CN204973576U - Administer device of synthetic leather waste gas - Google Patents
Administer device of synthetic leather waste gas Download PDFInfo
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- CN204973576U CN204973576U CN201520493832.1U CN201520493832U CN204973576U CN 204973576 U CN204973576 U CN 204973576U CN 201520493832 U CN201520493832 U CN 201520493832U CN 204973576 U CN204973576 U CN 204973576U
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Abstract
The utility model discloses an administer device of synthetic leather waste gas, including DMF absorption tower, defroster, optoelectronic integration equipment, whirl board absorption tower and the aiutage that communicates in proper order, the DMF absorption tower has the air intake that lets in synthetic leather waste gas, the export and the defroster entry on DMF absorption tower communicate through first tuber pipe, the export and the aiutage entry on whirl board absorption tower communicate through the second tuber pipe, optoelectronic integration equipment include the shell and arrange fillter section, photocatalysis section in the shell in proper order, discharge processing section and active carbon absorb the section, the wherein export butt joint of fillter section one side and defroster, the active carbon absorbs the entry butt joint on section one side and whirl board absorption tower. The utility model discloses according to the physicochemical property's of each composition in the synthetic leather waste gas difference, adopt DMF absorption tower, optoelectronic integration equipment etc. Respectively, the segmentation, branchs technology gets rid of the harmful components in the waste gas, can realize that DMF's regeneration is retrieved, and the power consumption hangs down, get rid of efficient, no secondary pollution.
Description
Technical field
The utility model relates to chemical adsorbing separation and Pollutant Control Technology field, particularly relates to a kind of device administering synthetic leather waste gas.
Background technology
In recent years, number of times and the duration of domestic large area outburst haze weather increase year by year, have a strong impact on national healthy and quality of life.Gray haze harm is large, and coverage is wide, has become one of subject matter of nowadays influence In The Atmosphere Over China environmental quality, is also the atmospheric environment problem paid close attention to the most of the common people instantly.
A large amount of discharges of industry volatile organic contaminant (VOCs), nitrogen oxide, sulfur dioxide, motor-vehicle tail-gas are the main causes that gray haze is formed.Domestic industry dust, sulfur dioxide and nitrogen oxide have all been put into effect strict standard and have been carried out control discharge.The improvement of VOCs relatively lags behind, but attracts great attention.The industries such as " key area prevention and control of air pollution " 12 " planning " regulation petrochemical industry, chemical industry, spraying, printing, textile printing and dyeing, leather processing, shoemaking, Wood-based Panel Production, daily use chemicals, food processing need be carried out VOCs and be collected and purified treatment, and purifying rate is not less than 90%.
A large amount of organic exhaust gas can be produced in synthetic leather, artificial leather process, the waste gas Main Ingredients and Appearance that wherein organic solvent produces in printing process on leather base cloth is dimethyl formamide (DMF), other also have toluene (TOL), butanone (MEK) etc., if this waste gas enters air without improvement, will major polluting atmosphere environment.Therefore, under all trades and professions carry out the overall background that " controlling haze " take action, exploiting economy, effective, safe, stable artificial leather three editions printing waste gas pollution control and treatment technology is very urgent.
Publication number is disclose a kind of integrated apparatus administering printing, advertising organic exhaust gas in the Chinese patent literature of CN204193748U, comprises waste gas collecting system, waste gas purification by adsorbsion system, uniform stream system, examine and replace system and emission control systems.But this integrated apparatus exists clearance for synthetic leather waste gas does not reach the problems such as processing requirements.
Utility model content
The utility model discloses a kind of controlling device of synthetic leather waste gas, utilize the difference of the physico-chemical property of each composition in synthetic leather waste gas, adopt the harmful components in the technology such as absorption process, optoelectronic integration segmentation removal waste gas respectively, reach the object of directly discharge.
Administer a device for synthetic leather waste gas, comprise be communicated with successively DMF absorption tower, demister, optoelectronic integration equipment, spiral board absorption tower and aiutage;
Described DMF absorption tower has the air inlet passing into synthetic leather waste gas;
The outlet on DMF absorption tower is communicated with by the first airduct with demister entrance;
The outlet on spiral board absorption tower is communicated with by the second airduct with aiutage entrance;
Optoelectronic integration equipment comprises shell and is arranged in fillter section, photocatalysis section, discharge process section and active carbon absorber portion in the enclosure successively, wherein fillter section side is docked with the outlet of demister, and active carbon absorber portion side is docked with the entrance on spiral board absorption tower.
First synthetic leather waste gas enter DMF absorption tower through air inlet after collecting, and absorbs DMF and part VOCs.Pass in demister through the first airduct after absorption, remove by after the part steam taken out of in DMF absorption tower and untreated particulate solid completely, directly enter optoelectronic integration equipment.Section first after filtration in optoelectronic integration equipment, tentatively remove demister through mechanical filter and do not remove particle completely, then respectively with photocatalysis section, discharge process section, react at the high energy electron of plasma and photocatalysis coupled generation, hydroxyl radical free radical, oxygen radical, the contour active particle of ozone, VOCs molecule (as butyl acetate, ethyl acetate, benzene,toluene,xylene, formaldehyde etc.) in waste gas is finally degraded to carbon dioxide and water, this process possibility forming section aerosol; Finally by active carbon absorber portion, adsorb do not degrade part VOCs molecule and ozone isoreactivity particle completely, the VOCs molecule of absorption and ozone isoreactivity particle can continue reaction, thus realize charcoal absorption and regenerate carrying out simultaneously.Waste gas after optoelectronic integration device processes enters spiral board absorption tower, under absorbing liquid effect, removes a small amount of aerosol.Last under the effect of centrifugal blower, the waste gas after aforementioned multiple device processes enters in aiutage, finally through high altitude discharge in air.
As preferably, described DMF absorption tower comprises tower shell and to be arranged in tower shell at least two-stage absorptive unit from the bottom to top, and each absorptive unit comprises absorbing liquid jet pipe, liquid distribution trough and stainless steel helices from top to bottom successively.
As preferably, be provided with between adjacent absorptive unit and rise gas plate.
Further preferably, described tower shell is made up of 304 stainless steels, described absorptive unit is three grades, the absorbing liquid that first order absorptive unit adopts is 10%DMF solution, the imbibition that second level absorptive unit adopts is 5%DMF solution, the absorbing liquid that third level absorptive unit adopts is clear water, complete to ensure the absorption of DMF in synthetic leather waste gas.And when in first order absorptive unit, when the DMF concentration in absorbing liquid reaches 15%, absorbing liquid is sent to rectifying column and is used for reclaiming DMF, the regeneration that can also realize DMF is reclaimed.
Described demister shell is made up of stainless steel, as preferably, is provided with stainless steel cloth in described demister.
As preferably, in described optoelectronic integration equipment:
Stainless steel cloth is provided with in fillter section;
Be provided with uviol lamp and the aluminium base titanium dioxide of support type in photocatalysis section, described uviol lamp adopts low pressure mercury lamp, and wavelength is 189 ~ 254nm;
Sparking electrode is provided with in discharge process section;
Active carbon filler is provided with in active carbon absorber portion.
As preferably, described sparking electrode comprises the stainless steel bar of external high voltage power supply and is in the peripheral and stainless steel cylinder of ground connection of stainless steel bar, and stainless steel cylinder inner surface is attached with catalyst layer.Further preferably, titanium dioxide, aluminium oxide, manganese oxide, iron oxide is comprised in described catalyst layer.
Further preferably, the diameter of described stainless steel cylinder is 60 ~ 120mm, and the diameter of stainless steel bar is 5 ~ 20mm.
Further preferably, photocatalysis section and discharge process section can be many groups, are specifically determined by process waste gas tolerance.
Described spiral board absorption tower is made up of polypropylene, as preferably, is provided with water pipe and Multi-stage spiral column plate in described spiral board absorption tower.The progression of rotating stream tray and the tower height on spiral board absorption tower and tower diameter are determined by the tolerance and concentration processing waste gas.
Described water pipe is connected with water pump, and clear water at the bottom of tower is delivered to tower top and flowed down through spiral board by delivery port by water pump, and clear water recycles.
Further preferably, the number of blade of every grade of rotating stream tray is 24, and the blade elevation angle is 25 °, and radial angle is 16 °.
Compared with prior art, the utility model has following advantage:
The utility model, according to the difference of the physico-chemical property of composition each in synthetic leather waste gas, adopts DMF absorption tower, optoelectronic integration equipment etc. respectively, and the harmful components in waste gas are removed in segmentation, division technique, the regeneration that can realize DMF is reclaimed, and it is low to consume energy, removal efficiency is high, non-secondary pollution.
Accompanying drawing explanation
Fig. 1 is the controlling device figure of synthetic leather waste gas of the present utility model;
Fig. 2 is the schematic diagram on DMF absorption tower;
Fig. 3 is the internal structure schematic diagram of optoelectronic integration equipment main perspective degree;
Fig. 4 is the internal structure schematic diagram of optoelectronic integration equipment depression angle;
In figure, 1-air inlet; 2-DMF absorption tower; 3-first airduct; 4-demister; 5-optoelectronic integration equipment; 6-spiral board absorption tower; 7-second airduct; 8-blower fan; 9-aiutage; 21-air inlet; 22-gas outlet; 23-manhole; 24-absorbing liquid jet pipe; 25-drain pipe; 26-stainless steel helices; 27-liquid distribution trough; 28-rises gas plate; 29-demist layer; 51-import; 52-stainless steel cloth; 53-uviol lamp; The aluminium base titanium dioxide of 54-support type; 55-discharge process section; 56-active carbon; 57-exports.
Detailed description of the invention
Describe the present invention in detail below in conjunction with embodiment and accompanying drawing, but the present invention is not limited to this.
Embodiment 1
As shown in Figure 1, the controlling device of the synthetic leather waste gas in the utility model comprises the air inlet 1, DMF absorption tower 2, first airduct 3, demister 4, optoelectronic integration equipment 5, spiral board absorption tower 6, second airduct 7, blower fan 8 and the aiutage 9 that are communicated with successively.
As shown in Figure 2, DMF absorption tower 2 comprises the tower shell be made up of 304 stainless steels and the three grades of absorptive units be arranged on from the bottom to top in tower shell, each absorptive unit comprises absorbing liquid jet pipe 24, liquid distribution trough 27 and stainless steel helices 26 from top to bottom successively, and is provided with between adjacent absorptive unit and rises gas plate 28 and drain pipe 25.The gas outlet 22 DMF absorption tower 2 is also provided with the air inlet 21 for passing into synthetic leather waste gas, being communicated with by the first airduct with demister entrance and manhole 23; The below of gas outlet 22 is provided with demist layer 29.The absorbing liquid that first order absorptive unit in the utility model adopts is 10%DMF solution, and the imbibition that second level absorptive unit adopts is 5%DMF solution, and the absorbing liquid that third level absorptive unit adopts is clear water, complete to ensure the absorption of DMF in synthetic leather waste gas.And when in first order absorptive unit, when the DMF concentration in absorbing liquid reaches 15%, absorbing liquid is sent to the regeneration recovery that rectifying column is used for DMF.
Demister 4 comprises the shell be made up of stainless steel and the stainless steel cloth arranged in the enclosure.
As shown in Figure 3 and Figure 4, optoelectronic integration equipment 5 comprises shell and is arranged in fillter section, photocatalysis section, discharge process section 55 and active carbon absorber portion in the enclosure successively.Optoelectronic integration equipment 5 is also provided with the import 51 of directly docking with the outlet of demister, and the outlet 57 of docking with the entrance on spiral board absorption tower.The power of this optoelectronic integration equipment 5 is 10kW.
Stainless steel cloth 52 is provided with in fillter section; Be provided with uviol lamp 53 and the aluminium base titanium dioxide 54 of support type in photocatalysis section, this uviol lamp adopts low pressure mercury lamp, and wavelength is 189 ~ 254nm; Sparking electrode is provided with in discharge process section 55, this sparking electrode comprises the stainless steel bar of external high voltage power supply and is in stainless steel bar periphery and the stainless steel cylinder of ground connection, the diameter of stainless steel cylinder is 80mm, and the diameter of stainless steel bar is 10mm, and stainless steel cylinder inner surface is attached with catalyst layer; Active carbon 56 is provided with in active carbon absorber portion.
The group number of photocatalysis section and discharge process section specifically determines by processing waste gas tolerance.
Spiral board absorption tower 6 is made up of polypropylene, is inside provided with water pipe and Multi-stage spiral column plate, and the number of blade of every grade of rotating stream tray is 24, and the blade elevation angle is 25 °, and radial angle is 16 °.Water pipe is connected with water pump, and clear water at the bottom of tower is delivered to tower top and flowed down through spiral board by delivery port by water pump, and clear water recycles.The progression of rotating stream tray and the tower height on spiral board absorption tower and tower diameter are determined by the tolerance and concentration processing waste gas.The outlet on spiral board absorption tower 6 is communicated with by the second airduct 7 with aiutage 9 entrance.
Concrete steps are as follows:
Step (1) is connected to complete equipment air inlet by after synthetic leather gas sampling;
Step (2) starts blower fan after checking airduct air-tightness;
Step (3) opens the water pump on DMF absorption tower and spiral board absorption tower respectively;
Step (4) opens optoelectronic integration device power supply (DPS), and equipment normally runs.
After step (5) exhaust-gas treatment terminates, turn off each equipment by the order of optoelectronic integration equipment, blower fan, water pump.
The course of work:
First synthetic leather waste gas enter DMF absorption tower 2 through air inlet 1 after collecting, and after three grades of absorptive units absorb, the clearance of DMF can reach more than 90%, and other organic exhaust gas compositions can remove about 30%.Waste gas after absorption passes in demister 4 through the first airduct 3, removes by after the part steam taken out of in DMF absorption tower 2 and untreated particulate solid completely, directly enters optoelectronic integration equipment 5.Section first after filtration in optoelectronic integration equipment 5, carries out mechanical filter stainless steel wire is off the net; Then respectively with photocatalysis section, discharge process section, react at the high energy electron of plasma and photocatalysis coupled generation, hydroxyl radical free radical, oxygen radical, the contour active particle of ozone, VOCs molecule (as butyl acetate, ethyl acetate, benzene,toluene,xylene, formaldehyde etc.) in waste gas is finally degraded to carbon dioxide and water, this process possibility forming section aerosol; Finally by active carbon absorber portion, under the effect of active carbon, remove VOCs molecule completely of not degrading.Waste gas after optoelectronic integration equipment 5 processes enters spiral board absorption tower 6, under the effect of water, removes a small amount of aerosol.Last under the effect of centrifugal blower 8, the waste gas after aforementioned multiple device processes reaches the standard of high altitude discharge, enters in aiutage 9, finally through high altitude discharge in air.
Longwan District, Wenzhou artificial leather limited company is the leading enterprise that in this district, artificial leather is produced, a large amount of organic solvent is used in three editions typographies, organic solvent printing can produce a large amount of organic exhaust gas to leather base cloth process, worsens shopwork environment and has a strong impact on the living environment of surrounding resident.According to in-site measurement and relevant criterion requirement, focus on after the gas sampling of two tracks, design is 30000m altogether
3/ h air quantity waste gas treatment engineering.Treatment process is as follows:
After processing according to above-mentioned device and technical process, detect through third party, result is as shown in table 1, and various pollutant outlet is all lower than the concentration of emission specified in " synthetic leather and artificial leather emission of industrial pollutants standard " (GB21902-2008).
Table 1
Claims (9)
1. administer a device for synthetic leather waste gas, it is characterized in that, comprise be communicated with successively DMF absorption tower, demister, optoelectronic integration equipment, spiral board absorption tower and aiutage;
Described DMF absorption tower has the air inlet passing into synthetic leather waste gas;
The outlet on DMF absorption tower is communicated with by the first airduct with demister entrance;
The outlet on spiral board absorption tower is communicated with by the second airduct with aiutage entrance;
Optoelectronic integration equipment comprises shell and is arranged in fillter section, photocatalysis section, discharge process section and active carbon absorber portion in the enclosure successively, wherein fillter section side is docked with the outlet of demister, and active carbon absorber portion side is docked with the entrance on spiral board absorption tower.
2. the device of improvement synthetic leather waste gas according to claim 1, it is characterized in that, described DMF absorption tower comprises tower shell and to be arranged in tower shell at least two-stage absorptive unit from the bottom to top, and each absorptive unit comprises absorbing liquid jet pipe, liquid distribution trough and stainless steel helices from top to bottom successively.
3. the device of improvement synthetic leather waste gas according to claim 2, is characterized in that, is provided with and rises gas plate between adjacent absorptive unit.
4. the device of improvement synthetic leather waste gas according to claim 1, is characterized in that, be provided with stainless steel cloth in described demister.
5. the device of improvement synthetic leather waste gas according to claim 1, is characterized in that, in described optoelectronic integration equipment:
Stainless steel cloth is provided with in fillter section;
Uviol lamp and the aluminium base titanium dioxide of support type is provided with in photocatalysis section;
Sparking electrode is provided with in discharge process section;
Active carbon filler is provided with in active carbon absorber portion.
6. the device of improvement synthetic leather waste gas according to claim 5, it is characterized in that, described sparking electrode comprises the stainless steel bar of external high voltage power supply and is in stainless steel bar periphery and the stainless steel cylinder of ground connection, and stainless steel cylinder inner surface is attached with catalyst layer.
7. the device of improvement synthetic leather waste gas according to claim 6, is characterized in that, the diameter of described stainless steel cylinder is 60 ~ 120mm, and the diameter of stainless steel bar is 5 ~ 20mm.
8. the device of improvement synthetic leather waste gas according to claim 1, is characterized in that, is provided with water pipe and Multi-stage spiral column plate in described spiral board absorption tower.
9. the device of improvement synthetic leather waste gas according to claim 8, is characterized in that, the number of blade of every grade of rotating stream tray is 24, and the blade elevation angle is 25 °, and radial angle is 16 °.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201520493832.1U CN204973576U (en) | 2015-07-06 | 2015-07-06 | Administer device of synthetic leather waste gas |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201520493832.1U CN204973576U (en) | 2015-07-06 | 2015-07-06 | Administer device of synthetic leather waste gas |
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| CN204973576U true CN204973576U (en) | 2016-01-20 |
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| CN201520493832.1U Active CN204973576U (en) | 2015-07-06 | 2015-07-06 | Administer device of synthetic leather waste gas |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105032179A (en) * | 2015-07-06 | 2015-11-11 | 浙江浙大环境工程有限公司 | Apparatus and process for treating synthetic leather exhaust gas |
| CN108774148A (en) * | 2018-07-11 | 2018-11-09 | 刘志 | A kind of PU synthetic leather wet method prepare in the recovery and treatment method of solvent |
| CN109364722A (en) * | 2018-10-26 | 2019-02-22 | 周贵英 | A kind of coking waste gas treatment equipment |
-
2015
- 2015-07-06 CN CN201520493832.1U patent/CN204973576U/en active Active
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105032179A (en) * | 2015-07-06 | 2015-11-11 | 浙江浙大环境工程有限公司 | Apparatus and process for treating synthetic leather exhaust gas |
| CN108774148A (en) * | 2018-07-11 | 2018-11-09 | 刘志 | A kind of PU synthetic leather wet method prepare in the recovery and treatment method of solvent |
| CN109364722A (en) * | 2018-10-26 | 2019-02-22 | 周贵英 | A kind of coking waste gas treatment equipment |
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