CN108085188A - A kind of tire mold release agent scavenger specially - Google Patents
A kind of tire mold release agent scavenger specially Download PDFInfo
- Publication number
- CN108085188A CN108085188A CN201711342085.1A CN201711342085A CN108085188A CN 108085188 A CN108085188 A CN 108085188A CN 201711342085 A CN201711342085 A CN 201711342085A CN 108085188 A CN108085188 A CN 108085188A
- Authority
- CN
- China
- Prior art keywords
- parts
- cleaning agent
- mold release
- agent
- tire mold
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000006082 mold release agent Substances 0.000 title claims abstract description 17
- 239000002516 radical scavenger Substances 0.000 title claims abstract description 17
- 239000012459 cleaning agent Substances 0.000 claims abstract description 65
- 239000007788 liquid Substances 0.000 claims abstract description 46
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 31
- 239000004094 surface-active agent Substances 0.000 claims abstract description 24
- 239000002904 solvent Substances 0.000 claims abstract description 23
- 239000003350 kerosene Substances 0.000 claims abstract description 16
- 239000000463 material Substances 0.000 claims abstract description 12
- WRYIIOKOQSICTB-UHFFFAOYSA-N 1,1,1,2,2,3,3,4,4,5,5,6,6-tridecafluorotetradecane Chemical compound CCCCCCCCC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F WRYIIOKOQSICTB-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000000049 pigment Substances 0.000 claims abstract description 10
- 150000001875 compounds Chemical class 0.000 claims abstract description 6
- 239000004615 ingredient Substances 0.000 claims abstract description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 45
- 239000011734 sodium Substances 0.000 claims description 45
- 229910052708 sodium Inorganic materials 0.000 claims description 45
- 238000013329 compounding Methods 0.000 claims description 21
- 239000000203 mixture Substances 0.000 claims description 16
- 150000004996 alkyl benzenes Chemical class 0.000 claims description 15
- 229940077388 benzenesulfonate Drugs 0.000 claims description 15
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 15
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 15
- 239000003208 petroleum Substances 0.000 claims description 14
- 229920002401 polyacrylamide Polymers 0.000 claims description 10
- 208000030208 low-grade fever Diseases 0.000 claims description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 8
- 239000002994 raw material Substances 0.000 claims description 8
- 238000005303 weighing Methods 0.000 claims description 7
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 6
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical group CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 claims description 6
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 claims description 6
- 238000002360 preparation method Methods 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 3
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 claims description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 2
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- 239000003599 detergent Substances 0.000 claims description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims 2
- VKEQBMCRQDSRET-UHFFFAOYSA-N Methylone Chemical compound CNC(C)C(=O)C1=CC=C2OCOC2=C1 VKEQBMCRQDSRET-UHFFFAOYSA-N 0.000 claims 1
- 229910052938 sodium sulfate Inorganic materials 0.000 claims 1
- 235000011152 sodium sulphate Nutrition 0.000 claims 1
- AGGKEGLBGGJEBZ-UHFFFAOYSA-N tetramethylenedisulfotetramine Chemical compound C1N(S2(=O)=O)CN3S(=O)(=O)N1CN2C3 AGGKEGLBGGJEBZ-UHFFFAOYSA-N 0.000 claims 1
- 229920002545 silicone oil Polymers 0.000 abstract description 16
- 238000004140 cleaning Methods 0.000 abstract description 10
- 230000000694 effects Effects 0.000 abstract description 9
- 239000000126 substance Substances 0.000 abstract description 8
- VKYKSIONXSXAKP-UHFFFAOYSA-N hexamethylenetetramine Chemical compound C1N(C2)CN3CN1CN2C3 VKYKSIONXSXAKP-UHFFFAOYSA-N 0.000 abstract description 4
- 239000012535 impurity Substances 0.000 abstract description 4
- 235000010299 hexamethylene tetramine Nutrition 0.000 abstract description 2
- 239000004312 hexamethylene tetramine Substances 0.000 abstract description 2
- 239000003921 oil Substances 0.000 description 13
- -1 alkoxy silane Chemical compound 0.000 description 12
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical group ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 10
- 230000000052 comparative effect Effects 0.000 description 8
- 239000004743 Polypropylene Substances 0.000 description 5
- 150000001408 amides Chemical class 0.000 description 5
- 150000001412 amines Chemical class 0.000 description 5
- 125000001434 methanylylidene group Chemical group [H]C#[*] 0.000 description 5
- 229920001155 polypropylene Polymers 0.000 description 5
- 229920001296 polysiloxane Polymers 0.000 description 4
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- NIPNSKYNPDTRPC-UHFFFAOYSA-N N-[2-oxo-2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 NIPNSKYNPDTRPC-UHFFFAOYSA-N 0.000 description 2
- 239000012752 auxiliary agent Substances 0.000 description 2
- 239000004519 grease Substances 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 238000002955 isolation Methods 0.000 description 2
- 239000005060 rubber Substances 0.000 description 2
- 230000006641 stabilisation Effects 0.000 description 2
- 238000011105 stabilization Methods 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000002199 base oil Substances 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 230000009849 deactivation Effects 0.000 description 1
- PCHPORCSPXIHLZ-UHFFFAOYSA-N diphenhydramine hydrochloride Chemical compound [Cl-].C=1C=CC=CC=1C(OCC[NH+](C)C)C1=CC=CC=C1 PCHPORCSPXIHLZ-UHFFFAOYSA-N 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 230000000855 fungicidal effect Effects 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 150000002632 lipids Chemical class 0.000 description 1
- 230000001050 lubricating effect Effects 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 239000002674 ointment Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920001921 poly-methyl-phenyl-siloxane Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000011257 shell material Substances 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 238000010189 synthetic method Methods 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2072—Aldehydes-ketones
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/24—Organic compounds containing halogen
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/24—Organic compounds containing halogen
- C11D3/245—Organic compounds containing halogen containing fluorine
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/28—Heterocyclic compounds containing nitrogen in the ring
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/34—Organic compounds containing sulfur
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/43—Solvents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
Abstract
The invention discloses a kind of tire mold release agent scavenger speciallies, belong to cleaning agent technical field.The ingredient and its parts by weight of cleaning agent be：150 160 parts of gasoline, 50 60 parts of kerosene, 10 30 parts of surfactant, 35 parts of Perfluorohexyloctane, 46 parts of hexamethylenetetramine, 26 parts of solvent, 24 parts of auxiliary addition agent, 35 parts of aqueous covering liquid, 37 parts of essence, 35 parts of pigment.The present invention, to the good intermiscibility of silicone oil substance, is added in cleaning agent formula, the effect of energy significant increase cleaning on a small quantity using Perfluorohexyloctane.Simultaneously, utilize similar compatibility principle, silicone oil residue can be dissolved well, and it is smaller to the damage of cleaned material, while specific aim is again strong, to there is the remaining object of silicone oil compound, cleaning performance is notable, impurity residual is few, and coordinates the essence and pigment of nonhazardous, adjusts the comprehensive value of cleaning agent.Coordinate with aqueous covering liquid and completely cut off contact of the ambient atmos with cleaning agent, avoid failing.
Description
Technical field
The present invention relates to a kind of tire mold release agent scavenger speciallies, belong to cleaning agent technical field.
Background technology
Silicone oil release agent is the silicone oil secondary operation product prepared using silicone oil as base oil and dispersed component, various auxiliary agents, is had
The forms such as oil type, emulsion-type, solvent-borne type, ointment type, aerial fog type.It is widely used in the industries such as rubber, plastics and shell moulded casting.
The silicone oil mold release agent that rubber tyre processing and forming uses is blocked frequently with methyl-silicone oil or polymethylphenyl siloxane fluid, through base
Silicone oil and it is a small amount of make main polymer with silicones of the active reactive group silicon through base, with alkoxy silane cross linked dose of appropriate amount
With organotin stannic acid salt catalyst, then silicone release made from the additives such as additional humectant, fungicide.The releasing agent is store
Stabilization is deposited, stripping result is good, and service life is long.Use it for the processing and forming of pneumatic tire or semisolid tire, tire appearance
Face removes that frictional force is low, and the separation lubrication of tire inner surface and air bag is good from steel membrane surface.
Exactly silicone oil release agent is in a large amount of uses of tyre industry, and the tire of production is often with various more complicated
Substance, cleaning acquire a certain degree of difficulty, and cleaning agent effect unobvious on the market at present, can not meet part needs additional processing
Tire.
Remaining silicone oil release agent on tire cannot be washed away very well for conventional clean agent, and publication number 102925305B is public
A kind of aqueous cleaning agent for removing silicone grease silicone oil is opened, mainly for the silicone grease of the lubricating system of motor-car.However, this function
Single cleaning agent can not but be applied to other field.
The content of the invention
In view of the above problems, the present invention provides that a kind of cleaning performance is good, at low cost, the simple tire of raw material type
Releasing agent scavenger specially.
To achieve these goals, the present invention uses following technical scheme：
A kind of tire mold release agent scavenger specially, the cleaning agent include following ingredient and its component of parts by weight：
150-160 parts of gasoline, 50-60 parts of kerosene, 10-30 parts of surfactant, 3-5 parts of Perfluorohexyloctane, hexamethylenetetramine
4-6 parts, 2-6 parts of solvent, 2-4 parts of auxiliary addition agent, covering liquid 3-5 parts aqueous, 3-7 parts of essence, 3-5 parts of pigment.
In existing cleaning agent proportioning, usually using the simple mixed of the substances such as common surfactant and part lipid
It closes, poor to impurity dissolubility, the field that can relate to is relatively narrow, it is impossible to play cleaning effect well, and common cleaning agent is past
Toward with penetrating odor.The main component of present invention cleaning agent prescription is although fairly simple, and gasoline is with kerosene as common
Hydrocarbon is often the mixture of the hydrocarbon of a variety of different carbon numbers, using similar compatibility principle, can dissolve well
Silicone oil residue, and it is smaller to the damage of cleaned material, while specific aim is again strong, to there is the remaining object of silicone oil compound
Body, cleaning performance is notable, and impurity residual is few, and coordinates the essence and pigment of nonhazardous, adjusts the comprehensive value of cleaning agent.It is and complete
Fluorine hexyl normal octane is commonly used for biological cleaning, is more to study its toxic to biology, but the present invention utilizes perfluor
Hexyl normal octane is added in cleaning agent formula, the effect of energy significant increase cleaning the good intermiscibility of silicone oil substance on a small quantity
Fruit.
Preferably, in cleaning agent, the surfactant includes sodium heavy alkyl benzene sulfonate, petroleum sodium sulfonate, stone
Oily carboxylic acid sodium, polyacrylamide.
Further preferably, petroleum sodium sulfonate and sodium heavy alkyl benzene sulfonate are 3-5 in mass ratio:1 compound.
Further preferably, oil carboxylic acid sodium and polyacrylamide are 1-3 in mass ratio:1 compound.
The compounding ratio between different components is controlled, the interfacial tension of cleaning agent system can be effectively increased, and expands interface
Power, can more effectively wrap up silicone oil impurity, and removal is more thorough.
Preferably, in cleaning agent, the solvent is carbon tetrachloride, one or both of acetone, auxiliary addition agent
For one or both of N-Methyl pyrrolidone, pyridine, aqueous covering liquid is NaLS, in triethanolamine, water
It is one or more.Solvent can break the lamination that may be present generated when incompatible, auxiliary between various compounding substances
Auxiliary agent can promote the using effect of cleaning agent, and aqueous covering liquid energy completely cuts off contact of the cleaning agent with air, avoids active principle
It is failed by oxidation.
Further preferably, aqueous covering liquid is NaLS, triethanolamine, the mixture of water.Aqueous covering liquid choosing
The density of mixture is smaller, can float on cleaning agent surface layer, and isolation effect is good.
The present invention additionally provides another technical solution while reasonable selection material mixture ratio：
A kind of preparation method of tire mold release agent scavenger specially, the method include the following steps：
(1) dispensing：Raw material is weighed by the ingredient and its parts by weight of above-mentioned detergent, by aqueous covering liquid low-grade fever, outside
Add microwave treatment；
(2) prepared by cleaning agent：First gasoline and kerosene are mixed into container, add solvent and remaining material, then
The surfactant after weighing and compounding is added in along chamber wall, auxiliary addition agent is finally instilled and obtains cleaning agent；
(3) cover：Aqueous covering liquid along chamber wall is poured into, cleaning agent finished product is obtained in cleaning agent.
Often various chemical combination substances are simply mixed for the synthetic method of cleaning agent, but this simple mixture
The phenomenon that being present with part active principle precipitation or layering, while easily contacted again with oxygen and cause oxidation deactivation, it can be very big
Ground reduces the washing effect of cleaning agent, and desired value is not achieved.And the present invention works in coordination aqueous covering liquid with cleaning agent, can have
Contact of the effect isolation ambient atmos with cleaning agent, while covering liquid will not influence the washing effect of cleaning agent in itself, and clean
The building-up process of agent is also that substep carries out, to play the optimum performance of various substances.
Preferably, in step (1), the temperature of the low-grade fever is 50-70 DEG C, keeps the temperature 5-10min.
Preferably, in step (1), the power of the microwave treatment is 250-350W, processing time 5-10min.
Either low-grade fever processing or external application microwave, is provided to cause the mixability of aqueous covering liquid more
Good, property is more stable.
Preferably, step (2) carries out under magnetic stirrer.Magnetic agitation is for glass bar stirring, stirring
Frequency stabilization, the stirring duration is long, and solution is homogeneous, stablizes.
Compared with other materials, the invention has the advantages that：
(1) cleaning agent material is simple and easy to get, and cleaning performance is good.
(2) cleaning agent coordinates with aqueous covering liquid, and cleaning agent is avoided to be failed by oxidation.
(3) product preparation method is easy, and the equipment volume used is small, and quantity is few.
Specific embodiment
It is specific embodiments of the present invention below, technical scheme is further described, but the present invention is simultaneously
It is not limited to these embodiments.
Embodiment 1
Dispensing：Raw material is weighed by the composition and its parts by weight of cleaning agent, including 4 parts of solvent, 3 parts of auxiliary addition agent, aqueous
4 parts, No. 120 155 parts of gasoline of covering liquid, 55 parts of kerosene, 20 parts of surfactant, 4 parts of Perfluorohexyloctane, six methines four
5 parts of amine, 5 parts of essence, 4 parts of pigment, wherein, surfactant includes sodium heavy alkyl benzene sulfonate, petroleum sodium sulfonate, oil carboxylic acid
The compounding of sodium, polyacrylamide, wherein petroleum sodium sulfonate and sodium heavy alkyl benzene sulfonate compares for 4:1, oil carboxylic acid sodium and polypropylene
The compounding of amide compares for 2:1, solvent is carbon tetrachloride, and auxiliary addition agent is N-Methyl pyrrolidone, and aqueous covering liquid is lauryl
Sodium sulphate, triethanolamine, the mixture of water.
It is prepared by aqueous covering liquid：By aqueous covering liquid low-grade fever to temperature 60 C, 8min, the microwave treatment of additional 300W are kept the temperature
8min。
It is prepared by cleaning agent：Under magnetic stirrer work, first No. 120 gasoline and kerosene are mixed into container, then are added
Enter solvent and remaining material, then add in the surfactant after weighing and compounding along chamber wall, finally instill auxiliary addition agent and obtain
Cleaning agent.
Covering：Aqueous covering liquid along chamber wall is poured into, cleaning agent finished product is obtained in cleaning agent.
Embodiment 2
Dispensing：Raw material is weighed by the composition and its parts by weight of cleaning agent, including 2 parts of solvent, 2 parts of auxiliary addition agent, aqueous
3 parts, No. 120 150 parts of gasoline of covering liquid, 50 parts of kerosene, 10 parts of surfactant, 3 parts of Perfluorohexyloctane, six methines four
4 parts of amine, 3 parts of essence, 3 parts of pigment, wherein, surfactant includes sodium heavy alkyl benzene sulfonate, petroleum sodium sulfonate, oil carboxylic acid
The compounding of sodium, polyacrylamide, wherein petroleum sodium sulfonate and sodium heavy alkyl benzene sulfonate compares for 3:1, oil carboxylic acid sodium and polypropylene
The compounding of amide compares for 1:1, solvent is acetone, and auxiliary addition agent is N-Methyl pyrrolidone, and aqueous covering liquid is lauryl sulfate
Sodium, triethanolamine, the mixture of water.
It is prepared by aqueous covering liquid：By aqueous covering liquid low-grade fever to temperature 60 C, 8min, the microwave treatment of additional 300W are kept the temperature
8min。
It is prepared by cleaning agent：Under magnetic stirrer work, first No. 120 gasoline and kerosene are mixed into container, then are added
Enter solvent and remaining material, then add in the surfactant after weighing and compounding along chamber wall, finally instill auxiliary addition agent and obtain
Cleaning agent.
Covering：Aqueous covering liquid along chamber wall is poured into, cleaning agent finished product is obtained in cleaning agent.
Embodiment 3
Dispensing：Raw material is weighed by the composition and its parts by weight of cleaning agent, including 6 parts of solvent, 4 parts of auxiliary addition agent, aqueous
5 parts, No. 120 160 parts of gasoline of covering liquid, 60 parts of kerosene, 30 parts of surfactant, 5 parts of Perfluorohexyloctane, six methines four
6 parts of amine, 7 parts of essence, 5 parts of pigment, wherein, surfactant includes sodium heavy alkyl benzene sulfonate, petroleum sodium sulfonate, oil carboxylic acid
The compounding of sodium, polyacrylamide, wherein petroleum sodium sulfonate and sodium heavy alkyl benzene sulfonate compares for 5:1, oil carboxylic acid sodium and polypropylene
The compounding of amide compares for 3:1, solvent is carbon tetrachloride, and auxiliary addition agent is pyridine, and aqueous covering liquid is NaLS, three second
The mixture of hydramine, water.
It is prepared by aqueous covering liquid：By aqueous covering liquid low-grade fever to temperature 60 C, 8min, the microwave treatment of additional 300W are kept the temperature
8min。
It is prepared by cleaning agent：Under magnetic stirrer work, first No. 120 gasoline and kerosene are mixed into container, then are added
Enter solvent and remaining material, then add in the surfactant after weighing and compounding along chamber wall, finally instill auxiliary addition agent and obtain
Cleaning agent.
Covering：Aqueous covering liquid along chamber wall is poured into, cleaning agent finished product is obtained in cleaning agent.
Embodiment 4
Dispensing：Raw material is weighed by the composition and its parts by weight of cleaning agent, including 4 parts of solvent, 3 parts of auxiliary addition agent, aqueous
4 parts, No. 120 155 parts of gasoline of covering liquid, 55 parts of kerosene, 20 parts of surfactant, 4 parts of Perfluorohexyloctane, six methines four
5 parts of amine, 5 parts of essence, 4 parts of pigment, wherein, surfactant includes sodium heavy alkyl benzene sulfonate, petroleum sodium sulfonate, oil carboxylic acid
The compounding of sodium, polyacrylamide, wherein petroleum sodium sulfonate and sodium heavy alkyl benzene sulfonate compares for 4:1, oil carboxylic acid sodium and polypropylene
The compounding of amide compares for 2:1, solvent is carbon tetrachloride, and auxiliary addition agent is N-Methyl pyrrolidone, and aqueous covering liquid is lauryl
Sodium sulphate, triethanolamine, the mixture of water.
It is prepared by aqueous covering liquid：By aqueous covering liquid low-grade fever to temperature 50 C, 5min, the microwave treatment of additional 250W are kept the temperature
5min obtains aqueous covering liquid.
It is prepared by cleaning agent：Under magnetic stirrer work, first No. 120 gasoline and kerosene are mixed into container, then are added
Enter solvent and remaining material, then add in the surfactant after weighing and compounding along chamber wall, finally instill auxiliary addition agent and obtain
Cleaning agent.
Covering：Aqueous covering liquid along chamber wall is poured into, cleaning agent finished product is obtained in cleaning agent.
Embodiment 5
Dispensing：Raw material is weighed by the composition and its parts by weight of cleaning agent, including 4 parts of solvent, 3 parts of auxiliary addition agent, aqueous
4 parts, No. 120 155 parts of gasoline of covering liquid, 55 parts of kerosene, 20 parts of surfactant, 4 parts of Perfluorohexyloctane, six methines four
5 parts of amine, 5 parts of essence, 4 parts of pigment, wherein, surfactant includes sodium heavy alkyl benzene sulfonate, petroleum sodium sulfonate, oil carboxylic acid
The compounding of sodium, polyacrylamide, wherein petroleum sodium sulfonate and sodium heavy alkyl benzene sulfonate compares for 4:1, oil carboxylic acid sodium and polypropylene
The compounding of amide compares for 2:1, solvent is carbon tetrachloride, and auxiliary addition agent is N-Methyl pyrrolidone, and aqueous covering liquid is lauryl
Sodium sulphate, triethanolamine, the mixture of water.
It is prepared by aqueous covering liquid：By aqueous covering liquid low-grade fever to temperature 70 C, 10min is kept the temperature, at the microwave of additional 350W
10min is managed, obtains aqueous covering liquid.
It is prepared by cleaning agent：Under magnetic stirrer work, first No. 120 gasoline and kerosene are mixed into container, then are added
Enter solvent and remaining material, then add in the surfactant after weighing and compounding along chamber wall, finally instill auxiliary addition agent and obtain
Cleaning agent.
Covering：Aqueous covering liquid along chamber wall is poured into, cleaning agent finished product is obtained in cleaning agent.
Comparative example 1
With differing only in for embodiment 1, Perfluorohexyloctane is free of in 1 ingredient of comparative example.
Comparative example 2
With differing only in for embodiment 1, the surfactant petroleum sodium sulfonate of comparative example 2 and sodium heavy alkyl benzene sulfonate
Compounding is than being 1:1, the compounding of oil carboxylic acid sodium and polyacrylamide compares for 5:1.
Comparative example 3
With differing only in for embodiment 1, comparative example 3 is without aqueous covering liquid.
Cleaning agent in embodiment 1-5 and comparative example 1-3 is tested, tests its cleaning performance to different material,
The results are shown in Table 1：
Table 1：The performance of product in embodiment 1-5 and comparative example 1-3
Specific data in table are the content using the various residues after over cleaning agent.
It is skilled to this field although having been made a detailed description to the present invention and being cited some specific embodiments
For technical staff, as long as it is obvious that can make various changes or correct without departing from the spirit and scope of the present invention.
Claims (10)
1. a kind of tire mold release agent scavenger specially, which is characterized in that the cleaning agent includes following ingredient and its parts by weight
Several components：150-160 parts of gasoline, 50-60 parts of kerosene, 10-30 parts of surfactant, 3-5 parts, six times of Perfluorohexyloctane
4-6 parts of tetramine, 2-6 parts of solvent, 2-4 parts of auxiliary addition agent, covering liquid 3-5 parts aqueous, 3-7 parts of essence, 3-5 parts of pigment.
A kind of 2. tire mold release agent scavenger specially according to claim 1, which is characterized in that the surfactant
Including sodium heavy alkyl benzene sulfonate, petroleum sodium sulfonate, oil carboxylic acid sodium, polyacrylamide.
3. a kind of tire mold release agent scavenger specially according to claim 1 or 2, which is characterized in that live on the surface
Property agent petrochina sodium sulfonate and sodium heavy alkyl benzene sulfonate be 3-5 in mass ratio:1 compound.
4. a kind of tire mold release agent scavenger specially according to claim 1 or 2, which is characterized in that live on the surface
Property agent petrochina carboxylic acid sodium and polyacrylamide be 1-3 in mass ratio:1 compound.
5. a kind of tire mold release agent scavenger specially according to claim 1, which is characterized in that the solvent is tetrachloro
Change carbon, one or both of acetone, auxiliary addition agent is N-Methyl pyrrolidone, one or both of pyridine, aqueous covering
Liquid is NaLS, the one or more in triethanolamine, water.
6. a kind of tire mold release agent scavenger specially according to claim 5, which is characterized in that aqueous covering liquid is bay
Base sodium sulphate, triethanolamine, the mixture of water.
7. a kind of preparation method of tire mold release agent scavenger specially, which is characterized in that the method includes the following steps：
(1) dispensing：Raw material is weighed by the ingredient and its parts by weight of detergent described in claim 1, aqueous covering liquid is micro-
Heat, additional microwave treatment；
(2) prepared by cleaning agent：First gasoline and kerosene are mixed into container, add solvent and remaining material, then along appearance
Wall adds in the surfactant after weighing and compounding, and finally instills auxiliary addition agent and obtains cleaning agent；
(3) cover：Aqueous covering liquid along chamber wall is poured into, cleaning agent finished product is obtained in cleaning agent.
A kind of 8. preparation method of tire mold release agent scavenger specially according to claim 7, which is characterized in that step
(1) temperature of the low-grade fever is 50-70 DEG C, keeps the temperature 5-10min.
A kind of 9. preparation method of tire mold release agent scavenger specially according to claim 7, which is characterized in that step
(1) power of the microwave treatment is 250-350W, processing time 5-10min.
A kind of 10. preparation method of tire mold release agent scavenger specially according to claim 7, which is characterized in that step
(2) carried out under magnetic stirrer.
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| CN201711342085.1A CN108085188B (en) | 2017-12-14 | 2017-12-14 | Special cleaning agent for tire release agent |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113583767A (en) * | 2021-08-23 | 2021-11-02 | 江苏普利玛斯轮胎科技有限公司 | Method for removing vulcanizing agent of release agent on inner surface of tire |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1034954A (en) * | 1988-02-13 | 1989-08-23 | 黄金邦 | High-efficient greasy dirt removing paste and preparation thereof |
| CN1834215A (en) * | 2006-03-21 | 2006-09-20 | 王士奎 | Waterfree car washing type fresh maintenance agent and its prepn. method |
| CN104277934A (en) * | 2013-07-03 | 2015-01-14 | 北京中科东亚纳米材料科技有限公司 | Dog urine-proofing tyre maintenance agent and preparation method thereof |
| CN105316128A (en) * | 2015-11-26 | 2016-02-10 | 广东新球清洗科技股份有限公司 | Anti-static hydrocarbon cleaner |
| CN107022423A (en) * | 2017-04-27 | 2017-08-08 | 陈凯 | A kind of automobile tire cleaning agent |
-
2017
- 2017-12-14 CN CN201711342085.1A patent/CN108085188B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1034954A (en) * | 1988-02-13 | 1989-08-23 | 黄金邦 | High-efficient greasy dirt removing paste and preparation thereof |
| CN1834215A (en) * | 2006-03-21 | 2006-09-20 | 王士奎 | Waterfree car washing type fresh maintenance agent and its prepn. method |
| CN104277934A (en) * | 2013-07-03 | 2015-01-14 | 北京中科东亚纳米材料科技有限公司 | Dog urine-proofing tyre maintenance agent and preparation method thereof |
| CN105316128A (en) * | 2015-11-26 | 2016-02-10 | 广东新球清洗科技股份有限公司 | Anti-static hydrocarbon cleaner |
| CN107022423A (en) * | 2017-04-27 | 2017-08-08 | 陈凯 | A kind of automobile tire cleaning agent |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113583767A (en) * | 2021-08-23 | 2021-11-02 | 江苏普利玛斯轮胎科技有限公司 | Method for removing vulcanizing agent of release agent on inner surface of tire |
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