CN108012542B - 使用返混步骤制备甲硅烷基化的聚合物的工艺 - Google Patents

使用返混步骤制备甲硅烷基化的聚合物的工艺 Download PDF

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Publication number
CN108012542B
CN108012542B CN201680047431.0A CN201680047431A CN108012542B CN 108012542 B CN108012542 B CN 108012542B CN 201680047431 A CN201680047431 A CN 201680047431A CN 108012542 B CN108012542 B CN 108012542B
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carbon atoms
reaction
unit
intermediate product
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Chinese (zh)
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CN108012542A (zh
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J.巴内维休斯
M.黄
B.奥基夫
V.库马尔
B.巴贝拉
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Momentive Performance Materials Inc
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Momentive Performance Materials Inc
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/2805—Compounds having only one group containing active hydrogen
    • C08G18/288—Compounds containing at least one heteroatom other than oxygen or nitrogen
    • C08G18/289—Compounds containing at least one heteroatom other than oxygen or nitrogen containing silicon
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/83—Chemically modified polymers
    • C08G18/837—Chemically modified polymers by silicon containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • B01J19/2415—Tubular reactors
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/71—Monoisocyanates or monoisothiocyanates
    • C08G18/718—Monoisocyanates or monoisothiocyanates containing silicon
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/49—Phosphorus-containing compounds
    • C08K5/51—Phosphorus bound to oxygen
    • C08K5/52—Phosphorus bound to oxygen only
    • C08K5/524—Esters of phosphorous acids, e.g. of H3PO3
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
    • B01J2219/00087—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor
    • B01J2219/00103—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor in a heat exchanger separate from the reactor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/24—Stationary reactors without moving elements inside
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/13—Phenols; Phenolates
    • C08K5/134—Phenols containing ester groups
    • C08K5/1345—Carboxylic esters of phenolcarboxylic acids

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
CN201680047431.0A 2015-08-11 2016-07-27 使用返混步骤制备甲硅烷基化的聚合物的工艺 Expired - Fee Related CN108012542B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US14/823,588 2015-08-11
US14/823,588 US9828459B2 (en) 2015-08-11 2015-08-11 Process for the preparation of silylated polymers employing a backmixing step
PCT/US2016/044240 WO2017027219A1 (en) 2015-08-11 2016-07-27 Process for the preparation of silylated polymers employing a backmixing step

Publications (2)

Publication Number Publication Date
CN108012542A CN108012542A (zh) 2018-05-08
CN108012542B true CN108012542B (zh) 2021-02-19

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CN201680047431.0A Expired - Fee Related CN108012542B (zh) 2015-08-11 2016-07-27 使用返混步骤制备甲硅烷基化的聚合物的工艺

Country Status (6)

Country Link
US (2) US9828459B2 (https=)
EP (1) EP3334770B1 (https=)
JP (1) JP6916166B2 (https=)
CN (1) CN108012542B (https=)
BR (1) BR112018002924B1 (https=)
WO (1) WO2017027219A1 (https=)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10138324B2 (en) 2015-08-11 2018-11-27 Momentive Performance Materials Inc. Process for the preparation of silylated polymers having low color and color stability

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1342188A (zh) * 1999-02-05 2002-03-27 陶氏化学公司 聚氨酯密封剂组合物
CN102348733A (zh) * 2009-03-11 2012-02-08 瓦克化学股份公司 硅烷封端预聚物的连续制备方法
CN102464788A (zh) * 2010-11-10 2012-05-23 拜尔技术服务有限责任公司 连续生产热塑性可加工聚氨酯的方法

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US3829505A (en) 1970-02-24 1974-08-13 Gen Tire & Rubber Co Polyethers and method for making the same
US3941849A (en) 1972-07-07 1976-03-02 The General Tire & Rubber Company Polyethers and method for making the same
DE2314512C3 (de) 1973-03-23 1980-10-09 Bayer Ag, 5090 Leverkusen Thermoplastische, nichtionische, in Wasser despergierbare im wesentlichen lineare Polyurethanelastomere
JPS55164270A (en) 1979-06-07 1980-12-20 Kuraray Co Ltd Laminate
US4242490A (en) 1979-07-20 1980-12-30 The General Tire & Rubber Company Thermoset polyurethane prepared from a polypropylene ether triol obtained using a double metal cyanide complex catalyst, ethylene glycol and tolylene diisocyanate
US4687851A (en) 1985-08-15 1987-08-18 The Dow Chemical Company Polyurethane elastomers prepared from high equivalent weight polyahls
US5106874A (en) 1989-06-16 1992-04-21 The Dow Chemical Company Process for preparing elastomeric polyurethane or polyurethane-urea polymers, and polyurethanes so prepared
US4985491A (en) 1989-10-05 1991-01-15 Olin Corporation Polyurethane sealants made using high molecular weight polyols prepared with double metal cyanide catalysts
US5100997A (en) 1990-05-29 1992-03-31 Olin Corporation Preparation of elastomers using high molecular weight polyols or polyamines, said polyols prepared using a double metal cyanide complex catalyst
US5116931A (en) 1990-09-28 1992-05-26 Olin Corporation Thermoset polyurethane elastomers and polyurea elastomers made using high functionality, low unsaturation level polyols prepared with double metal cyanide catalysts
US5136010A (en) 1990-09-28 1992-08-04 Olin Corporation Polyurethane elastomers and polyurea elastomers made using high functionality, low unsaturation level polyols prepared with double metal cyanide catalysts
US5185420A (en) 1990-11-02 1993-02-09 Olin Corporation Thermoplastic polyurethane elastomers and polyurea elastomers made using low unsaturation level polyols prepared with double metal cyanide catalysts
US5096993A (en) 1990-11-02 1992-03-17 Olin Corporation Thermoplastic polyurethane elastomers and polyurea elastomers made using low unsaturation level polyols prepared with double metal cyanide catalysts
US5266681A (en) 1992-08-03 1993-11-30 Olin Corporation Process and composition for providing double metal cyanide catalyzed polyols having enhanced reactivity
DE59307600D1 (de) 1992-11-16 1997-12-04 Bayer Ag Kontinuierliches Verfahren zur Umsatzsteuerung von Polyurethan-Prepolymeren durch teilweise Vermischung des Prepolymeren mit den Monomeren
US5688863A (en) * 1993-10-04 1997-11-18 Bayer Aktiengesellschaft Soft thermoplastic polyurethane ureas a process for their preparation and their use
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MX2007001369A (es) * 2004-08-04 2007-04-10 Ciba Sc Holding Ag Particulas funcionales.
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US7435787B2 (en) * 2005-09-14 2008-10-14 Momentive Performance Materials Inc. Process for the continuous production of silylated resin
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CN1342188A (zh) * 1999-02-05 2002-03-27 陶氏化学公司 聚氨酯密封剂组合物
CN102348733A (zh) * 2009-03-11 2012-02-08 瓦克化学股份公司 硅烷封端预聚物的连续制备方法
CN102464788A (zh) * 2010-11-10 2012-05-23 拜尔技术服务有限责任公司 连续生产热塑性可加工聚氨酯的方法

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Publication number Publication date
JP6916166B2 (ja) 2021-08-11
WO2017027219A1 (en) 2017-02-16
JP2018522998A (ja) 2018-08-16
BR112018002924A2 (https=) 2018-02-15
EP3334770B1 (en) 2020-10-28
CN108012542A (zh) 2018-05-08
US20170044303A1 (en) 2017-02-16
US10336857B2 (en) 2019-07-02
BR112018002924B1 (pt) 2022-02-15
US9828459B2 (en) 2017-11-28
US20180044466A1 (en) 2018-02-15
EP3334770A1 (en) 2018-06-20

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Granted publication date: 20210219