CN103882439A - Water-soluble metal oil and rust removal antirust fluid and preparation method thereof - Google Patents
Water-soluble metal oil and rust removal antirust fluid and preparation method thereof Download PDFInfo
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- CN103882439A CN103882439A CN201410063881.1A CN201410063881A CN103882439A CN 103882439 A CN103882439 A CN 103882439A CN 201410063881 A CN201410063881 A CN 201410063881A CN 103882439 A CN103882439 A CN 103882439A
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Abstract
The invention discloses water-soluble metal oil and rust removal antirust fluid which is prepared from the following raw materials in parts by weight: 3-4 parts of polyoxyethylene alkyl ether, 1-2 parts of sodium dodecyl sulfate, 2-3 parts of 1,3-butylthiourea, 1-2 parts of tartaric acid, 0.5-1.1 parts of 2-methyl imidazoline, 1-2 parts of diamylamine, 30-35 parts of epoxy acrylate, 5-10 parts of propylene glycol monomethyl ether acetate, 1-2 parts of ethylenediaminetetraacetic acid disodium salt, 4-5 parts of auxiliaries and 300 parts of water. The antirust fluid disclosed by the invention can implement one-time oil and rust removal, phosphatization, passivation and anti-rusting on metal surface; by a high-molecular polymer and a chelating agent, the antirust fluid can rapidly form a film on the metal surface to isolate air; the antirust fluid is good in antirust effect and easy to clean, applicable to assembly line work and free from influence on next processes; moreover, the antirust fluid is harmless to humans and free from pollution on environment.
Description
Technical field
The present invention relates to antirust technology field, relate in particular to a kind of water-soluble metal degreasing derusting rust-proofing liquid and preparation method thereof.
Background technology
Metallic surface is antirust is the important topic in industrial production, and traditional rust protection liquid, slushing oil has advantage also to have shortcoming.In common aqueous rust preventive, containing a large amount of Sodium Nitrites, there is carinogenicity, be unfavorable for environmental protection and person health, and adopt wetting Agent for Printing Inks to extend the life-span of aqueous rust preventive, bring again the disadvantage of touching with one's hand, being covered with dust, and can not be antirust for a long time; Although it is antirust for a long time that general hard film rust preventive oil is applicable to, film forming is also transparent attractive in appearance, and water white resin kind is less, and unstable also easy oxidation discoloration, also needs organic solvent dissolution, brings inflammable and explosive danger to be also unfavorable for environmental protection and health; General slushing oil uses mineral oil, difficult degradation, and also can bring the problem of oil removing difficulty when antirust for short-term.Therefore, comprehensive study performance is more excellent, and the antirust product being more applicable to for different occasion research is new direction and trend.
Summary of the invention
The object of the present invention is to provide a kind of water-soluble metal degreasing derusting rust-proofing liquid and preparation method thereof, this rust protection liquid has the feature of rust cleaning, antirust, easy-clear.
Technical scheme of the present invention is as follows:
A kind of water-soluble metal degreasing derusting rust-proofing liquid, is characterized in that being made up of the raw material of following weight part: Voranol EP 2001 3-4, sodium laurylsulfonate 1-2,1.3-dibutyl thiourea 2-3, tartrate 1-2,2-Methylimidazole quinoline 0.5-1.1, diamylamine 1-2, epoxy acrylate 30-35,1-Methoxy-2-propyl acetate 5-10, EDETATE SODIUM 1-2, auxiliary agent 4-5, water 300.Described auxiliary agent is made up of the raw material of following weight part: polyoxyethylene sorbitan monooleate 2-3, nano titanium oxide 0.1-0.2, tripoly phosphate sodium STPP 1-2, water glass 1-2, urotropine 1-2, Resorcinol 1-2, borax 3-4, urea 2-3, ammonium persulphate 1-2, peach gum 2-3, water 20-24; Preparation method be ammonium persulphate is water-soluble after, then add other leftover materials, stir 10-15 minute, be heated to 70-80 DEG C, stirring reaction 1-2 hour, to obtain final product.
The preparation method of described water-soluble metal degreasing derusting rust-proofing liquid, is characterized in that comprising the following steps: heat water to 40-50 DEG C, add Voranol EP 2001, sodium laurylsulfonate; Continue to be heated to 85-90 DEG C, add epoxy acrylate, 1-Methoxy-2-propyl acetate, EDETATE SODIUM, stir 10-15 minute; Add other remaining components, continue to stir 15-20 minute, to obtain final product.
Beneficial effect of the present invention
Rust protection liquid of the present invention can carry out disposable oil removing, rust cleaning, phosphatization, passivation and antirust to metallic surface, by using high molecular polymer and sequestrant, can be at metallic surface fast filming, isolated air, favorable rust preventing effect, cleans easily, be applicable to pipelining, do not affect next step operation and carry out, and harmless, environmentally safe.
Embodiment
A kind of water-soluble metal degreasing derusting rust-proofing liquid, by following weight part (kilogram) raw material make: Voranol EP 2001 3.5, sodium laurylsulfonate 1.5,1.3-dibutyl thiourea 2.5, tartrate 1.5,2-Methylimidazole quinoline 0.8, diamylamine 1.5, epoxy acrylate 33,1-Methoxy-2-propyl acetate 7, EDETATE SODIUM 1.5, auxiliary agent 4.5, water 300.Described auxiliary agent by following weight part (kilogram) raw material make: polyoxyethylene sorbitan monooleate 3, nano titanium oxide 0.1, tripoly phosphate sodium STPP 1, water glass 2, urotropine 2, Resorcinol 1, borax 3, urea 3, ammonium persulphate 1, peach gum 2, water 20; Preparation method be ammonium persulphate is water-soluble after, then add other leftover materials, stir 10-15 minute, be heated to 70-80 DEG C, stirring reaction 1-2 hour, to obtain final product.
The preparation method of described water-soluble metal degreasing derusting rust-proofing liquid, comprises the following steps: heat water to 45 DEG C, add Voranol EP 2001, sodium laurylsulfonate; Continue to be heated to 88 DEG C, add epoxy acrylate, 1-Methoxy-2-propyl acetate, EDETATE SODIUM, stir 13 minutes; Add other remaining components, continue to stir 18 minutes, to obtain final product.
The water-soluble anti-rust liquid that this embodiment obtains detects by national standard, and humid heat test * (1) is qualified; Salt water immersion test * (1): qualified; Corrosion test * (2): qualified; Rust removability (inferior) < 6.Prepared water-soluble anti-rust liquid is brushed on the steel matrix surface of being newly processed into and there is no greasy dirt, be placed in and within indoor 20 days, have no obvious iron mold.
Claims (2)
1. a water-soluble metal degreasing derusting rust-proofing liquid, is characterized in that being made up of the raw material of following weight part: Voranol EP 2001 3-4, sodium laurylsulfonate 1-2,1.3-dibutyl thiourea 2-3, tartrate 1-2,2-Methylimidazole quinoline 0.5-1.1, diamylamine 1-2, epoxy acrylate 30-35,1-Methoxy-2-propyl acetate 5-10, EDETATE SODIUM 1-2, auxiliary agent 4-5, water 300; Described auxiliary agent is made up of the raw material of following weight part: polyoxyethylene sorbitan monooleate 2-3, nano titanium oxide 0.1-0.2, tripoly phosphate sodium STPP 1-2, water glass 1-2, urotropine 1-2, Resorcinol 1-2, borax 3-4, urea 2-3, ammonium persulphate 1-2, peach gum 2-3, water 20-24; Preparation method be ammonium persulphate is water-soluble after, then add other leftover materials, stir 10-15 minute, be heated to 70-80 DEG C, stirring reaction 1-2 hour, to obtain final product.
2. the preparation method of water-soluble metal degreasing derusting rust-proofing liquid according to claim 1, is characterized in that comprising the following steps: heat water to 40-50 DEG C, add Voranol EP 2001, sodium laurylsulfonate; Continue to be heated to 85-90 DEG C, add epoxy acrylate, 1-Methoxy-2-propyl acetate, EDETATE SODIUM, stir 10-15 minute; Add other remaining components, continue to stir 15-20 minute, to obtain final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410063881.1A CN103882439B (en) | 2014-02-25 | 2014-02-25 | A kind of water-soluble metal degreasing derusting rust-proofing liquid and preparation method thereof |
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| CN201410063881.1A CN103882439B (en) | 2014-02-25 | 2014-02-25 | A kind of water-soluble metal degreasing derusting rust-proofing liquid and preparation method thereof |
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| CN103882439A true CN103882439A (en) | 2014-06-25 |
| CN103882439B CN103882439B (en) | 2016-03-16 |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104131287A (en) * | 2014-07-01 | 2014-11-05 | 蚌埠天光传感器有限公司 | Antirust chemically mechanical polishing solution and preparation method thereof |
| CN104532256A (en) * | 2014-12-30 | 2015-04-22 | 合肥华清方兴表面技术有限公司 | Steel online waterborne rust inhibitor and preparation method thereof |
| CN106521521A (en) * | 2016-12-29 | 2017-03-22 | 柳州市凯夕贸易有限公司 | Dust remover for copper product and preparation method therefor |
| CN106752747A (en) * | 2016-12-19 | 2017-05-31 | 苏州耐思特塑胶有限公司 | A kind of preparation method and application of environmentally friendly metal rust-inhibiting liquid |
| CN107299354A (en) * | 2017-07-29 | 2017-10-27 | 巢湖鹏远金属焊管有限公司 | A kind of inner wall of metal tube cleaning fluid and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1327324A (en) * | 1970-10-15 | 1973-08-22 | Dow Corning | Process and composition for removing rust |
| US4395365A (en) * | 1980-09-08 | 1983-07-26 | Nissan Motor Co., Ltd. | Metal cleaning composition containing a fatty acid succrose ester and other detergent components |
| KR20120128236A (en) * | 2011-05-17 | 2012-11-27 | 주식회사 삼녹 | Rust Resisting Composition and Method For Rust Resist |
| CN102993877A (en) * | 2012-11-01 | 2013-03-27 | 安徽荣达阀门有限公司 | Metal rust inhibitor containing sodium dodecyl sulfate |
| CN103540241A (en) * | 2013-10-18 | 2014-01-29 | 安徽蓝柯复合材料有限公司 | Ultraviolet-curing primer wood coating and preparation method thereof |
-
2014
- 2014-02-25 CN CN201410063881.1A patent/CN103882439B/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1327324A (en) * | 1970-10-15 | 1973-08-22 | Dow Corning | Process and composition for removing rust |
| US4395365A (en) * | 1980-09-08 | 1983-07-26 | Nissan Motor Co., Ltd. | Metal cleaning composition containing a fatty acid succrose ester and other detergent components |
| KR20120128236A (en) * | 2011-05-17 | 2012-11-27 | 주식회사 삼녹 | Rust Resisting Composition and Method For Rust Resist |
| CN102993877A (en) * | 2012-11-01 | 2013-03-27 | 安徽荣达阀门有限公司 | Metal rust inhibitor containing sodium dodecyl sulfate |
| CN103540241A (en) * | 2013-10-18 | 2014-01-29 | 安徽蓝柯复合材料有限公司 | Ultraviolet-curing primer wood coating and preparation method thereof |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104131287A (en) * | 2014-07-01 | 2014-11-05 | 蚌埠天光传感器有限公司 | Antirust chemically mechanical polishing solution and preparation method thereof |
| CN104532256A (en) * | 2014-12-30 | 2015-04-22 | 合肥华清方兴表面技术有限公司 | Steel online waterborne rust inhibitor and preparation method thereof |
| CN104532256B (en) * | 2014-12-30 | 2017-01-11 | 合肥华清方兴表面技术有限公司 | Steel online waterborne rust inhibitor and preparation method thereof |
| CN106752747A (en) * | 2016-12-19 | 2017-05-31 | 苏州耐思特塑胶有限公司 | A kind of preparation method and application of environmentally friendly metal rust-inhibiting liquid |
| CN106521521A (en) * | 2016-12-29 | 2017-03-22 | 柳州市凯夕贸易有限公司 | Dust remover for copper product and preparation method therefor |
| CN107299354A (en) * | 2017-07-29 | 2017-10-27 | 巢湖鹏远金属焊管有限公司 | A kind of inner wall of metal tube cleaning fluid and preparation method thereof |
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| Publication number | Publication date |
|---|---|
| CN103882439B (en) | 2016-03-16 |
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Effective date of registration: 20170713 Address after: 528000, 3-2-3, two, three Village Industrial Zone, five street, Daliang street, Shunde District, Guangdong, Foshan Patentee after: Foshan city Shunde District Yuanhao Metal Industrial Co.,Ltd. Address before: 510000 unit 2414-2416, building, No. five, No. 371, Tianhe District, Guangdong, China Patentee before: GUANGDONG GAOHANG INTELLECTUAL PROPERTY OPERATION Co.,Ltd. Effective date of registration: 20170713 Address after: 510000 unit 2414-2416, building, No. five, No. 371, Tianhe District, Guangdong, China Patentee after: GUANGDONG GAOHANG INTELLECTUAL PROPERTY OPERATION Co.,Ltd. Address before: 233000 No. 404 South Daqing Road, hi tech Zone, Anhui, Bengbu Patentee before: Anhui Topcell Battery Co.,Ltd. |
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Granted publication date: 20160316 Termination date: 20190225 |