CN108003903A - A kind of pyrolysis liquefaction device of Biomedia - Google Patents

A kind of pyrolysis liquefaction device of Biomedia Download PDF

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Publication number
CN108003903A
CN108003903A CN201711127370.1A CN201711127370A CN108003903A CN 108003903 A CN108003903 A CN 108003903A CN 201711127370 A CN201711127370 A CN 201711127370A CN 108003903 A CN108003903 A CN 108003903A
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CN
China
Prior art keywords
cyclone separator
pyrolysis
tube
bed reactor
heat exchanger
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Pending
Application number
CN201711127370.1A
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Chinese (zh)
Inventor
陈玉
陈运洲
陈哲
王思嘉
李安冉
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Anhui Polytechnic University
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Anhui Polytechnic University
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Priority to CN201711127370.1A priority Critical patent/CN108003903A/en
Publication of CN108003903A publication Critical patent/CN108003903A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10BDESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B53/00Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10BDESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B57/00Other carbonising or coking processes; Features of destructive distillation processes in general
    • C10B57/08Non-mechanical pretreatment of the charge, e.g. desulfurization
    • C10B57/10Drying
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10Feedstock materials
    • C10G2300/1011Biomass

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

The invention discloses a kind of pyrolysis liquefaction device of Biomedia,Including pretreatment system,Gas solid separation system,Pyrolysis reactor and condenser system,Discharge pipe is connected with gas solid separation system,Gas solid separation system includes the first cyclone separator,First cyclone separator is fixedly connected with pyrolysis reactor,Pyrolysis reactor includes fluidized-bed reactor,Fluidized-bed reactor is equipped with heat smoke conduit,Heat smoke conduit is connected with drying shell,Fluid bed reactor is connected with condenser system,Condenser system includes the second cyclone separator and condensation tube,The bottom of second cyclone separator is connected with powdered carbon recovery tube,Powdered carbon recovery tube is connected with one end of fluid bed reactor,The connection of second cyclone separator and condensation tube,Condensation tube bottom is equipped with bio oil receiving bottle,Condenser pipe is equipped with gas flow tube,Gas flow tube is connected with fluid bed reactor,By to heat recovery fuel gas and powdered carbon,Greatly reduce the operation energy consumption of equipment,Save the energy.

Description

A kind of pyrolysis liquefaction device of Biomedia
Technical field
The present invention relates to Biomedia pyrolytic technique field, is specially a kind of pyrolysis liquefaction device of Biomedia.
Background technology
Biomass energy is unique carbon resource in current regenerative resource, can be used for producing energy products, chemical industry original Material etc..It is the method by thermochemical study that rapidly pyrolysing and liquefying biomass, which prepares biological oil tech, by the life of low energy densities Material is converted into the new bio mass-energy utilization technology of three kinds of high energy products such as gas, liquid, solid at the same time, has very big development potentiality With wide application prospect.In three kinds of products, based on the bio oil of liquid phase, pyrolytic carbon can be used for prepare activated carbon, soil changes Good dose etc., tail gas is mainly small molecule permanent gases, is often directly emptied or discarded.
Step up and study increasingly deep with national energy-saving emission reduction requirement, people start self-heated pyrolysis technology Research, the approaches and methods that rationally utilize of tail gas will be pyrolyzed by exploring, and to meet environmental requirement, and current technology scheme is also deposited In problems with:
(1) the byproduct tail gas of rapidly pyrolysing and liquefying biomass is the non-condensable gas produced in pyrolytic process, including CO, CO2, H2, CH4 etc., have certain calorific value, and pyrolysis tail gas directly empties, and not only causes the waste of resource, but also right Environment pollutes;
(2) pyrolysis reactor is inefficient, the load for causing heat source to use, also so that the efficiency of Bioliquefication reduces.
The content of the invention
In order to overcome the shortcomings of prior art, the present invention provides a kind of pyrolysis liquefaction device of Biomedia, uses The detachable integrated structure of pretreatment system, gas solid separation system, pyrolysis reactor and condenser system so that the heat of biomass Solution liquefaction is more efficient, and is also convenient for the maintenance and cleaning in later stage, adds pretreatment system, significantly improves biological raw material Drying and crush efficiency so that pyrolysis fast reaction, save energy cost, also improve liquefaction yield, in addition will pyrolysis The powdered carbon and non-condensable gas of generation carry out recycling, improve pyrolysis environment temperature, realize biomass fast pyrogenation Liquefied self-heating production, improves production efficiency, has also reached the national standard of energy-saving and emission-reduction.
The technical solution adopted by the present invention to solve the technical problems is:A kind of pyrolysis liquefaction device of Biomedia, bag Pretreatment system, gas solid separation system, pyrolysis reactor and condenser system are included, the pretreatment system includes drying shell, institute State and baker and pulper are equipped with drying shell, the drying cover top portion is equipped with biological feeding mouth, the drying shell bottom Portion is equipped with discharge pipe, and the discharge pipe is connected with gas solid separation system, and the gas solid separation system includes the first whirlwind point From device, first cyclone separator is fixedly connected with pyrolysis reactor, and the pyrolysis reactor includes fluidized-bed reactor, institute State fluidized-bed reactor and be equipped with heat smoke conduit, the heat smoke conduit is connected with drying shell, the liquid bed reaction Device is connected with condenser system, and the condenser system includes the second cyclone separator and condensation tube, second cyclone separator Bottom is connected with powdered carbon recovery tube, and the powdered carbon recovery tube is connected with one end of fluid bed reactor, second cyclonic separation The side of device air outlet slit and condensation tube connects, and the condensation tube bottom is equipped with bio oil receiving bottle, the condenser pipe it is another Side is equipped with gas flow tube, and the gas flow tube is connected with fluid bed reactor.
As a kind of preferable technical solution of the present invention, some thin filter screens are equipped with the heat smoke conduit, it is described thin Filter screen is installed for drawer type, described to be carefully sealedly and fixedly connected between filter screen and heat smoke conduit.
As a kind of preferable technical solution of the present invention, the baker is separately mounted to the top and bottom of drying shell Portion, the pulper are installed on perpendicular to the drying vertical center axial position of shell, and the pulper has several, and is drying Interval is uniformly distributed in dry shell.
As a kind of preferable technical solution of the present invention, the discharge pipe is connected with the import of the first cyclone separator Connect, the import of the ash bucket and fluidized-bed reactor of the first cyclone separator bottom connects.
As a kind of preferable technical solution of the present invention, thermophore outlet and the second whirlwind point of the fluid bed reactor Import from device is connected, and the air outlet slit of the second cyclone separator is connected with a side-entrance of condensation tube.
As a kind of preferable technical solution of the present invention, the upper end of the condensation tube is equipped with spray congealing mouth, the spraying Condensate liquid is that refined biometric oil atomization forms, and condenser pipe is had additional on the outside of the condensation tube.
As a kind of preferable technical solution of the present invention, First Heat Exchanger and second are equipped with the outside of the fluidized-bed reactor Heat exchanger, the First Heat Exchanger and the second heat exchanger are installed in the input end close to fluid bed reactor, and described first changes The import of hot device is connected with powdered carbon recovery tube, and the import of second heat exchanger is connected with gas flow tube, in the First Heat Exchanger Be equipped with device for igniting in the second heat exchanger, the outlet of the First Heat Exchanger and the second heat exchanger with fluid bed reactor Gas feed is connected.
As a kind of preferable technical solution of the present invention, activated carbon fiber filter and wind turbine are equipped with the gas flow tube, The activated carbon fiber filter is installed for drawer type, seals and fixes between the activated carbon fiber filter and gas flow tube.
Compared with prior art, the beneficial effects of the invention are as follows:The present invention using pretreatment system, gas solid separation system, The detachable integrated structure of pyrolysis reactor and condenser system so that the pyrolysis liquefaction of biomass is more efficient, and is also convenient for The maintenance and cleaning in later stage, add pretreatment system, significantly improve drying and the crush efficiency of biological raw material so that heat Fast reaction is solved, energy cost is saved, also improves liquefaction yield, in addition will be pyrolyzed the powdered carbon produced and non-condensable gas Recycling is carried out, improves pyrolysis environment temperature, the self-heating production of rapidly pyrolysing and liquefying biomass is realized, improves life Efficiency is produced, has also reached the national standard of energy-saving and emission-reduction.
Brief description of the drawings
Fig. 1 is the overall structure diagram of the present invention;
Fig. 2 is the pretreatment system structure diagram of the present invention;
In figure:1- pretreatment systems;2- gas solid separation systems;The first cyclone separators of 201-;3- pyrolysis reactors;4- is cold Solidifying system;5- dries shell;501- bakers;502- pulpers;503- discharge pipes;6- fluidized-bed reactors;The hot cigarettes of 601- Airway;The thin filter screens of 602-;The second cyclone separators of 7-;701- powdered carbon recovery tubes;8- condensation tubes;801- bio oils receive Bottle;802- gas flow tubes;803- spray congealing mouths;804- condenser pipes;805- activated carbon fiber filters;806- wind turbines;9- first Heat exchanger;The second heat exchangers of 10-;11- device for igniting.
Embodiment
Below in conjunction with the attached drawing in the embodiment of the present invention, the technical solution in the embodiment of the present invention is carried out clear, complete Site preparation describes, it is clear that described embodiment is only part of the embodiment of the present invention, instead of all the embodiments.It is based on Embodiment in the present invention, those of ordinary skill in the art are obtained every other without making creative work Embodiment, belongs to the scope of protection of the invention.
The explanation of following embodiment is refer to the attached drawing, can be to the specific embodiment implemented to the example present invention. The direction and position term that the present invention is previously mentioned, for example, " on ", " in ", " under ", "front", "rear", "left", "right", " interior ", " Outside ", " side " etc., is only direction and position with reference to annexed drawings.Therefore, the direction and position term used is to illustrate And understand the present invention, and it is not used to the limitation present invention.
Embodiment:
As depicted in figs. 1 and 2, the present invention provides a kind of pyrolysis liquefaction device of Biomedia, including pretreatment system 1st, gas solid separation system 2, pyrolysis reactor 3 and condenser system 4, the pretreatment system 1 is that biomass material is dried And crushing, because if moisture in biomass material is too many or feed particles diameter is too big, pyrolysis reactor 3 can be influenced Working effect, is unable to reach the effect of fast pyrogenation, the pretreatment system 1 includes drying shell 5, described to dry in shell 5 Equipped with baker 501 and pulper 502, the baker 501 is separately mounted to the top and bottom of drying shell 5, described to stir Millstone 502 is installed on perpendicular to drying 5 vertical center axial position of shell, and the pulper 502 has several, and is drying Interval is uniformly distributed in dry shell 5, and 5 top of drying shell is equipped with biological feeding mouth, and 5 bottom of the drying shell is equipped with out Pipe material 503, the left and right sides for being installed on 5 center of drying shell of baker 501, such mounting means can cause The contact area of biomass material and heat source increases, while the use of multiple pulpers 502, ensures the crushing effect of biomass material Fruit.
As shown in Figure 1, the discharge pipe 503 is connected with gas solid separation system 2, gas solid separation system 2 is in order to by sky Gas is kept completely separate with biological particle, so as on the one hand reduce the air into pyrolysis reactor 3, make in pyrolysis reactor 3 Environment reach the condition of anaerobic or anoxic, still further aspect can also reduce the dust impurity in biological raw material so that Effect when pyrolysis and condensation reaches optimum state, and the gas solid separation system 2 includes the first cyclone separator 201, described First cyclone separator 201 is fixedly connected with pyrolysis reactor 3,504 and first cyclone separator 201 of discharge pipe Import is connected, and the ash bucket of 201 bottom of the first cyclone separator is connected with the import of fluidized-bed reactor 6.
As shown in Figure 1, the pyrolysis reactor 3 includes fluidized-bed reactor 6, the fluidized-bed reactor 6 is equipped with heat Smoke tube 601, the heat smoke conduit 601 are connected with drying shell 5, and the use of heat smoke conduit 601 is for resource Recycle, can cause dry shell 5 in temperature increase, strengthen the drying effect of raw material, and the heat smoke is led Pipe 601 is installed on the input end of fluid bed reactor 6, will not discharge the pyrolysis gas of generation.
The fluid bed reactor 6 is connected with condenser system 4, and the condenser system 4 includes the second cyclone separator 7 and cold Solidifying cylinder 8, the thermophore outlet of the fluid bed reactor 6 are connected with the import of the second cyclone separator 7, liquid bed are reacted Device 6 produces product and is all introduced into the second cyclone separator 7, and the effect of the second cyclone separator 7 is by pyrolysis gas and powdered carbon It is kept completely separate, wherein powdered carbon is to circulate heat production, and pyrolysis gas carries out condensation production bio oil, second cyclone separator 7 Bottom is connected with powdered carbon recovery tube 701, and the powdered carbon recovery tube 701 is connected with one end of fluid bed reactor 6, and powdered carbon can fire Burning recycles, and 7 air outlet slit of the second cyclone separator is connected with the side of condensation tube 8, and the upper end of the condensation tube 8 is set There is spray congealing mouth 803, the spray congealing liquid is that refined biometric oil atomization forms, and the outside of the condensation tube 8 has additional cold Solidifying pipe 804, the effect of the spray congealing liquid and condenser pipe 804 is all the mode of bio oil condensation, wherein the condensate liquid being atomized Directly condensed with pyrolysis gases contact, the heat for condensing generation is discharged by condenser pipe, and 8 bottom of condensation tube is equipped with Bio oil receiving bottle 801, the opposite side of the condensation tube 8 are equipped with gas flow tube 802, the gas flow tube 802 and fluid bed reactor 6 Connection, the gas flow tube 802 are in order to which the fuel gas of no condensation is recycled burning heat production.
Preferably, some thin filter screens 602 are equipped with the heat smoke conduit 601, the thin filter screen 602 is to take out Drawer formula is installed, described to be carefully sealedly and fixedly connected between filter screen 602 and heat smoke conduit 601, the effect of the thin filter screen 602 It is the flue dust filtered in hot-air, reduces flue dust in drying shell 5 and increase, the mode of drawer type installation carefully to filter Net 602 is beneficial to replace and cleaning, prevents the obstruction of heat smoke conduit 601.
Preferably, the outside of the fluidized-bed reactor 6 is connected with 9 and second heat exchanger 10 of First Heat Exchanger, and described the One heat exchanger 9 and the second heat exchanger 10 are installed in the input end close to fluid bed reactor 6, the First Heat Exchanger 9 into Mouth is connected with powdered carbon recovery tube 701, and the import of second heat exchanger 10 is connected with gas flow tube 802,9 He of First Heat Exchanger Device for igniting 11 is equipped with second heat exchanger 9, the outlet of 9 and second heat exchanger 10 of First Heat Exchanger is anti-with liquid bed The gas feed of device 6 is answered to be connected, the purpose of 9 and second heat exchanger tube 10 of the first heat exchanger tube is provided to powdered carbon and cannot be cold Solidifying fuel gas carries out reusable edible, powdered carbon and gas is burnt heat production, so as to improve inside fluid bed reactor 6 Reaction temperature so that biological raw material pyrolysis is more efficient, improves pyrolysis efficiency.
Preferably, activated carbon fiber filter 805 and wind turbine 806, the active carbon fibre are equipped with the gas flow tube 802 Dimensional filter device 805 is installed for drawer type, seals and fixes between 803 device of active carbon fibre dimensional filter and gas flow tube 802, the work Property Carbon fibe filter 805 effect be absorption due to condensation effect, the moisture in gas recovery so that gas recovery is more It is dry, be easier burning heat production in the second heat exchanger 10, the use of wind turbine 806 be in order to strengthen the mobility of gas recovery, Replacement and maintenance of the drawer type installation beneficial to the later stage.
In conclusion the main characteristic of the invention lies in that:The present invention is using pretreatment system, gas solid separation system, pyrolysis The detachable integrated structure of reactor and condenser system so that the pyrolysis liquefaction of biomass is more efficient, and is also convenient for the later stage Maintenance and cleaning, add pretreatment system, significantly improve drying and the crush efficiency of biological raw material so that pyrolysis is fast Speed reaction, saves energy cost, also improves liquefaction yield, in addition will be pyrolyzed the powdered carbon produced and non-condensable gas carries out Recycling, improves pyrolysis environment temperature, realizes the self-heating production of rapidly pyrolysing and liquefying biomass, improves production effect Rate, has also reached the national standard of energy-saving and emission-reduction.
It is obvious to a person skilled in the art that the invention is not restricted to the details of above-mentioned one exemplary embodiment, Er Qie In the case of without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter From the point of view of which point, the present embodiments are to be considered as illustrative and not restrictive, and the scope of the present invention is by appended power Profit requires rather than described above limits, it is intended that all in the implication and scope of the equivalency of claim by falling Change is included in the present invention.Any reference numeral in claim should not be considered as to the involved claim of limitation.

Claims (8)

1. a kind of pyrolysis liquefaction device of Biomedia, including pretreatment system (1), gas solid separation system (2), pyrolysis reactor (3) and condenser system (4), it is characterised in that:The pretreatment system (1) includes drying shell (5), the drying shell (5) It is interior to be equipped with baker (501) and pulper (502), biological feeding mouth, the drying shell are equipped with the top of the drying shell (5) (5) bottom is equipped with discharge pipe (503), and the discharge pipe (503) is connected with gas solid separation system (2), the gas solid separation System (2) includes the first cyclone separator (201), first cyclone separator (201) and the fixed company of pyrolysis reactor (3) Connect, the pyrolysis reactor (3) includes fluidized-bed reactor (6), and the fluidized-bed reactor (6) is equipped with heat smoke conduit (601), the heat smoke conduit (601) is connected with drying shell (5), the fluid bed reactor (6) and condenser system (4) Connection, the condenser system (4) include the second cyclone separator (7) and condensation tube (8), second cyclone separator (7) Bottom is connected with powdered carbon recovery tube (701), and the powdered carbon recovery tube (701) is connected with one end of fluid bed reactor (6), described Second cyclone separator (7) air outlet slit is connected with the side of condensation tube (8), and condensation tube (8) bottom connects equipped with bio oil Bottle (801) is received, the opposite side of the condensation tube (8) is equipped with gas flow tube (802), the gas flow tube (802) and fluid bed reactor (6) connect.
A kind of 2. pyrolysis liquefaction device of Biomedia according to claim 1, it is characterised in that:The heat smoke conduit (601) some thin filter screens (602) are equipped with, the thin filter screen (602) is installed for drawer type, the thin filter screen (602) It is sealedly and fixedly connected between heat smoke conduit (601).
A kind of 3. pyrolysis liquefaction device of Biomedia according to claim 1, it is characterised in that:The baker (501) top and bottom of drying shell (5) are separately mounted to, the pulper (502) is installed on perpendicular to drying shell (5) Vertical center axial position, the pulper (502) have several, and interval is uniformly distributed in drying shell (5).
A kind of 4. pyrolysis liquefaction device of Biomedia according to claim 1, it is characterised in that:The discharge pipe (504) import with the first cyclone separator (201) is connected, the ash bucket and stream of the first cyclone separator (201) bottom The import connection of fluidized bed reactor (6).
A kind of 5. pyrolysis liquefaction device of Biomedia according to claim 1, it is characterised in that:The liquid bed reaction The thermophore outlet of device (6) is connected with the import of the second cyclone separator (7), and the air of the second cyclone separator (7) goes out Mouth is connected with a side-entrance of condensation tube (8).
A kind of 6. pyrolysis liquefaction device of Biomedia according to claim 4, it is characterised in that:The condensation tube (8) Upper end be equipped with spray congealing mouth (803), the spray congealing liquid is that refined biometric oil atomization forms, the condensation tube (8) Outside has additional condenser pipe (804).
A kind of 7. pyrolysis liquefaction device of Biomedia according to claim 1, it is characterised in that:The fluidized-bed reaction First Heat Exchanger (9) and the second heat exchanger (10), the First Heat Exchanger (9) and the second heat exchanger are connected with the outside of device (6) (10) input end close to fluid bed reactor (6), import and the powdered carbon recovery tube of the First Heat Exchanger (9) are installed in (701) it is connected, the import of second heat exchanger (10) is connected with gas flow tube (802), and the First Heat Exchanger (9) and second is changed Device for igniting (11) is equipped with hot device (9), the outlet of the First Heat Exchanger (9) and the second heat exchanger (10) is anti-with liquid bed The gas feed of device (6) is answered to be connected.
A kind of 8. pyrolysis liquefaction device of Biomedia according to claim 1, it is characterised in that:The gas flow tube (802) activated carbon fiber filter (805) and wind turbine (806) are equipped with, the activated carbon fiber filter (805) is drawer type Installation, seals between active carbon fibre dimensional filter (805) device and gas flow tube (802) and fixes.
CN201711127370.1A 2017-11-15 2017-11-15 A kind of pyrolysis liquefaction device of Biomedia Pending CN108003903A (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103031139A (en) * 2012-10-22 2013-04-10 华北电力大学 Device and method for preparing bio-oil through rapid biomass pyrolysis
US20160177184A1 (en) * 2014-12-18 2016-06-23 The United States Of America, As Represented By The Secretary Of Agriculture Bio-Oils and Methods of Producing Bio-Oils from Guayule Bagasse and/or Leaves
CN106147818A (en) * 2016-07-29 2016-11-23 上海交通大学 One utilizes biomass castoff to produce liquid fuel device and using method
CN106440741A (en) * 2016-11-19 2017-02-22 无锡大功机械制造有限公司 Garbage drying and smashing device

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103031139A (en) * 2012-10-22 2013-04-10 华北电力大学 Device and method for preparing bio-oil through rapid biomass pyrolysis
US20160177184A1 (en) * 2014-12-18 2016-06-23 The United States Of America, As Represented By The Secretary Of Agriculture Bio-Oils and Methods of Producing Bio-Oils from Guayule Bagasse and/or Leaves
CN106147818A (en) * 2016-07-29 2016-11-23 上海交通大学 One utilizes biomass castoff to produce liquid fuel device and using method
CN106440741A (en) * 2016-11-19 2017-02-22 无锡大功机械制造有限公司 Garbage drying and smashing device

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