CN107986754A - A kind of high resistance to compression water-permeable brick prepared using municipal sludge and cinder of electric power plant - Google Patents

A kind of high resistance to compression water-permeable brick prepared using municipal sludge and cinder of electric power plant Download PDF

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Publication number
CN107986754A
CN107986754A CN201610943220.7A CN201610943220A CN107986754A CN 107986754 A CN107986754 A CN 107986754A CN 201610943220 A CN201610943220 A CN 201610943220A CN 107986754 A CN107986754 A CN 107986754A
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parts
cinder
power plant
electric power
permeable brick
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CN201610943220.7A
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Chinese (zh)
Inventor
刘建军
江薇
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Prosperous Glad Science And Technology Ltd Co In Hanchuan City
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Prosperous Glad Science And Technology Ltd Co In Hanchuan City
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Priority to CN201610943220.7A priority Critical patent/CN107986754A/en
Publication of CN107986754A publication Critical patent/CN107986754A/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/13Compounding ingredients
    • C04B33/132Waste materials; Refuse; Residues
    • C04B33/1321Waste slurries, e.g. harbour sludge, industrial muds
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/13Compounding ingredients
    • C04B33/1305Organic additives
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/13Compounding ingredients
    • C04B33/131Inorganic additives
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/13Compounding ingredients
    • C04B33/132Waste materials; Refuse; Residues
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/13Compounding ingredients
    • C04B33/132Waste materials; Refuse; Residues
    • C04B33/135Combustion residues, e.g. fly ash, incineration waste
    • C04B33/1355Incineration residues
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3418Silicon oxide, silicic acids or oxide forming salts thereof, e.g. silica sol, fused silica, silica fume, cristobalite, quartz or flint
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/349Clays, e.g. bentonites, smectites such as montmorillonite, vermiculites or kaolines, e.g. illite, talc or sepiolite
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/38Non-oxide ceramic constituents or additives
    • C04B2235/3817Carbides
    • C04B2235/3826Silicon carbides
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/70Aspects relating to sintered or melt-casted ceramic products
    • C04B2235/96Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00Technologies relating to the processing of minerals
    • Y02P40/60Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Road Paving Structures (AREA)

Abstract

The present invention relates to a kind of high resistance to compression water-permeable brick, specifically a kind of high resistance to compression water-permeable brick being mixed with using municipal sludge and cinder of electric power plant.The high resistance to compression water-permeable brick is made from the following raw materials in parts by weight:20 22 parts of phosphorus slag, 13 15 parts of municipal sludge, 24 parts of cement, 18 20 parts of cinder of electric power plant, 23 parts of carborundum, 13 15 parts of clay, 79 parts of sepiolite, 35 parts of diatomite, 17 20 parts of phenol aldehyde modified epoxy resin, 56 parts of starch.Using the trade wastes such as municipal sludge, cinder of electric power plant prepare water-permeable brick to economizing on resources, the energy, avoid pollution of the solid waste to environment, Development of Urban Ecological Human Settlements and green building have great economic results in society.It can be widely used for pavement, square, parking lot, park, residential quarter etc..

Description

A kind of high resistance to compression water-permeable brick prepared using municipal sludge and cinder of electric power plant
Technical field
It is specifically a kind of to utilize municipal sludge and cinder of electric power plant mixing system the present invention relates to a kind of high resistance to compression water-permeable brick Standby high resistance to compression water-permeable brick.
Background technology
Municipal sludge and the flyash in thermal power plant are the two big pollution sources for influencing urban environment, are produced and given birth to using them State environmentally conscious materials meet the developing direction of circular economy.Existing waterproof stone pavements, concrete road surface, conventional ceramic brick road The interception face infiltration of rainwater of face, bituminous paving and various houses and building is poor, and the long-term excess exploitation of underground water, makes in addition Urban groundwater resource is decayed year by year, and level of ground water significantly declines.Therefore, novel water permeable brick is researched and developed to protecting urban ecology ring Border, improve the significant of life of urban resident quality.
Ecological sintering brick permeable to water is prepared using municipal sludge and cinder of electric power plant, can not only make full use of municipal sludge and electricity The main aluminosilicate component of factory's lime-ash, can also utilize unburned in 30% or so organic matter and cinder of electric power plant in municipal sludge Most carbon reduces the energy consumption needed for product sintering as internal combustion component;While base substrate is through high-temperature roasting, the pathogeny bacterium in sludge It is scorched to death with parasitic ovum, heavy metal is cemented in aluminium silicate mineral composition, thoroughly avoids the secondary pollution of sludge.This The pollution circle of resource, the energy and solid waste to environment can be greatlyd save.This sintering brick permeable to water has saturating Functional characteristic and the environment compatibilities such as water, ventilative, anti-skidding, noise abatement, can be widely used for pavement, square, parking lot, park, live Development of Urban Ecological Human Settlements and green building are had great economic results in society by quarter etc..
The content of the invention
The defects of the object of the invention is exactly to make up prior art, there is provided one kind utilizes municipal sludge and cinder of electric power plant The high resistance to compression water-permeable brick being mixed with.
The present invention is achieved by the following technical solutions:
A kind of high resistance to compression water-permeable brick being mixed with using municipal sludge and cinder of electric power plant, is made from the following raw materials in parts by weight: 20-22 parts of phosphorus slag, 13-15 parts of municipal sludge, 2-4 parts of cement, 18-20 parts of cinder of electric power plant, 2-3 parts of carborundum, clay 13-15 Part, 7-9 parts of sepiolite, 3-5 parts of diatomite, epoxy resin 17-20 parts phenol aldehyde modified, 5-6 parts of starch.
A kind of preparation method that high resistance to compression water-permeable brick is mixed with using municipal sludge and cinder of electric power plant, including following preparation Step:Clay and municipal sludge are put at 80 DEG C and dried, is cooled to room temperature and is sent into grinder, add phosphorus slag, Power Plant Ash Slag, carborundum, sepiolite, diatomite mixed grinding are uniform;Then add in mortar mixer, continue to add cement, starch, phenol Aldehyde modified epoxy, stirs 30 minutes, the mixture being stirred is inserted in mould, and dry idiosome, is put into high temperature furnace and forges Burn, 750 DEG C of calcining heat, cooled to room temperature discharging.
It is an advantage of the invention that:
(1)Municipal sludge and cinder of electric power plant are prepared into water-permeable brick, two kinds of discarded object synthesis are converted into the Building wood of clean environment firendly Material.
(2)It with the addition of cement, clay, starch, phenol aldehyde modified epoxy resin in water-permeable brick, play unexpected association Same-action, improves the compression strength of brick.
(3)Carborundum, sepiolite, diatomaceous mixture are added in water-permeable brick as aggregate, is played unexpectedly Synergistic effect, improve the compression strength of brick.
(4)Additive is not not added with concrete, reduces production cost.
Specific embodiment mode
Municipal sludge is derived from the liquid sludge of Wuhan City thing lake sewage treatment plant, and cinder of electric power plant is derived from Hanchuan City thermal power generation Factory.
Embodiment 1:
Take 20 parts of phosphorus slag, 13 parts of municipal sludge, 2 parts of cement, 18 parts of cinder of electric power plant, 2 parts of carborundum, 13 parts of clay, sepiolite 7 Part, 3 parts of diatomite, 17 parts of phenol aldehyde modified epoxy resin, 5 parts of starch, obtain after drying, grind, stir, dry, calcine Water-permeable brick.
Embodiment 2:
Take 22 parts of phosphorus slag, 15 parts of municipal sludge, 4 parts of cement, 20 parts of cinder of electric power plant, 3 parts of carborundum, 15 parts of clay, sepiolite 9 Part, 5 parts of diatomite, 20 parts of phenol aldehyde modified epoxy resin, 6 parts of starch, obtain after drying, grind, stir, dry, calcine Water-permeable brick.
Embodiment 3:
Take 21 parts of phosphorus slag, 14 parts of municipal sludge, 3 parts of cement, 19 parts of cinder of electric power plant, 3 parts of carborundum, 14 parts of clay, sepiolite 8 Part, 4 parts of diatomite, 18 parts of phenol aldehyde modified epoxy resin, 6 parts of starch, obtain after drying, grind, stir, dry, calcine Water-permeable brick.
Comparative example 1:
14 parts of municipal sludge, 19 parts of cinder of electric power plant, 9 parts of outer adding assistant.
The coating of embodiment 1-3 and the gained of comparative example 1 are subjected to performance comparison, test result is shown in Table 1.
Table 1
Sample Compression strength(MPa) Flexural strength(MPa) Coefficient of permeability(*10-2cm/s)
Embodiment 1 57.2 5.1 6.0
Embodiment 2 58.4 5.3 5.4
Embodiment 3 60.1 6.2 6.8
Comparative example 1 28.6 3.2 1.3

Claims (3)

  1. A kind of 1. high resistance to compression water-permeable brick prepared using municipal sludge and cinder of electric power plant, it is characterised in that:The water-permeable brick is under The raw material of row parts by weight is made:20-22 parts of phosphorus slag, 13-15 parts of municipal sludge, 2-4 parts of cement, 18-20 parts of cinder of electric power plant, carbonization 2-3 parts of silicon, 13-15 parts of clay, 7-9 parts of sepiolite, 3-5 parts of diatomite, epoxy resin 17-20 parts phenol aldehyde modified, starch 5-6 Part.
  2. 2. water-permeable brick according to claim 1, it is characterised in that:The water-permeable brick is made from the following raw materials in parts by weight: 21 parts of phosphorus slag, 14 parts of municipal sludge, 3 parts of cement, 19 parts of cinder of electric power plant, 3 parts of carborundum, 14 parts of clay, 8 parts of sepiolite, diatom 4 parts of soil, 18 parts of phenol aldehyde modified epoxy resin, 6 parts of starch.
  3. It is 3. a kind of such as the preparation method of claim 1-2 any one of them water-permeable bricks, it is characterised in that:Step is prepared including following Suddenly:Clay and municipal sludge are put at 80 DEG C and dried, be cooled to room temperature be sent into grinder in, add phosphorus slag, cinder of electric power plant, Carborundum, sepiolite, diatomite mixed grinding are uniform;Then add in mortar mixer, continue to add cement, starch, phenolic aldehyde Modified epoxy, stirs 30 minutes, the mixture being stirred is inserted in mould, and dry idiosome, is put into high temperature furnace and calcines, 750 DEG C of calcining heat, cooled to room temperature discharging.
CN201610943220.7A 2016-10-26 2016-10-26 A kind of high resistance to compression water-permeable brick prepared using municipal sludge and cinder of electric power plant Pending CN107986754A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610943220.7A CN107986754A (en) 2016-10-26 2016-10-26 A kind of high resistance to compression water-permeable brick prepared using municipal sludge and cinder of electric power plant

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Application Number Priority Date Filing Date Title
CN201610943220.7A CN107986754A (en) 2016-10-26 2016-10-26 A kind of high resistance to compression water-permeable brick prepared using municipal sludge and cinder of electric power plant

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108585783A (en) * 2018-06-29 2018-09-28 陈雨 A kind of environmental protection and energy saving brick
CN112358255A (en) * 2020-10-29 2021-02-12 荆门市意祥机械有限公司 Environment-friendly water permeable brick and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108585783A (en) * 2018-06-29 2018-09-28 陈雨 A kind of environmental protection and energy saving brick
CN112358255A (en) * 2020-10-29 2021-02-12 荆门市意祥机械有限公司 Environment-friendly water permeable brick and preparation method thereof

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