CN108018563A - Derusting rust-proofing liquid and preparation method thereof - Google Patents

Derusting rust-proofing liquid and preparation method thereof Download PDF

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Publication number
CN108018563A
CN108018563A CN201610928719.0A CN201610928719A CN108018563A CN 108018563 A CN108018563 A CN 108018563A CN 201610928719 A CN201610928719 A CN 201610928719A CN 108018563 A CN108018563 A CN 108018563A
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China
Prior art keywords
parts
derusting
sodium sulfate
proofing liquid
derusting rust
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Application number
CN201610928719.0A
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Chinese (zh)
Inventor
计富宝
余成琴
张微微
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Henan World Intellectual Property Operation Co Ltd
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Henan World Intellectual Property Operation Co Ltd
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Priority to CN201610928719.0A priority Critical patent/CN108018563A/en
Publication of CN108018563A publication Critical patent/CN108018563A/en
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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23GCLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G1/00Cleaning or pickling metallic material with solutions or molten salts
    • C23G1/02Cleaning or pickling metallic material with solutions or molten salts with acid solutions
    • C23G1/04Cleaning or pickling metallic material with solutions or molten salts with acid solutions using inhibitors
    • C23G1/06Cleaning or pickling metallic material with solutions or molten salts with acid solutions using inhibitors organic inhibitors
    • C23G1/061Cleaning or pickling metallic material with solutions or molten salts with acid solutions using inhibitors organic inhibitors nitrogen-containing compounds
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/05Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
    • C23C22/06Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
    • C23C22/48Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 not containing phosphates, hexavalent chromium compounds, fluorides or complex fluorides, molybdates, tungstates, vanadates or oxalates
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/05Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
    • C23C22/06Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
    • C23C22/48Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 not containing phosphates, hexavalent chromium compounds, fluorides or complex fluorides, molybdates, tungstates, vanadates or oxalates
    • C23C22/50Treatment of iron or alloys based thereon
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23GCLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G1/00Cleaning or pickling metallic material with solutions or molten salts
    • C23G1/02Cleaning or pickling metallic material with solutions or molten salts with acid solutions
    • C23G1/08Iron or steel
    • C23G1/088Iron or steel solutions containing organic acids

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Preventing Corrosion Or Incrustation Of Metals (AREA)
  • Detergent Compositions (AREA)

Abstract

The present invention provides a kind of derusting rust-proofing liquid, it includes the raw material of following parts by weight:5~9 parts of long oil alkyd, 2~6 parts of citric acid, 2~8 parts of lauryl sodium sulfate, 2~4 parts of tartaric acid, 1~2 part of disodium ethylene diamine tetraacetate, 2~6 parts of poly-aspartate, 0.4~1.2 part of oxidized starch, 5~10 parts of trimethyl cetyl ammonium bromide, 10~15 parts of sodium sulfate of polyethenoxy ether of fatty alcohol, 1~2 part of turkey red oil, 1~3 part of carboxymethyl cellulose, 2~8 parts of mesoporous silicon oxide, 10~20 parts of ethylene glycol, 15~20 parts of propandiol butyl ether, 60~90 parts of water.The present invention also provides a kind of preparation method of above-mentioned derusting rust-proofing liquid.The derusting rust-proofing liquid provided by the invention has the multiple functions such as derusting, decontamination, phosphatization, passivation, and reacts at normal temperatures, and the time of derusting is short, antirust time is grown, to metal non-corrosiveness.

Description

Derusting rust-proofing liquid and preparation method thereof
Technical field
The invention belongs to field of metal surface treatment technology, more particularly to a kind of derusting rust-proofing liquid and preparation method thereof.
Background technology
Metal surface antirust is the important topic in industrial production, and traditional antirust solution, antirust oil have advantage also to have shortcoming. Contain substantial amounts of sodium nitrite in common antirust solution, there is carcinogenicity, be unfavorable for environmental protection and human body health, and prolonged using moisturizer The service life of long antirust solution, and the disadvantage brought and touched with one's hand, be covered with dust, and it is unable to long-term rust prevention.Although general hard film rust preventive oil is adapted to Long-term rust prevention, form a film also transparent beauty, but the resin types of water white transparency are less, unstable also easy oxidation discoloration, it is also necessary to Organic solvent dissolves, and brings inflammable and explosive danger to be also unfavorable for environmental protection and health.General antirust oil uses mineral oil, hardly possible drop Solution, and be to also bring along the problem of oil removing is difficult for short-term rust prevention.Therefore, comprehensive study performance is more excellent, for difference The antirust product that occasion research is more suitable for is new direction and trend.
The content of the invention
In view of this, it is necessory to provide a kind of derusting rust-proofing liquid and preparation method thereof, and the derusting rust-proofing liquid has and removes The characteristics of rust is fast, favorable rust preventing effect.
The present invention provides a kind of derusting rust-proofing liquid, it includes the raw material of following parts by weight:5~9 parts of long oil alkyd, 2~6 parts of citric acid, 2~8 parts of lauryl sodium sulfate, 2~4 parts of tartaric acid, 1~2 part of disodium ethylene diamine tetraacetate, poly- asparagus fern 2~6 parts of propylhomoserin, 0.4~1.2 part of oxidized starch, 5~10 parts of trimethyl cetyl ammonium bromide, fatty alcohol polyoxyethylene ether sulphur Sour 10~15 parts of sodium, 1~2 part of turkey red oil, 1~3 part of carboxymethyl cellulose, 2~8 parts of mesoporous silicon oxide, ethylene glycol 10~20 Part, 15~20 parts of propandiol butyl ether, 60~90 parts of water.
Based on above-mentioned, the derusting rust-proofing liquid includes the raw material of following parts by weight:6~8 parts of long oil alkyd, lemon 3~5 parts of acid, 4~7 parts of lauryl sodium sulfate, 3~4 parts of tartaric acid, 1~2 part of disodium ethylene diamine tetraacetate, poly-aspartate 3 ~5 parts, 0.5~1 part of oxidized starch, 6~9 parts of trimethyl cetyl ammonium bromide, sodium sulfate of polyethenoxy ether of fatty alcohol 12~ 13 parts, 1~2 part of turkey red oil, 1~3 part of carboxymethyl cellulose, 4~5 parts of mesoporous silicon oxide, 14~18 parts of ethylene glycol, propane diols 17~18 parts of butyl ether, 70~80 parts of water.
The present invention also provides a kind of preparation method of above-mentioned derusting rust-proofing liquid, it comprises the following steps:According to above-mentioned quality Part, 50~70 DEG C are first heated the water to, adds tartaric acid, lauryl sodium sulfate, citric acid, oxidized starch, trimethyl ten Six alkyl bromination ammoniums, carboxymethyl cellulose, mesoporous silicon oxide, disodium ethylene diamine tetraacetate, are stirred 30~60 minutes;Then, Add long oil alkyd, poly-aspartate, sodium sulfate of polyethenoxy ether of fatty alcohol, turkey red oil, ethylene glycol and propane diols Butyl ether, is stirred 30~60 minutes, cools down and derusting rust-proofing liquid is made.
Compared with prior art, the citric acid in above-mentioned derusting rust-proofing liquid provided by the invention, tartaric acid, dodecyl sulphur Sour sodium and sodium sulfate of polyethenoxy ether of fatty alcohol are mainly used for derusting, decontamination cleaning, and have preferable chelating to metal ion Effect, the residue that effectively can prevent from being formed in descaling process are deposited on metal surface and form secondary corrosion, pollute environment;It is poly- Aspartic acid has stronger scale inhibition performance and dispersiveness concurrently;Poly-aspartate and oxidized starch and trimethyl cetyl bromination at the same time Ammonium, which coordinates, plays the role of metal inhibitor, forms protective film in metallic substrate surface, prevents metal surface in derusting rust-proofing mistake It is corroded in journey;The protective film that long oil alkyd can promote to be formed in metal surface has preferable gloss and weather-proof Property;Oxidized starch also has preferable freeze-thaw resistance, it is ensured that at a lower temperature using the derusting rust-proofing liquid, expands The temperature range that the derusting rust-proofing liquid uses;Trimethyl cetyl ammonium bromide, turkey red oil etc. also permeate with excellent, are soft The performance such as change, emulsification, antistatic, sterilization;Propandiol butyl ether has the smell of relatively happy people, is a kind of advanced solvent of environment-friendly type.Cause This, derusting rust-proofing liquid provided by the invention has the multiple functions such as derusting, decontamination, phosphatization, passivation, and by using inhibition The collective effects such as agent, chelating agent and phosphatization salt form protective film in metal surface, play isolation air, anti-oxidation effect;It is raw Production. art is simple, it is easy to remove, and cost is low, is reacted under room temperature, and the derusting time is short, antirust time length, to metal non-corrosiveness, no It is environmentally safe containing venomous injurant, it is adapted to large-scale production.
Embodiment
Below by embodiment, technical scheme is described in further detail.
Embodiment 1
The present embodiment provides a kind of derusting rust-proofing liquid, it includes the raw material of following parts by weight:5 parts of long oil alkyd, lemon 2 parts of acid, 2 parts of lauryl sodium sulfate, 2 parts of tartaric acid, 1 part of disodium ethylene diamine tetraacetate, 2 parts of poly-aspartate, oxidized starch 0.4 part, 5 parts of trimethyl cetyl ammonium bromide, 10 parts of sodium sulfate of polyethenoxy ether of fatty alcohol, 1 part of turkey red oil, carboxymethyl it is fine 1 part of dimension element, 2 parts of mesoporous silicon oxide, 10 parts of ethylene glycol, 15 parts of propandiol butyl ether, 60 parts of water.
A kind of preparation method of the derusting rust-proofing liquid provided the present embodiment provides above-described embodiment, it comprises the following steps: According to above-mentioned mass parts, first heat the water to 60 DEG C, add tartaric acid, lauryl sodium sulfate, citric acid, oxidized starch, Trimethyl cetyl ammonium bromide, carboxymethyl cellulose, mesoporous silicon oxide, disodium ethylene diamine tetraacetate, are stirred 45 minutes;So Afterwards, long oil alkyd, poly-aspartate, sodium sulfate of polyethenoxy ether of fatty alcohol, turkey red oil, ethylene glycol and the third two are added Alcohol butyl ether, is stirred 45 minutes, cools down and derusting rust-proofing liquid is made.
Embodiment 2
The present embodiment provides the raw material that a kind of derusting rust-proofing liquid includes following parts by weight:6 parts of long oil alkyd, citric acid 3 Part, 3 parts of lauryl sodium sulfate, 2.5 parts of tartaric acid, 1.5 parts of disodium ethylene diamine tetraacetate, 3 parts of poly-aspartate, oxidized starch 0.5 part, 6 parts of trimethyl cetyl ammonium bromide, 11 parts of sodium sulfate of polyethenoxy ether of fatty alcohol, 1.5 parts of turkey red oil, carboxymethyl 1.5 parts of cellulose, 3 parts of mesoporous silicon oxide, 12 parts of ethylene glycol, 16 parts of propandiol butyl ether, 65 parts of water.
The present embodiment also provides a kind of preparation method of above-mentioned derusting rust-proofing liquid, which provides with embodiment 1 The preparation method of derusting rust-proofing liquid is essentially identical, and part is:The mass parts of raw material are different.
Embodiment 3
The present embodiment provides the raw material that a kind of derusting rust-proofing liquid includes following parts by weight:7 parts of long oil alkyd, citric acid 3 Part, 4 parts of lauryl sodium sulfate, 3 parts of tartaric acid, 2 parts of disodium ethylene diamine tetraacetate, 4 parts of poly-aspartate, oxidized starch 0.8 Part, 7 parts of trimethyl cetyl ammonium bromide, 12 parts of sodium sulfate of polyethenoxy ether of fatty alcohol, 1.5 parts of turkey red oil, carboxymethyl cellulose 2 parts of element, 4 parts of mesoporous silicon oxide, 14 parts of ethylene glycol, 17 parts of propandiol butyl ether, 70 parts of water.
The present embodiment also provides a kind of preparation method of above-mentioned derusting rust-proofing liquid, which provides with embodiment 1 The preparation method of derusting rust-proofing liquid is essentially identical, and part is:The mass parts of raw material are different.
Embodiment 4
The present embodiment provides the raw material that a kind of derusting rust-proofing liquid includes following parts by weight:7 parts of long oil alkyd, citric acid 5 Part, 6 parts of lauryl sodium sulfate, 3 parts of tartaric acid, 2 parts of disodium ethylene diamine tetraacetate, 5 parts of poly-aspartate, 1 part of oxidized starch, 8 parts of trimethyl cetyl ammonium bromide, 13 parts of sodium sulfate of polyethenoxy ether of fatty alcohol, 2 parts of turkey red oil, carboxymethyl cellulose 3 Part, 5 parts of mesoporous silicon oxide, 16 parts of ethylene glycol, 18 parts of propandiol butyl ether, 75 parts of water.
The present embodiment also provides a kind of preparation method of above-mentioned derusting rust-proofing liquid, which provides with embodiment 1 The preparation method of derusting rust-proofing liquid is essentially identical, and part is:The mass parts of raw material are different.
Embodiment 5
The present embodiment provides a kind of derusting rust-proofing liquid, it includes the raw material of following parts by weight:8 parts of long oil alkyd, lemon 6 parts of acid, 7 parts of lauryl sodium sulfate, 4 parts of tartaric acid, 2 parts of disodium ethylene diamine tetraacetate, 5 parts of poly-aspartate, oxidized starch 1 Part, 9 parts of trimethyl cetyl ammonium bromide, 14 parts of sodium sulfate of polyethenoxy ether of fatty alcohol, 2 parts of turkey red oil, carboxymethyl cellulose 3 parts, 7 parts of mesoporous silicon oxide, 18 parts of ethylene glycol, 19 parts of propandiol butyl ether, 80 parts of water.
The present embodiment also provides a kind of preparation method of above-mentioned derusting rust-proofing liquid, which provides with embodiment 1 The preparation method of derusting rust-proofing liquid is essentially identical, and part is:The mass parts of raw material are different.
Embodiment 6
The present embodiment provides a kind of derusting rust-proofing liquid, it includes the raw material of following parts by weight:9 parts of long oil alkyd, lemon 6 parts of acid, 8 parts of lauryl sodium sulfate, 4 parts of tartaric acid, 2 parts of disodium ethylene diamine tetraacetate, 6 parts of poly-aspartate, oxidized starch 1.2 parts, 10 parts of trimethyl cetyl ammonium bromide, 15 parts of sodium sulfate of polyethenoxy ether of fatty alcohol, 2 parts of turkey red oil, carboxymethyl it is fine 3 parts of dimension element, 8 parts of mesoporous silicon oxide, 20 parts of ethylene glycol, 20 parts of propandiol butyl ether, 90 parts of water.
The present embodiment also provides a kind of preparation method of above-mentioned derusting rust-proofing liquid, which provides with embodiment 1 The preparation method of derusting rust-proofing liquid is essentially identical, and part is:The mass parts of raw material are different.
Performance test
The derusting rust-proofing liquid provided above-described embodiment 1~6 is detected according to national standard, and damp heat test result is closed after testing Lattice, salt water immersion test result is qualified, and corrosion test result is qualified, and rust removability is less than 6 times.
By the derusting rust-proofing liquid brushing that above-described embodiment 1~6 provides in steel matrix table be newly processed into, surface oil-free Face, has no obvious iron mold, favorable rust preventing effect in 1 month disposed within.
After the derusting ability for the derusting rust-proofing liquid that above-described embodiment 1~6 is provided and derusting needed for the secondary corrosion of metal Time is tested, as a result as shown in the table:
Project Before derusting Derust the time(min) After derusting The secondary corrosion time(My god)
Embodiment 1 Rusty stain is more, matt 13 Without rusty stain, lustrous surface 80
Embodiment 2 Rusty stain is more, matt 11 Without rusty stain, lustrous surface 86
Embodiment 3 Rusty stain is more, matt 11 Without rusty stain, lustrous surface 91
Embodiment 4 Rusty stain is more, matt 9 Without rusty stain, lustrous surface 99
Embodiment 5 Rusty stain is more, matt 10 Without rusty stain, lustrous surface 93
Embodiment 6 Rusty stain is more, matt 10 Without rusty stain, lustrous surface 90
Finally it should be noted that:The above embodiments are merely illustrative of the technical scheme of the present invention and are not intended to be limiting thereof;Although ginseng The present invention is described in detail according to preferred embodiment, those of ordinary skills in the art should understand that:Still can be with Modify to the embodiment of the present invention or equivalent substitution is carried out to some technical characteristics;Without departing from skill of the present invention The spirit of art scheme, it should all cover among the claimed technical solution scope of the present invention.

Claims (3)

1. a kind of derusting rust-proofing liquid, it is characterised in that it includes the raw material of following parts by weight:5~9 parts of long oil alkyd, 2~6 parts of citric acid, 2~8 parts of lauryl sodium sulfate, 2~4 parts of tartaric acid, 1~2 part of disodium ethylene diamine tetraacetate, poly- asparagus fern 2~6 parts of propylhomoserin, 0.4~1.2 part of oxidized starch, 5~10 parts of trimethyl cetyl ammonium bromide, fatty alcohol polyoxyethylene ether sulphur Sour 10~15 parts of sodium, 1~2 part of turkey red oil, 1~3 part of carboxymethyl cellulose, 2~8 parts of mesoporous silicon oxide, ethylene glycol 10~20 Part, 15~20 parts of propandiol butyl ether, 60~90 parts of water.
2. derusting rust-proofing liquid according to claim 1, it is characterised in that it includes the raw material of following parts by weight:Long oil 6~8 parts of alkyd resin, 3~5 parts of citric acid, 4~7 parts of lauryl sodium sulfate, 3~4 parts of tartaric acid, ethylenediamine tetra-acetic acid two 1~2 part of sodium, 3~5 parts of poly-aspartate, 0.5~1 part of oxidized starch, 6~9 parts of trimethyl cetyl ammonium bromide, fatty alcohol 12~13 parts of polyethenoxy ether sodium sulfate, 1~2 part of turkey red oil, 1~3 part of carboxymethyl cellulose, 4~5 parts of mesoporous silicon oxide, 14~18 parts of ethylene glycol, 17~18 parts of propandiol butyl ether, 70~80 parts of water.
3. a kind of preparation method of the derusting rust-proofing liquid described in claim 1 or 2, it includes:50~70 DEG C are first heated the water to, Add tartaric acid, lauryl sodium sulfate, citric acid, oxidized starch, trimethyl cetyl ammonium bromide, carboxymethyl cellulose Element, mesoporous silicon oxide, disodium ethylene diamine tetraacetate, are stirred 30~60 minutes;Then, add long oil alkyd, gather Aspartic acid, sodium sulfate of polyethenoxy ether of fatty alcohol, turkey red oil, ethylene glycol and propandiol butyl ether, are stirred 30~60 minutes, cooling Derusting rust-proofing liquid is made.
CN201610928719.0A 2016-10-31 2016-10-31 Derusting rust-proofing liquid and preparation method thereof Withdrawn CN108018563A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109181529A (en) * 2018-08-17 2019-01-11 南京力同重工机械有限公司 A kind of steel member impregnating fluid and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101792908A (en) * 2009-12-22 2010-08-04 金福东 Environment-friendly rust remover and production method thereof
CN103103547A (en) * 2013-02-27 2013-05-15 杨东佑 Non-phosphorus environment-friendly metal degreasing agent, and production method and usage method thereof
CN105315859A (en) * 2015-11-24 2016-02-10 苏州盖德精细材料有限公司 High-temperature-resistant rust-proof metal surface protectant and preparing method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101792908A (en) * 2009-12-22 2010-08-04 金福东 Environment-friendly rust remover and production method thereof
CN103103547A (en) * 2013-02-27 2013-05-15 杨东佑 Non-phosphorus environment-friendly metal degreasing agent, and production method and usage method thereof
CN105315859A (en) * 2015-11-24 2016-02-10 苏州盖德精细材料有限公司 High-temperature-resistant rust-proof metal surface protectant and preparing method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109181529A (en) * 2018-08-17 2019-01-11 南京力同重工机械有限公司 A kind of steel member impregnating fluid and preparation method thereof

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Application publication date: 20180511