CN108083913A - A kind of big bone polypeptide nucleosides chelating mother liquor, preparation method and its usage - Google Patents

A kind of big bone polypeptide nucleosides chelating mother liquor, preparation method and its usage Download PDF

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Publication number
CN108083913A
CN108083913A CN201711439475.0A CN201711439475A CN108083913A CN 108083913 A CN108083913 A CN 108083913A CN 201711439475 A CN201711439475 A CN 201711439475A CN 108083913 A CN108083913 A CN 108083913A
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parts
acid
chelating
sulfate
nucleosides
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白宝祥
杨秀莲
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Heilongjiang Bao Xiang Agricultural Science And Technology Development Co Ltd
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Heilongjiang Bao Xiang Agricultural Science And Technology Development Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05CNITROGENOUS FERTILISERS
    • C05C3/00Fertilisers containing other salts of ammonia or ammonia itself, e.g. gas liquor
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/60Biocides or preservatives, e.g. disinfectants, pesticides or herbicides; Pest repellants or attractants
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/80Soil conditioners

Abstract

The composite fertilizer used the present invention relates to agriculture and forestry more particularly to a kind of big bone polypeptide nucleosides chelating mother liquor, preparation method and its usage.The big bone polypeptide nucleosides chelating mother liquor of the present invention, is made of following raw materials according:Water, bone, hair, sulfuric acid, nucleotide, scurf, the dregs of fat, slaughterhouse leftover bits and pieces, granulated slag, acid protease, glucose, polyglyceryl fatty acid ester, zinc sulfate, ferrous sulfate, manganese sulfate, sodium ethylene diamine tetracetate, copper sulphate, borax, ammonium molybdate, magnesium sulfate, amino acid, humic acid, sodium selenite, Laurocapram, propylene glycol, monoalky lether phosphate kalium salt, citric acid, cod-liver oil, sodium glutamate, citric acid fatty glyceride, milk.Big bone polypeptide nucleosides chelating mother liquor of the invention can significantly improve the immune function of crops, promote photosynthesis, Uptake and translocation, make crops healthy growth.

Description

A kind of big bone polypeptide nucleosides chelating mother liquor, preparation method and its usage
Technical field
The composite fertilizer more particularly to a kind of big bone polypeptide nucleosides chelating mother liquor, preparation side used the present invention relates to agriculture and forestry Method and application thereof.
Background technology
In agricultural production, fertilizer is essential material used for agriculture.Present existing fertilizer is divided into inorganic fertilizer and has Machine fertilizer, inorganic fertilizer are the fertilizer that minerals are process through inorganic polymer composite flocculant, and production technology is very ripe;It is existing Inorganic fertilizer has the single fertilizers such as urea, calcium superphosphate, monoammonium phosphate or Diammonium phosphate (DAP), potassium sulfate or potassium chloride.Biological organic Fertilizer be microorganisms with specific functions with mainly using plant and animal residues as source and through harmless treatment, decomposed organic materials it is compound and Into one kind have both microbial manure and the fertilizer of organic fertilizer effect.Have by the vital movement and abundant of its contained microorganism Machine matter, it is applied to the utilization rate that agricultural production can improve fertilizer, promotes plant growth, enhances the disease resistance of crop, improves Yield.Biological organic fertilizer obtains agriculture as that can improve the soil organism but also increase the fertilizer product of soil microbe quantity Industry authorities at different levels widely popularize.It but, must be containing big since biological organic fertilizer requirement is while the content of organic matter is ensured The soil beneficial microbe of amount, such standard add the technology content and production difficulty of bio-organic fertilizer product.
Compound fertilizer has been more and more widely used, but due to the limitation of technology, the composite fertilizer of domestic manufacturer's production The material overwhelming majority is solid forms, and existing compound fertilizer is all that graininess is used to spread fertilizer over the fields.Peasant combines pipeline fertilising skill Art or while being applied as Water soluble fertilizer, find that these fertilizer are insoluble in water.Therefore, the demand of China's liquid fertilizer is very Greatly.But the research of the Liquid Fertilizer in China is constantly in relatively backward state, and the fertilizer of liquid form is few, although some producers Liquid Fertilizer can be produced, but these Liquid Fertilizers are mostly the relatively low clear liquid fertilizer of nutrient content, also add transportation cost.
It is disclosed in the patent application of Chinese patent application Publication No. CN107445739A disclosed in 8 days December in 2017 A kind of rice reproductive stage dedicated fertilizer, though the dedicated fertilizer can effectively promote the yield and quality of rice, this is specially It is solid forms with fertilizer, when use is insoluble in water, can so influence fertilizer efficiency.
The content of the invention
It is existing to solve the object of the present invention is to provide a kind of big bone polypeptide nucleosides chelating mother liquor, preparation method and its usage The problem of with the presence of technology.
According to an aspect of the present invention, a kind of big bone polypeptide nucleosides chelating mother liquor provided by the invention, by following raw materials according It is made:Water, bone, hair, sulfuric acid, nucleotide, scurf, the dregs of fat, slaughterhouse leftover bits and pieces, granulated slag, acid protease, glucose, Polyglyceryl fatty acid ester, zinc sulfate, ferrous sulfate, manganese sulfate, sodium ethylene diamine tetracetate, copper sulphate, borax, ammonium molybdate, sulfuric acid Magnesium, amino acid, humic acid, sodium selenite, Laurocapram, propylene glycol, monoalky lether phosphate kalium salt, citric acid, cod-liver oil, Sodium glutamate, citric acid fatty glyceride, milk.
Further, big bone polypeptide nucleosides chelating mother liquor is made from the following raw materials in parts by weight:30-60 parts of water, 10-15 parts of bone, 2-10 parts of hair, 6-20 parts of sulfuric acid, 8-10 parts of nucleotide, 15-30 parts of scurf, 10-30 parts of the dregs of fat, slaughterhouse 5-15 parts of leftover bits and pieces, 5-15 parts of granulated slag, 0.2-1 parts of acid protease, 2-10 parts of glucose, polyglyceryl fatty acid ester 0.1-0.6 Part, 6-30 parts of zinc sulfate, 3-20 parts of ferrous sulfate, 1-2.5 parts of manganese sulfate, 1-3 parts of sodium ethylene diamine tetracetate, 2-6 parts of copper sulphate, 2-10 parts of borax, 0.1-0.5 parts of ammonium molybdate, 2-5 parts of magnesium sulfate, 5-10 parts of amino acid, 1-5 parts of humic acid, sodium selenite 0.001-1 parts, 0.1-0.5 parts of Laurocapram, 0.3-0.5 parts of propylene glycol, 3-13 parts of monoalky lether phosphate kalium salt, citric acid 0.5-7 parts, 0.05-0.7 parts of cod-liver oil, 0.5-2.0 parts of sodium glutamate, 0.1-0.8 parts of citric acid fatty glyceride, milk 5- 35 parts.
Further, big bone polypeptide nucleosides chelating mother liquor is made from the following raw materials in parts by weight:35-55 parts of water, 11-14 parts of bone, 3-8 parts of hair, 8.5-9.5 parts of nucleotide, 18-28 parts of scurf, 12-28 parts of the dregs of fat, are butchered at 8-18 parts of sulfuric acid Heel 8-13 parts off field, 8-12 parts of granulated slag, 0.4-0.8 parts of acid protease, 4-8 parts of glucose, polyglyceryl fatty acid ester 0.3- 0.5 part, 8-28 parts of zinc sulfate, 5-18 parts of ferrous sulfate, 1.5-2.0 parts of manganese sulfate, 1.5-2.5 parts of sodium ethylene diamine tetracetate, sulphur Sour copper 3-5 parts, 4-8 parts of borax, 0.2-0.4 parts of ammonium molybdate, 3-4 parts of magnesium sulfate, 7-8 parts of amino acid, 2-4 parts of humic acid, sub- selenium Sour sodium 0.05-0.8 parts, 0.2-0.4 parts of Laurocapram, 0.35-0.45 parts of propylene glycol, monoalky lether phosphate kalium salt 5-10 Part, 1-5 parts of citric acid, 0.1-0.5 parts of cod-liver oil, 0.7-1.5 parts of sodium glutamate, 0.2-0.5 parts of citric acid fatty glyceride, 10-30 parts of milk.
Further, big bone polypeptide nucleosides chelating mother liquor is made from the following raw materials in parts by weight:45 parts of water, bone 12 parts, 5 parts of hair, 15 parts of sulfuric acid, 9 parts of nucleotide, 25 parts of scurf, 25 parts of the dregs of fat, 10 parts of slaughterhouse leftover bits and pieces, 10 parts of granulated slag, 0.6 part of acid protease, 6 parts of glucose, 0.4 part of polyglyceryl fatty acid ester, 18 parts of zinc sulfate, 13 parts of ferrous sulfate, manganese sulfate 1.8 parts, 2 parts of sodium ethylene diamine tetracetate, 4 parts of copper sulphate, 6 parts of borax, 0.3 part of ammonium molybdate, 3.5 parts of magnesium sulfate, amino acid 7.5 Part, 3 parts of humic acid, 0.5 part of sodium selenite, 0.3 part of Laurocapram, 0.4 part of propylene glycol, 8 parts of monoalky lether phosphate kalium salt, 3 parts of citric acid, 0.3 part of cod-liver oil, 1.0 parts of sodium glutamate, 0.4 part of citric acid fatty glyceride, 20 parts of milk.
According to an aspect of the present invention, the preparation method of a kind of big bone polypeptide nucleosides chelating mother liquor provided by the invention, Including step:
1) bone soup is boiled:By bone, hair, sulfuric acid, nucleotide, scurf, the dregs of fat, slaughterhouse leftover bits and pieces, granulated slag, single alkane Base ether phosphate sylvite, citric acid are added to the water, and heat, boil, the extraction of cooling filtering afterwards;
2) it is trace element chelated:By acid protease, glucose, polyglyceryl fatty acid ester, zinc sulfate, ferrous sulfate, sulphur Sour manganese, sodium ethylene diamine tetracetate, copper sulphate, borax, ammonium molybdate, magnesium sulfate, amino acid, humic acid, sodium selenite, bay nitrogen are tall and erect Ketone, propylene glycol, cod-liver oil, sodium glutamate, citric acid fatty glyceride, milk are added in the bone soup of tanning, heat, chela Close, stirring, extraction, postcooling.
Further, 100-130 DEG C, tanning to solid-state reactants dissolving are heated to during the tanning bone soup.
Further, it is described it is trace element chelated during be heated to 45-65 DEG C, chelating to trace element melt.
According to an aspect of the present invention, the big bone polypeptide nucleosides chelating mother liquor provided by the invention is used for large area kind Application on the crops or plant of plant.
Compared with prior art, the present invention it has the following advantages:
1) big bone polypeptide nucleosides of the invention chelating mother liquor, wherein containing the benefit materials amino for being easy to crops absorption Acid, with reference to various trace elements, can salt resistance alkali, low-temperature resistance, anti-continuous cropping, cold-resistant drought resisting, improvement soil, improve water quality, both can be with It prevents and cures diseases and can disease and insect resistance;
2) big bone polypeptide nucleosides of the invention chelating mother liquor can significantly improve the immune function of crops, promote photosynthetic work With, increase that Chlorophyll synthesis, robust plant, blade be plump, crops healthy growth, so as to reduce labor intensity, reduce production Cost improves crop yield, improves crop quality, and agricultural product is promoted to list in advance;Make agricultural product are nontoxic, green organic without Residual.
Above description is only the general introduction of technical solution of the present invention, in order to better understand the technological means of the present invention, And can be practiced according to the content of specification, and in order to allow above and other objects of the present invention, feature and advantage can It is clearer and more comprehensible, below the special specific embodiment for lifting the present invention.
Specific embodiment
Technical scheme is clearly and completely described below in conjunction with embodiment, it is clear that described reality It is part of the embodiment of the present invention to apply example, instead of all the embodiments.Based on the embodiments of the present invention, the common skill in this field Art personnel all other embodiments obtained without making creative work belong to the model that the present invention protects It encloses.
The big bone polypeptide nucleosides chelating mother liquor of the present invention, is made of following raw materials according:Water, bone, hair, sulfuric acid, nucleotide, Scurf, the dregs of fat, slaughterhouse leftover bits and pieces, granulated slag, acid protease, glucose, polyglyceryl fatty acid ester, zinc sulfate, ferrous sulfate, Manganese sulfate, sodium ethylene diamine tetracetate, copper sulphate, borax, ammonium molybdate, magnesium sulfate, amino acid, humic acid, sodium selenite, bay nitrogen Tall and erect ketone, propylene glycol, monoalky lether phosphate kalium salt, citric acid, cod-liver oil, sodium glutamate, citric acid fatty glyceride, ox Milk.
Laurocapram can promote the infiltration of blade, soak plant leaf surface, promote absorption of the plant to fertilizer or drug, reduce Dosage.Environmental pollution can be mitigated by reducing Fertilizer application amount, while reduce cost.Laurocapram so that chelating mother liquor is planting Quickly conducted in object, reduce sunlight to the evaporation of liquid, drug effect can be improved 2-3 times.
Polyglyceryl fatty acid ester is a kind of efficient, excellent surfactant, emulsifier, stabilizer, thickener, resistive connection Agent has the multiple performances such as scattered, moistening, stable, and is highly safe.Polyglyceryl fatty acid ester makes chelating mother liquor not It is layered, does not precipitate, do not freeze, drug effect is more stable, effect is more prominent.
Citric acid fatty acid glycerine fat has emulsification, scattered, chelating, antioxidation;, can with micro heavy be complexed, Synergy and solubilization have been used in mixed way with antioxidant;The brown stain of product is can inhibit, improves its stability.
Embodiment 1
Prepare raw material according to following parts by weight:
Under 45 parts of water, 12 parts of bone, 5 parts of hair, 15 parts of sulfuric acid, 9 parts of nucleotide, 25 parts of scurf, 25 parts of the dregs of fat, slaughterhouse 10 parts of heel, 10 parts of granulated slag, 0.6 part of acid protease, 6 parts of glucose, 0.4 part of polyglyceryl fatty acid ester, 18 parts of zinc sulfate, sulphur Sour 13 parts ferrous, 1.8 parts of manganese sulfate, 2 parts of sodium ethylene diamine tetracetate, 4 parts of copper sulphate, 6 parts of borax, 0.3 part of ammonium molybdate, magnesium sulfate 3.5 parts, 7.5 parts of amino acid, 3 parts of humic acid, 0.5 part of sodium selenite, 0.3 part of Laurocapram, 0.4 part of propylene glycol, monoalkyl 8 parts of ether phosphate sylvite, 3 parts of citric acid, 0.3 part of cod-liver oil, 1.0 parts of sodium glutamate, 0.4 part of citric acid fatty glyceride, 20 parts of milk.
Specific preparation method:
1) bone soup is boiled:By bone, hair, sulfuric acid, nucleotide, scurf, the dregs of fat, slaughterhouse leftover bits and pieces, granulated slag, single alkane Base ether phosphate sylvite, citric acid are added to the water, and are heated to 100 DEG C, tanning 68h, cool down afterwards, filter, extraction;
2) it is trace element chelated:By acid protease, glucose, polyglyceryl fatty acid ester, zinc sulfate, ferrous sulfate, sulphur Sour manganese, sodium ethylene diamine tetracetate, copper sulphate, borax, ammonium molybdate, magnesium sulfate, amino acid, humic acid, sodium selenite, bay nitrogen are tall and erect Ketone, propylene glycol, cod-liver oil, sodium glutamate, citric acid fatty glyceride, milk are added in the bone soup of tanning, are heated to 45 DEG C, chelating 3.8h, stirring 7h, extraction.
Embodiment 2
Prepare raw material according to following parts by weight:
30 parts of water, 10 parts of bone, 2 parts of hair, 20 parts of sulfuric acid, 10 parts of nucleotide, 30 parts of scurf, 10 parts of the dregs of fat, slaughterhouse 5 parts of leftover bits and pieces, 5 parts of granulated slag, 1 part of acid protease, 2 parts of glucose, 0.6 part of polyglyceryl fatty acid ester, 6 parts of zinc sulfate, sulfuric acid 20 parts ferrous, 2.5 parts of manganese sulfate, 1 part of sodium ethylene diamine tetracetate, 6 parts of copper sulphate, 2 parts of borax, 0.5 part of ammonium molybdate, magnesium sulfate 2 Part, 0 part of amino acid/11,1 part of humic acid, 1 part of sodium selenite, 0.1 part of Laurocapram, 0.5 part of propylene glycol, monoalky lether phosphoric acid 3 parts of ester sylvite, 0.5 part of citric acid, 0.05 part of cod-liver oil, 0.5 part of sodium glutamate, 0.1 part of citric acid fatty glyceride, milk 5 parts.
Specific preparation method:
1) bone soup is boiled:By bone, hair, sulfuric acid, nucleotide, scurf, the dregs of fat, slaughterhouse leftover bits and pieces, granulated slag, single alkane Base ether phosphate sylvite, citric acid are added to the water, and are heated to 130 DEG C, tanning 60h, cool down afterwards, filter, extraction;
2) it is trace element chelated:By acid protease, glucose, polyglyceryl fatty acid ester, zinc sulfate, ferrous sulfate, sulphur Sour manganese, sodium ethylene diamine tetracetate, copper sulphate, borax, ammonium molybdate, magnesium sulfate, amino acid, humic acid, sodium selenite, bay nitrogen are tall and erect Ketone, propylene glycol, cod-liver oil, sodium glutamate, citric acid fatty glyceride, milk are added in the bone soup of tanning, are heated to 65 DEG C, chelating 4.8h, stirring 8h, extraction.
Embodiment 3
Prepare raw material according to following parts by weight:
Under 60 parts of water, 15 parts of bone, 10 parts of hair, 6 parts of sulfuric acid, 8 parts of nucleotide, 15 parts of scurf, 30 parts of the dregs of fat, slaughterhouse 15 parts of heel, 15 parts of granulated slag, 0.2 part of acid protease, 10 parts of glucose, 0.1 part of polyglyceryl fatty acid ester, 30 parts of zinc sulfate, 3 parts of ferrous sulfate, 1 part of manganese sulfate, 3 parts of sodium ethylene diamine tetracetate, 2 parts of copper sulphate, 10 parts of borax, 0.1 part of ammonium molybdate, magnesium sulfate 5 parts, 5 parts of amino acid, 5 parts of humic acid, 0.001 part of sodium selenite, 0.5 part of Laurocapram, 0.3 part of propylene glycol, monoalky lether 13 parts of phosphate kalium salt, 7 parts of citric acid, 0.7 part of cod-liver oil, 2.0 parts of sodium glutamate, 0.8 part of citric acid fatty glyceride, ox 35 parts of milk.
Specific preparation method:
1) bone soup is boiled:By bone, hair, sulfuric acid, nucleotide, scurf, the dregs of fat, slaughterhouse leftover bits and pieces, granulated slag, single alkane Base ether phosphate sylvite, citric acid are added to the water, and are heated to 105 DEG C, tanning 65h, cool down afterwards, filter, extraction;
2) it is trace element chelated:By acid protease, glucose, polyglyceryl fatty acid ester, zinc sulfate, ferrous sulfate, sulphur Sour manganese, sodium ethylene diamine tetracetate, copper sulphate, borax, ammonium molybdate, magnesium sulfate, amino acid, humic acid, sodium selenite, bay nitrogen are tall and erect Ketone, propylene glycol, cod-liver oil, sodium glutamate, citric acid fatty glyceride, milk are added in the bone soup of tanning, are heated to 50 DEG C, chelate 4.5h, stir 7.5h, extraction.
Embodiment 4
Prepare raw material according to following parts by weight:
35 parts of water, 11 parts of bone, 3 parts of hair, 18 parts of sulfuric acid, 9.5 parts of nucleotide, 28 parts of scurf, 12 parts of the dregs of fat, slaughterhouse 8 parts of leftover bits and pieces, 8 parts of granulated slag, 0.8 part of acid protease, 4 parts of glucose, 0.5 part of polyglyceryl fatty acid ester, 8 parts of zinc sulfate, sulphur Sour 18 parts ferrous, 2.0 parts of manganese sulfate, 1.5 parts of sodium ethylene diamine tetracetate, 5 parts of copper sulphate, 4 parts of borax, 0.4 part of ammonium molybdate, sulfuric acid 3 parts of magnesium, 8 parts of amino acid, 2 parts of humic acid, 0.8 part of sodium selenite, 0.2 part of Laurocapram, 0.45 part of propylene glycol, monoalky lether 5 parts of phosphate kalium salt, 1 part of citric acid, 0.1 part of cod-liver oil, 0.7 part of sodium glutamate, 0.2 part of citric acid fatty glyceride, ox 10 parts of milk.
Specific preparation method:
1) bone soup is boiled:By bone, hair, sulfuric acid, nucleotide, scurf, the dregs of fat, slaughterhouse leftover bits and pieces, granulated slag, single alkane Base ether phosphate sylvite, citric acid are added to the water, and are heated to 110 DEG C, tanning 60h, cool down afterwards, filter, extraction;
2) it is trace element chelated:By acid protease, glucose, polyglyceryl fatty acid ester, zinc sulfate, ferrous sulfate, sulphur Sour manganese, sodium ethylene diamine tetracetate, copper sulphate, borax, ammonium molybdate, magnesium sulfate, amino acid, humic acid, sodium selenite, bay nitrogen are tall and erect Ketone, propylene glycol, cod-liver oil, sodium glutamate, citric acid fatty glyceride, milk are added in the bone soup of tanning, are heated to 55 DEG C, chelating 4h, stirring 7h, extraction.
Embodiment 5
Prepare raw material according to following parts by weight:
55 parts of water, 14 parts of bone, 8 parts of hair, 8 parts of sulfuric acid, 8.5 parts of nucleotide, 18 parts of scurf, 28 parts of the dregs of fat, slaughterhouse 13 parts of leftover bits and pieces, 12 parts of granulated slag, 0.4 part of acid protease, 8 parts of glucose, 0.3 part of polyglyceryl fatty acid ester, 28 parts of zinc sulfate, sulphur Sour 5 parts ferrous, 1.5 parts of manganese sulfate, 2.5 parts of sodium ethylene diamine tetracetate, 3 parts of copper sulphate, 8 parts of borax, 0.2 part of ammonium molybdate, sulfuric acid 4 parts of magnesium, 7 parts of amino acid, 4 parts of humic acid, 0.05 part of sodium selenite, 0.4 part of Laurocapram, 0.35 part of propylene glycol, monoalkyl 10 parts of ether phosphate sylvite, 5 parts of citric acid, 0.5 part of cod-liver oil, 1.5 parts of sodium glutamate, 0.5 part of citric acid fatty glyceride, 30 parts of milk.
Specific preparation method:
1) bone soup is boiled:By bone, hair, sulfuric acid, nucleotide, scurf, the dregs of fat, slaughterhouse leftover bits and pieces, granulated slag, single alkane Base ether phosphate sylvite, citric acid are added to the water, and are heated to 115 DEG C, tanning 55h, cool down afterwards, filter, extraction;
2) it is trace element chelated:By acid protease, glucose, polyglyceryl fatty acid ester, zinc sulfate, ferrous sulfate, sulphur Sour manganese, sodium ethylene diamine tetracetate, copper sulphate, borax, ammonium molybdate, magnesium sulfate, amino acid, humic acid, sodium selenite, bay nitrogen are tall and erect Ketone, propylene glycol, cod-liver oil, sodium glutamate, citric acid fatty glyceride, milk are added in the bone soup of tanning, are heated to 60 DEG C, chelating 3.5h, stirring 8h, extraction.
Embodiment 6
Prepare raw material according to following parts by weight:
33 parts of water, 10.5 parts of bone, 2.5 parts of hair, 19 parts of sulfuric acid, 9.8 parts of nucleotide, 29 parts of scurf, 11 parts of the dregs of fat, Tu 7 parts of slaughterhouse leftover bits and pieces, 7 parts of granulated slag, 0.9 part of acid protease, 3 parts of glucose, 0.55 part of polyglyceryl fatty acid ester, zinc sulfate 7 Part, 19 parts of ferrous sulfate, 2.3 parts of manganese sulfate, 1.3 parts of sodium ethylene diamine tetracetate, 5.5 parts of copper sulphate, 3 parts of borax, ammonium molybdate 0.45 part, 2.5 parts of magnesium sulfate, 9 parts of amino acid, 1.5 parts of humic acid, 0.9 part of sodium selenite, 0.15 part of Laurocapram, the third two 0.48 part of alcohol, 4 parts of monoalky lether phosphate kalium salt, 0.8 part of citric acid, 0.08 part of cod-liver oil, 0.6 part of sodium glutamate, citric acid 0.15 part of fatty glyceride, 8 parts of milk.
Specific preparation method:
1) bone soup is boiled:By bone, hair, sulfuric acid, nucleotide, scurf, the dregs of fat, slaughterhouse leftover bits and pieces, granulated slag, single alkane Base ether phosphate sylvite, citric acid are added to the water, and are heated to 120 DEG C, tanning 70h, cool down afterwards, filter, extraction;
2) it is trace element chelated:By acid protease, glucose, polyglyceryl fatty acid ester, zinc sulfate, ferrous sulfate, sulphur Sour manganese, sodium ethylene diamine tetracetate, copper sulphate, borax, ammonium molybdate, magnesium sulfate, amino acid, humic acid, sodium selenite, bay nitrogen are tall and erect Ketone, propylene glycol, cod-liver oil, sodium glutamate, citric acid fatty glyceride, milk are added in the bone soup of tanning, are heated to 60 DEG C, chelating 5h, stirring 7.5h, extraction.
Embodiment 7
Prepare raw material according to following parts by weight:
58 parts of water, 14.5 parts of bone, 7 parts of sulfuric acid, 8.3 parts of nucleotide, 17 parts of scurf, 29 parts of the dregs of fat, are butchered at 9 parts of hair 14 parts of heel, 14 parts of granulated slag, 0.3 part of acid protease, 9 parts of glucose, 0.2 part of polyglyceryl fatty acid ester, zinc sulfate 29 off field Part, 4 parts of ferrous sulfate, 1.3 parts of manganese sulfate, 2.8 parts of sodium ethylene diamine tetracetate, 2.5 parts of copper sulphate, 9 parts of borax, ammonium molybdate 0.15 Part, 4.5 parts of magnesium sulfate, 6 parts of amino acid, 4.5 parts of humic acid, 0.03 part of sodium selenite, 0.45 part of Laurocapram, propylene glycol 0.32 part, 12 parts of monoalky lether phosphate kalium salt, 6 parts of citric acid, 0.6 part of cod-liver oil, 1.8 parts of sodium glutamate, citric acid fat 0.6 part of acid glyceride, 32 parts of milk.
Specific preparation method:
1) bone soup is boiled:By bone, hair, sulfuric acid, nucleotide, scurf, the dregs of fat, slaughterhouse leftover bits and pieces, granulated slag, single alkane Base ether phosphate sylvite, citric acid are added to the water, and are heated to 125 DEG C, tanning 50h, cool down afterwards, filter, extraction;
2) it is trace element chelated:By acid protease, glucose, polyglyceryl fatty acid ester, zinc sulfate, ferrous sulfate, sulphur Sour manganese, sodium ethylene diamine tetracetate, copper sulphate, borax, ammonium molybdate, magnesium sulfate, amino acid, humic acid, sodium selenite, bay nitrogen are tall and erect Ketone, propylene glycol, cod-liver oil, sodium glutamate, citric acid fatty glyceride, milk are added in the bone soup of tanning, are heated to 63 DEG C, chelating 3h, stirring 8h, extraction.
Laurocapram ingredient is not added in its material composition of comparative example 1
Under 45 parts of water, 12 parts of bone, 5 parts of hair, 15 parts of sulfuric acid, 9 parts of nucleotide, 25 parts of scurf, 25 parts of the dregs of fat, slaughterhouse 10 parts of heel, 10 parts of granulated slag, 0.6 part of acid protease, 6 parts of glucose, 0.4 part of polyglyceryl fatty acid ester, 18 parts of zinc sulfate, sulphur Sour 13 parts ferrous, 1.8 parts of manganese sulfate, 2 parts of sodium ethylene diamine tetracetate, 4 parts of copper sulphate, 6 parts of borax, 0.3 part of ammonium molybdate, magnesium sulfate 3.5 parts, 7.5 parts of amino acid, 3 parts of humic acid, 0.5 part of sodium selenite, 0.3 part of Laurocapram, 0.4 part of propylene glycol, monoalkyl 8 parts of ether phosphate sylvite, 3 parts of citric acid, 0.3 part of cod-liver oil, 1.0 parts of sodium glutamate, 0.4 part of citric acid fatty glyceride, 20 parts of milk.
Specific preparation method:
1) bone soup is boiled:By bone, hair, sulfuric acid, nucleotide, scurf, the dregs of fat, slaughterhouse leftover bits and pieces, granulated slag, single alkane Base ether phosphate sylvite, citric acid are added to the water, and are heated to 100 DEG C, tanning 68h, cool down afterwards, filter, extraction;
2) it is trace element chelated:By acid protease, glucose, polyglyceryl fatty acid ester, zinc sulfate, ferrous sulfate, sulphur Sour manganese, sodium ethylene diamine tetracetate, copper sulphate, borax, ammonium molybdate, magnesium sulfate, amino acid, humic acid, sodium selenite, propylene glycol, Cod-liver oil, sodium glutamate, citric acid fatty glyceride, milk are added in the bone soup of tanning, are heated to 45 DEG C, chelating 3.8h, stirring 7h, extraction.
Fertilizer efficiency application test
The manure trial of 1 continuous 3 year plantation soybean of case
Continuous 3 years of 2014-2016 chooses a piece of soy bean test field on Heilongjiang Province Suihua Area Helen farm and carries out fertilizer efficiency Application test;May is sowed, and October, maturation harvested.Experimental plot is divided into 4 pieces of same size and respectively number 1,2,3 and 4;The 1-3 groups apply fertilizer made from embodiment 1-3 respectively, and the 4th group is applied comparative example fertilizer as a control group.During all grouping fertilisings Between with fertilising dosage it is identical.Other cultivation management measures are the same as local Soybean Field.Annual July 12 sprays once.
1 2014-2016 soy bean tests field fertilizer test result of table
It can be seen that by above-mentioned result of the test clearly demarcated to the effect of increasing production all ten of soybean using fertilizer produced by the present invention It is aobvious.When there is no the Laurocapram using the present invention especially compared with the same year control group, in formula, after plantation in continuous 3 years, production Measure that low, fruit quality is poor;And the trend increased year by year is presented substantially using the yield of continuous 3 years soybean after the fertilizer of the present invention, This is because the fertilizer of the continuous administration present invention, significantly improves soil compaction phenomenon, the quality of soil is enhanced, promotes agriculture Absorption of the crop to nutrient improves utilization rate of fertilizer, reduces nutrient loss.Further, since the use of Laurocapram, due to It can promote fertilizer to permeate blade, soak plant leaf surface, therefore can promote absorption of the plant to fertilizer using Laurocapram, subtract Few dosage.
The manure trial of 2. continuous 3 years rice cultivations of case
Continuous 3 years of 2014-2016, in Heilongjiang Province Jiamusi, JianSanjiang farm seven, which is reelected, takes a piece of rice experimental plot Carry out fertilizer efficiency application test;The rice transplanting of 5 the end of month, October, maturation harvested.Experimental plot be divided into 4 pieces of same size and respectively number 1, 2nd, 3 and 4;1-3 groups apply fertilizer made from embodiment 1-3 respectively, and the 4th group is applied comparative example fertilizer as a control group.It is all It is identical with fertilising dosage to be grouped fertilization time.Other cultivation management measures are the same as local rice terrace.Annual July 20 sprays once.
2 22014-2016 rice tests field fertilizer test result of table
It can be seen that by above-mentioned result of the test clearly demarcated to the effect of increasing production all ten of rice using fertilizer produced by the present invention It is aobvious.When there is no the Laurocapram using the present invention especially compared with the same year control group, in formula, after plantation in continuous 3 years, production Measure that low, fruit quality is poor;And the trend increased year by year is presented substantially using the yield of continuous 3 years rice after the fertilizer of the present invention, This is because the fertilizer of the continuous administration present invention, significantly improves soil compaction phenomenon, the quality of soil is enhanced, promotes agriculture Absorption of the crop to nutrient improves utilization rate of fertilizer, reduces nutrient loss.Further, since the use of Laurocapram, due to It can promote fertilizer to permeate blade, soak plant leaf surface, therefore can promote absorption of the plant to fertilizer using Laurocapram, subtract Few dosage.
The manure trial of 3 continuous 3 years plantation capsicums of case
Continuous 3 years of 2014-2016 chooses a piece of capsicum experimental plot in Heilongjiang Province Suihua City Beilin District red flag township and carries out fertilizer Imitate application test;Late May is sowed, the ripe harvest of August.Experimental plot be divided into 4 pieces of same size and respectively number 1,2,3 with 4;1-3 groups apply fertilizer made from embodiment 1-3 respectively, and the 4th group is applied comparative example fertilizer as a control group.All groupings are applied The fertile time is identical with fertilising dosage.Other cultivation management measures are the same as local capsicum field.Annual July 15 sprays once.
3 2014-2016 capsicums experimental plot fertilizer test result of table
It can be seen that by above-mentioned result of the test clearly demarcated to the effect of increasing production all ten of capsicum using fertilizer produced by the present invention It is aobvious.When there is no the Laurocapram using the present invention especially compared with the same year control group, in formula, after plantation in continuous 3 years, production Measure that low, fruit quality is poor;And the trend increased year by year is presented substantially using the yield of continuous 3 years capsicums after the fertilizer of the present invention, This is because the fertilizer of the continuous administration present invention, significantly improves soil compaction phenomenon, the quality of soil is enhanced, promotes agriculture Absorption of the crop to nutrient improves utilization rate of fertilizer, reduces nutrient loss.Further, since the use of Laurocapram, due to It can promote fertilizer to permeate blade, soak plant leaf surface, therefore can promote absorption of the plant to fertilizer using Laurocapram, subtract Few dosage.
The manure trial of 4 continuous 3 years plantation watermelons of case
Continuous 3 years of 2014-2016 chooses a piece of watermelon experimental plot in Heilongjiang Province Suihua City Beilin District red flag township and carries out fertilizer Imitate application test;Late May is sowed, the ripe harvest of August.Experimental plot be divided into 4 pieces of same size and respectively number 1,2,3 with 4;1-3 groups apply fertilizer made from embodiment 1-3 respectively, and the 4th group is applied comparative example fertilizer as a control group.All groupings are applied The fertile time is identical with fertilising dosage.Other cultivation management measures are the same as local watermelon field.Annual July 6 sprays once.
4 2014-2016 watermelons experimental plot fertilizer test result of table
It can be seen that by above-mentioned result of the test clearly demarcated to the effect of increasing production all ten of watermelon using fertilizer produced by the present invention It is aobvious.When there is no the Laurocapram using the present invention especially compared with the same year control group, in formula, after plantation in continuous 3 years, production Measure that low, fruit quality is poor;And the trend increased year by year is presented substantially using the yield of continuous 3 years watermelons after the fertilizer of the present invention, This is because the fertilizer of the continuous administration present invention, significantly improves soil compaction phenomenon, the quality of soil is enhanced, promotes agriculture Absorption of the crop to nutrient improves utilization rate of fertilizer, reduces nutrient loss.Further, since the use of Laurocapram, due to It can promote fertilizer to permeate blade, soak plant leaf surface, therefore can promote absorption of the plant to fertilizer using Laurocapram, subtract Few dosage.
The manure trial of 5 continuous 3 years plantation garlics of case
Continuous 3 years of 2014-2016 chooses a piece of garlic experimental plot in Heilongjiang Province Daqing Zhaozhou County Feng Le towns and carries out fertilizer Imitate application test;Late May is sowed, the ripe harvest of August.Experimental plot be divided into 4 pieces of same size and respectively number 1,2,3 with 4;1-3 groups apply fertilizer made from embodiment 1-3 respectively, and the 4th group is applied comparative example fertilizer as a control group.All groupings are applied The fertile time is identical with fertilising dosage.Other cultivation management measures are the same as local garlic field.Annual July 8 sprays once.
5 2014-2016 garlics experimental plot fertilizer test result of table
It can be seen that by above-mentioned result of the test clearly demarcated to the effect of increasing production all ten of garlic using fertilizer produced by the present invention It is aobvious.When there is no the Laurocapram using the present invention especially compared with the same year control group, in formula, after plantation in continuous 3 years, production Measure that low, fruit quality is poor;And the trend increased year by year is presented substantially using the yield of continuous 3 years garlics after the fertilizer of the present invention, This is because the fertilizer of the continuous administration present invention, significantly improves soil compaction phenomenon, the quality of soil is enhanced, promotes agriculture Absorption of the crop to nutrient improves utilization rate of fertilizer, reduces nutrient loss.Further, since the use of Laurocapram, due to It can promote fertilizer to permeate blade, soak plant leaf surface, therefore can promote absorption of the plant to fertilizer using Laurocapram, subtract Few dosage.
Case 6
The Chinese cabbage farmland conduct of 4 pieces of similary sizes is chosen in Mei Lisi areas of Qiqihaer City of Heilongjiang Province planting base Experimental plot, every piece is 1 mu, wherein 3 pieces of farmlands use the fertilizer obtained by 4-6 of the embodiment of the present invention respectively, another piece of use is commercially available Common compound fertilizer as a control group.Yield and pest and disease damage situation are observed after 1 year.
6 Chinese cabbage experimental plot fertilizer test result of table
Per mu yield Pest and disease damage frequency
Embodiment 4 5947 0
Embodiment 5 5547 1
Embodiment 6 6167 0
Commercially available Common compound fertilizer 4514 3
Case 7
The potato agriculture of 4 pieces of similary sizes is chosen in Heilongjiang Province In Mudanjiang District Ning'an city stone Yan Zhen planting bases As experimental plot, every piece is 1 mu in field, wherein 3 pieces of farmlands, respectively using the fertilizer obtained by 4-6 of the embodiment of the present invention, another piece makes With commercially available Common compound fertilizer as a control group.Yield and pest and disease damage situation are observed after 1 year.
7 potato plot fertilizer test result of table
Per mu yield Pest and disease damage frequency
Embodiment 4 6670 1
Embodiment 5 7304 0
Embodiment 6 7112 0
Commercially available Common compound fertilizer 5946 2
Finally it should be noted that:The above embodiments are only used to illustrate the technical solution of the present invention., rather than its limitations;To the greatest extent Pipe is described in detail the present invention with reference to foregoing embodiments, it will be understood by those of ordinary skill in the art that:Its according to Can so modify to the technical solution recorded in foregoing embodiments either to which part or all technical characteristic into Row equivalent substitution;And these modifications or replacement, the essence of appropriate technical solution is not made to depart from various embodiments of the present invention technology The scope of scheme.

Claims (8)

1. a kind of big bone polypeptide nucleosides chelating mother liquor, which is characterized in that be made of following raw materials according:Water, bone, hair, sulfuric acid, core Thuja acid, scurf, the dregs of fat, slaughterhouse leftover bits and pieces, granulated slag, acid protease, glucose, polyglyceryl fatty acid ester, zinc sulfate, sulfuric acid Ferrous iron, manganese sulfate, sodium ethylene diamine tetracetate, copper sulphate, borax, ammonium molybdate, magnesium sulfate, amino acid, humic acid, sodium selenite, Laurocapram, propylene glycol, monoalky lether phosphate kalium salt, citric acid, cod-liver oil, sodium glutamate, citric acid fatty acid glycerine Ester, milk.
2. big bone polypeptide nucleosides chelating mother liquor according to claim 1, which is characterized in that by the raw material system of following parts by weight Into:30-60 parts of water, 10-15 parts of bone, 2-10 parts of hair, 6-20 parts of sulfuric acid, 8-10 parts of nucleotide, 15-30 parts of scurf, the dregs of fat 10-30 parts, leftover bits and pieces 5-15 parts of slaughterhouse, 5-15 parts of granulated slag, 0.2-1 parts of acid protease, 2-10 parts of glucose, polyglycerol ester 0.1-0.6 parts of fat acid esters, 6-30 parts of zinc sulfate, 3-20 parts of ferrous sulfate, 1-2.5 parts of manganese sulfate, sodium ethylene diamine tetracetate 1-3 Part, 2-6 parts of copper sulphate, 2-10 parts of borax, 0.1-0.5 parts of ammonium molybdate, 2-5 parts of magnesium sulfate, 5-10 parts of amino acid, humic acid 1-5 Part, 0.001-1 parts of sodium selenite, 0.1-0.5 parts of Laurocapram, 0.3-0.5 parts of propylene glycol, monoalky lether phosphate kalium salt 3- 13 parts, 0.5-7 parts of citric acid, 0.05-0.7 parts of cod-liver oil, 0.5-2.0 parts of sodium glutamate, citric acid fatty glyceride 0.1- 0.8 part, 5-35 parts of milk.
3. big bone polypeptide nucleosides chelating mother liquor according to claim 2, which is characterized in that by the raw material system of following parts by weight Into:35-55 parts of water, 11-14 parts of bone, 3-8 parts of hair, 8-18 parts of sulfuric acid, 8.5-9.5 parts of nucleotide, 18-28 parts of scurf, oil It is 12-28 parts of slag, leftover bits and pieces 8-13 parts of slaughterhouse, 8-12 parts of granulated slag, 0.4-0.8 parts of acid protease, 4-8 parts of glucose, poly- sweet 0.3-0.5 parts of oil and fat acid esters, 8-28 parts of zinc sulfate, 5-18 parts of ferrous sulfate, 1.5-2.0 parts of manganese sulfate, ethylenediamine tetra-acetic acid 1.5-2.5 parts of sodium, 3-5 parts of copper sulphate, 4-8 parts of borax, 0.2-0.4 parts of ammonium molybdate, 3-4 parts of magnesium sulfate, 7-8 parts of amino acid, corruption Grow 2-4 parts sour, 0.05-0.8 parts of sodium selenite, 0.2-0.4 parts of Laurocapram, 0.35-0.45 parts of propylene glycol, monoalky lether phosphorus 5-10 parts of acid esters sylvite, 1-5 parts of citric acid, 0.1-0.5 parts of cod-liver oil, 0.7-1.5 parts of sodium glutamate, citric acid fatty acid glycerine 0.2-0.5 parts of ester, 10-30 parts of milk.
4. big bone polypeptide nucleosides chelating mother liquor according to claim 3, which is characterized in that by the raw material system of following parts by weight Into:45 parts of water, 12 parts of bone, 5 parts of hair, 15 parts of sulfuric acid, 9 parts of nucleotide, 25 parts of scurf, 25 parts of the dregs of fat, slaughterhouse leftover bits and pieces 10 parts, 10 parts of granulated slag, 0.6 part of acid protease, 6 parts of glucose, 0.4 part of polyglyceryl fatty acid ester, 18 parts of zinc sulfate, sulfuric acid it is sub- 13 parts of iron, 1.8 parts of manganese sulfate, 2 parts of sodium ethylene diamine tetracetate, 4 parts of copper sulphate, 6 parts of borax, 0.3 part of ammonium molybdate, magnesium sulfate 3.5 Part, 7.5 parts of amino acid, 3 parts of humic acid, 0.5 part of sodium selenite, 0.3 part of Laurocapram, 0.4 part of propylene glycol, monoalky lether phosphorus 8 parts of acid esters sylvite, 3 parts of citric acid, 0.3 part of cod-liver oil, 1.0 parts of sodium glutamate, 0.4 part of citric acid fatty glyceride, milk 20 parts.
It is 5. a kind of such as the preparation method of the big bone polypeptide nucleosides chelating mother liquor of claim 1-4 any one of them, which is characterized in that Including step:
1) bone soup is boiled:By bone, hair, sulfuric acid, nucleotide, scurf, the dregs of fat, slaughterhouse leftover bits and pieces, granulated slag, monoalky lether Phosphate kalium salt, citric acid are added to the water, and heat, boil, the extraction of cooling filtering afterwards;
2) it is trace element chelated:By acid protease, glucose, polyglyceryl fatty acid ester, zinc sulfate, ferrous sulfate, manganese sulfate, Sodium ethylene diamine tetracetate, copper sulphate, borax, ammonium molybdate, magnesium sulfate, amino acid, humic acid, sodium selenite, Laurocapram, third Glycol, cod-liver oil, sodium glutamate, citric acid fatty glyceride, milk are added in the bone soup of tanning, heat, chelate, stir Mix, extract out, postcooling.
6. according to the preparation method of the big bone polypeptide nucleosides chelating mother liquor described in claim 5, which is characterized in that the tanning 100-130 DEG C, tanning to solid-state reactants dissolving are heated to during bone soup.
7. according to the preparation method of the big bone polypeptide nucleosides chelating mother liquor described in claim 5, which is characterized in that described micro Element is heated to 45-65 DEG C, chelating to trace element thawing during chelating.
8. the big bone polypeptide nucleosides chelating mother liquor of claim 1-4 any one of them is used for the crops or plant of large area plantation On application.
CN201711439475.0A 2017-12-27 2017-12-27 A kind of big bone polypeptide nucleosides chelating mother liquor, preparation method and its usage Pending CN108083913A (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108503416A (en) * 2018-06-14 2018-09-07 山东省潍坊市农业科学院 A kind of accurate foliar fertilizer of green turnip special efficient and its method of administration
WO2020029831A1 (en) * 2018-08-08 2020-02-13 南京工业大学 High-energy phosphoryl compound fertilizer and application thereof

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Publication number Priority date Publication date Assignee Title
WO2007072208A3 (en) * 2005-12-23 2009-04-16 Chang Ken Metal complex polymer and application thereof
CN105439716A (en) * 2015-12-11 2016-03-30 安徽省中日农业环保科技有限公司 Internode-shortening anti-adverse liquid fertilizer with function of strengthening seedlings and preparation method thereof
CN107512950A (en) * 2017-09-05 2017-12-26 安徽益丰生态农业开发有限公司 A kind of polypeptide vegetable fertilizer

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007072208A3 (en) * 2005-12-23 2009-04-16 Chang Ken Metal complex polymer and application thereof
CN105439716A (en) * 2015-12-11 2016-03-30 安徽省中日农业环保科技有限公司 Internode-shortening anti-adverse liquid fertilizer with function of strengthening seedlings and preparation method thereof
CN107512950A (en) * 2017-09-05 2017-12-26 安徽益丰生态农业开发有限公司 A kind of polypeptide vegetable fertilizer

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108503416A (en) * 2018-06-14 2018-09-07 山东省潍坊市农业科学院 A kind of accurate foliar fertilizer of green turnip special efficient and its method of administration
WO2020029831A1 (en) * 2018-08-08 2020-02-13 南京工业大学 High-energy phosphoryl compound fertilizer and application thereof
CN112566883A (en) * 2018-08-08 2021-03-26 南京工业大学 High-energy phosphoryl compound fertilizer and application thereof

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