CN108085188B - Special cleaning agent for tire release agent - Google Patents
Special cleaning agent for tire release agent Download PDFInfo
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- CN108085188B CN108085188B CN201711342085.1A CN201711342085A CN108085188B CN 108085188 B CN108085188 B CN 108085188B CN 201711342085 A CN201711342085 A CN 201711342085A CN 108085188 B CN108085188 B CN 108085188B
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- cleaning agent
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- 239000012459 cleaning agent Substances 0.000 title claims abstract description 82
- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 19
- 239000007788 liquid Substances 0.000 claims abstract description 42
- 239000004094 surface-active agent Substances 0.000 claims abstract description 26
- 239000002904 solvent Substances 0.000 claims abstract description 24
- 239000000654 additive Substances 0.000 claims abstract description 22
- 230000000996 additive effect Effects 0.000 claims abstract description 21
- VKYKSIONXSXAKP-UHFFFAOYSA-N hexamethylenetetramine Chemical compound C1N(C2)CN3CN1CN2C3 VKYKSIONXSXAKP-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000003350 kerosene Substances 0.000 claims abstract description 16
- HYZQZWDYBKVIRI-UHFFFAOYSA-N 1,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13,14,14,14-triacontafluorotetradecane Chemical compound FC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F HYZQZWDYBKVIRI-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000000049 pigment Substances 0.000 claims abstract description 10
- 235000010299 hexamethylene tetramine Nutrition 0.000 claims abstract description 8
- 239000004312 hexamethylene tetramine Substances 0.000 claims abstract description 8
- 150000001875 compounds Chemical group 0.000 claims abstract description 7
- 229910052708 sodium Inorganic materials 0.000 claims description 38
- 239000011734 sodium Substances 0.000 claims description 38
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 35
- 239000003208 petroleum Substances 0.000 claims description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 21
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 20
- 239000000203 mixture Substances 0.000 claims description 18
- 239000000463 material Substances 0.000 claims description 17
- 229920002401 polyacrylamide Polymers 0.000 claims description 15
- 239000002994 raw material Substances 0.000 claims description 13
- 150000007942 carboxylates Chemical class 0.000 claims description 12
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 claims description 12
- 238000010438 heat treatment Methods 0.000 claims description 9
- 238000002360 preparation method Methods 0.000 claims description 9
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 8
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 8
- -1 alkylbenzene sulfonate Chemical class 0.000 claims description 8
- 235000019333 sodium laurylsulphate Nutrition 0.000 claims description 8
- 238000005303 weighing Methods 0.000 claims description 7
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 6
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 claims description 6
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 3
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 claims description 3
- 230000000694 effects Effects 0.000 abstract description 14
- 229920002545 silicone oil Polymers 0.000 abstract description 14
- 238000004140 cleaning Methods 0.000 abstract description 11
- 239000000126 substance Substances 0.000 abstract description 9
- 239000012535 impurity Substances 0.000 abstract description 5
- 231100000252 nontoxic Toxicity 0.000 abstract description 2
- 230000003000 nontoxic effect Effects 0.000 abstract description 2
- 238000013329 compounding Methods 0.000 description 11
- 230000000052 comparative effect Effects 0.000 description 8
- 229920001296 polysiloxane Polymers 0.000 description 4
- 150000004996 alkyl benzenes Chemical class 0.000 description 3
- 229910052710 silicon Inorganic materials 0.000 description 3
- 239000010703 silicon Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- 239000012752 auxiliary agent Substances 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 239000003599 detergent Substances 0.000 description 2
- 239000004519 grease Substances 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000000443 aerosol Substances 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 239000002199 base oil Substances 0.000 description 1
- 229940077388 benzenesulfonate Drugs 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 230000032798 delamination Effects 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 150000002632 lipids Chemical class 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- 238000003760 magnetic stirring Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 239000002674 ointment Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000010112 shell-mould casting Methods 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 229940071182 stannate Drugs 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 238000001308 synthesis method Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2072—Aldehydes-ketones
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/24—Organic compounds containing halogen
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/24—Organic compounds containing halogen
- C11D3/245—Organic compounds containing halogen containing fluorine
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/28—Heterocyclic compounds containing nitrogen in the ring
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/34—Organic compounds containing sulfur
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/43—Solvents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
Abstract
The invention discloses a special cleaning agent for a tire release agent, and belongs to the technical field of cleaning agents. The cleaning agent comprises the following components in parts by weight: 160 parts of gasoline 150-one, 50-60 parts of kerosene, 10-30 parts of surfactant, 3-5 parts of perfluorohexyl n-octane, 4-6 parts of hexamethylenetetramine, 2-6 parts of solvent, 2-4 parts of auxiliary additive, 3-5 parts of aqueous covering liquid, 3-7 parts of essence and 3-5 parts of pigment. The invention utilizes the good intermiscibility of the perfluorohexyl n-octane to silicone oil substances, and a small amount of the perfluorohexyl n-octane is added into the formula of the cleaning agent, so that the cleaning effect can be greatly improved. Meanwhile, by utilizing a similar compatibility principle, the cleaning agent can well dissolve silicone oil residues, has small damage to cleaned objects, has strong pertinence, has obvious cleaning effect on objects with silicone oil compound residues, has less impurity residues, and is matched with non-toxic essence and pigment to adjust the comprehensive value of the cleaning agent. The cleaning agent is matched with the aqueous covering liquid to isolate the contact of the external gas and the cleaning agent, thereby avoiding the failure.
Description
Technical Field
The invention relates to a special cleaning agent for a tire release agent, and belongs to the technical field of cleaning agents.
Background
The silicone oil type release agent is a silicone oil secondary processed product prepared by using silicone oil as a base oil, a dispersing component and various auxiliaries, and has the forms of oil type, emulsion type, solvent type, ointment type, aerosol type and the like. It is widely used in rubber, plastic and shell mold casting industries.
The silicone release agent used for rubber tyre forming processing is prepared by using methyl silicone oil or benzyl silicone oil, radical-terminated silicone oil and a small amount of silicon resin with active reaction group silicon radical as main polymer, matching with a proper amount of alkoxy silane cross-linking agent and organic tin stannate catalyst, and then adding additives such as wetting agent, bactericide and the like. The release agent has the advantages of stable storage, good release effect and long service life. When the rubber is used for molding processing of pneumatic tires or semi-pneumatic tires, the peeling friction force of the outer surface of the tire from the surface of a steel film is low, and the separation lubricity of the inner surface of the tire and an inflatable air bag is good.
The silicon oil release agent is used in a large amount in the tire industry, the produced tire is often provided with various complicated substances, the cleaning of the tire is difficult, the effect of the cleaning agent on the market is not obvious at present, and the requirement of additionally processing a part of tires cannot be met.
In order to solve the problem that the conventional detergent cannot well remove the residual silicone release agent on the tire, publication No. 102925305B discloses a water-based detergent for removing silicone grease and silicone oil, which is mainly used for silicone grease of a lubrication system of a motor car. However, such a single-function cleaning agent cannot be applied to other fields.
Disclosure of Invention
Aiming at the problems, the invention provides the special cleaning agent for the tire release agent, which has the advantages of good cleaning effect, low cost and simple raw material types.
In order to achieve the purpose, the invention adopts the following technical scheme:
the special cleaning agent for the tire release agent comprises the following components in parts by weight: 160 parts of gasoline 150-one, 50-60 parts of kerosene, 10-30 parts of surfactant, 3-5 parts of perfluorohexyl n-octane, 4-6 parts of hexamethylenetetramine, 2-6 parts of solvent, 2-4 parts of auxiliary additive, 3-5 parts of aqueous covering liquid, 3-7 parts of essence and 3-5 parts of pigment.
In the existing cleaning agent proportion, a common surfactant and a part of lipid and other substances are generally simply mixed, the impurity solubility is poor, the applicable field is narrow, the cleaning effect cannot be well exerted, and the common cleaning agent often has pungent smell. Although the main components of the formula of the cleaning agent are simple, gasoline and kerosene are used as common hydrocarbon and are often the mixture of hydrocarbons with different carbon atoms, the cleaning agent can well dissolve silicone oil residues by utilizing the similar compatibility principle, has small damage to the cleaned object, has strong pertinence, has obvious cleaning effect on the object with the silicone oil compound residues, has less impurity residues, and is matched with non-toxic essence and pigment to adjust the comprehensive value of the cleaning agent. The perfluorohexyl n-octane is usually used for biological cleaning, and the toxicity of the perfluorohexyl n-octane to organisms is researched more, but the cleaning effect can be greatly improved by utilizing the good intermiscibility of the perfluorohexyl n-octane to silicone oil substances and adding a small amount of the perfluorohexyl n-octane into a cleaning agent formula.
Preferably, in the cleaning agent, the surfactant comprises sodium heavy alkyl benzene sulfonate, sodium petroleum carboxylate and polyacrylamide.
Further preferably, the petroleum sodium sulfonate and the heavy alkyl benzene sodium sulfonate are a compound according to the mass ratio of 3-5: 1.
Further preferably, the sodium petrocarboxylate and the polyacrylamide are a compound in a mass ratio of 1-3: 1.
The compounding ratio of different components is controlled, so that the interfacial tension of a cleaning agent system can be effectively increased, the interfacial tension is enlarged, silicone oil impurities can be effectively wrapped, and the silicone oil impurities can be removed more thoroughly.
Preferably, in the cleaning agent, the solvent is one or two of carbon tetrachloride and acetone, the auxiliary agent is one or two of N-methylpyrrolidone and pyridine, and the aqueous covering liquid is one or more of sodium lauryl sulfate, triethanolamine and water. The solvent can break the possible layering phenomenon between various mixed substances due to incompatibility, the auxiliary agent can promote the use effect of the cleaning agent, and the aqueous covering liquid can isolate the contact of the cleaning agent and air, so that the failure caused by oxidation of effective substances is avoided.
More preferably, the aqueous coating solution is a mixture of sodium lauryl sulfate, triethanolamine and water. The mixture selected by the water-based covering liquid has low density, can float on the surface layer of the cleaning agent and has good isolation effect.
The invention also provides another technical scheme while reasonably selecting the material proportion:
a preparation method of a special cleaning agent for a tire release agent comprises the following steps:
(1) preparing materials: weighing the raw materials according to the components and the weight parts of the cleaning agent, slightly heating the aqueous covering liquid, and externally applying microwave treatment;
(2) preparing a cleaning agent: firstly, mixing gasoline and kerosene, putting the mixture into a container, adding a solvent and the rest materials, then adding a weighed and compounded surfactant along the wall of the container, and finally dripping an auxiliary additive to obtain a cleaning agent;
(3) covering: and pouring the aqueous covering liquid into the cleaning agent along the wall of the container to obtain a finished cleaning agent product.
The synthesis method of the cleaning agent is usually formed by simply mixing various chemical compounds, but the simple mixture can cause the phenomenon of partial precipitation or delamination of effective substances, and is easy to contact with oxygen to cause oxidation failure, so that the cleaning effect of the cleaning agent can be greatly reduced, and the expected value cannot be reached. The invention combines the water-based covering liquid and the cleaning agent, can effectively isolate the contact of the outside air and the cleaning agent, simultaneously, the covering liquid does not influence the washing effect of the cleaning agent, and the synthesis process of the cleaning agent is also carried out step by step, so as to exert the optimal performance of various substances.
Preferably, in the step (1), the temperature of the micro-heating is 50-70 ℃, and the temperature is kept for 5-10 min.
Preferably, in the step (1), the power of the microwave treatment is 250-350W, and the treatment time is 5-10 min.
The reason for this is that the mixing of the aqueous coating solution is improved and the properties are more stable, both by the micro-heat treatment and by the external application of microwaves.
Preferably, step (2) is carried out under a magnetic stirrer. For the stirring of the glass rod, the stirring frequency of the magnetic stirring is stable, the stirring duration is long, and the solution is uniform and stable.
Compared with other materials, the invention has the following advantages:
(1) the cleaning agent has the advantages of simple and easily obtained material and good cleaning effect.
(2) The cleaning agent is matched with the aqueous covering liquid, so that the cleaning agent is prevented from being oxidized and losing efficacy.
(3) The preparation method of the product is simple and convenient, and the used equipment has small volume and small quantity.
Detailed Description
The following are specific examples of the present invention and further describe the technical solutions of the present invention, but the present invention is not limited to these examples.
Example 1
Preparing materials: weighing raw materials according to the composition and the weight parts of the cleaning agent, wherein the raw materials comprise 4 parts of a solvent, 3 parts of an auxiliary additive, 4 parts of a water-based covering liquid, 155 parts of No. 120 gasoline, 55 parts of kerosene, 20 parts of a surfactant, 4 parts of perfluorohexyl N-octane, 5 parts of hexamethylenetetramine, 5 parts of essence and 4 parts of a pigment, wherein the surfactant comprises sodium dialkylbenzene sulfonate, sodium petroleum carboxylate and polyacrylamide, the compounding ratio of the sodium petroleum sulfonate to the sodium dialkylbenzene sulfonate is 4:1, the compounding ratio of the sodium petroleum carboxylate to the polyacrylamide is 2:1, the solvent is carbon tetrachloride, the auxiliary additive is N-methylpyrrolidone, and the water-based covering liquid is a mixture of sodium lauryl sulfate, triethanolamine and water.
Preparation of an aqueous covering liquid: slightly heating the aqueous covering liquid to 60 ℃, preserving the heat for 8min, and additionally performing microwave treatment at 300W for 8 min.
Preparing a cleaning agent: under the work of a magnetic stirrer, the No. 120 gasoline and the kerosene are mixed and put into a container, then the solvent and the rest materials are added, then the weighed and compounded surfactant is added along the wall of the container, and finally the auxiliary additive is dropped to obtain the cleaning agent.
Covering: and pouring the aqueous covering liquid into the cleaning agent along the wall of the container to obtain a finished cleaning agent product.
Example 2
Preparing materials: weighing raw materials according to the composition and the weight parts of the cleaning agent, wherein the raw materials comprise 2 parts of a solvent, 2 parts of an auxiliary additive, 3 parts of a water-based covering liquid, 150 parts of No. 120 gasoline, 50 parts of kerosene, 10 parts of a surfactant, 3 parts of perfluorohexyl N-octane, 4 parts of hexamethylenetetramine, 3 parts of essence and 3 parts of a pigment, wherein the surfactant comprises sodium dialkylbenzene sulfonate, sodium petroleum carboxylate and polyacrylamide, the complex ratio of the sodium petroleum sulfonate to the sodium dialkylbenzene sulfonate is 3:1, the complex ratio of the sodium petroleum carboxylate to the polyacrylamide is 1:1, the solvent is acetone, the auxiliary additive is N-methylpyrrolidone, and the water-based covering liquid is a mixture of sodium lauryl sulfate, triethanolamine and water.
Preparation of an aqueous covering liquid: slightly heating the aqueous covering liquid to 60 ℃, preserving the heat for 8min, and additionally performing microwave treatment at 300W for 8 min.
Preparing a cleaning agent: under the work of a magnetic stirrer, the No. 120 gasoline and the kerosene are mixed and put into a container, then the solvent and the rest materials are added, then the weighed and compounded surfactant is added along the wall of the container, and finally the auxiliary additive is dropped to obtain the cleaning agent.
Covering: and pouring the aqueous covering liquid into the cleaning agent along the wall of the container to obtain a finished cleaning agent product.
Example 3
Preparing materials: weighing raw materials according to the composition and the weight parts of the cleaning agent, wherein the raw materials comprise 6 parts of a solvent, 4 parts of an auxiliary additive, 5 parts of a water-based covering liquid, 160 parts of No. 120 gasoline, 60 parts of kerosene, 30 parts of a surfactant, 5 parts of perfluorohexyl n-octane, 6 parts of hexamethylenetetramine, 7 parts of essence and 5 parts of a pigment, wherein the surfactant comprises sodium dialkylbenzene sulfonate, sodium petroleum carboxylate and polyacrylamide, the compounding ratio of the sodium petroleum sulfonate to the sodium dialkylbenzene sulfonate is 5:1, the compounding ratio of the sodium petroleum carboxylate to the polyacrylamide is 3:1, the solvent is carbon tetrachloride, the auxiliary additive is pyridine, and the water-based covering liquid is a mixture of sodium lauryl sulfate, triethanolamine and water.
Preparation of an aqueous covering liquid: slightly heating the aqueous covering liquid to 60 ℃, preserving the heat for 8min, and additionally performing microwave treatment at 300W for 8 min.
Preparing a cleaning agent: under the work of a magnetic stirrer, the No. 120 gasoline and the kerosene are mixed and put into a container, then the solvent and the rest materials are added, then the weighed and compounded surfactant is added along the wall of the container, and finally the auxiliary additive is dropped to obtain the cleaning agent.
Covering: and pouring the aqueous covering liquid into the cleaning agent along the wall of the container to obtain a finished cleaning agent product.
Example 4
Preparing materials: weighing raw materials according to the composition and the weight parts of the cleaning agent, wherein the raw materials comprise 4 parts of a solvent, 3 parts of an auxiliary additive, 4 parts of a water-based covering liquid, 155 parts of No. 120 gasoline, 55 parts of kerosene, 20 parts of a surfactant, 4 parts of perfluorohexyl N-octane, 5 parts of hexamethylenetetramine, 5 parts of essence and 4 parts of a pigment, wherein the surfactant comprises sodium dialkylbenzene sulfonate, sodium petroleum carboxylate and polyacrylamide, the compounding ratio of the sodium petroleum sulfonate to the sodium dialkylbenzene sulfonate is 4:1, the compounding ratio of the sodium petroleum carboxylate to the polyacrylamide is 2:1, the solvent is carbon tetrachloride, the auxiliary additive is N-methylpyrrolidone, and the water-based covering liquid is a mixture of sodium lauryl sulfate, triethanolamine and water.
Preparation of an aqueous covering liquid: slightly heating the aqueous covering liquid to 50 ℃, preserving the heat for 5min, and additionally performing microwave treatment at 250W for 5min to obtain the aqueous covering liquid.
Preparing a cleaning agent: under the work of a magnetic stirrer, the No. 120 gasoline and the kerosene are mixed and put into a container, then the solvent and the rest materials are added, then the weighed and compounded surfactant is added along the wall of the container, and finally the auxiliary additive is dropped to obtain the cleaning agent.
Covering: and pouring the aqueous covering liquid into the cleaning agent along the wall of the container to obtain a finished cleaning agent product.
Example 5
Preparing materials: weighing raw materials according to the composition and the weight parts of the cleaning agent, wherein the raw materials comprise 4 parts of a solvent, 3 parts of an auxiliary additive, 4 parts of a water-based covering liquid, 155 parts of No. 120 gasoline, 55 parts of kerosene, 20 parts of a surfactant, 4 parts of perfluorohexyl N-octane, 5 parts of hexamethylenetetramine, 5 parts of essence and 4 parts of a pigment, wherein the surfactant comprises sodium dialkylbenzene sulfonate, sodium petroleum carboxylate and polyacrylamide, the compounding ratio of the sodium petroleum sulfonate to the sodium dialkylbenzene sulfonate is 4:1, the compounding ratio of the sodium petroleum carboxylate to the polyacrylamide is 2:1, the solvent is carbon tetrachloride, the auxiliary additive is N-methylpyrrolidone, and the water-based covering liquid is a mixture of sodium lauryl sulfate, triethanolamine and water.
Preparation of an aqueous covering liquid: slightly heating the aqueous covering liquid to 70 ℃, preserving the heat for 10min, and additionally performing microwave treatment at 350W for 10min to obtain the aqueous covering liquid.
Preparing a cleaning agent: under the work of a magnetic stirrer, the No. 120 gasoline and the kerosene are mixed and put into a container, then the solvent and the rest materials are added, then the weighed and compounded surfactant is added along the wall of the container, and finally the auxiliary additive is dropped to obtain the cleaning agent.
Covering: and pouring the aqueous covering liquid into the cleaning agent along the wall of the container to obtain a finished cleaning agent product.
Comparative example 1
The only difference from example 1 is that the composition of comparative example 1 does not contain perfluorohexyl n-octane.
Comparative example 2
The difference from the example 1 is only that the compounding ratio of the surfactant petroleum sodium sulfonate and the heavy alkyl benzene sodium sulfonate in the comparative example 2 is 1:1, and the compounding ratio of the petroleum sodium carboxylate and the polyacrylamide is 5: 1.
Comparative example 3
The only difference from example 1 is that comparative example 3 is an anhydrous cover fluid.
The cleaning agents of examples 1 to 5 and comparative examples 1 to 3 were tested for their cleaning effect on various substances, and the results are shown in table 1:
table 1: properties of the products of examples 1 to 5 and comparative examples 1 to 3
The specific data in the table are the content of various residues after the use of the cleaning agent.
While the invention has been described in detail and with reference to specific embodiments thereof, it will be apparent to one skilled in the art that various changes and modifications can be made therein without departing from the spirit and scope thereof.
Claims (7)
1. The special cleaning agent for the tire release agent is characterized by comprising the following components in parts by weight: 150-160 parts of gasoline, 50-60 parts of kerosene, 10-30 parts of surfactant, 3-5 parts of perfluorohexyl n-octane, 4-6 parts of hexamethylenetetramine, 2-6 parts of solvent, 2-4 parts of auxiliary additive, 3-5 parts of aqueous covering liquid, 3-7 parts of essence and 3-5 parts of pigment; the surfactant comprises sodium heavy alkylbenzene sulfonate, sodium petroleum carboxylate and polyacrylamide; the solvent is one or two of carbon tetrachloride and acetone, the auxiliary additive is one or two of N-methyl pyrrolidone and pyridine, and the aqueous covering liquid is a mixture of sodium lauryl sulfate, triethanolamine and water.
2. The special cleaning agent for the tire release agent as claimed in claim 1, wherein the surfactant is a compound of sodium petroleum sulfonate and sodium heavy alkylbenzene sulfonate in a mass ratio of 3-5: 1.
3. The special cleaning agent for the tire release agent as claimed in claim 1, wherein the sodium petrocarboxylate and the polyacrylamide in the surfactant are a compound in a mass ratio of 1-3: 1.
4. The preparation method of the special cleaning agent for the tire release agent is characterized by comprising the following steps of:
(1) preparing materials: weighing the raw materials according to the components and the weight parts of the cleaning agent of claim 1, slightly heating the aqueous covering liquid, and additionally carrying out microwave treatment;
(2) preparing a cleaning agent: firstly, mixing gasoline and kerosene, putting the mixture into a container, adding a solvent and the rest materials, then adding a weighed and compounded surfactant along the wall of the container, and finally dripping an auxiliary additive to obtain a cleaning agent;
(3) covering: and pouring the aqueous covering liquid into the cleaning agent along the wall of the container to obtain a finished cleaning agent product.
5. The preparation method of the special cleaning agent for the tire release agent as claimed in claim 4, wherein the temperature of the slight heat in the step (1) is 50-70 ℃, and the temperature is kept for 5-10 min.
6. The method for preparing the special cleaning agent for the tire release agent as claimed in claim 4, wherein the microwave treatment power in the step (1) is 250-350W, and the treatment time is 5-10 min.
7. The method for preparing the cleaning agent special for the tire release agent as claimed in claim 4, wherein the step (2) is carried out under a magnetic stirrer.
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN1034954A (en) * | 1988-02-13 | 1989-08-23 | 黄金邦 | High-efficient greasy dirt removing paste and preparation thereof |
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| CN100386418C (en) * | 2006-03-21 | 2008-05-07 | 王士奎 | Waterfree car washing type fresh maintenance agent and its prepn. method |
| CN104277934A (en) * | 2013-07-03 | 2015-01-14 | 北京中科东亚纳米材料科技有限公司 | Dog urine-proofing tyre maintenance agent and preparation method thereof |
| CN105316128A (en) * | 2015-11-26 | 2016-02-10 | 广东新球清洗科技股份有限公司 | Anti-static hydrocarbon cleaner |
| CN107022423A (en) * | 2017-04-27 | 2017-08-08 | 陈凯 | A kind of automobile tire cleaning agent |
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| CN1034954A (en) * | 1988-02-13 | 1989-08-23 | 黄金邦 | High-efficient greasy dirt removing paste and preparation thereof |
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