is one or more.
Preferably, municipal refuse includes the one or more of dead leaf, pericarp and waste paper in step 5.
Beneficial effects of the present invention
(1) present invention reduces the viscosity of waste oil in kitchen garbage by the way of high-temperature heating, improves separation of solid and liquid journey Degree, is preferably minimized the fat content in sustained release fertilizer, and high temperature also makes useless water content in oil and penetrating odor volatilize away, makes Environmental protective soap is more easy to condensation shaping, free from extraneous odour;
(2) dense H in the present invention2SO4It can make phosphatide and its derivative carbonization, precipitation in waste oil, and remove what is generated in reaction Moisture, purifying prepare the higher fatty acids needed for environmental protective soap;
(3) curing agent and adhesion agent can make sodium soap molecule combination closer in the present invention, and soap is made to be not easy deliquescence, is made Soap quality is more strong, improves the service life of soap;
(4) YM bacterium can decompose rapidly rapidly protein in kitchen garbage under aerobic conditions in the present invention, shorten hair The ferment time and fertilizer that generates is without apparent corrupt acid smell, in addition, YM bacterium are preferential bacillus, can inhibit in soil nigrospora and The growth and breeding of other harmful levels of pathogens reduce the incidence of soil-borne disease and root rot, improve crops insect pest ability;
(5) sustained release agent can make fertilizer long duration discharge fertility in the present invention, improve utilization rate of the plant to fertilizer, Crop yield is improved, wherein, solubility is relatively low in water for sub- two urea of isobutyl, and the nitrogen in fertilizer can be controlled slowly to discharge, And increase soil aggregate structure, and increasing gas permeability, dicyandiamide and cyanogen elder brother can inhibit nitrifier effect and strengthen the activity of nitrogen-fixing bacteria, Make the conversion rate of nitrogenous fertilizer in the soil adjusted, reduce the loss of nitrogen, improve the service efficiency of fertilizer, contain in ammonium polyphosphate Have abundant phosphorus, a nitrogen, fertilizer efficiency is high, and can chelated metal ions, improve the activity of the trace element such as zinc, iron, manganese, promote Plant growth.
Specific embodiment
With reference to embodiment, the present invention is described in further detail, to make those skilled in the art with reference to specification Word can be implemented according to this.
Embodiment 1
Step 1:Heat kitchen garbage to 100 DEG C, be stirred continuously to bubble-free generates when, be obtained by filtration kitchen waste oil with Solid residue adds in the dense H that 5% mass fraction is 75% into kitchen waste oil2SO4With 20% neopelex, reaction When being kept completely separate to oil, water layer, water layer liquid is removed, is made and slightly carries grease;
Step 2:In the thick H for proposing addition 3% in grease of step 12O2Atlapulgite with 3.5%, is stirred at 60 DEG C 20min obtains decoloration grease;
Step 3:It adds in NaOH in decoloration grease into step 2, stirs saponification 2h, until PH stablizes 7.5, add 10% NaCl obtains soap glue;
Step 4:At 40 DEG C, the soap glue in step 3 and 0.5% peroxide human relations methyl ethyl ketone, 13% polyacrylic acid are uniformly mixed It closes, after staticly settling 1 day, solidification, compacting, dry, i.e., the obtained environmental protective soap;
Step 5:According to 1.5:1:0.8 weight ratio mixes the solid residue after being filtered in step 1 with dead leaf, plant ash It closes uniformly, crushed 30 mesh sieves, obtain fertilizer substrate;
Step 6:11 parts of two ureas of sub- isobutyl, 13 parts of dicyandiamides, 25 parts of cyanogen elder brothers and 42 parts of ammonium polyphosphate are uniformly mixed, are made Sustained release agent is obtained, 1%YM bacterium and 11% sustained release agent is added in the fertilizer substrate into step 5, stirs evenly, treat substrate temperature Reach 80 DEG C, carry out turning over fertilizer, ferment 4 days, that is, the sustained release fertilizer is made.
Embodiment 2
It operates with embodiment 1, wherein, heating temperature in step 1:105 DEG C, dense H2SO4Throwing amount and mass fraction:7%th, 80%, surfactant:25%th, sodium hexadecyl sulfate;H in step 22O2:3.5%, atlapulgite:5%, stirring:65℃、 25min;Lye in step 3:Na2CO3, saponification:2.5h, PH:7.6, NaCl:15%;Temperature in step 4:45 DEG C, curing agent: 1.25%th, peroxidating ring the sixth of the twelve Earthly Branches ketone, adhesion agent:15%th, methyl hydroxyethylcellulose, precipitation:1.5 my god;Municipal refuse in step 5: Pericarp, each weight ratio of constituents of substrate:2:1.5:1, grit number:55;Each Composition Weight Parts of sustained release agent in step 6:17、14、 27、46;Sustained release agent throwing amount:13%, YM bacterium:2%, temperature:85 DEG C, fermentation:5 days.
Embodiment 3
It operates with embodiment 1, wherein, heating temperature in step 1:110 DEG C, dense H2SO4Throwing amount and mass fraction:10%th, 85%, surfactant:30%th, sodium sulfate of polyethenoxy ether of fatty alcohol;H in step 22O2:4%, atlapulgite:6.5%, it stirs It mixes:70℃、30min;Lye in step 3:KOH, saponification:3h, PH:7.8, NaCl:30%;Temperature in step 4:50 DEG C, firmly Agent:1.25%th, peroxidating ring the sixth of the twelve Earthly Branches ketone, adhesion agent:17%th, associate type polyurethane, precipitation:2 days;Municipal refuse in step 5: Waste paper, each weight ratio of constituents of substrate:2.5:2:1.2, grit number:80;Each Composition Weight Parts of sustained release agent in step 6:23、15、 30、50;Sustained release agent throwing amount:15%, YM bacterium:3%, temperature:90 DEG C, fermentation:6 days.
Comparative example
Operation does not add curing agent and adhesion agent in step 4, sustained release agent is not added in step 6 with embodiment 1.
Table 1 is the index parameter using the environmental protective soap of embodiment 1, embodiment 2, embodiment 3 and comparative example production.
Table 2 is the index parameter using the sustained release fertilizer of embodiment 1, embodiment 2, embodiment 3 and comparative example production.
Table 1
As it can be seen from table 1 each physical and chemical index of environmental protective soap produced by the invention reaches national two level soap production mark Standard, and hardness is moderate, foaming abundancy and it is fine and smooth, there is stronger cleaning function, be good cleaning product.
Table 2
From table 2 it can be seen that slow release fertilizer PH produced by the invention, nutrient content are up to state standards, compared with routine Composite fertilizer, plant about improves 10 percentage points to the utilization rate of nutrient in fertilizer, and can discharge fertility for a long time, Ensure crop growth needed nutrient matter, enhance the disease resistance and resistance of crops.
Although the embodiments of the present invention have been disclosed as above, but its be not restricted in specification and embodiment it is listed With it can be fully applied to various fields suitable for the present invention, for those skilled in the art, can be easily Realize other modification, therefore without departing from the general concept defined in the claims and the equivalent scope, it is of the invention and unlimited In specific details.

Claims (7)

  1. A kind of 1. method that environmental protective soap and sustained release fertilizer are produced using kitchen garbage, which is characterized in that comprise the following steps:
    Step 1:Heat kitchen garbage to 100-110 DEG C, be stirred continuously to bubble-free generates when, be obtained by filtration kitchen waste oil with Solid residue adds in the dense H of 5-10% into kitchen waste oil2SO4With 20-30% surfactants, react to oil, water layer and divide completely From when, remove water layer liquid, be made slightly carry grease;
    Step 2:In the thick H for carrying addition 3-4% in grease of step 12O2With the atlapulgite of 3.5-6.5%, at 60-70 DEG C 20-30min is stirred, obtains decoloration grease;
    Step 3:Lye is added in decoloration grease into step 2, stirs saponification 2-3h, until PH stablizes in 7.5-7.8, then is added Enter the NaCl of 10-20%, obtain soap glue;
    Step 4:At 40-50 DEG C, the soap glue in step 3 is uniformly mixed with 0.5-2% curing agents, 13-17% adhesion agents, it is quiet Precipitation is put after 1-2 days, solidification, compacting, dry, i.e., the obtained environmental protective soap;
    Step 5:According to (1.5-2.5):(1-2):The weight ratio of (0.8-1.2) by step 1 filter after solid residue with Municipal refuse, plant ash are uniformly mixed, and crushed 30-80 mesh sieves, obtain fertilizer substrate;
    Step 6:1-3%YM bacterium and the sustained release agent of 11-15% are added in fertilizer substrate into step 5, stirs evenly, treats bottom Object temperature reaches 80-90 DEG C, carries out turning over fertilizer, ferment 4-6 days, that is, the sustained release fertilizer is made.
    Wherein, the sustained release agent in parts by weight, including following components:
  2. 2. a kind of method that environmental protective soap and sustained release fertilizer are produced using kitchen garbage according to claim 1, feature It is, dense H in step 12SO4Mass fraction is 75-85%.
  3. 3. a kind of method that environmental protective soap and sustained release fertilizer are produced using kitchen garbage according to claim 1, feature It is, surfactant includes neopelex, sodium hexadecyl sulfate and fatty alcohol polyoxyethylene ether in step 1 The one or more of sodium sulphate.
  4. 4. a kind of method that environmental protective soap and sustained release fertilizer are produced using kitchen garbage according to claim 1, feature It is, lye includes NaOH, Na in step 32CO3With the one or more of KOH.
  5. 5. a kind of method that environmental protective soap and sustained release fertilizer are produced using kitchen garbage according to claim 1, feature It is, curing agent includes peroxide human relations methyl ethyl ketone and the one or more of peroxidating ring the sixth of the twelve Earthly Branches ketone in step 4.
  6. 6. a kind of method that environmental protective soap and sustained release fertilizer are produced using kitchen garbage according to claim 1, feature It is, adhesion agent includes the one or more of polyacrylic acid, methyl hydroxyethylcellulose and the type polyurethane that associates in step 4.
  7. 7. a kind of method that environmental protective soap and sustained release fertilizer are produced using kitchen garbage according to claim 1, feature It is, municipal refuse includes the one or more of dead leaf, pericarp and waste paper in step 5.
CN201711388261.5A 2017-12-20 2017-12-20 A kind of method that environmental protective soap and sustained release fertilizer are produced using kitchen garbage Pending CN108114967A (en)

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Publication number Priority date Publication date Assignee Title
CN110950700A (en) * 2019-12-31 2020-04-03 安徽晟鑫农业科技发展有限公司 Preparation method of carbon-based efficient compound fertilizer

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Application publication date: 20180605