CN108085119A - A kind of high-speed canning line is with lubricator and preparation method thereof - Google Patents
A kind of high-speed canning line is with lubricator and preparation method thereof Download PDFInfo
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- CN108085119A CN108085119A CN201711296203.XA CN201711296203A CN108085119A CN 108085119 A CN108085119 A CN 108085119A CN 201711296203 A CN201711296203 A CN 201711296203A CN 108085119 A CN108085119 A CN 108085119A
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M173/00—Lubricating compositions containing more than 10% water
- C10M173/02—Lubricating compositions containing more than 10% water not containing mineral or fatty oils
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/02—Hydroxy compounds
- C10M2207/021—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/104—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/105—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing three carbon atoms only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/12—Polysaccharides, e.g. cellulose, biopolymers
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/10—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring
- C10M2219/104—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring containing sulfur and carbon with nitrogen or oxygen in the ring
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
- C10N2010/02—Groups 1 or 11
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
Abstract
The invention belongs to technical field of lubricant, and in particular to a kind of high-speed canning line is with lubricator and preparation method thereof.In parts by weight, raw material composition is：Trans 5~15 parts of block polyether, 4~12 parts of alkyl glycosides, 2~10 parts of fat alcohol ether phosphate, 1~5 part of disodium ethylene diamine tetraacetate, 1~5 part of isothiazolinone, 1~8 part of ethyl alcohol, 45~86 parts of water；The lubricant of the present invention has abandoned traditional fatty amine system, using trans block polyether as main lubricant, and compounds alkyl glycosides, fatty alcohol ether phosphate, has excellent performance of anti-blockage and greasy property, solves the problems, such as to tremble filling when high-speed line is filling；Lubricant of the present invention is compounded in room temperature, and production process free from extraneous odour, preparation process is simple to operation, and low energy consumption, green pollution-free.
Description
Technical field
The invention belongs to technical field of lubricant, and in particular to a kind of high-speed canning line is with lubricator and preparation method thereof.
Background technology
Lubrication is exactly that apparatus has specific characteristics the material (liquid, gas, solid etc.) of matter, the friction table of relative motion will occur
Face is separated, and two friction surfaces is avoided to contact directly, and change dry friction reaches reduction mill into the intermolecular friction of lubriation material
Damage, the effect for extending service life of equipment.Wine holding container is conveyed using automatic transport chain in Beer Brewage, if cannot be normal
It phenomena such as lubrication, transport box will appear from down bottle, card bottle, influences normally to produce.
It is persistently promoted recently as the tinned wine accounting of can, major beer brewery groups are newly mounted with that numerous cans is listened
Wiring, filling speed are increased to 90000-120000 current fillings/hour, industry by 30000-60000 original fillings/hour
Filling speed is usually inside referred to as high-speed canning line in 90000 fillings/production line more than hour.High-speed canning line chain strip adoption is put down
Whole property and the better acetal plastic of toughness, the interface of contact are changed to aluminium and plastics by glass and stainless steel.Filling speed it is big
Width is promoted and the variation of interface material, the requirement to lubricant are also harsher.
Fatty amine based lubricant is the canning line lubrication product of current mainstream, which is that fatty amine has
Machine hydrochlorate, belongs to cationic surfactant, synthetically produced by long-chain fat amine (carbon chain lengths are in 12-18) and organic acid, this
Class product has excellent biocidal property, but since such aliphatic amine derivative belongs to weak acid and mild base salt, it is unstable under alkaline water quality,
Hydrophobic fatty amine can be hydrolyzed into, generates sediment；Fatty amine cation can be with sulfate ion, the carbonate in water simultaneously
The reactions such as ion generate fatty amine inorganic salts not soluble in water, to prevent from blocking, need periodically with acidic cleaner to lubricating system
It is cleaned.The lubricity of fatty amine based lubricant is difficult to meet the needs of high-speed canning line, is present in full production
Filling phenomenon is trembled, causes filling amount deviation, makes production that can not be normally carried out.Fatty amine based lubricant production process need to heat up heating,
There is pungent peculiar smell, it is cumbersome.Therefore, in order to meet the lubrication needs of high-speed canning line, there is an urgent need for invent a kind of novel lubricant.
The content of the invention
In order to solve the above-mentioned technical problem, present inventor provides a kind of high-speed canning line with lubricator and its makes
Preparation Method.
With lubricator, in parts by weight, raw material composition is a kind of high-speed canning line：1st, a kind of high-speed canning line lubrication
Agent, which is characterized in that in parts by weight, raw material composition is：
Trans 5~15 parts of block polyether, 4~12 parts of alkyl glycosides, 2~10 parts of fatty alcohol ether phosphate, ethylenediamine tetrem
1~5 part of acid disodium, 1~5 part of isothiazolinone, 1~8 part of ethyl alcohol, 45~86 parts of water.
Preferably, the trans block polyether is BASF RPE1740.
Preferably, the alkyl glycosides is at least one of APG0810 and APG0814.
Preferably, with lubricator, in parts by weight, raw material composition is the high-speed canning line：Trans block
12 parts of polyethers, 7 parts of APG0810,5.5 parts of fatty alcohol ether phosphate, 4 parts of disodium ethylene diamine tetraacetate, 2.5 parts of isothiazolinone,
2.5 parts of ethyl alcohol, 66.5 parts of water.
Preferably, with lubricator, in parts by weight, raw material composition is the high-speed canning line：Trans block
10 parts of polyethers, 2 parts of 6 parts of APG0810, APG0814,5 parts of fatty alcohol ether phosphate, 3.8 parts of disodium ethylene diamine tetraacetate, different thiophene
2.5 parts of oxazoline ketone, 3 parts of ethyl alcohol, 67.7 parts of water.
The invention also discloses the preparation method of above-mentioned high-speed canning line with lubricator, comprise the following steps：
Step (1)：Trans block polyether, alkyl glycosides, fatty alcohol ether phosphorus are weighed according to the raw material of lubricant composition
Acid esters, disodium ethylene diamine tetraacetate, isothiazolinone, ethyl alcohol, water；
Step (2)：Trans block polyether and alkyl glycosides are sequentially added in water, stirring makes it be uniformly dispersed；
Step (3)：Fatty alcohol ether phosphate is added in into the mixed solution obtained by step (2), stirring makes it be uniformly dispersed；
Step (4)：Disodium ethylene diamine tetraacetate is added in into the mixed solution obtained by step (3), stirring makes it scattered equal
It is even；
Step (5)：Isothiazolinone is sequentially added into the mixed solution obtained by step (4), ethyl alcohol stirs evenly；Thus
Obtained high-speed canning line is with lubricator.
Further, step (1)~(5) carry out at normal temperatures.
Further, the mixing time in step (2) is 10~15min, and the mixing time in step (3) is 5~10min,
Mixing time in step (4) is 10~15min.
The compounding principle and effect of each ingredient in above-mentioned lubricant：
(1) trans block polyether is ethylene oxide and the block polymer of propylene oxide, is nonionic surfactant.Point
Sub- both ends are polypropylene oxide group, are between two parties polyethylene oxide group, general molecular formula is：HO[CH(CH3)CH2O]X-
(CH2CH2O)Y-[CH(CH3)CH2O]XH.With excellent greasy property, good water solubility, low bubble, while can also effectively inhibit body
It is that foam generates.
(2) alkyl glycosides is also known as alkyl poly glucoside, and english abbreviation APG is closed by natural fatty alcohol and alkyl sugar
Into, it is a kind of comprehensive new non-ionic surfactants of performance, there is good lubrication, wetting and permeability, there is height
Surface-active, good ecological security and intermiscibility are internationally recognized preferred green functional surfactants.The present invention
The alkyl glycosides is that (APG0810 is the alkyl sugar that carbochain is distributed in 8~10 by least one of APG0810 and APG0814
The trade name of glycosides, APG0814 are the trade name for the alkyl glycosides that carbochain is distributed in 8~14).Alkyl glycosides surface tension is low, nothing
Cloud point, HLB value are adjustable, wetting power is strong, strong detergency, foaming abundancy are fine and smooth, compatibility is strong, nontoxic, harmless, stingless to skin
Swash, it is biodegradable rapid thorough, can be with any types surfactant compound, synergistic effect is apparent.Resist with stronger wide spectrum
Bacterium activity, product thickening effect is notable, is easy to dilution, without gelatin phenomenon, easy to use.It is and resistance to highly basic, resistance to strong acid, resistance to hard
Water, salt-resistance are strong.
(3) fatty alcohol ether phosphate has the property such as excellent decontamination, emulsification, lubrication, washing, scattered, antistatic and antirust
Can, improve greasy property simultaneously in the present invention, moreover it is possible to improve the border membrane stability that lubricant is formed in use, prevent from setting
It is standby to get rusty.
(4) disodium ethylene diamine tetraacetate is PH conditioning agents and chelating agent, has very strong chelating metal ion (Ca2+、Ma2 +) ability, the hardness of water can be reduced, prevent that redeposition, while regulation system pH is precipitated.
(5) isothiazolinone is fungicide, is to act what is killed livestock by disconnecting the key of bacterium and algae protein matter.It is different
After thiazolinone is contacted with microorganism, it promptly can irreversibly inhibit its growth, so as to cause the death of microbial cell, therefore
There is very strong inhibition and killing effect to common bacteria, fungi, algae etc..It kills livestock efficient, degradability is good, has and does not generate
The features such as residual, safe operation, compatibility are good, stability is strong, use cost is low.It can be with chlorine and most of anions and canons and non-
Ionic surface active agent is miscible.Isothiazolinone mainly prevents product of the present invention, and chain road grows micro- life in use
Object.
(6) ethyl alcohol is commonly called as alcohol, can be dissolved each other with water with arbitrary proportion, plays defoaming and solubilization in the present invention, also
System solidification point can be reduced, improves anti-freezing property.
(7) water is solvent, the other components in dissolution system.
Compared with prior art, high-speed canning line provided by the invention with lubricator and preparation method thereof, has as follows
Innovative point：
The lubricant of the present invention has abandoned traditional fatty amine system, using trans block polyether as main lubricant, and it is multiple
With alkyl glycosides, fatty alcohol polyoxyethylene ether phosphate monoester, there is excellent performance of anti-blockage and greasy property, solve at a high speed
Filling problem is trembled when line is filling；Lubricant of the present invention is compounded in room temperature, and production process free from extraneous odour, preparation process is simple to operation, energy
Consume low, green pollution-free.
Description of the drawings
It in order to illustrate more clearly about the embodiment of the present invention or technical scheme of the prior art, below will be to embodiment or existing
There is attached drawing needed in technology description to be briefly described, it should be apparent that, the accompanying drawings in the following description is only this
Some embodiments of invention, for those of ordinary skill in the art, without creative efforts, can be with
Other attached drawings are obtained according to these attached drawings.
Attached drawing 1 is the practical situations figure of high-speed canning line of the present invention with lubricator；
Attached drawing 2 is the practical situations figure of commercially available high-speed canning line with lubricator.
Specific embodiment
The present invention is further described with reference to embodiment.
The trans block polyether that the present invention selects is RPE1740 (molecular weight about 2650g/mol, the cloud point of BASF production
About 50 DEG C) there is excellent greasy property, good water solubility, low bubble can also effectively inhibition system foam generate simultaneously.Other companies
The trans block polyether of production also applies to prepare high-speed canning line of the present invention with lubricator.In practical operation,
The molecular weight of the trans block polyether of other producers can also be used as profit of the present invention in about 50 DEG C of 2650g/mol and cloud point
The raw material of lubrication prescription.
The fatty alcohol ether phosphate that the present invention selects is the fatty alcohol ether phosphate of Jiangsu Province Hai'an petrochemical plants
MOA-9P.The fatty alcohol ether phosphate MOA-9P of other producers also can be as the raw material of lubricant of the present invention.
The alkyl glycosides that the present invention selects is the APG0810 and APG0814 of Taiyuan Fa Kai Chemical Co., Ltd.s production.Other
The alkyl glycosides of producer can also be used as the raw material of lubricant of the present invention.
Remaining is general industrial chemicals.
Embodiment 1
With lubricator, raw material composition is a kind of high-speed canning line：RPE1740 10g, APG0810 6g, APG0814
2g, fatty alcohol ether phosphate 5g, disodium ethylene diamine tetraacetate 3.8g, isothiazolinone 2.5g, ethyl alcohol 3g, water 67.7g.
Step (1)：Each raw material is weighed according to above-mentioned weight；
Step (2)：RPE1740 and APG0810, APG0814 are sequentially added in water, stirring makes it be uniformly dispersed, and stirs
Time control is in 10~15min；
Step (3)：Fatty alcohol ether phosphate is added in into the mixed solution obtained by step (2), stirring makes it be uniformly dispersed,
Mixing time is controlled in 5~10min；
Step (4)：Disodium ethylene diamine tetraacetate is added in into the mixed solution obtained by step (3), stirring makes it scattered equal
Even, mixing time is controlled in 10~15min；
Step (5)：Isothiazolinone is sequentially added into the mixed solution obtained by step (4), ethyl alcohol stirs evenly；Thus
Obtained high-speed canning line is with lubricator.
Above-mentioned steps (1)~(5) carry out at normal temperatures.
Embodiment 2
With lubricator, raw material composition is a kind of high-speed canning line：RPE1740 12g, APG0810 7g, fatty alcohol ether phosphorus
Acid esters 5.5g, disodium ethylene diamine tetraacetate 4g, isothiazolinone 2.5g, ethyl alcohol 2.5g, water 66.5g.
Step (1)：Each raw material is weighed according to above-mentioned weight；
Step (2)：RPE1740 and APG0810 are sequentially added in water, stirring makes it be uniformly dispersed, mixing time control
In 10~15min；
Step (3)：Fatty alcohol ether phosphate is added in into the mixed solution obtained by step (2), stirring makes it be uniformly dispersed,
Mixing time is controlled in 5~10min；
Step (4)：Disodium ethylene diamine tetraacetate is added in into the mixed solution obtained by step (3), stirring makes it scattered equal
Even, mixing time is controlled in 10~15min；
Step (5)：Isothiazolinone is sequentially added into the mixed solution obtained by step (4), ethyl alcohol stirs evenly；Thus
Obtained high-speed canning line is with lubricator.
Above-mentioned steps (1)~(5) carry out at normal temperatures.
Embodiment 3
With lubricator, raw material composition is a kind of high-speed canning line：RPE1740 5g, APG0810 8g, APG0814 4g,
Fatty alcohol ether phosphate 2g, disodium ethylene diamine tetraacetate 5g, isothiazolinone 1g, ethyl alcohol 8g, water 45g.
Step (1)：Each raw material is weighed according to above-mentioned weight；
Step (2)：RPE1740 and APG0810 are sequentially added in water, stirring makes it be uniformly dispersed, mixing time control
In 10~15min；
Step (3)：Fatty alcohol ether phosphate is added in into the mixed solution obtained by step (2), stirring makes it be uniformly dispersed,
Mixing time is controlled in 5~10min；
Step (4)：Disodium ethylene diamine tetraacetate is added in into the mixed solution obtained by step (3), stirring makes it scattered equal
Even, mixing time is controlled in 10~15min；
Step (5)：Isothiazolinone is sequentially added into the mixed solution obtained by step (4), ethyl alcohol stirs evenly；Thus
Obtained high-speed canning line is with lubricator.
Above-mentioned steps (1)~(5) carry out at normal temperatures.
Embodiment 4
With lubricator, raw material composition is a kind of high-speed canning line：RPE1740 15g, APG0810 4g, fatty alcohol ether phosphorus
Acid esters 10g, disodium ethylene diamine tetraacetate 1g, isothiazolinone 5g, ethyl alcohol 1g, water 86g.
Step (1)：Each raw material is weighed according to above-mentioned weight；
Step (2)：RPE1740 and APG0810 are sequentially added in water, stirring makes it be uniformly dispersed, mixing time control
In 10~15min；
Step (3)：Fatty alcohol ether phosphate is added in into the mixed solution obtained by step (2), stirring makes it be uniformly dispersed,
Mixing time is controlled in 5~10min；
Step (4)：Disodium ethylene diamine tetraacetate is added in into the mixed solution obtained by step (3), stirring makes it scattered equal
Even, mixing time is controlled in 10~15min；
Step (5)：Isothiazolinone is sequentially added into the mixed solution obtained by step (4), ethyl alcohol stirs evenly；Thus
Obtained high-speed canning line is with lubricator.
Above-mentioned steps (1)~(5) carry out at normal temperatures.
To the high-speed canning line of preparation, with lubricator effect is further examined below.
The high-speed canning line that the present invention is prepared using embodiment 1 carries out following realization with lubricator as experimental subjects, right
Ratio uses current fatty amine based lubricant common on the market, is the fatty amine based lubricant of the easy company's production in Henan,
Main component is fatty amines, it is following in order to represent to facilitate use it is " commercially available " represent comparative example.
(1) practical situations of high-speed canning line of the present invention with lubricator by Fig. 1 as shown in Figure 1, can be seen
Go out, lubricant prepared by the present invention in actual use, generates extremely low foam or non-foam generates, will not be to aluminium or plastics
The normal operation that chain road is made generates application, will not cause the accumulative of foam, avoid the influence to workshop hygiene environment；It is commercially available
High-speed canning line practical situations with lubricator as shown in Fig. 2, as seen from Figure 2：Commercially available high-speed canning line is used
There is the gathering, it is necessary to periodically carry out foam of a large amount of blistering group in chain Dao Shanghelian roads both sides made of the aluminium or plastics of lubricant
Cleaning seriously affects the hygienic conditions situation in workshop.It follows that lubricant efficiently solves high-speed canning made of the present invention
The foaming phenomena of line with lubricator.
(2) lubricant of the invention has very strong chelant using disodium ethylene diamine tetraacetate as PH conditioning agents and chelating agent
Metal ion (Ca2+、Ma2+) ability, the hardness of water can be reduced, prevent that redeposition, while regulation system is precipitated
pH.High-speed canning line prepared by the embodiment of the present invention 1 is with lubricator using the depositional phenomenon for not occurring dirt so far.
(3) fungistatic effect of lubricant of the invention is as shown in table 1-2.
The lubricant and commercially available lubricant of 1 embodiment 1 of table are in working concentration to the fungistatic effect of Escherichia coli
Note："-" represents asepsis growth in table, and "+" indicates bacterium growth.With 1:Exemplified by 150, " 1 " represents the use of lubricant
It measures as 1 part, " 150 " represent that the dosage of softened water is 150 parts.
As shown in Table 1, the high-speed canning line that prepared by the embodiment of the present invention 1 is with lubricator 1 in dilution ratio:150、1:
200、1:250、1:Escherichia coli are shown with good fungistatic effect in the case of 300, and commercially available high-speed canning line is used
Lubricant is 1 in dilution ratio:150、1:When 200 Escherichia coli are shown with good fungistatic effect, and is in dilution ratio
1:250、1:It is poor to the fungistatic effect of Escherichia coli when 300, hence it is evident that have Escherichia coli generation.
Lubricant made from 2 example 1 of table and commercially available lubricant are in working concentration to the antibacterial effect of staphylococcus aureus
Fruit
Note："-" represents asepsis growth in table, and "+" indicates bacterium growth.With 1:Exemplified by 150, " 1 " represents the use of lubricant
It measures as 1 part, " 150 " represent that the dosage of softened water is 150 parts.
As shown in Table 2, the high-speed canning line that prepared by the embodiment of the present invention 1 is with lubricator 1 in dilution ratio:150、1:
200、1:250、1:Good fungistatic effect is shown in the case of 300 to staphylococcus aureus, and commercially available high speed fills
Wiring is with lubricator 1 in dilution ratio:150、1:Good fungistatic effect is shown when 200 to staphylococcus aureus, and
It is 1 in dilution ratio:250、1:It is poor to the fungistatic effect of staphylococcus aureus when 300, hence it is evident that have Escherichia coli generation.
It follows that the bacteriostasis property of the high-speed canning line of the present invention with lubricator, has and is substantially better than commercially available lubricant.
(4) high-speed canning line for preparing the embodiment of the present invention 1-3 with lubricator with commercially available fatty amine based lubricant
It is respectively used to 120000 bottle of certain brewery/hour tinned high-speed canning line and tests its greasy property, the results are shown in Table 3.Ratio of the present invention
The greasy property of commercially available fatty amine based lubricant at least improves 17.0%, and the lubricating coefficient in the exit of wine filling machine is averaged
24.8% is reduced, the lubricating coefficient of the lubricant of embodiment 2 reduces 25.68%, the four of selection in the exit of wine filling machine
The greasy property of a position averagely improves 21.2%.
The greasy property test result of high-speed canning line prepared by 3 the embodiment of the present invention 1~3 of table with lubricator
Note：Lubricating coefficient refers to：The illness coefficient that rubs between chain and container bottom contact surface.Good lubricant can significantly reduce
The coefficient of friction between carrier bar and container-contacting surface is transmitted, and excellent lubricant effect can be generated.Lubricating coefficient assay method is as follows：
1st, the wine filling machine outlet of 120000 Wan bottle of the brewery/hour tinned high-speed canning line, sterilization machine import are chosen, is killed
Bacterium machine exports and four positions of fan outlet, and the spray concentration of four position lubricants of adjustment is all 0.2%, is spray between the spray stopping time
Leaching 20 seconds stops 30 seconds, and chain road lubrication is carried out using different lubricants；
2nd, the filling of tested constant weight beer with non-resilient retainer plate is fixed and be connected with connecting line (non-resilient) with tensiometer；
3rd, the constant weight beer grouting horizontal connected is positioned on the selected carrier chain of constant motion；
4th, slowly decontrol tested beer to fill, beer is kept to fill and is stablized with tensiometer, reads tensiometer pulling force numerical value Fx, unit
For N；
5th, the mass M y that tested constant weight beer fills is weighed, constant weight beer is calculated and fills weight Fy=My*g, unit N, g
For acceleration of gravity, it is worth for 9.8N/kg；
6th, the calculating of lubricating coefficient：F (lubricating coefficient)=Fx/Fy；
When the 7th, measuring pulling force is kept to stablize, do not pull tensiometer quickly；When doing greasy property comparison, measuring condition need to be kept
Unanimously.
(5) lubricant for preparing the present invention uses half for 120000 bottle of the brewery/hour tinned high-speed canning line
Nian Hou, it is as follows that user integrates service condition：
1st, high lubricating effect trembles filling when using fatty amine based lubricant filling before solving the problems, such as.Use the present invention
Product also never occurred trembling filling phenomenon in production line oepration at full load, while poured in down a chimney rate and decline more than 35%.
2nd, low bubble, free from extraneous odour are corrosion-free.
3rd, generated without sediment, produced in spring and autumn in the use of half a year in busy season and do not occurred blocking pipeline and nozzle phenomenon,
Without periodic cleaning lubricating system.Refer to table 4.
The lubricant of 4 1-3 of the embodiment of the present invention of table is compared with the using effect of commercially available fatty amine based lubricant
4th, decontamination, bacteriostasis property are good, do not occur mildew in use and wine glues.
The foregoing description of the disclosed embodiments enables professional and technical personnel in the field to realize or use the present invention.
A variety of modifications of these embodiments will be apparent for those skilled in the art, it is as defined herein
General Principle can be realized in other embodiments without departing from the spirit or scope of the present invention.Therefore, it is of the invention
The embodiments shown herein is not intended to be limited to, but more to be met and the principles and novel features disclosed herein phase
Consistent most wide scope.
Claims (8)
1. a kind of high-speed canning line is with lubricator, which is characterized in that in parts by weight, raw material composition is：
Trans 5~15 parts of block polyether, 4~12 parts of alkyl glycosides, 2~10 parts of fatty alcohol ether phosphate, ethylenediamine tetra-acetic acid two
1~5 part of sodium, 1~5 part of isothiazolinone, 1~8 part of ethyl alcohol, 45~86 parts of water.
2. high-speed canning line according to claim 1 is with lubricator, which is characterized in that the trans block polyether is bar
This husband RPE1740.
3. high-speed canning line according to claim 1 is with lubricator, which is characterized in that the alkyl glycosides is
At least one of APG0810 and APG0814.
4. high-speed canning line according to claim 3 is with lubricator, which is characterized in that in parts by weight, raw material composition
For：Trans 12 parts of block polyether, 7 parts of APG0810,5.5 parts of fatty alcohol ether phosphate, 4 parts of disodium ethylene diamine tetraacetate, different thiophene
2.5 parts of oxazoline ketone, 2.5 parts of ethyl alcohol, 66.5 parts of water.
5. high-speed canning line according to claim 3 is with lubricator, which is characterized in that in parts by weight, raw material composition
For：Trans 10 parts of block polyether, 2 parts of 6 parts of APG0810, APG0814,5 parts of fatty alcohol ether phosphate, ethylenediamine tetra-acetic acid two
3.8 parts of sodium, 2.5 parts of isothiazolinone, 3 parts of ethyl alcohol, 67.7 parts of water.
6. the preparation method of high-speed canning line with lubricator according to Claims 1 to 5 any one, which is characterized in that
Comprise the following steps：
Step (1)：According to the raw material of the lubricant composition weigh trans block polyether, alkyl glycosides, fatty alcohol ether phosphate,
Disodium ethylene diamine tetraacetate, isothiazolinone, ethyl alcohol, water；
Step (2)：Trans block polyether and alkyl glycosides are sequentially added in water, stirring makes it be uniformly dispersed；
Step (3)：Fatty alcohol ether phosphate is added in into the mixed solution obtained by step (2), stirring makes it be uniformly dispersed；
Step (4)：Disodium ethylene diamine tetraacetate is added in into the mixed solution obtained by step (3), stirring makes it be uniformly dispersed；
Step (5)：Isothiazolinone is sequentially added into the mixed solution obtained by step (4), ethyl alcohol stirs evenly；Thus it is made
High-speed canning line is with lubricator.
7. the preparation method of high-speed canning line according to claim 6 with lubricator, which is characterized in that step (1)~(5)
It carries out at normal temperatures.
8. the preparation method of high-speed canning line according to claim 6 with lubricator, which is characterized in that in step (2)
Mixing time is 10~15min, and the mixing time in step (3) is 5~10min, the mixing time in step (4) for 10~
15min。
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| CN112680271A (en) * | 2020-12-24 | 2021-04-20 | 成都优力赛科技有限公司 | Water-based lubricant for high-speed pop can |
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| CN108085119B (en) | 2020-12-01 |
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