CN105174912A - Architectural composite ceramic material and preparation method thereof - Google Patents
Architectural composite ceramic material and preparation method thereof Download PDFInfo
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- CN105174912A CN105174912A CN201510587573.3A CN201510587573A CN105174912A CN 105174912 A CN105174912 A CN 105174912A CN 201510587573 A CN201510587573 A CN 201510587573A CN 105174912 A CN105174912 A CN 105174912A
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Abstract
The invention discloses a preparation method of an architectural composite ceramic material. The preparation method comprises the following steps: dissolving zirconium alkoxide, aluminum nitrate and nickel nitrate in nitrate with a certain concentration, stirring, and carrying out hydrolysis and polymerization reaction to generate a composite precursor; adding sodium lignosulfonate, a surfactant and a dispersing agent into a certain amount of deionized water, and stirring while controlling the temperature in a water bath, thereby obtaining a modifier solution; and mixing the modifier solution and composite precursor, naturally cooling, standing to react to obtain a composite colloidal solution, regulating the pH value to neutrality with an alkali solution, adding kaolin, stirring, filtering, drying and carrying out heat treatment to obtain the ordered-structure composite ceramic material. The ordered-structure excellent-performance architectural composite ceramic is prepared by using the chemical synthesis technique. The preparation technique can be popularized for preparing the multicomponent functional ceramic material.
Description
Technical field
The invention belongs to preparation technology of ceramic materials, particularly a kind of preparation method containing zirconium white, aluminum oxide, nickel oxide and kaolinic building composite ceramics.
Background technology
Stupalith has plurality of advantages, as elegant in appearance, acid and alkali-resistance, high temperature resistant etc., has extensive use in various fields such as daily necessities, building materials, mechanical workouts.Aluminum oxide and zirconium white are two kinds of components common in stupalith, and aluminum oxide has the excellent properties such as proportion is low, high temperature resistant, has widespread use in stupalith field, but its folding strength and fracture toughness property lower; Zirconium white has good folding strength, is described as " Ceramo-steel ", but its proportion is comparatively large, usually can increase the weight of finished product.The combination of zirconium white and aluminum oxide, prepares composite ceramic material technology and receives increasing attention.Nickel oxide is typically used as the pigment of stupalith.CN103922705A reports a kind of low-temperature sintering Zirconia reinforced alumina material and preparation method thereof, by Physical mixed oxidization zirconium and alumina powder.
Chemosynthesis technology of preparing is a kind of a kind of method of organic and inorganic materials being carried out combine, there is many advantages, such as: factorial praluction, do not need the structure of expensive plant and instrument, controlled prepared material and character, the advantage such as cheap, the numerous areas such as inorganic materials, organic materials, matrix material are related to.CN102351532A reports the preparation method of zirconium white and alumina composite ceramic, by self-assembling technique synthesising complex, obtains composite ceramic material through low-temperature heat treatment.
Summary of the invention
The object of the invention is to: the preparation method that a kind of architectural pottery is provided.By chemical preparation techniques, prepare structurally ordered, excellent performance, containing zirconium white, aluminum oxide, nickel oxide and kaolinic architectural pottery.
Technical solution of the present invention is: zirconium alkoxide, aluminum nitrate and nickelous nitrate are dissolved in certain density nitric acid, through stir, be hydrolyzed, polyreaction generation composite precursor; In a certain amount of deionized water, add sodium lignosulfonate, tensio-active agent and dispersion agent, water-bath temperature control, stirring obtain modifier solution; Modifier solution is mixed with composite precursor, naturally cooling, standing and reacting obtain composite colloidal solution, the liquid caustic soda solution adjust ph of mass concentration 30%, to neutral, adds kaolin, obtains structurally ordered composite ceramic material through stirring, filtration, drying, thermal treatment.
The present invention compared with prior art, its remarkable advantage: one, in chemosynthesis process, organic zirconium alkoxide, inorganic aluminate, nickel salt, through acidolysis, chemical action, form the stable Ni-based presoma of zirconium aluminium, contribute to forming zirconium white, aluminum oxide and nickel oxide composite ceramics; In the ceramic product two, obtained, zirconium white, aluminum oxide, nickel oxide are dispersed in kaolin, have good microtexture; Three, the method preparation technology can promote for the preparation of multi-functional and component is ceramic.
Embodiment
Further illustrate technical solution of the present invention below in conjunction with specific embodiment, these embodiments can not be interpreted as it is restriction to technical solution.
Embodiment 1: prepare composite ceramics according to following steps
Step 1: be dissolved in the concentrated nitric acid of 200ml mass concentration 60% by 100g zirconium-n-butylate, 10g ANN aluminium nitrate nonahydrate and 5g nickelous nitrate, mechanical vigorous stirring 1h, obtains the composite precursor solution A clarified;
Step 2: in 100ml deionized water, adds 10g sodium lignosulfonate, 5g sodium laurylsulfonate, 2g Polyethylene glycol-2000, warming-in-water to 30
oc, mechanical stirring 1h, obtain the modifier solution B mixed;
Step 3: modifier solution B is mixed with composite precursor solution A, naturally cooling, standing 12h, obtain composite colloidal solution C;
Step 4: adopt 30% liquid caustic soda solution to regulate the pH value of composite colloidal solution C to neutral, add 100g kaolin, stir 3h, obtain composite solution D;
Step 5: composite solution D after filtration, 110
othe dry 12h, 600 of C
oc thermal treatment 6h obtains structurally ordered composite ceramics.
Embodiment 2: prepare composite ceramics according to following steps
Step 1: be dissolved in the concentrated nitric acid of 200ml mass concentration 60% by 100g zirconium-n-butylate, 20g ANN aluminium nitrate nonahydrate and 10g nickelous nitrate, mechanical stirring 2h, obtains the composite precursor solution A clarified;
Step 2: in 100ml deionized water, adds 20g sodium lignosulfonate, 10g sodium laurylsulfonate, 5g PEG-4000, warming-in-water to 50
oc, mechanical stirring 2h, obtain the modifier solution B mixed;
Step 3: modifier solution B is mixed with composite precursor solution A, naturally cooling, standing 36h, obtain composite colloidal solution C;
Step 4: adopt 30% liquid caustic soda solution to regulate the pH value of composite colloidal solution C to neutral, add 300g kaolin, stir 6h, obtain composite solution D;
Step 5: composite solution D after filtration, 150
othe dry 8h, 800 of C
oc thermal treatment 3h obtains structurally ordered composite ceramics.
Embodiment 3: prepare composite ceramics according to following steps
Step 1: be dissolved in the concentrated nitric acid of 200ml mass concentration 60% by 100g zirconium-n-propylate, 15g ANN aluminium nitrate nonahydrate and 8g nickelous nitrate, mechanical stirring 1.5h, obtains the composite precursor solution A clarified;
Step 2: in 100ml deionized water, adds 15g sodium lignosulfonate, 8g sodium laurylsulfonate, 3g PEG-4000, warming-in-water to 40
oc, mechanical stirring 1.5h, obtain the modifier solution B mixed;
Step 3: modifier solution B is mixed with composite precursor solution A, naturally cooling, standing 24h, obtain composite colloidal solution C;
Step 4: adopt 30% liquid caustic soda solution to regulate the pH value of composite colloidal solution C to neutral, add 200g kaolin, stir 4h, obtain composite solution D;
Step 5: composite solution D after filtration, 120
othe dry 10h, 700 of C
oc thermal treatment 5h obtains structurally ordered composite ceramics.
Embodiment 4: prepare composite ceramics according to following steps
Step 1: with the step 1 in embodiment 1;
Step 2: in 100ml deionized water, adds 12g sodium lignosulfonate, 6g sodium lauryl sulphate, 4g PEG-8 000, warming-in-water to 40
oc, mechanical stirring 1.5h, obtain the modifier solution B mixed;
Step 3: with the step 1 in embodiment 1;
Step 4: with the step 1 in embodiment 1;
Step 5: with the step 1 in embodiment 1.
Embodiment 5: prepare composite ceramics according to following steps
Step 1: with the step 1 in embodiment 2;
Step 2: in 100ml deionized water, adds 18g sodium lignosulfonate, 7g Sodium dodecylbenzene sulfonate, 3.5g Polyethylene glycol-2000, warming-in-water to 60
oc, mechanical stirring 2h, obtain the modifier solution B mixed;
Step 3: with the step 2 in embodiment 2;
Step 4: with the step 2 in embodiment 2;
Step 5: with the step 2 in embodiment 2.
Claims (3)
1. building composite ceramic material and preparation method thereof, is characterized in that: this composite ceramic material formula main raw material is organic zirconium alkoxide, aluminum nitrate and nickelous nitrate, and its respective quality ratio is 1:10%-20%:5%-10%; Sodium lignosulfonate, tensio-active agent, dispersion agent polyoxyethylene glycol, kaolin, it accounts for zirconium alkoxide mass ratio and is respectively: 10%-20%:5%-10%:2%-5%:1-3;
A kind of building composite ceramic material and preparation method thereof, it is characterized in that, this preparation method is:
A. composite precursor preparation: zirconium alkoxide, aluminum nitrate and nickelous nitrate are dissolved in the nitric acid of mass concentration 60%, through stir, be hydrolyzed, polyreaction generation composite precursor;
B. modifier solution preparation: in a certain amount of deionized water, add sodium lignosulfonate, tensio-active agent and dispersion agent, water-bath temperature control, stirring obtain modifier solution;
C. composite ceramic material preparation: modifier solution is mixed with composite precursor, naturally cooling, standing and reacting obtain composite colloidal solution, mass concentration 30% liquid caustic soda solution adjust ph is to neutral, add kaolin, obtain structurally ordered composite ceramic material through stirring, filtration, drying, thermal treatment.
2. one building composite ceramics according to claim 1 and preparation method thereof, is characterized in that: the one in the described optional zirconium-n-butylate of zirconium alkoxide, zirconium-n-propylate; The one in sodium lauryl sulphate, sodium laurylsulfonate, Sodium dodecylbenzene sulfonate selected by tensio-active agent; Dispersion agent selects polyoxyethylene glycol, and molecular weight is 2000,4000, and 6000, the one in 8000.
3. one building composite ceramics according to claim 1 and preparation method thereof, is characterized in that: in the step a of this preparation method, churning time control 1h-2h; In step b, water-bath temperature control 30
oc-50
oc, churning time control 1h-2h; In step c, standing and reacting time controling 12h-36h, drying temperature controls 110
oc-150
oc, time controling 8h-12h, thermal treatment temp controls 600
oc-800
oc, time controling 3h-6h.
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Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105670088A (en) * | 2016-04-14 | 2016-06-15 | 季红军 | Preparation method of halogen-free high-fire-retardancy cable material |
| CN105819872A (en) * | 2016-03-17 | 2016-08-03 | 季红军 | Preparation method of fireproof plate composite material |
| CN106630961A (en) * | 2016-12-01 | 2017-05-10 | 芜湖浩权建筑工程有限公司 | High-strength building composite ceramic material and preparation method thereof |
| CN106673600A (en) * | 2016-12-05 | 2017-05-17 | 钦州市钦南区生产力促进中心 | Building ceramic material and preparation method thereof |
| CN106699149A (en) * | 2016-12-15 | 2017-05-24 | 芜湖浩权建筑工程有限公司 | High-performance composite ceramic material for buildings and preparation method thereof |
| CN106747309A (en) * | 2016-12-15 | 2017-05-31 | 芜湖浩权建筑工程有限公司 | A kind of building composite ceramics of environment protection type heat insulating insulation and preparation method thereof |
| CN107805049A (en) * | 2017-11-16 | 2018-03-16 | 南京市雨花台区绿宝工业设计服务中心 | A kind of preparation method of architectural pottery composite |
| CN108017375A (en) * | 2017-11-10 | 2018-05-11 | 安徽嘉中金属材料有限公司 | A kind of environmentally friendly composite ceramic material for building and preparation method thereof |
| CN108046746A (en) * | 2017-11-02 | 2018-05-18 | 安徽嘉中金属材料有限公司 | A kind of ceramic material of modified composite environmental-friendly for building and preparation method thereof |
| CN108484109A (en) * | 2018-06-24 | 2018-09-04 | 龚娟 | A kind of preparation method of ceramic material |
| CN108640650A (en) * | 2018-06-24 | 2018-10-12 | 龚娟 | A kind of preparation method of composite ceramic material |
| CN108911782A (en) * | 2018-09-13 | 2018-11-30 | 龚娟 | A kind of preparation method of heat preserving ceramic material |
| CN108947485A (en) * | 2018-09-13 | 2018-12-07 | 龚娟 | A kind of preparation method of domestic ceramics composite material |
| CN108996989A (en) * | 2018-09-13 | 2018-12-14 | 龚娟 | A kind of preparation method of heat preserving ceramic composite material |
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Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105819872A (en) * | 2016-03-17 | 2016-08-03 | 季红军 | Preparation method of fireproof plate composite material |
| CN105670088A (en) * | 2016-04-14 | 2016-06-15 | 季红军 | Preparation method of halogen-free high-fire-retardancy cable material |
| CN106630961A (en) * | 2016-12-01 | 2017-05-10 | 芜湖浩权建筑工程有限公司 | High-strength building composite ceramic material and preparation method thereof |
| CN106673600A (en) * | 2016-12-05 | 2017-05-17 | 钦州市钦南区生产力促进中心 | Building ceramic material and preparation method thereof |
| CN106699149A (en) * | 2016-12-15 | 2017-05-24 | 芜湖浩权建筑工程有限公司 | High-performance composite ceramic material for buildings and preparation method thereof |
| CN106747309A (en) * | 2016-12-15 | 2017-05-31 | 芜湖浩权建筑工程有限公司 | A kind of building composite ceramics of environment protection type heat insulating insulation and preparation method thereof |
| CN108046746A (en) * | 2017-11-02 | 2018-05-18 | 安徽嘉中金属材料有限公司 | A kind of ceramic material of modified composite environmental-friendly for building and preparation method thereof |
| CN108017375A (en) * | 2017-11-10 | 2018-05-11 | 安徽嘉中金属材料有限公司 | A kind of environmentally friendly composite ceramic material for building and preparation method thereof |
| CN107805049A (en) * | 2017-11-16 | 2018-03-16 | 南京市雨花台区绿宝工业设计服务中心 | A kind of preparation method of architectural pottery composite |
| CN108484109A (en) * | 2018-06-24 | 2018-09-04 | 龚娟 | A kind of preparation method of ceramic material |
| CN108640650A (en) * | 2018-06-24 | 2018-10-12 | 龚娟 | A kind of preparation method of composite ceramic material |
| CN108911782A (en) * | 2018-09-13 | 2018-11-30 | 龚娟 | A kind of preparation method of heat preserving ceramic material |
| CN108947485A (en) * | 2018-09-13 | 2018-12-07 | 龚娟 | A kind of preparation method of domestic ceramics composite material |
| CN108996989A (en) * | 2018-09-13 | 2018-12-14 | 龚娟 | A kind of preparation method of heat preserving ceramic composite material |
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