CN108041075A - 一种高效复合型杀菌剂 - Google Patents

一种高效复合型杀菌剂 Download PDF

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CN108041075A
CN108041075A CN201711310929.4A CN201711310929A CN108041075A CN 108041075 A CN108041075 A CN 108041075A CN 201711310929 A CN201711310929 A CN 201711310929A CN 108041075 A CN108041075 A CN 108041075A
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Prior art keywords
efficient compound
water
isothiazolinone
fungicide
copper sulphate
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李瑞标
谢小兰
李桂花
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Foshan Gaofu CNPC Fuel Asphalt Co Ltd
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Foshan Gaofu CNPC Fuel Asphalt Co Ltd
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Priority to CN201711310929.4A priority Critical patent/CN108041075A/zh
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • A01N59/16—Heavy metals; Compounds thereof
    • A01N59/20—Copper
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
    • A01N33/02—Amines; Quaternary ammonium compounds
    • A01N33/04—Nitrogen directly attached to aliphatic or cycloaliphatic carbon atoms
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/50—Treatment of water, waste water, or sewage by addition or application of a germicide or by oligodynamic treatment
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/40—Monoamines or polyamines; Salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/046—Salts
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/34—Organic compounds containing sulfur
    • C11D3/349—Organic compounds containing sulfur additionally containing nitrogen atoms, e.g. nitro, nitroso, amino, imino, nitrilo, nitrile groups containing compounds or their derivatives or thio urea

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  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Environmental Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Zoology (AREA)
  • Plant Pathology (AREA)
  • Pest Control & Pesticides (AREA)
  • Dentistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Agronomy & Crop Science (AREA)
  • Inorganic Chemistry (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

本发明所述一种高效复合型杀菌剂，其成分为：溴化十二烷基苄基铵25‑35％、异噻唑啉酮2‑7％、硫酸铜0.1‑0.2％和水60‑70％。杀菌效果显著，经实践发现还有去垢、增溶、粘泥剥离和清洗作用，在用量为50mg/L更加显著。

Description

一种高效复合型杀菌剂
技术领域
本发明涉及杀菌剂，具体的说，涉及一种高效复合型杀菌剂。
背景技术
为了缓解水资源短缺和经济的增长的矛盾，循环冷却水是工业用水的大户，随着循环冷却水中杂质的浓缩，致使循环冷却水系统发生结垢、腐蚀和生物污垢等突出问题，使热效率呈数量级下降，不但浪费了大量能源，而且由于管道、设备等生锈，大大地降低整个系统的使用寿命。
近几年来随着循环水浓缩倍数的提高，细菌抗药性问题，已使用非氧化性杀菌剂杀菌效率因温度高分解或存放时间过长导致有效成分含量大为降低，系统因微生物繁殖而形成的粘泥故障越来越突出。
发明内容
本发明克服了现有技术中的缺点，提供了一种高效复合型杀菌剂，杀菌效果更加显著，运用更适合循环水水质。
为了解决上述技术问题，本发明是通过以下技术方案实现的：
一种高效复合型杀菌剂，其成分为：溴化十二烷基苄基铵、异噻唑啉酮、硫酸铜和水。
进一步，按照质量比，其成分为：溴化十二烷基苄基铵25-35％、异噻唑啉酮2-7％、硫酸铜0.1-0.2％和水60-70％
进一步，按照质量比，其成分为：溴化十二烷基苄基铵30％、异噻唑啉酮5％、硫酸铜0.1％和水64.9％。
进一步，投药浓度为6mg/L。
进一步，配制方法为：将上述组分加入搅拌机搅拌，先加入水，再加入溴化十二烷基苄基铵、异噻唑啉酮和硫酸铜。
与现有技术相比，本发明的有益效果是：
本发明所述一种高效复合型杀菌剂，其成分为：溴化十二烷基苄基铵、异噻唑啉酮、硫酸铜和水。以硫酸铜作为稳定剂，杀菌效果显著，经实践发现还有去垢、增溶、粘泥剥离和清洗作用，在用量为50mg/L更加显著。
具体实施方式
以下对本发明的优选实施例进行说明，应当理解，此处所描述的优选实施例仅用于说明和解释本发明，并不用于限定本发明。
一种高效复合型杀菌剂配方
序号 药剂名称 质量比例
1. 溴化十二烷基苄基铵 30％
2. 异噻唑啉酮 5％
3. 硫酸铜 0.1％
4. 水 64.9％
试验效果情况
对于每一种杀菌剂，取几种不同的浓度，测定不同时间的杀菌率，从而筛选出最佳投药量，对各种杀菌剂的最佳投药量、药效持续时间以及不同时间的杀菌率进行比较，并将筛选出来的最佳投药量到具体的系统作应用试验，验证高效复合型杀菌剂的效果情况如下：
试验的结果表明，菌藻清杀菌剂在2d时杀菌率达到85.33％，接着又慢慢降下来，7d后就下降至50.55％；异噻唑啉酮、高效复合型杀菌剂在4d时杀菌率达到最高；异噻唑啉酮以及高效复合型杀菌剂投加6h后杀菌率就达到80％以上，说明其在短时间内杀菌效果较高，为速效杀菌剂，而且药效持续时间也较长，7d后还能在80％以上。由此可见，对于这几种杀菌剂在应用时可每周投一次药，对微生物的控制都能达到部颁标准异养菌<10个/mL。经实践发现还有去垢、增溶、粘泥剥离和清洗作用，在用量为50mg/L更加显著。
最后应说明的是：以上仅为本发明的优选实施例而已，并不用于限制本发明，尽管参照实施例对本发明进行了详细的说明，对于本领域的技术人员来说，其依然可以对前述各实施例所记载的技术方案进行修改，或者对其中部分技术特征进行等同替换，但是凡在本发明的精神和原则之内，所作的任何修改、等同替换、改进等，均应包含在本发明的保护范围之内。

Claims (5)

1.一种高效复合型杀菌剂，其特征在于，其成分为：溴化十二烷基苄基铵、异噻唑啉酮、硫酸铜和水。
2.根据权利要求1所述一种高效复合型杀菌剂，其特征在于，按照质量比，其成分为：溴化十二烷基苄基铵25-35％、异噻唑啉酮2-7％、硫酸铜0.1-0.2％和水60-70％。
3.根据权利要求1所述一种高效复合型杀菌剂，其特征在于，按照质量比，其成分为：溴化十二烷基苄基铵30％、异噻唑啉酮5％、硫酸铜0.1％和水64.9％。
4.根据权利要求1所述一种高效复合型杀菌剂，其特征在于，投药浓度为6mg/L。
5.根据权利要求1所述一种高效复合型杀菌剂，其特征在于，配制方法为：将上述组分加入搅拌机搅拌，先加入水，再加入溴化十二烷基苄基铵、异噻唑啉酮和硫酸铜。
CN201711310929.4A 2017-12-11 2017-12-11 一种高效复合型杀菌剂 Pending CN108041075A (zh)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110742085A (zh) * 2019-11-07 2020-02-04 山东鲁东环保科技有限公司 一种用于复合型水质处理的杀菌剂
CN111955480A (zh) * 2020-08-03 2020-11-20 江苏姚氏环保技术有限公司 一种水处理杀菌剂

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10319966A1 (de) * 2003-05-05 2004-12-02 Ochsmann Chemie Gmbh Wasserbettkonditionierer
CN1775025A (zh) * 2004-11-16 2006-05-24 罗门哈斯公司 杀微生物剂组合物
CN101601409A (zh) * 2009-05-26 2009-12-16 兰州华星高科技开发有限公司 循环水用杀菌灭藻剥离剂
CN104068028A (zh) * 2014-06-25 2014-10-01 国家海洋局天津海水淡化与综合利用研究所 一种复合菌藻抑制剂及其应用

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10319966A1 (de) * 2003-05-05 2004-12-02 Ochsmann Chemie Gmbh Wasserbettkonditionierer
CN1775025A (zh) * 2004-11-16 2006-05-24 罗门哈斯公司 杀微生物剂组合物
CN101601409A (zh) * 2009-05-26 2009-12-16 兰州华星高科技开发有限公司 循环水用杀菌灭藻剥离剂
CN104068028A (zh) * 2014-06-25 2014-10-01 国家海洋局天津海水淡化与综合利用研究所 一种复合菌藻抑制剂及其应用

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110742085A (zh) * 2019-11-07 2020-02-04 山东鲁东环保科技有限公司 一种用于复合型水质处理的杀菌剂
CN111955480A (zh) * 2020-08-03 2020-11-20 江苏姚氏环保技术有限公司 一种水处理杀菌剂

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Application publication date: 20180518