CN107986754A - A kind of high resistance to compression water-permeable brick prepared using municipal sludge and cinder of electric power plant - Google Patents
A kind of high resistance to compression water-permeable brick prepared using municipal sludge and cinder of electric power plant Download PDFInfo
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- CN107986754A CN107986754A CN201610943220.7A CN201610943220A CN107986754A CN 107986754 A CN107986754 A CN 107986754A CN 201610943220 A CN201610943220 A CN 201610943220A CN 107986754 A CN107986754 A CN 107986754A
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- parts
- cinder
- power plant
- electric power
- permeable brick
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- 239000011449 brick Substances 0.000 title claims abstract description 28
- 239000010802 sludge Substances 0.000 title claims abstract description 28
- 239000003818 cinder Substances 0.000 title claims abstract description 22
- 230000006835 compression Effects 0.000 title claims abstract description 14
- 238000007906 compression Methods 0.000 title claims abstract description 14
- 239000004113 Sepiolite Substances 0.000 claims abstract description 10
- 229920002472 Starch Polymers 0.000 claims abstract description 10
- 239000004568 cement Substances 0.000 claims abstract description 10
- 239000004927 clay Substances 0.000 claims abstract description 10
- -1 phenol aldehyde Chemical class 0.000 claims abstract description 10
- 229910052624 sepiolite Inorganic materials 0.000 claims abstract description 10
- 235000019355 sepiolite Nutrition 0.000 claims abstract description 10
- 235000019698 starch Nutrition 0.000 claims abstract description 10
- 239000008107 starch Substances 0.000 claims abstract description 10
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract description 9
- 239000011574 phosphorus Substances 0.000 claims abstract description 9
- 229910010271 silicon carbide Inorganic materials 0.000 claims abstract description 9
- 239000002893 slag Substances 0.000 claims abstract description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000003822 epoxy resin Substances 0.000 claims abstract description 8
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 8
- 239000002994 raw material Substances 0.000 claims abstract description 4
- 238000003756 stirring Methods 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 4
- 238000002360 preparation method Methods 0.000 claims description 3
- 239000004593 Epoxy Substances 0.000 claims description 2
- 238000001354 calcination Methods 0.000 claims description 2
- 238000007599 discharging Methods 0.000 claims description 2
- 238000000227 grinding Methods 0.000 claims description 2
- 239000004570 mortar (masonry) Substances 0.000 claims description 2
- 238000003763 carbonization Methods 0.000 claims 1
- 229910052710 silicon Inorganic materials 0.000 claims 1
- 239000010703 silicon Substances 0.000 claims 1
- 239000002689 soil Substances 0.000 claims 1
- 239000002910 solid waste Substances 0.000 abstract description 2
- 239000002699 waste material Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 238000005245 sintering Methods 0.000 description 3
- 229910000323 aluminium silicate Inorganic materials 0.000 description 2
- 239000004567 concrete Substances 0.000 description 2
- 239000003673 groundwater Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 102000002322 Egg Proteins Human genes 0.000 description 1
- 108010000912 Egg Proteins Proteins 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- PZZYQPZGQPZBDN-UHFFFAOYSA-N aluminium silicate Chemical compound O=[Al]O[Si](=O)O[Al]=O PZZYQPZGQPZBDN-UHFFFAOYSA-N 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 239000002956 ash Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000010881 fly ash Substances 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 210000004681 ovum Anatomy 0.000 description 1
- 230000003071 parasitic effect Effects 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 238000010248 power generation Methods 0.000 description 1
- 238000009738 saturating Methods 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/132—Waste materials; Refuse; Residues
- C04B33/1321—Waste slurries, e.g. harbour sludge, industrial muds
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/1305—Organic additives
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/131—Inorganic additives
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/132—Waste materials; Refuse; Residues
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/132—Waste materials; Refuse; Residues
- C04B33/135—Combustion residues, e.g. fly ash, incineration waste
- C04B33/1355—Incineration residues
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3418—Silicon oxide, silicic acids or oxide forming salts thereof, e.g. silica sol, fused silica, silica fume, cristobalite, quartz or flint
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/349—Clays, e.g. bentonites, smectites such as montmorillonite, vermiculites or kaolines, e.g. illite, talc or sepiolite
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/38—Non-oxide ceramic constituents or additives
- C04B2235/3817—Carbides
- C04B2235/3826—Silicon carbides
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
- C04B2235/96—Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/60—Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Dispersion Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Environmental & Geological Engineering (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Road Paving Structures (AREA)
Abstract
The present invention relates to a kind of high resistance to compression water-permeable brick, specifically a kind of high resistance to compression water-permeable brick being mixed with using municipal sludge and cinder of electric power plant.The high resistance to compression water-permeable brick is made from the following raw materials in parts by weight:20 22 parts of phosphorus slag, 13 15 parts of municipal sludge, 24 parts of cement, 18 20 parts of cinder of electric power plant, 23 parts of carborundum, 13 15 parts of clay, 79 parts of sepiolite, 35 parts of diatomite, 17 20 parts of phenol aldehyde modified epoxy resin, 56 parts of starch.Using the trade wastes such as municipal sludge, cinder of electric power plant prepare water-permeable brick to economizing on resources, the energy, avoid pollution of the solid waste to environment, Development of Urban Ecological Human Settlements and green building have great economic results in society.It can be widely used for pavement, square, parking lot, park, residential quarter etc..
Description
Technical field
It is specifically a kind of to utilize municipal sludge and cinder of electric power plant mixing system the present invention relates to a kind of high resistance to compression water-permeable brick
Standby high resistance to compression water-permeable brick.
Background technology
Municipal sludge and the flyash in thermal power plant are the two big pollution sources for influencing urban environment, are produced and given birth to using them
State environmentally conscious materials meet the developing direction of circular economy.Existing waterproof stone pavements, concrete road surface, conventional ceramic brick road
The interception face infiltration of rainwater of face, bituminous paving and various houses and building is poor, and the long-term excess exploitation of underground water, makes in addition
Urban groundwater resource is decayed year by year, and level of ground water significantly declines.Therefore, novel water permeable brick is researched and developed to protecting urban ecology ring
Border, improve the significant of life of urban resident quality.
Ecological sintering brick permeable to water is prepared using municipal sludge and cinder of electric power plant, can not only make full use of municipal sludge and electricity
The main aluminosilicate component of factory's lime-ash, can also utilize unburned in 30% or so organic matter and cinder of electric power plant in municipal sludge
Most carbon reduces the energy consumption needed for product sintering as internal combustion component;While base substrate is through high-temperature roasting, the pathogeny bacterium in sludge
It is scorched to death with parasitic ovum, heavy metal is cemented in aluminium silicate mineral composition, thoroughly avoids the secondary pollution of sludge.This
The pollution circle of resource, the energy and solid waste to environment can be greatlyd save.This sintering brick permeable to water has saturating
Functional characteristic and the environment compatibilities such as water, ventilative, anti-skidding, noise abatement, can be widely used for pavement, square, parking lot, park, live
Development of Urban Ecological Human Settlements and green building are had great economic results in society by quarter etc..
The content of the invention
The defects of the object of the invention is exactly to make up prior art, there is provided one kind utilizes municipal sludge and cinder of electric power plant
The high resistance to compression water-permeable brick being mixed with.
The present invention is achieved by the following technical solutions:
A kind of high resistance to compression water-permeable brick being mixed with using municipal sludge and cinder of electric power plant, is made from the following raw materials in parts by weight:
20-22 parts of phosphorus slag, 13-15 parts of municipal sludge, 2-4 parts of cement, 18-20 parts of cinder of electric power plant, 2-3 parts of carborundum, clay 13-15
Part, 7-9 parts of sepiolite, 3-5 parts of diatomite, epoxy resin 17-20 parts phenol aldehyde modified, 5-6 parts of starch.
A kind of preparation method that high resistance to compression water-permeable brick is mixed with using municipal sludge and cinder of electric power plant, including following preparation
Step:Clay and municipal sludge are put at 80 DEG C and dried, is cooled to room temperature and is sent into grinder, add phosphorus slag, Power Plant Ash
Slag, carborundum, sepiolite, diatomite mixed grinding are uniform;Then add in mortar mixer, continue to add cement, starch, phenol
Aldehyde modified epoxy, stirs 30 minutes, the mixture being stirred is inserted in mould, and dry idiosome, is put into high temperature furnace and forges
Burn, 750 DEG C of calcining heat, cooled to room temperature discharging.
It is an advantage of the invention that:
(1)Municipal sludge and cinder of electric power plant are prepared into water-permeable brick, two kinds of discarded object synthesis are converted into the Building wood of clean environment firendly
Material.
(2)It with the addition of cement, clay, starch, phenol aldehyde modified epoxy resin in water-permeable brick, play unexpected association
Same-action, improves the compression strength of brick.
(3)Carborundum, sepiolite, diatomaceous mixture are added in water-permeable brick as aggregate, is played unexpectedly
Synergistic effect, improve the compression strength of brick.
(4)Additive is not not added with concrete, reduces production cost.
Specific embodiment mode
Municipal sludge is derived from the liquid sludge of Wuhan City thing lake sewage treatment plant, and cinder of electric power plant is derived from Hanchuan City thermal power generation
Factory.
Embodiment 1:
Take 20 parts of phosphorus slag, 13 parts of municipal sludge, 2 parts of cement, 18 parts of cinder of electric power plant, 2 parts of carborundum, 13 parts of clay, sepiolite 7
Part, 3 parts of diatomite, 17 parts of phenol aldehyde modified epoxy resin, 5 parts of starch, obtain after drying, grind, stir, dry, calcine
Water-permeable brick.
Embodiment 2:
Take 22 parts of phosphorus slag, 15 parts of municipal sludge, 4 parts of cement, 20 parts of cinder of electric power plant, 3 parts of carborundum, 15 parts of clay, sepiolite 9
Part, 5 parts of diatomite, 20 parts of phenol aldehyde modified epoxy resin, 6 parts of starch, obtain after drying, grind, stir, dry, calcine
Water-permeable brick.
Embodiment 3:
Take 21 parts of phosphorus slag, 14 parts of municipal sludge, 3 parts of cement, 19 parts of cinder of electric power plant, 3 parts of carborundum, 14 parts of clay, sepiolite 8
Part, 4 parts of diatomite, 18 parts of phenol aldehyde modified epoxy resin, 6 parts of starch, obtain after drying, grind, stir, dry, calcine
Water-permeable brick.
Comparative example 1:
14 parts of municipal sludge, 19 parts of cinder of electric power plant, 9 parts of outer adding assistant.
The coating of embodiment 1-3 and the gained of comparative example 1 are subjected to performance comparison, test result is shown in Table 1.
Table 1
Sample | Compression strength(MPa) | Flexural strength(MPa) | Coefficient of permeability(*10-2cm/s) |
Embodiment 1 | 57.2 | 5.1 | 6.0 |
Embodiment 2 | 58.4 | 5.3 | 5.4 |
Embodiment 3 | 60.1 | 6.2 | 6.8 |
Comparative example 1 | 28.6 | 3.2 | 1.3 |
Claims (3)
- A kind of 1. high resistance to compression water-permeable brick prepared using municipal sludge and cinder of electric power plant, it is characterised in that:The water-permeable brick is under The raw material of row parts by weight is made:20-22 parts of phosphorus slag, 13-15 parts of municipal sludge, 2-4 parts of cement, 18-20 parts of cinder of electric power plant, carbonization 2-3 parts of silicon, 13-15 parts of clay, 7-9 parts of sepiolite, 3-5 parts of diatomite, epoxy resin 17-20 parts phenol aldehyde modified, starch 5-6 Part.
- 2. water-permeable brick according to claim 1, it is characterised in that:The water-permeable brick is made from the following raw materials in parts by weight: 21 parts of phosphorus slag, 14 parts of municipal sludge, 3 parts of cement, 19 parts of cinder of electric power plant, 3 parts of carborundum, 14 parts of clay, 8 parts of sepiolite, diatom 4 parts of soil, 18 parts of phenol aldehyde modified epoxy resin, 6 parts of starch.
- It is 3. a kind of such as the preparation method of claim 1-2 any one of them water-permeable bricks, it is characterised in that:Step is prepared including following Suddenly:Clay and municipal sludge are put at 80 DEG C and dried, be cooled to room temperature be sent into grinder in, add phosphorus slag, cinder of electric power plant, Carborundum, sepiolite, diatomite mixed grinding are uniform;Then add in mortar mixer, continue to add cement, starch, phenolic aldehyde Modified epoxy, stirs 30 minutes, the mixture being stirred is inserted in mould, and dry idiosome, is put into high temperature furnace and calcines, 750 DEG C of calcining heat, cooled to room temperature discharging.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201610943220.7A CN107986754A (en) | 2016-10-26 | 2016-10-26 | A kind of high resistance to compression water-permeable brick prepared using municipal sludge and cinder of electric power plant |
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CN201610943220.7A CN107986754A (en) | 2016-10-26 | 2016-10-26 | A kind of high resistance to compression water-permeable brick prepared using municipal sludge and cinder of electric power plant |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108585783A (en) * | 2018-06-29 | 2018-09-28 | 陈雨 | A kind of environmental protection and energy saving brick |
CN112358255A (en) * | 2020-10-29 | 2021-02-12 | 荆门市意祥机械有限公司 | Environment-friendly water permeable brick and preparation method thereof |
-
2016
- 2016-10-26 CN CN201610943220.7A patent/CN107986754A/en active Pending
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108585783A (en) * | 2018-06-29 | 2018-09-28 | 陈雨 | A kind of environmental protection and energy saving brick |
CN112358255A (en) * | 2020-10-29 | 2021-02-12 | 荆门市意祥机械有限公司 | Environment-friendly water permeable brick and preparation method thereof |
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