CN108077311A - A kind of antimicrobial spray of haze and its preparation method and application - Google Patents
A kind of antimicrobial spray of haze and its preparation method and application Download PDFInfo
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- CN108077311A CN108077311A CN201611046110.7A CN201611046110A CN108077311A CN 108077311 A CN108077311 A CN 108077311A CN 201611046110 A CN201611046110 A CN 201611046110A CN 108077311 A CN108077311 A CN 108077311A
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- antimicrobial
- antimicrobial spray
- spray
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/26—Phosphorus; Compounds thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
- A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
- A01N25/06—Aerosols
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
- A01N33/02—Amines; Quaternary ammonium compounds
- A01N33/12—Quaternary ammonium compounds
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/16—Heavy metals; Compounds thereof
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D13/00—Professional, industrial or sporting protective garments, e.g. surgeons' gowns or garments protecting against blows or punches
- A41D13/05—Professional, industrial or sporting protective garments, e.g. surgeons' gowns or garments protecting against blows or punches protecting only a particular body part
- A41D13/11—Protective face masks, e.g. for surgical use, or for use in foul atmospheres
- A41D13/1192—Protective face masks, e.g. for surgical use, or for use in foul atmospheres with antimicrobial agent
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D31/00—Materials specially adapted for outerwear
- A41D31/04—Materials specially adapted for outerwear characterised by special function or use
- A41D31/30—Antimicrobial, e.g. antibacterial
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/77—Liquid phase processes
- B01D53/79—Injecting reactants
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/20—Reductants
- B01D2251/206—Ammonium compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/60—Inorganic bases or salts
- B01D2251/61—Phosphates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/91—Bacteria; Microorganisms
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2258/00—Sources of waste gases
- B01D2258/06—Polluted air
Abstract
The present invention provides a kind of antimicrobial sprays of haze and its preparation method and application, and each component and its content are in the antimicrobial spray：5~90g/L of compound ion anti-biotic material, 5~90g/L of film forming agent, 5~90g/L of thickener, 1~5g/L of nano-titanium dioxide, 1~10g/L of plant extract agent, 1~10g/L of 1~10g/L of preservative, 1~10g/L of solubilizer and freshener, surplus is water.Antimicrobial spray of the present invention can form protecting film in body surface, play the antibacterial effect of sustained anti-microbial, simultaneously, the antimicrobial spray utilizes the synergistic effect of compound ion anti-biotic material and nano-titanium dioxide, good bactericidal effect is made it have, there is stronger bactericidal effect to methicillin-resistant staphylococcus aureus (superbacteria represents bacterium), Escherichia coli, Legionella, pyococcus, hepatitis virus and Candida albicans and all kinds of epidemic infectious diseases and bacterial spore etc..
Description
Technical field
The invention belongs to medical preparation fields, are related to a kind of antimicrobial spray of haze and its preparation method and application, especially
It is related to a kind of antimicrobial spray of haze and its preparation method and application that protecting film can be formed in body surface.
Background technology
In recent years, due to the abuse of antibiotic, the appearance of superbacteria is caused, at present MRSA (methicillin-resistant staphylococcus
Staphylococcus) become one of highest inside-hospital infection pathogen of global incidence, MRSA infection is listed in the world 3 and is most difficult to greatly
The infectious diseases (MRSA, hepatitis B and HIV infection) of solution is the first.
Bacterial resistance sex chromosome mosaicism is very serious.In developed country, the inpatient for having 5%~10% every year occurred
One or more infection.The patient that hospital infection occurs every year for the U.S. is about 2,000,000, dead 90000 people, and economic loss is up to 45
Hundred million~5,700,000,000 dollars.In developing country, the danger of hospital infection, which occurs, will be higher by 2 times~20 times of developed country.Chinese Hospitals
Infection rate is 6% or so, but rate of failing to report is very high, up to more than 50%.The U.S. in 2007《American Journal of Medicine》Weekly
1 part of government's survey report of publication is said, annual to be expected to have more than 90,000 people's severe infections MRSA.Dutch National Public Health and environment
Pointed by research, the whole world may have up to 53,000,000 people to carry fatal superbug MRSA.2010, statistics display was printing
Degree and Pakistan confirm the case for infecting " superbacteria " up to 150, and Britain also has 70, in addition European Austria,
Belgium, Germany, Holland, Norway, Sweden and France, the Canada and the U.S. of North America, African Kenya, Asia Japan and
There are confirmation case in varying numbers in the states such as Singapore.According to incompletely statistics, Japan, Brazil and Britain respectively because it lethal 27
People, 18 people, 5 people.On October 26th, 2010, Chinese Center for Disease Control and Prevention circulated a notice of the super antibiotic resistant bacterial pathogens disease of three infection
Example, wherein dead 1.CHINET (Chinese bacterial drug resistance monitoring) investigation to domestic 18 large hospitals in 2014, it is super
The first six digits that bacterium firmly infects in occupation of clinical bacteria, and the drug resistance of bacterium goes up year by year, highest is up to more than 80%.
In April, 2015, British government was newest《National emergency management risk inventory》It is pointed out in report, since doctor uses antibiotic not
When, in fact it could happen that a variety of " superbacterias " to develop immunity to drugs to antibiotic.Once locality outburst is related to " super thin on a large scale
The blood infection event of bacterium ", it will have 200,000 people impacted, have about 80,000 people " may be dead " in the middle.In May, 2016,
A authoritative research report of Britain is pointed out, if the problems such as countries in the world are not with regard to abuse of antibiotics is promptly taken action, to 2050
Year, so-called " superbacteria " will cause a patient death in every three seconds.In July, 2016, tool《The Beijing News》Report, in Brazilian
About Federal University microorganism institute issues a report and claims recently, and scientific research personnel has found after sampling detection in 1 year, inner
At Yue Reneilu 5 there is " superbacteria " in the waters at seabeach, and this kind of bacterium can trigger a variety of diseases, the people of particularly immune force difference
Group is easily infected, this has undoubtedly coverd with one layer of shade to the Rio Olympic Games that will be held.In July, 2016, the U.S. are found
Second case carries " superbacteria " case of the CR-1 containing gene M, this gene can make bacterium " last to being referred to as in antibiotic
The polymyxins in one of defence line " generates drug resistance.These soul-stirring message one by one, even more allow people to ecological environment and
The danger that the deterioration of microbial environment is brought to the earth and human health is worried.
In recent years, there is haze phenomenon in the most cities of China, and haze is by dust, sulfuric acid, nitric acid and the organic carbon in air
The grains such as hydrogen compound are molecular.Include acid, alkali, salt, amine, phenol etc. and dust, pollen, acarid, influenza virus, tuberculosis
Bacillus, pneumococcus etc., compared with mist, haze is to the harm bigger of the health of people.Due in haze tiny granular float
Particulate matter diameter directly can enter bronchus or even lung generally below 0.01 μm by respiratory system.So haze influences
Maximum is exactly the respiratory system of people, caused by disease be concentrated mainly on the diseases such as breathing problem, cranial vascular disease, nasal cavity inflammation
In kind.Meanwhile during haze weather, air pressure reduction, Inhalable Particulate abruptly increase, air flow property are poor, harmful bacteria and
Virus slows to what surrounding was spread, and virus concentration in air is caused to increase, and the risk of transmission is very high.So in haze
Weather, which is gone out, has to wear masks.Market muzzles there are many style, such as mask with breather valve, without breather valve mask,
The cotton mask, non-woven fabrics disposable breathing mask, disposable medical for having strainer nurse mask, general cotton mask and with various
Color and cartoon pattern mask etc..
In actual use, general mask may filter that the particulate matter of more than PM10, but the filter effect of PM2.5 is paid no attention to
Think.CN 204579964U disclose a kind of haze antibacterial mask, are connected including mask outer layer, with the mask outer layer
Mask internal layer, the filter disc placed cavity being arranged between the mask outer layer and the mask internal layer and medicinal bag placed cavity are set
Filter disc in the filter disc placed cavity, the medicinal bag being arranged in the medicinal bag placed cavity are arranged on the mask outer layer
Nose bridge batten in one side is symmetricly set on the frenulum at the mask outer layer both ends, is arranged on inserting for the mask internal layer one side
Mouthful.But since the facial personalization of people differs greatly, the closely connected degree for being affected by it mask and face also has larger difference, centainly
Anti- haze effect is affected in degree.
Meanwhile during mask air valve air-breathing air-tightness quality, also influence whether the anti-haze effect of mask.And long periods of wear
Mask, the gas of oral cavity exhalation are attached to always on the inside of mask, easily grow bacterium.Can also have outside mask because of breathing largely
PM2.5 fogs particle and various bacteriums and virus, and as time went on, bacterium is internally moved by outside, to health
It can cause very big harm.
Therefore, how to find one kind can effectively antibacterial (especially ultra-fine grade bacterium) and can the method for effectively haze be
The problem of urgent need to resolve.
The content of the invention
Facial personalization for people differs greatly, and the closely connected degree for being affected by it mask and face also has larger difference,
The problems such as influencing anti-haze effect to a certain extent and easily growing bacterium, the present invention provides a kind of antimicrobial sprays of haze
And its preparation method and application.Antimicrobial spray of the present invention can form protecting film in body surface, and it is antibacterial to play sustained anti-microbial
Effect, meanwhile, the antimicrobial spray is made it have using the synergistic effect of compound ion anti-biotic material and nano-titanium dioxide
Good bactericidal effect, to methicillin-resistant staphylococcus aureus (superbacteria represents bacterium), Escherichia coli, Legionella,
Pyococcus, hepatitis virus and Candida albicans and all kinds of epidemic infectious diseases and bacterial spore etc. have stronger sterilization
Effect.
For this purpose, the present invention uses following technical scheme：
Each component and its contain in a first aspect, the present invention provides a kind of antimicrobial spray of haze, in the antimicrobial spray
It measures and is：
Wherein, the content of compound ion anti-biotic material can be 5g/L, 10g/L, 20g/L, 30g/L, 40g/L, 50g/L,
60g/L, 70g/L, 80g/L or 90g/L etc., it is not limited to cited numerical value, other interior numerical value of listed scope are feasible；
The content of the film forming agent can be 5g/L, 10g/L, 20g/L, 30g/L, 40g/L, 50g/L, 60g/L, 70g/L, 80g/L or
90g/L etc., it is not limited to cited numerical value, other interior numerical value of listed scope are feasible；The content of the thickener can
For 5g/L, 10g/L, 20g/L, 30g/L, 40g/L, 50g/L, 60g/L, 70g/L, 80g/L or 90g/L etc., it is not limited to
Cited numerical value, other interior numerical value of listed scope are feasible；The content of the nano-titanium dioxide can 1g/L, 2g/L, 3g/L,
4g/L or 5g/L etc., it is not limited to cited numerical value, other interior numerical value of listed scope are feasible；The plant extract agent
Content can be 1g/L, 2g/L, 3g/L, 4g/L, 5g/L, 6g/L, 7g/L, 8g/L, 9g/L or 10g/L etc., it is not limited to
Cited numerical value, other interior numerical value of listed scope are feasible；The content of the preservative can be 1g/L, 2g/L, 3g/L, 4g/
L, 5g/L, 6g/L, 7g/L, 8g/L, 9g/L or 10g/L etc., it is not limited to cited numerical value, other interior numbers of listed scope
Value is feasible；The content of solubilizer can be 1g/L, 2g/L, 3g/L, 4g/L, 5g/L, 6g/L, 7g/L, 8g/L, 9g/L or 10g/L
Deng it is not limited to cited numerical value, other numerical value are feasible in listed scope；The content of freshener can be 1g/L, 2g/
L, 3g/L, 4g/L, 5g/L, 6g/L, 7g/L, 8g/L, 9g/L or 10g/L etc., it is not limited to cited numerical value, listed model
Other numerical value are feasible in enclosing.
In the present invention, using the synergistic effect of compound ion anti-biotic material and nano-titanium dioxide, make it have good
Bactericidal effect, if the content of nano-titanium dioxide is more than the 1~5g/L, the bactericidal effect of antimicrobial spray is unable to reach this
Invent the level.
Below as currently preferred technical solution, but not as the limitation of technical solution provided by the invention, pass through
Following technical scheme can preferably reach and realize the technical purpose and advantageous effect of the present invention.
As currently preferred technical solution, each component and its content are in the antimicrobial spray：
Preferably, each component and its content are in the antimicrobial spray：
As currently preferred technical solution, the compound ion anti-biotic material is by ionic liquid and inorganic nano stratification
The progress intercalation assembling of object alpha-phosphate hydrogen zirconium is closed to be prepared.The preparation method of the compound ion anti-biotic material is CN
Preparation method described in 102113484A under normal pressure mixes ionic liquid and inorganic nano layer compound alpha-phosphate hydrogen zirconium
It closes stirring and ion-exchange reactions occurs, be then centrifuged for separating, wash, be dried to obtain compound ion anti-biotic material.
Preferably, the ionic liquid be quaternary ammonium ion liquid and/or quaternary phosphonium ion liquid, further preferably quaternary ammonium from
Sub- liquid.In the present invention, the compound ion that is prepared with quaternary ammonium ion liquid and inorganic nano layer compound alpha-phosphate hydrogen zirconium
The effect that the synergistic effect of anti-biotic material and nano-titanium dioxide reaches is best.
Preferably, the molar ratio of the ionic liquid and inorganic nano layer compound alpha-phosphate hydrogen zirconium is 1:(2~5), example
Such as 1:2、1:3、1:4 or 1:5 etc., it is not limited to cited numerical value, other interior numerical value of listed scope are feasible.Experiment card
The molar ratio of bright ionic liquid and inorganic nano layer compound alpha-phosphate hydrogen zirconium can be that compound ion is made to resist within this range
Bacterium material has more excellent anti-microbial property, further preferably 1:3.
As currently preferred technical solution, the film forming agent is polyvinyl alcohol, 2,2,4- trimethyl -1,3- pentanediols
Any one in mono isobutyrate, propandiol butyl ether, propylene glycol methyl ether acetate, diacetone alcohol or dimethyl ether or extremely
Combination two kinds few, the combination is typical but non-limiting examples have：Polyvinyl alcohol and 2,2,4- trimethyl -1,3- pentanediol lists
The combination of the combination of isobutyrate, propandiol butyl ether and propylene glycol methyl ether acetate, diacetone alcohol and dimethyl ether
Combination, polyvinyl alcohol, 2, the combination of 2,4- trimethyl -1,3- pentanediol mono isobutyrates and propandiol butyl ether, polyvinyl alcohol, 2,
2,4- trimethyl -1,3- pentanediol mono isobutyrates, propandiol butyl ether, propylene glycol methyl ether acetate, diacetone alcohol and dipropyl two
Combination of diethylene glycol dimethyl ether etc., further preferably 2,2,4- trimethyl -1,3- pentanediol mono isobutyrates.
As currently preferred technical solution, the thickener is sodium carboxymethylcellulose, propylene glycol alginate, card
Any one in ripple nurse, starch phosphate sodium, chitin, tamarind gum or hydroxypropyl starch ether or at least two combination, institute
It states combination typical case but non-limiting examples has：The combination of sodium carboxymethylcellulose and propylene glycol alginate, carbomer, starch phosphorus
The combination of acid esters sodium and chitin, the combination of chitin, tamarind gum and hydroxypropyl starch ether, sodium carboxymethylcellulose, seaweed
The combination of acid propylene glycol ester, carbomer, starch phosphate sodium and chitin, carbomer, starch phosphate sodium, chitin, Luo Wang
The combination of sub- glue and hydroxypropyl starch ether, sodium carboxymethylcellulose, propylene glycol alginate, carbomer, starch phosphate sodium, first
Combination of shell element, tamarind gum and hydroxypropyl starch ether etc., further preferably sodium carboxymethylcellulose.
As currently preferred technical solution, the plant extract agent is grape seed extract, cherry extract, aloe
Any one in extract, ginkgo biloba p.e, Lotus Plumule P.E. or wolfberry fruit extract or at least two combination, the combination
Typical but non-limiting examples have：The combination of grape seed extract and cherry extract, cherry extract and aloe extract
Combination, the combination of aloe extract, ginkgo biloba p.e and Lotus Plumule P.E., aloe extract, ginkgo biloba p.e, lotus seeds
The combination of heart extract and wolfberry fruit extract, grape seed extract, cherry extract, aloe extract, ginkgo biloba p.e, lotus
Combination of sub- heart extract and wolfberry fruit extract etc., further preferably grape seed extract.
As currently preferred technical solution, the preservative for imidazolidinyl urea, interior uride, isothiazolinone,
Any one in p-hydroxybenzoate, benzoic acid or potassium sorbate or at least two combination, it is described to combine typical but non-limit
Property example processed has：Imidazolidinyl urea and the combination of interior uride, the combination of isothiazolinone and p-hydroxybenzoate, benzoic acid
With the combination of potassium sorbate, the combination of imidazolidinyl urea, interior uride and isothiazolinone, isothiazolinone, para hydroxybenzene first
The combination of acid esters, benzoic acid and potassium sorbate, imidazolidinyl urea, interior uride, isothiazolinone, p-hydroxybenzoate, benzene
Combination of formic acid and potassium sorbate etc., further preferably isothiazolinone.
Preferably, the solubilizer is polyoxyethylene hardened castor oil, Emulsifier EL-60, aliphatic alcohol polyethenoxy
It is arbitrary in ether, aliphatic alcohol polyethenoxy-polyethenoxy ether, polyoxyethylene sorbitan fatty acid ester or polyglyceryl fatty acid ester
It is a kind of or at least two combination, it is described combination typical case but non-limiting examples have：Polyoxyethylene hardened castor oil and polyoxy second
The combination of alkene castor oil, the combination of fatty alcohol polyoxyethylene ether and aliphatic alcohol polyethenoxy-polyethenoxy ether, polyoxyethylene sorbitan
The combination of Span and polyglyceryl fatty acid ester, polyoxyethylene hardened castor oil, Emulsifier EL-60 and fat
The combination of alcohol polyoxyethylene ether, fatty alcohol polyoxyethylene ether, aliphatic alcohol polyethenoxy-polyethenoxy ether and polyoxyethylene sorbitan mountain
The combination of pears alcohol fatty acid ester, polyoxyethylene hardened castor oil, Emulsifier EL-60, fatty alcohol polyoxyethylene ether, fatty alcohol
Combination of polyoxyethylene polyoxypropylene ether, polyoxyethylene sorbitan fatty acid ester and polyglyceryl fatty acid ester etc., further
Preferably polyoxyethylene hardened castor oil.
Preferably, the freshener is menthol, menthyl lactate, amide of mint, menthyl succinate, N- ethyls-right
Any one in menthyl -3- formamides or 2-Isopropyl-N,2,3-trimethylbutyramide or at least two combination, described group
It closes typical case but non-limiting examples has：The combination of the combination of menthol and menthyl lactate, amide of mint and menthyl succinate,
The combination of N- ethyls-to menthyl -3- formamides and 2-Isopropyl-N,2,3-trimethylbutyramide, menthol, lactic acid peppermint
The combination of ester, amide of mint and menthyl succinate, menthyl succinate, N- ethyls-to menthyl -3- formamides and 2- isopropyls
Base-N, the combination of 2,3- trimethylbutyramides, menthol, menthyl lactate, amide of mint, menthyl succinate, N- ethyls-right
Combination of menthyl -3- formamides and 2-Isopropyl-N,2,3-trimethylbutyramide etc., further preferably menthyl lactate.
As currently preferred technical solution, each component and its content are in the antimicrobial spray：
Wherein, compound ion anti-biotic material is inserted by quaternary ammonium ion liquid and inorganic nano layer compound alpha-phosphate hydrogen zirconium
Layer assembling is prepared.
In the present invention, the bactericidal effect of obtained antimicrobial spray and the protecting film of formation are prepared with above-mentioned each substance and proportioning
It is optimal into film persistence.
Second aspect, the present invention provides the preparation method of above-mentioned antimicrobial spray, the antimicrobial spray is by following methods system
It is standby to obtain：
By the compound ion anti-biotic material of formula ratio, film forming agent, thickener, nano-titanium dioxide, plant extract agent, anti-corrosion
Agent, solubilizer, freshener and water are added in container, and 3~5h is stirred at 100~150 DEG C, and antimicrobial spray is made.
Wherein, whipping temp can be 100 DEG C, 110 DEG C, 120 DEG C, 130 DEG C, 140 DEG C or 150 DEG C etc., it is not limited to
Cited numerical value, other interior numerical value of listed scope are feasible；Mixing time can be 3h, 4h or 5h etc., it is not limited to institute
The numerical value enumerated, other interior numerical value of listed scope are feasible.
The third aspect, the present invention provides the purposes of above-mentioned antimicrobial spray, and antimicrobial spray is sprayed on and treats degerming object table
Face forms protecting film.
Preferably, it is described to treat that degerming object includes mask, air conditioner filter screen, air purifier strainer, further preferably mouth
Cover.
Compared with prior art, the invention has the advantages that：
(1) antimicrobial spray of haze of the present invention can form protection film in body surface, play sustained anti-microbial
Antibacterial effect；The present invention is made it have good using the synergistic effect of compound ion anti-biotic material and nano-titanium dioxide
Bactericidal effect can kill methicillin-resistant staphylococcus aureus (superbacteria represents bacterium), Escherichia coli, Legionella, suppuration
Property coccus, hepatitis virus, Candida albicans, all kinds of epidemic infectious diseases and bacterial spore etc., sterilizing rate is more than 95%.
(2) antimicrobial spray of haze of the present invention has preferable film forming in the protection film that body surface is formed
Persistence, persistence is up to for 24 hours.
(3) the compound ion anti-biotic material in antimicrobial spray of the present invention is a kind of cheap, environmental-friendly resists
The compatibility of bacterium material and organic material is good；And the antimicrobial spray is free of toxic component, and it is non-corrosive, especially suitable for
People's haze sky is sterilized when going out to wear mask in mask outer surface spray disinfectant.
Specific embodiment
For the present invention is better described, technical scheme is readily appreciated, below to the present invention further specifically
It is bright.But following embodiments is only the simple example of the present invention, does not represent or limit the scope of the present invention, this
Invention protection domain is subject to claims.
Embodiment 1：
A kind of antimicrobial spray of haze is present embodiments provided, contains following components in every liter of antimicrobial spray：It is compound from
Sub- anti-biotic material 37g, film forming agent 2,2,4- trimethyl -1,3- pentanediol mono isobutyrates 45g, thickener sodium carboxymethylcellulose
45g, nano-titanium dioxide 3g, plant extract agent grape seed extract 6g, preservative isothiazolinone 7g, solubilizer polyoxyethylene
Hardened castor oil 5g and freshener menthyl lactate 5g, surplus are pure water.
Wherein, compound ion anti-biotic material is carried out using quaternary ammonium ion liquid and inorganic nano layer compound alpha-phosphate hydrogen zirconium
Intercalation assembling is prepared, and the molar ratio of quaternary ammonium ion liquid and inorganic nano layer compound alpha-phosphate hydrogen zirconium is 1:3.
Embodiment 2：
A kind of antimicrobial spray of haze is present embodiments provided, contains following components in every liter of antimicrobial spray：It is compound from
Sub- anti-biotic material 20g, film forming agent 2,2,4- trimethyl -1,3- pentanediol mono isobutyrates 70g, thickener propylene glycol alginate
40g, nano-titanium dioxide 2g, plant extract agent cherry extract 6g, preservative interior uride 6g, solubilizer fatty alcohol polyoxy second
Alkene ether 5g and freshener menthyl lactate 5g, surplus are pure water.
Wherein, compound ion anti-biotic material is carried out using quaternary phosphonium ion liquid and inorganic nano layer compound alpha-phosphate hydrogen zirconium
Intercalation assembling is prepared, and the molar ratio of quaternary phosphonium ion liquid and inorganic nano layer compound alpha-phosphate hydrogen zirconium is 1:2.
Embodiment 3：
A kind of antimicrobial spray of haze is present embodiments provided, contains following components in every liter of antimicrobial spray：It is compound from
Sub- anti-biotic material 10g, film forming agent polyvinyl alcohol 50g, thickener sodium carboxymethylcellulose 20g, nano-titanium dioxide 4g, plant carry
Take agent grape seed extract 4g, preservative imidazolidinyl urea 8g, solubilizer polyoxyethylene hardened castor oil 3g and freshener n-ethyl-p-menthane-3
Alcohol 2g, surplus are pure water.
Wherein, compound ion anti-biotic material is carried out using quaternary phosphonium ion liquid and inorganic nano layer compound alpha-phosphate hydrogen zirconium
Intercalation assembling is prepared, and the molar ratio of quaternary phosphonium ion liquid and inorganic nano layer compound alpha-phosphate hydrogen zirconium is 1:5.
Embodiment 4：
A kind of antimicrobial spray of haze is present embodiments provided, contains following components in every liter of antimicrobial spray：It is compound from
Sub- anti-biotic material 40g, film forming agent propandiol butyl ether 30g, thickener carboxylic carbomer 60g, nano-titanium dioxide 1g, plant extract agent
Aloe extract 3g, preservative isothiazolinone 7g, solubilizer fatty alcohol polyoxyethylene ether 6g and amide of mint 3g, surplus are pure
Water purification.
The preparation method and materials of the compound ion anti-biotic material are in the same manner as in Example 1.
Embodiment 5：
A kind of antimicrobial spray of haze is present embodiments provided, contains following components in every liter of antimicrobial spray：It is compound from
Sub- anti-biotic material 15g, film forming agent are propylene glycol methyl ether acetate 20g, thickener is chitin 50g, nano-titanium dioxide 5g, plant
Object extract is ginkgo biloba p.e 2g, preservative is p-hydroxybenzoate 5g, solubilizer is aliphatic alcohol polyethenoxy-polyoxy
Propylene ether 8g and freshener are menthyl succinate 6g, and surplus is pure water.
The preparation method and materials of the compound ion anti-biotic material are in the same manner as in Example 1.
Embodiment 6：
A kind of antimicrobial spray of haze is present embodiments provided, contains following components in every liter of antimicrobial spray：It is compound from
Sub- anti-biotic material 30g, film forming agent are diacetone alcohol 60g, thickener is hydroxypropyl starch ether 70g, nano-titanium dioxide 3g, plant
Extract is Lotus Plumule P.E. 7g, and preservative is benzoic acid 3g, and solubilizer is polyoxyethylene sorbitan fatty acid ester 7g
It is N- ethyls-to menthyl -3- formamide 5g with freshener, surplus is pure water.
The preparation method and materials of the compound ion anti-biotic material are in the same manner as in Example 1.
Embodiment 7：
A kind of antimicrobial spray of haze is present embodiments provided, contains following components in every liter of antimicrobial spray：It is compound from
Sub- anti-biotic material 5g, film forming agent are dimethyl ether 40g, thickener is tamarind gum 80g, nano-titanium dioxide 4g, plant
Object extract is wolfberry fruit extract 5g, and preservative is potassium sorbate 4g, and solubilizer is polyglyceryl fatty acid ester 4g and freshener is
2-Isopropyl-N,2,3-trimethylbutyramide 8g, surplus are pure water.
The preparation method and materials of the compound ion anti-biotic material are in the same manner as in Example 1.
Embodiment 8：
A kind of antimicrobial spray of haze is present embodiments provided, contains following components in every liter of antimicrobial spray：It is compound from
Sub- anti-biotic material 60g, film forming agent 2,2,4- trimethyl -1,3- pentanediol mono isobutyrates 50g, thickener sodium carboxymethylcellulose
40g, nano-titanium dioxide 3g, plant extract agent grape seed extract 8g, preservative isothiazolinone 8g, solubilizer polyoxyethylene
Hardened castor oil 2g and freshener menthyl lactate 7g, surplus are pure water.
The preparation method and materials of the compound ion anti-biotic material are in the same manner as in Example 1.
Embodiment 9：
The preparation method of the antimicrobial spray of haze in above-described embodiment 1-8 is present embodiments provided, the method is as follows：
By the compound ion anti-biotic material of formula ratio, film forming agent, thickener, nano-titanium dioxide, plant extract agent, anti-corrosion
Agent, solubilizer, freshener and water are added in container, and 4h is stirred at 130 DEG C, and antimicrobial spray is made.
Embodiment 10：
Except the temperature being stirred is 100 DEG C, the time being stirred is unclassified stores dosage and preparation process outside 3h
It is in the same manner as in Example 9.
Embodiment 11：
Except the temperature being stirred is 150 DEG C, the time being stirred is unclassified stores dosage and preparation process outside 5h
It is in the same manner as in Example 9.
Embodiment 12：
The purposes of the antimicrobial spray of haze in above-described embodiment 1-8 is present embodiments provided, the antimicrobial spray is sprayed
It spills in mask outer surface, layer protecting film can be formed in mask outer surface.
Embodiment 13：
The purposes of the antimicrobial spray of haze in above-described embodiment 1-8 is present embodiments provided, the antimicrobial spray is sprayed
It spills in air conditioner filter screen outer surface, layer protecting film can be formed in air conditioner filter screen outer surface.
Embodiment 14：
The purposes of the antimicrobial spray of haze in above-described embodiment 1-8 is present embodiments provided, the antimicrobial spray is sprayed
It spills in air purifier strainer outer surface, layer protecting film can be formed in air purifier strainer outer surface.
Comparative example 1：
This comparative example provides a kind of antimicrobial spray, forms in addition to being free of nano-titanium dioxide, other composition contents
It is in the same manner as in Example 1.
Comparative example 2：
This comparative example provides a kind of antimicrobial spray, forms in addition to being free of compound ion anti-biotic material, other compositions
Content is in the same manner as in Example 1.
Antimicrobial spray in above-described embodiment 1-8 and comparative example 1-2 is tested for the property, tests it to superbacteria
The bactericidal effect of methicillin-resistant staphylococcus aureus (MRSA), through Guangdong Province's microbiological analysis Spot detection, testability
The results are shown in Table 1 for energy.
Table 1：Antimicrobial spray performance test table in embodiment 1-8 and comparative example 1-2
The antimicrobial spray that the result of integrated embodiment 1-8 and comparative example 1-2 can be seen that haze of the present invention can
Protection film is formed in body surface, plays the antibacterial effect of sustained anti-microbial；The present invention is using compound ion anti-biotic material and receives
The synergistic effect of rice titanium dioxide, makes it have good bactericidal effect, and it is (super can to kill methicillin-resistant staphylococcus aureus
Grade bacterium represent bacterium), Escherichia coli, Legionella, pyococcus, hepatitis virus, Candida albicans, all kinds of epidemic infectious diseases
And bacterial spore etc., sterilizing rate is more than 95%.The antimicrobial spray of haze of the present invention forms anti-in body surface
Protecting film has preferably into film persistence, and persistence is up to for 24 hours.Meanwhile in antimicrobial spray of the present invention it is compound from
Sub- anti-biotic material is that the compatibility of a kind of cheap, environmental-friendly anti-biotic material and organic material is good；And the antibacterial spray
Agent is free of toxic component, and non-corrosive, is sprayed when going out to wear mask especially suitable for people's haze sky in mask outer surface
Disinfection.
Applicant states that the present invention illustrates the method detailed of the present invention, but not office of the invention by above-described embodiment
It is limited to above-mentioned method detailed, that is, does not mean that the present invention has to rely on above-mentioned method detailed and could implement.Technical field
Technical staff it will be clearly understood that any improvement in the present invention, equivalence replacement and auxiliary element to each raw material of product of the present invention
Addition, selection of concrete mode etc., all fall within protection scope of the present invention and the open scope.
Claims (10)
1. a kind of antimicrobial spray of haze, which is characterized in that each component and its content are in the antimicrobial spray：
2. antimicrobial spray according to claim 1, which is characterized in that each component and its content are in the antimicrobial spray：
Preferably, each component and its content are in the antimicrobial spray：
3. antimicrobial spray according to claim 1 or 2, which is characterized in that the compound ion anti-biotic material is by ionic liquid
Body carries out intercalation assembling with inorganic nano layer compound alpha-phosphate hydrogen zirconium and is prepared；
Preferably, the ionic liquid is quaternary ammonium ion liquid and/or quaternary phosphonium ion liquid, further preferably quaternary ammonium ion liquid
Body；
Preferably, the molar ratio of the ionic liquid and inorganic nano layer compound alpha-phosphate hydrogen zirconium is 1:(2~5), further
Preferably 1:3.
4. according to claim 1-3 any one of them antimicrobial sprays, which is characterized in that the film forming agent for polyvinyl alcohol, 2,
2,4- trimethyl -1,3- pentanediol mono isobutyrates, propandiol butyl ether, propylene glycol methyl ether acetate, diacetone alcohol or dipropyl two
Any one in diethylene glycol dimethyl ether or at least two combination, further preferably 2,2,4- trimethyl -1,3- pentanediol list isobutyls
Acid esters.
5. according to claim 1-4 any one of them antimicrobial sprays, which is characterized in that the thickener is carboxymethyl cellulose
Any one in sodium, propylene glycol alginate, carbomer, starch phosphate sodium, chitin, tamarind gum or hydroxypropyl starch ether
Or at least two combination, further preferably sodium carboxymethylcellulose.
6. according to claim 1-5 any one of them antimicrobial sprays, which is characterized in that the plant extract agent carries for grape pip
Take any one in object, cherry extract, aloe extract, ginkgo biloba p.e, Lotus Plumule P.E. or wolfberry fruit extract or
At least two combination, further preferably grape seed extract.
7. according to claim 1-6 any one of them antimicrobial sprays, which is characterized in that the preservative for imidazolidinyl urea,
Any one in interior uride, isothiazolinone, p-hydroxybenzoate, benzoic acid or potassium sorbate or at least two group
It closes, further preferably isothiazolinone；
Preferably, the solubilizer is polyoxyethylene hardened castor oil, Emulsifier EL-60, fatty alcohol polyoxyethylene ether, fat
Any one in fat alcohol polyoxyethylene polyoxypropylene ether, polyoxyethylene sorbitan fatty acid ester or polyglyceryl fatty acid ester
Or at least two combination, further preferably polyoxyethylene hardened castor oil；
Preferably, the freshener be menthol, menthyl lactate, amide of mint, menthyl succinate, N- ethyls-to peppermint
Any one in base -3- formamides or 2-Isopropyl-N,2,3-trimethylbutyramide or at least two combination, further preferably
For menthyl lactate.
8. according to claim 1-7 any one of them antimicrobial sprays, which is characterized in that in the antimicrobial spray each component and its
Content is：
Wherein, compound ion anti-biotic material carries out intercalation group by quaternary ammonium ion liquid and inorganic nano layer compound alpha-phosphate hydrogen zirconium
Dress is prepared.
9. according to the preparation method of claim 1-8 any one of them antimicrobial sprays, which is characterized in that the antimicrobial spray by
Following methods are prepared：
By the compound ion anti-biotic material of formula ratio, film forming agent, thickener, nano-titanium dioxide, plant extract agent, preservative,
Solubilizer, freshener and water are added in container, and 3~5h is stirred at 100~150 DEG C, and antimicrobial spray is made.
10. according to the purposes of claim 1-8 any one of them antimicrobial sprays, which is characterized in that antimicrobial spray is sprayed on
Treat that degerming body surface forms protecting film；
Preferably, it is described to treat that degerming object includes mask, air conditioner filter screen, air purifier strainer, further preferably mask.
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| CN108078959A (en) * | 2016-11-22 | 2018-05-29 | 北京赛特瑞科技发展有限公司 | A kind of antibacterial and protective film and its preparation method and application |
| CN111084183A (en) * | 2019-12-30 | 2020-05-01 | 江苏神涛环保科技有限公司 | Fabric surface antibacterial disinfectant and preparation method thereof |
| CN111286234A (en) * | 2020-04-08 | 2020-06-16 | 晋州市大成变性淀粉有限公司 | Disposable isolation protective film and use method |
| CN111345288A (en) * | 2020-03-12 | 2020-06-30 | 优仕康生（天津）科技发展有限公司 | A colloidal carrier capable of forming antibacterial and antiviral coating on the surface of respiratory protector, colloidal tincture and application thereof |
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| CN111345288A (en) * | 2020-03-12 | 2020-06-30 | 优仕康生（天津）科技发展有限公司 | A colloidal carrier capable of forming antibacterial and antiviral coating on the surface of respiratory protector, colloidal tincture and application thereof |
| CN111408221A (en) * | 2020-03-30 | 2020-07-14 | 广西精典化工新材料有限公司 | Anti-haze agent and preparation method thereof |
| CN111286234A (en) * | 2020-04-08 | 2020-06-16 | 晋州市大成变性淀粉有限公司 | Disposable isolation protective film and use method |
| CN111602673A (en) * | 2020-06-05 | 2020-09-01 | 江苏中新瑞光学材料有限公司 | Nano photocatalyst and silver ion composite hydrophobic disinfectant |
| CN111773140A (en) * | 2020-07-21 | 2020-10-16 | 广州润峰婴儿用品有限公司 | Plant essential oil composition and application thereof |
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| CN114521559A (en) * | 2022-04-07 | 2022-05-24 | 鹰潭荣嘉集团医疗器械实业有限公司 | Preparation method of medical antibacterial material, medical antibacterial material and application thereof |
| CN115531313A (en) * | 2022-09-06 | 2022-12-30 | 杭州先康医疗科技有限公司 | Antibacterial liquid and preparation method and application thereof |
| CN115554453A (en) * | 2022-10-22 | 2023-01-03 | 泉州中科森宝贝生物科技有限公司 | Continuous negative ion air purification antibacterial formaldehyde-removing spray and preparation method thereof |
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