CN107998824A - A kind of VOCs recyclings treatment process - Google Patents

A kind of VOCs recyclings treatment process Download PDF

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Publication number
CN107998824A
CN107998824A CN201711245447.5A CN201711245447A CN107998824A CN 107998824 A CN107998824 A CN 107998824A CN 201711245447 A CN201711245447 A CN 201711245447A CN 107998824 A CN107998824 A CN 107998824A
Authority
CN
China
Prior art keywords
vocs
diesel oil
treatment process
recyclings
gases
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711245447.5A
Other languages
Chinese (zh)
Inventor
谢民
谢一民
张娟
李春刚
徐建
杨晓丽
杨惠琳
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Chemical Laboratory Center Of Ningxia Baota (co Ltd)
Original Assignee
Chemical Laboratory Center Of Ningxia Baota (co Ltd)
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chemical Laboratory Center Of Ningxia Baota (co Ltd) filed Critical Chemical Laboratory Center Of Ningxia Baota (co Ltd)
Priority to CN201711245447.5A priority Critical patent/CN107998824A/en
Publication of CN107998824A publication Critical patent/CN107998824A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1487Removing organic compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/002Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by condensation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1493Selection of liquid materials for use as absorbents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/18Absorbing units; Liquid distributors therefor
    • B01D53/185Liquid distributors
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2252/00Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20Organic absorbents
    • B01D2252/205Other organic compounds not covered by B01D2252/00 - B01D2252/20494
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/70Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/708Volatile organic compounds V.O.C.'s
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treating Waste Gases (AREA)
  • Gas Separation By Absorption (AREA)

Abstract

The present invention relates to technical field of waste gas treatment, is specially a kind of VOCs recyclings treatment process.The technical process is:VOCs gases after high-efficiency dust remover dedusting enter in VOCs collectors from bottom, and diesel oil enters from the top of collector and sprays on VOCs gases, and VOCs is after coolant cools down, diesel oil absorbs, and diesel oil VOCs mixed liquors are by exporting recycling.Compared with traditional VOCs absorption techniqueses, treatment process of the present invention recycles VOCs according to the similar principle that mixes of organic compound, it is simple with technical process, the features such as treatment effeciency is high, safe, non-secondary pollution, can be used as fuel, improve economic value after recycling.

Description

A kind of VOCs recyclings treatment process
Technical field
The invention belongs to technical field of waste gas treatment, and in particular to the VOCs discharged in a kind of chemical industry production process Recycle technique.
Background technology
VOCs(Volatile organic compounds)That is volatile organic compounds, is generally existing in air A kind of organic pollution, is mainly derived from the industries such as petrochemical industry, automobile engine tail gas, pharmacy, its main component for hydro carbons, Phenols, fragrant same clan etc..VOCs can form photochemical fog in an atmosphere, and environment and human body are caused greatly to endanger.VOCs After entering human body by respiratory tract and skin, the system such as breathing, blood, liver to people and organ cause temporary or permanent The polycyclic aromatic hydrocarbon such as damage, especially benzene class and the fragrant same clan has carcinogenesis to human body.The excessive emissions of VOCs also to agricultural and The industries such as herding damage.Therefore the processing of VOCs is increasingly paid attention to be subject to countries in the world, and many countries have promulgated accordingly Decree, limit the discharge of VOCs.
The main method of domestic processing VOCs has absorption method, membrane separation process, absorption process, Production by Catalytic Combustion Process and condensation method at present Deng.Although absorption method removal rate is high, since adsorption capacity is limited, it is not suitable for handling high concentration organic gas, when in exhaust gas When having micelle material or other impurity, adsorbent is vulnerable, while adsorbent needs to regenerate.Membrane separation process have it is energy-efficient, The characteristics of easy to operate, but invest big, business burden weight, still without practical application.Common WATER-WASHING METHOD removes effect in absorption process Rate is low, can only remove water miscible organic matter, while can also produce secondary pollution.Burning not only waste of energy is catalyzed, if combustion Burn insufficient, can also produce new pollutant.Condensation method is simply directly using just significant under high concentration.
The content of the invention
Present invention aims to overcome that prior art defect, there is provided a kind of VOCs recyclings treatment process, the technique Process is simple, obvious processing effect, cost is low, safe, economic benefit is obvious, non-secondary pollution.
The purpose of the present invention is achieved through the following technical solutions:
A kind of VOCs recyclings treatment process, is specially:VOCs gases after dedusting enter in VOCs collectors from bottom, Diesel oil enters from the top of collector and sprays on VOCs gases, and VOCs is after coolant cools down, diesel oil absorbs, by exporting back Receive and recycle
Further, netted condenser pipe is housed in the collector.
Further, the coolant is industrial alcohol.
Further, it is provided with efficient nozzle at the top of the absorption plant.
Further, the diesel oil is ordinary diesel oil or diesel oil, gasoline blending component.
The invention has the advantages that:
Compared with traditional VOCs absorption techniqueses, treatment process of the present invention is according to the similar principle that mixes of organic compound, in diesel oil Mixed alkanes and other components, can effectively absorb VOCs components, absorb the diesel oil after VOCs and recycled as fuel, this mistake Journey not only recycles VOCs, reduces secondary pollution, while also increases the additional calorific value of fuel oil, improves burning Efficiency, produces the economic benefit of bigger.Absorbing liquid selects diesel oil or bavin gasoline mixture, its boiling point and flash-point are higher, compare pure For gasoline or other one pack systems, safety coefficient is higher, treatment effeciency higher.
Brief description of the drawings
Fig. 1 absorbs treatment process schematic diagram for VOCs of the present invention.
Embodiment
With reference to specific embodiment, the present invention will be further described:
As shown in Figure 1, a kind of VOCs recyclings treatment process, is specially:The VOCs sources of the gas of plant area are filtered by particulate matter Afterwards, ethanol condensation diesel oil absorption plant is entered from below left side, gaseous matter is dissolved in the bavin of top spray while cooling In oil, the diesel oil-VOCs mixed liquors after absorption, enter recovery pond from the pipeline of bottom of device.
VOCs waste gas treatment process provided by the invention and processing method, not only eliminate discharge of the VOCs exhaust gas to environment Pollution, meets cost-effective modern enterprise, raising productivity effect, the requirement of comprehensive utilization of waste materials, suitable under different situations Hydro carbons, phenols, the volatile organic compounds such as the fragrant same clan absorption processing, possess extensive market application value.

Claims (3)

1. a kind of VOCs recyclings treatment process, it is characterised in that the VOCs gases after dedusting are received from bottom into VOCs In storage, diesel oil(Or diesel oil, gasoline blending component)Self-priming receiving apparatus is sprayed on VOCs gases, and VOCs is cooled down through ethanol, bavin Oil(Or diesel oil, gasoline blending component)After absorption, by exporting recycling.
2. a kind of VOCs recyclings treatment process as claimed in claim 1, it is characterised in that the collector is built-in There is netted condenser pipe, coolant is industrial alcohol.
3. a kind of VOCs recyclings treatment process as claimed in claim 1, it is characterised in that set at the top of absorption plant There is efficient nozzle.
CN201711245447.5A 2017-12-01 2017-12-01 A kind of VOCs recyclings treatment process Pending CN107998824A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711245447.5A CN107998824A (en) 2017-12-01 2017-12-01 A kind of VOCs recyclings treatment process

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711245447.5A CN107998824A (en) 2017-12-01 2017-12-01 A kind of VOCs recyclings treatment process

Publications (1)

Publication Number Publication Date
CN107998824A true CN107998824A (en) 2018-05-08

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201711245447.5A Pending CN107998824A (en) 2017-12-01 2017-12-01 A kind of VOCs recyclings treatment process

Country Status (1)

Country Link
CN (1) CN107998824A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108687126A (en) * 2018-05-23 2018-10-23 昆明理工大学 A kind of organic material contaminated soil eluent solvent Coupling Thermal desorption processing method and system
CN110302658A (en) * 2019-07-03 2019-10-08 上海力皇环保工程有限公司 It is a kind of for handling the devices and methods therefor of coalification coking organic exhaust gas
CN112121549A (en) * 2020-09-25 2020-12-25 李琰 VOC exhaust pollution treatment system
CN114011210A (en) * 2021-11-30 2022-02-08 山东牧一环保节能科技合伙企业(有限合伙) VOC gas condensation absorption process

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN201537401U (en) * 2009-11-09 2010-08-04 沈阳化工学院 Condensation and absorption integrated oil gas recovering device
CN104083981A (en) * 2014-07-02 2014-10-08 天津大学 Direct-contact-type deep cooling device for recycling volatile organic compound waste gas and recycling method
CN106823696A (en) * 2017-03-14 2017-06-13 常州大学 Based on two grades of absorptions, the VOCs retracting devices of three steps condensation integrated technique and method
CN206262322U (en) * 2016-12-07 2017-06-20 吐哈石油勘探开发指挥部石油天然气化工厂 A kind of petrochemical industry VOC collection devices

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN201537401U (en) * 2009-11-09 2010-08-04 沈阳化工学院 Condensation and absorption integrated oil gas recovering device
CN104083981A (en) * 2014-07-02 2014-10-08 天津大学 Direct-contact-type deep cooling device for recycling volatile organic compound waste gas and recycling method
CN206262322U (en) * 2016-12-07 2017-06-20 吐哈石油勘探开发指挥部石油天然气化工厂 A kind of petrochemical industry VOC collection devices
CN106823696A (en) * 2017-03-14 2017-06-13 常州大学 Based on two grades of absorptions, the VOCs retracting devices of three steps condensation integrated technique and method

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108687126A (en) * 2018-05-23 2018-10-23 昆明理工大学 A kind of organic material contaminated soil eluent solvent Coupling Thermal desorption processing method and system
CN108687126B (en) * 2018-05-23 2023-05-12 昆明理工大学 Organic matter contaminated soil solvent leaching coupling thermal desorption treatment method and system
CN110302658A (en) * 2019-07-03 2019-10-08 上海力皇环保工程有限公司 It is a kind of for handling the devices and methods therefor of coalification coking organic exhaust gas
CN112121549A (en) * 2020-09-25 2020-12-25 李琰 VOC exhaust pollution treatment system
CN114011210A (en) * 2021-11-30 2022-02-08 山东牧一环保节能科技合伙企业(有限合伙) VOC gas condensation absorption process

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Application publication date: 20180508

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