CN108017375A - A kind of environmentally friendly composite ceramic material for building and preparation method thereof - Google Patents
A kind of environmentally friendly composite ceramic material for building and preparation method thereof Download PDFInfo
- Publication number
- CN108017375A CN108017375A CN201711101949.0A CN201711101949A CN108017375A CN 108017375 A CN108017375 A CN 108017375A CN 201711101949 A CN201711101949 A CN 201711101949A CN 108017375 A CN108017375 A CN 108017375A
- Authority
- CN
- China
- Prior art keywords
- parts
- building
- environmentally friendly
- friendly composite
- glair
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/62204—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products using waste materials or refuse
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3201—Alkali metal oxides or oxide-forming salts thereof
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3205—Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
- C04B2235/3206—Magnesium oxides or oxide-forming salts thereof
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3205—Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
- C04B2235/3208—Calcium oxide or oxide-forming salts thereof, e.g. lime
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3217—Aluminum oxide or oxide forming salts thereof, e.g. bauxite, alpha-alumina
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/327—Iron group oxides, their mixed metal oxides, or oxide-forming salts thereof
- C04B2235/3275—Cobalt oxides, cobaltates or cobaltites or oxide forming salts thereof, e.g. bismuth cobaltate, zinc cobaltite
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3409—Boron oxide, borates, boric acids, or oxide forming salts thereof, e.g. borax
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3418—Silicon oxide, silicic acids, or oxide forming salts thereof, e.g. silica sol, fused silica, silica fume, cristobalite, quartz or flint
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/44—Metal salt constituents or additives chosen for the nature of the anions, e.g. hydrides or acetylacetonate
- C04B2235/448—Sulphates or sulphites
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/48—Organic compounds becoming part of a ceramic after heat treatment, e.g. carbonising phenol resins
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Processing Of Solid Wastes (AREA)
Abstract
It is prepared the invention discloses a kind of environmentally friendly composite ceramic material for building and preparation method thereof, including by the raw material of following parts by weight：20 35 parts of calcium carbonate-base waste material, 20 30 parts of zirconium alkoxide, 15 30 parts of road pavements pitch, 10 20 parts of glair, 8 15 parts of borax decahydrate, 20 35 parts of solid-phase powder material, 10 12 parts of earthy cobalt, 11 22 parts of polyurethane, 7 15 parts of zinc sulfate, 8 18 parts of magnesia, 5 10 parts of Chinese milk vetch, 5 10 parts of organic fiber.Entirety of the invention is made of ceramic material, and temperature in use is up to 900 DEG C, completely fire prevention, and the high service life length of intensity, alternative existing materials for wall and inflammable thermal insulation material, substantially increases the security of building construction；Ceramic discarded object greatly reduces the production cost of heat-insulating construction material as raw materials for production；Ceramic discarded object takes a large amount of soils, causes environmental pollution, and the present invention realizes the comprehensive utilization to trade waste, energy conservation and environmental protection, reduces pollution using it as a kind of raw material of industry.
Description
Technical field
The present invention relates to technical field of ceramic preparation, and in particular to a kind of environmentally friendly composite ceramic material for building and its preparation
Method.
Background technology
With increasing with wall heat insulation material associated fire disaster accident, building field is proposed in exterior insulation
Using fire prevention isolation and without ways such as cavitys in system, it can so solve organic insulation material combustion characteristics Flame and easily pass
The defects of broadcasting, easily spreading, so as to avoid the fire incident caused by inflammable thermal insulation material triggers flame spread, propagates.But
It is that temperature tolerance of the organic insulation material on wall body structure, flame resistance, and organic guarantor are not researched and solved in fireproof construction
Adiabator discharge in a fire the thermoplasticity such as cigarette poison gas, EPS, XPS organic insulation material itself produce in combustion it is molten
The problems such as melting, dripping.This means that low fire-protection rating existing for organic insulation material technology, stability and durability difference
Inherent shortcoming has not adapted to requirement of the society to building thermal insulation material.
With social economy and the fast development of ceramic industry, ceramic industry waste material is increasing, and handling these waste materials needs
Substantial amounts of social resources are expended, the sustainable development of development and the ceramic industry of urban economy is limited on partial extent.Mesh
Before, with producing level than relatively low, substantial amounts of waste residue ties up public resource, is subject to environment for the processing of China's ceramic industry waste material
Pollution.With the increase of ceramics production capacity, the quantity of waste material is more and more, and substantial amounts of calcium carbonate-base waste material has not been simple
Soluble problem is filled, the accumulation of calcium carbonate-base waste material ties up soil, and fine dust influences the quality of local air, and
The landfill of calcium carbonate-base waste material expends substantial amounts of manpower and materials, goes back polluted underground water matter, how to turn waste into wealth, by calcium carbonate-base
Waste material carries out recycling and rationally utilizes, and has become the task of top priority of science and technology and environmental protection administration.
Ceramic material has many advantages, such as that such as beautiful and generous, acid and alkali-resistance, high temperature resistant, add in daily necessities, building materials, machinery
The various fields such as work have extensive use.Aluminium oxide and zirconium oxide are two kinds of components common in ceramic material, and aluminium oxide has
The excellent properties such as proportion is low, high temperature resistant, have extensive use in ceramic material field, but its flexural strength and fracture toughness are relatively low
；Zirconium oxide has good flexural strength, is known as " Ceramo-steel ", but its proportion is larger, it will usually increase the weight of finished product.Oxygen
Change the combination of both zirconium and aluminium oxide, prepare composite ceramic material technology and receive more and more attention.Nickel oxide leads to
It is commonly used for the pigment of ceramic material.
The content of the invention
To solve the above problems, high the present invention provides a kind of building waste utilization rate, product water absorption rate is low, antifouling property
Environmentally friendly composite ceramic material for building good, intensity is high and preparation method thereof.
To achieve the above object, the technical solution taken of the present invention is：
A kind of environmentally friendly composite ceramic material for building and preparation method thereof, including be prepared by the raw material of following parts by weight：Carbon
Sour 20-35 parts of calcium base waste material, 20-30 parts of zirconium alkoxide, 15-30 parts of road pavements pitch, 10-20 parts of glair, borax decahydrate
8-15 parts, 20-35 parts of solid-phase powder material, 10-12 parts of earthy cobalt, 11-22 parts of polyurethane, 7-15 parts of zinc sulfate, 8-18 parts of magnesia,
It is 5-10 parts of Chinese milk vetch, 5-10 parts of organic fiber, 4-8 parts of foaming agent, gelling agent 5-9 parts additional.
Further, a kind of environmentally friendly composite ceramic material for building, including be prepared by the raw material of following parts by weight：Carbon
Sour 21-34 parts of calcium base waste material, 21-28 parts of zirconium alkoxide, 16-27 parts of road pavements pitch, 11-19 parts of glair, borax decahydrate
9-14 parts, 22-33 parts of solid-phase powder material, 11-12 parts of earthy cobalt, 15-20 parts of polyurethane, 8-14 parts of zinc sulfate, 9-17 parts of magnesia,
It is 6-8 parts of Chinese milk vetch, 6-9 parts of organic fiber, 5-7 parts of foaming agent, gelling agent 6-8 parts additional.
Further, the glair is the one or more in silica, aluminium oxide, calcium oxide, sodium oxide molybdena and potassium oxide.
Further, a kind of preparation method of environmentally friendly composite ceramic material for building, includes the following steps：
S1, by 21-34 parts of calcium carbonate-base waste material, 21-28 parts of zirconium alkoxide, 16-27 parts of road pavements pitch, borax decahydrate 8-
15 parts, 20-35 parts of solid-phase powder material, after the mixing of 11-12 parts of earthy cobalt, add after pulverizer crushed, cross the filter of 100-130 mesh
Sieve, obtains material；
Step S1, is obtained material and adds water to carry out ball milling by S2, then adds 11-19 parts of glair, 15-20 parts of polyurethane, zinc sulfate
8-14 parts, 9-17 parts of magnesia, 6-8 parts of Chinese milk vetch, 6-9 parts of organic fiber progress wet ball mill 10-20min, repeatedly ball milling 2-3
It is secondary, obtain ceramic slurry；
S3, by 5-7 parts of foaming agent, it is additional gelling agent 6-8 parts plus water stirring, be heated up to 30-40 DEG C, stir evenly；It is modified
Solution；
S4, obtain modified solution by the ceramic slurry obtained by step S2 and step S3 and be uniformly mixed, the powder after pressed compact, heat treatment
Mill, crosses 100 mesh sieves, and the mixture crossed after shining, which is placed in fireproof die after firing, obtains building composite ceramics.
Further, a kind of environmentally friendly composite ceramic material for building, including be prepared by the raw material of following parts by weight：Carbon
Sour 28 parts of calcium base waste material, 25 parts of zirconium alkoxide, 19 parts of road pavements pitch, 17 parts of glair, 11 parts of borax decahydrate, solid-phase powder material
27 parts, 11 parts of earthy cobalt, 18 parts of polyurethane, 11 parts of zinc sulfate, 15 parts of magnesia, 7 parts of Chinese milk vetch, 8 parts of organic fiber, foaming agent
6 parts, 7 parts of additional gelling agent.
The present invention is using calcium carbonate-base waste material, zirconium alkoxide, road pavements pitch, glair, borax decahydrate, solid phase powder
Material, earthy cobalt, polyurethane, zinc sulfate, magnesia, Chinese milk vetch, organic fiber effectively match, and obtain building ceramics, use
Temperature is up to 900 DEG C, completely fire prevention, and the high service life length of intensity, alternative existing materials for wall and inflammable thermal insulating material
Material, the security enhancing ceramics strength that substantially increases building construction is high, compactness is good, toughness significantly improves, and high temperature resistant and
It is wear-resisting excellent, it can be widely used for the various fields high to strength of materials requirement and use mineral and industrial chemicals.
Entirety of the invention is made of ceramic material, and temperature in use is up to 900 DEG C, fire prevention, and the high service life of intensity completely
Length, alternative existing materials for wall and inflammable thermal insulation material, substantially increase the security of building construction；Ceramic discarded object
As raw materials for production, the production cost of heat-insulating construction material is greatly reduced；Ceramic discarded object takes a large amount of soils, causes ring
Border is polluted, and the present invention realizes the comprehensive utilization to trade waste, energy conservation and environmental protection, is reduced dirty using it as a kind of raw material of industry
Dye；Production cost is relatively low, is easy to large-scale production, can make a variety of moulding and texture, saves mineral resources；Cheap, production
Technique is simple, is adapted to large-scale production.
Embodiment
In order to which objects and advantages of the present invention are more clearly understood, the present invention is carried out with reference to embodiments further detailed
Explanation.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, it is not intended to limit the present invention.
The present invention includes being prepared by the raw material of following parts by weight：20-35 parts of calcium carbonate-base waste material, zirconium alkoxide 20-30
Part, 15-30 parts of road pavements pitch, 10-20 parts of glair, 8-15 parts of borax decahydrate, 20-35 parts of solid-phase powder material, earthy cobalt
10-12 parts, 11-22 parts of polyurethane, 7-15 parts of zinc sulfate, 8-18 parts of magnesia, 5-10 parts of Chinese milk vetch, 5-10 parts of organic fiber,
It is 4-8 parts of foaming agent, gelling agent 5-9 parts additional.
A kind of environmentally friendly composite ceramic material for building, including be prepared by the raw material of following parts by weight：Calcium carbonate-base gives up
Material 21-34 part, 21-28 parts of zirconium alkoxide, 16-27 parts of road pavements pitch, 11-19 parts of glair, 9-14 parts of borax decahydrate, consolidate
22-33 parts of phase powder, 11-12 parts of earthy cobalt, 15-20 parts of polyurethane, 8-14 parts of zinc sulfate, 9-17 parts of magnesia, Chinese milk vetch 6-8
It is part, 6-9 parts of organic fiber, 5-7 parts of foaming agent, gelling agent 6-8 parts additional.
The glair is the one or more in silica, aluminium oxide, calcium oxide, sodium oxide molybdena and potassium oxide.
A kind of preparation method of environmentally friendly composite ceramic material for building, includes the following steps：
S1, by 21-34 parts of calcium carbonate-base waste material, 21-28 parts of zirconium alkoxide, 16-27 parts of road pavements pitch, borax decahydrate 8-
15 parts, 20-35 parts of solid-phase powder material, after the mixing of 11-12 parts of earthy cobalt, add after pulverizer crushed, cross the filter of 100-130 mesh
Sieve, obtains material；
Step S1, is obtained material and adds water to carry out ball milling by S2, then adds 11-19 parts of glair, 15-20 parts of polyurethane, zinc sulfate
8-14 parts, 9-17 parts of magnesia, 6-8 parts of Chinese milk vetch, 6-9 parts of organic fiber progress wet ball mill 10-20min, repeatedly ball milling 2-3
It is secondary, obtain ceramic slurry；
S3, by 5-7 parts of foaming agent, it is additional gelling agent 6-8 parts plus water stirring, be heated up to 30-40 DEG C, stir evenly；It is modified
Solution；
S4, obtain modified solution by the ceramic slurry obtained by step S2 and step S3 and be uniformly mixed, the powder after pressed compact, heat treatment
Mill, crosses 100 mesh sieves, and the mixture crossed after shining, which is placed in fireproof die after firing, obtains building composite ceramics.
Embodiment 1：
A kind of preparation method of environmentally friendly composite ceramic material for building, includes the following steps：
S1, by 26 parts of calcium carbonate-base waste material, 26 parts of zirconium alkoxide, 19 parts of road pavements pitch, 12 parts of borax decahydrate, solid phase powder
After 11 parts of 28 parts of material, earthy cobalt mixing, after addition pulverizer is crushed, 120 mesh screens are crossed, obtain material；
Step S1, is obtained material and adds water to carry out ball milling by S2, then adds 17 parts of glair, 17 parts of polyurethane, 11 parts of zinc sulfate, oxygen
Change 7 parts of 15 parts of magnesium, 7 parts of Chinese milk vetch, organic fiber progress wet ball mill 16min, ball milling 2-3 times repeatedly, obtains ceramic slurry；
S3, by 6 parts of foaming agent, 7 parts of additional gelling agent plus water stirring, be heated up to 36 DEG C, stir evenly；Obtain modified solution；
S4, obtain modified solution by the ceramic slurry obtained by step S2 and step S3 and be uniformly mixed, the powder after pressed compact, heat treatment
Mill, crosses 100 mesh sieves, and the mixture crossed after shining, which is placed in fireproof die after firing, obtains building composite ceramics.
Embodiment 2：
A kind of preparation method of environmentally friendly composite ceramic material for building, includes the following steps：
S1, by 34 parts of calcium carbonate-base waste material, 28 parts of zirconium alkoxide, 27 parts of road pavements pitch, 15 parts of borax decahydrate, solid phase powder
After 12 parts of 35 parts of material, earthy cobalt mixing, after addition pulverizer is crushed, 130 mesh screens are crossed, obtain material；
Step S1, is obtained material and adds water to carry out ball milling by S2, then adds 19 parts of glair, 20 parts of polyurethane, 14 parts of zinc sulfate, oxygen
Change 9 parts of 17 parts of magnesium, 8 parts of Chinese milk vetch, organic fiber progress wet ball mill 20min, ball milling 3 times, obtain ceramic slurry repeatedly；
S3, by 7 parts of foaming agent, 8 parts of additional gelling agent plus water stirring, be heated up to 40 DEG C, stir evenly；Obtain modified solution；
S4, obtain modified solution by the ceramic slurry obtained by step S2 and step S3 and be uniformly mixed, the powder after pressed compact, heat treatment
Mill, crosses 100 mesh sieves, and the mixture crossed after shining, which is placed in fireproof die after firing, obtains building composite ceramics.
Embodiment 3：
A kind of preparation method of environmentally friendly composite ceramic material for building, includes the following steps：
S1, by 21 parts of calcium carbonate-base waste material, 21 parts of zirconium alkoxide, 16 parts of road pavements pitch, 8 parts of borax decahydrate, solid phase powder
After 11 parts of 20 parts of material, earthy cobalt mixing, after addition pulverizer is crushed, 100 mesh screens are crossed, obtain material；
Step S1, is obtained material and adds water to carry out ball milling by S2, then adds 11 parts of glair, 15 parts of polyurethane, 8 parts of zinc sulfate, oxygen
Change 6 parts of 9 parts of magnesium, 6 parts of Chinese milk vetch, organic fiber progress wet ball mill 10min, ball milling 2 times, obtain ceramic slurry repeatedly；
S3, by 5 parts of foaming agent, 6 parts of additional gelling agent plus water stirring, be heated up to 30 DEG C, stir evenly；Obtain modified solution；
S4, obtain modified solution by the ceramic slurry obtained by step S2 and step S3 and be uniformly mixed, the powder after pressed compact, heat treatment
Mill, crosses 100 mesh sieves, and the mixture crossed after shining, which is placed in fireproof die after firing, obtains building composite ceramics.
The present invention is using calcium carbonate-base waste material, zirconium alkoxide, road pavements pitch, glair, borax decahydrate, solid phase powder
Material, earthy cobalt, polyurethane, zinc sulfate, magnesia, Chinese milk vetch, organic fiber effectively match, and obtain building ceramics, use
Temperature is up to 900 DEG C, completely fire prevention, and the high service life length of intensity, alternative existing materials for wall and inflammable thermal insulating material
Material, the security enhancing ceramics strength that substantially increases building construction is high, compactness is good, toughness significantly improves, and high temperature resistant and
It is wear-resisting excellent, it can be widely used for the various fields high to strength of materials requirement and use mineral and industrial chemicals.
Entirety of the invention is made of ceramic material, and temperature in use is up to 900 DEG C, fire prevention, and the high service life of intensity completely
Length, alternative existing materials for wall and inflammable thermal insulation material, substantially increase the security of building construction；Ceramic discarded object
As raw materials for production, the production cost of heat-insulating construction material is greatly reduced；Ceramic discarded object takes a large amount of soils, causes ring
Border is polluted, and the present invention realizes the comprehensive utilization to trade waste, energy conservation and environmental protection, is reduced dirty using it as a kind of raw material of industry
Dye；Production cost is relatively low, is easy to large-scale production, can make a variety of moulding and texture, saves mineral resources；Cheap, production
Technique is simple, is adapted to large-scale production.
The above is only the preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art
For member, without departing from the principle of the present invention, some improvements and modifications can also be made, these improvements and modifications also should
It is considered as protection scope of the present invention.
Claims (5)
1. a kind of environmentally friendly composite ceramic material for building, it is characterised in that including being prepared by the raw material of following parts by weight：Carbon
Sour 20-35 parts of calcium base waste material, 20-30 parts of zirconium alkoxide, 15-30 parts of road pavements pitch, 10-20 parts of glair, borax decahydrate
8-15 parts, 20-35 parts of solid-phase powder material, 10-12 parts of earthy cobalt, 11-22 parts of polyurethane, 7-15 parts of zinc sulfate, 8-18 parts of magnesia,
It is 5-10 parts of Chinese milk vetch, 5-10 parts of organic fiber, 4-8 parts of foaming agent, gelling agent 5-9 parts additional.
2. one kind according to claim 1 environmentally friendly composite ceramic material for building, it is characterised in that including by following weight
The raw material of part is prepared：21-34 parts of calcium carbonate-base waste material, 21-28 parts of zirconium alkoxide, 16-27 parts of road pavements pitch, glaze
11-19 parts of paddle, 9-14 parts of borax decahydrate, 22-33 parts of solid-phase powder material, 11-12 parts of earthy cobalt, 15-20 parts of polyurethane, zinc sulfate 8-
14 parts, it is 9-17 parts of magnesia, 6-8 parts of Chinese milk vetch, 6-9 parts of organic fiber, 5-7 parts of foaming agent, gelling agent 6-8 parts additional.
3. one kind according to claim 1 environmentally friendly composite ceramic material for building, it is characterised in that the glair is oxidation
One or more in silicon, aluminium oxide, calcium oxide, sodium oxide molybdena and potassium oxide.
A kind of 4. preparation method of environmentally friendly composite ceramic material for building according to claim 1, it is characterised in that including
Following steps：
S1, by 21-34 parts of calcium carbonate-base waste material, 21-28 parts of zirconium alkoxide, 16-27 parts of road pavements pitch, borax decahydrate 8-
15 parts, 20-35 parts of solid-phase powder material, after the mixing of 11-12 parts of earthy cobalt, add after pulverizer crushed, cross the filter of 100-130 mesh
Sieve, obtains material；
Step S1, is obtained material and adds water to carry out ball milling by S2, then adds 11-19 parts of glair, 15-20 parts of polyurethane, zinc sulfate
8-14 parts, 9-17 parts of magnesia, 6-8 parts of Chinese milk vetch, 6-9 parts of organic fiber progress wet ball mill 10-20min, repeatedly ball milling 2-3
It is secondary, obtain ceramic slurry；
S3, by 5-7 parts of foaming agent, it is additional gelling agent 6-8 parts plus water stirring, be heated up to 30-40 DEG C, stir evenly；It is modified
Solution；
S4, obtain modified solution by the ceramic slurry obtained by step S2 and step S3 and be uniformly mixed, the powder after pressed compact, heat treatment
Mill, crosses 100 mesh sieves, and the mixture crossed after shining, which is placed in fireproof die after firing, obtains building composite ceramics.
5. one kind according to claim 1 environmentally friendly composite ceramic material for building, it is characterised in that including by following weight
The raw material of part is prepared：28 parts of calcium carbonate-base waste material, 25 parts of zirconium alkoxide, 19 parts of road pavements pitch, 17 parts of glair, ten
11 parts of water borax, 27 parts of solid-phase powder material, 11 parts of earthy cobalt, 18 parts of polyurethane, 11 parts of zinc sulfate, 15 parts of magnesia, Chinese milk vetch 7
Part, 8 parts of organic fiber, 6 parts of foaming agent, 7 parts of additional gelling agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711101949.0A CN108017375A (en) | 2017-11-10 | 2017-11-10 | A kind of environmentally friendly composite ceramic material for building and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711101949.0A CN108017375A (en) | 2017-11-10 | 2017-11-10 | A kind of environmentally friendly composite ceramic material for building and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108017375A true CN108017375A (en) | 2018-05-11 |
Family
ID=62079775
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711101949.0A Pending CN108017375A (en) | 2017-11-10 | 2017-11-10 | A kind of environmentally friendly composite ceramic material for building and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108017375A (en) |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR0141246B1 (en) * | 1995-12-29 | 1998-06-01 | 정진호 | A light weight aggregate and the light weight mortar & building materials using them |
| CN104072026A (en) * | 2014-07-17 | 2014-10-01 | 杨冰 | Road paving material adopting ceramic wastes and preparation method thereof |
| CN104355677A (en) * | 2014-10-25 | 2015-02-18 | 青岛智谷创新技术有限公司 | Improved construction ceramic glaze |
| CN104829263A (en) * | 2015-05-25 | 2015-08-12 | 吴江华诚复合材料科技有限公司 | Novel lightweight composite heat-insulation ceramic construction material and preparation method thereof |
| CN105174912A (en) * | 2015-09-16 | 2015-12-23 | 季红军 | Architectural composite ceramic material and preparation method thereof |
| CN106565211A (en) * | 2016-10-28 | 2017-04-19 | 芜湖浩权建筑工程有限公司 | High-performance environment-friendly building-use ceramic material and preparation method thereof |
| CN106587941A (en) * | 2016-12-14 | 2017-04-26 | 苏州耐思特塑胶有限公司 | Low-expansion building ceramic material and preparation method thereof |
-
2017
- 2017-11-10 CN CN201711101949.0A patent/CN108017375A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR0141246B1 (en) * | 1995-12-29 | 1998-06-01 | 정진호 | A light weight aggregate and the light weight mortar & building materials using them |
| CN104072026A (en) * | 2014-07-17 | 2014-10-01 | 杨冰 | Road paving material adopting ceramic wastes and preparation method thereof |
| CN104355677A (en) * | 2014-10-25 | 2015-02-18 | 青岛智谷创新技术有限公司 | Improved construction ceramic glaze |
| CN104829263A (en) * | 2015-05-25 | 2015-08-12 | 吴江华诚复合材料科技有限公司 | Novel lightweight composite heat-insulation ceramic construction material and preparation method thereof |
| CN105174912A (en) * | 2015-09-16 | 2015-12-23 | 季红军 | Architectural composite ceramic material and preparation method thereof |
| CN106565211A (en) * | 2016-10-28 | 2017-04-19 | 芜湖浩权建筑工程有限公司 | High-performance environment-friendly building-use ceramic material and preparation method thereof |
| CN106587941A (en) * | 2016-12-14 | 2017-04-26 | 苏州耐思特塑胶有限公司 | Low-expansion building ceramic material and preparation method thereof |
Non-Patent Citations (3)
| Title |
|---|
| 孟广耀等: "《材料化学若干前沿研究》", 31 January 2013, 中国科学技术大学出版社 * |
| 尹邦跃等: "《陶瓷核燃料工艺》", 31 January 2016, 哈尔滨工程大学出版社 * |
| 贾兴文等: "《土木工程材料》", 31 August 2017, 重庆大学出版社 * |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103342468B (en) | Composite sheet of foam pyroceram and pure devitrified glass and preparation method thereof | |
| CN101955349B (en) | Sintered permeable environmental-friendly brick produced by using ceramic waste residue and manufacturing method thereof | |
| CN104829263B (en) | A kind of light ceramics composite heat-insulating construction material and preparation method | |
| CN101994283B (en) | Steamed ecological water permeable environmentally friendly brick produced by waste ceramic residues and manufacturing method thereof | |
| CN105367024B (en) | A kind of external-wall heat-insulation material | |
| CN102797299A (en) | Insulation board made of fiber reinforced composites and preparation method of insulation board | |
| CN102418308A (en) | Water permeable bricks produced by using building waste residue and manufacturing method thereof | |
| CN105110720A (en) | Modified building residue baking-free brick | |
| CN107188484A (en) | A kind of high-strength heat preservation sound isolating and flame-retardant environment friendly wall material and preparation method thereof | |
| CN105442725B (en) | A kind of energy-saving prevention fire type external wall construction | |
| CN104563425B (en) | Integration board for decorating, preventing fire and keeping warm | |
| CN107235679A (en) | A kind of graphene enhancing water-permeable brick and preparation method thereof | |
| CN108314408A (en) | Environment-friendly compression-resistant light water permeable brick and preparation method thereof | |
| CN106518149B (en) | A kind of method of oil shale semi-coke and iron tailing sintered water-permeable brick | |
| CN106747309A (en) | A kind of building composite ceramics of environment protection type heat insulating insulation and preparation method thereof | |
| CN102173717B (en) | Production method of high-strength light environment-friendly insulation fire-proof plate | |
| CN108298948A (en) | A kind of high-strength composite building ceramics and preparation method thereof | |
| CN105503101B (en) | Foam concrete and preparation method thereof | |
| CN103924763A (en) | Manufacturing process for external wall decoration hanging plate | |
| CN104230273B (en) | A kind of body of wall energy-conserving and environment-protective insulation material | |
| CN201125482Y (en) | Core foaming concrete heat preserving building blocks | |
| CN108558208A (en) | A kind of environment protection architecture ceramic glaze and preparation method thereof | |
| CN103992071A (en) | Fabrication process for producing concrete brick by using polished tile waste residue | |
| CN103711274A (en) | Composite thermal insulation board and preparation method thereof | |
| CN108275921A (en) | A kind of adiabatic heat-insulation wall material and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180511 |
|
| RJ01 | Rejection of invention patent application after publication |