CN107956131A - A kind of big suede degreasing deodorization process of grey goose based on bioenzyme washing method - Google Patents
A kind of big suede degreasing deodorization process of grey goose based on bioenzyme washing method Download PDFInfo
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- CN107956131A CN107956131A CN201711121963.7A CN201711121963A CN107956131A CN 107956131 A CN107956131 A CN 107956131A CN 201711121963 A CN201711121963 A CN 201711121963A CN 107956131 A CN107956131 A CN 107956131A
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M19/00—Treatment of feathers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38618—Protease or amylase in liquid compositions only
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38627—Preparations containing enzymes, e.g. protease or amylase containing lipase
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38663—Stabilised liquid enzyme compositions
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L1/00—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L1/00—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods
- D06L1/22—Processes involving successive treatments with aqueous and organic agents
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
- D06M16/003—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic with enzymes or microorganisms
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- Oil, Petroleum & Natural Gas (AREA)
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- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
The invention discloses a kind of big suede degreasing deodorization process of grey goose based on bioenzyme washing method, it is related to natural feather washing technology field, comprises the following steps：(1) pre-process, (2) complex enzyme degreasing, (3) clear water rinsings, (4) deodorization and washing, (5) secondary clear water rinsing, (6) are dry.The present invention is using compound enzyme washing as main cleaning way, by the synergistic effect of lipase, amylase, acid protease with fat and greasy dirt unnecessary in tydrophilization down fiber, so as to remove the dirt and yellow enzyme spot remained on down fiber；Strength protection is played to the keratin of down fiber at the same time, chemical damage will not be produced to down fiber, that reduces down fiber in cleaning process washes damage, and it is vivid fresh that imparting natural feather gloss and elasticity moisten hair color.
Description
Technical field：
The present invention relates to natural feather washing technology field, and in particular to a kind of big suede degreasing of grey goose based on bioenzyme washing method
Deodorization process.
Background technology：
Natural feather is to grow to be feather in the lupine-like fine hair of the belly of geese and ducks, slabbing.Since natural feather is a kind of dynamic
Physical property protein fibre, the tiny stomata for ten million triangle that gathers on natural feather nodular fibrous, can shrink swollen with temperature Change
It is swollen, temperature adjustment function is produced, absorbable human body distributes the hot gas of flowing, completely cuts off the invasion of cool ambient air.From the detection of fluffy degree
On analyze, natural feather than the heat insulating materials such as silk, cotton will a high grade, so natural feather is purely by way of a warming material
Material, its economic value are significantly larger than other heat insulating materials.Big suede belongs to the elite in natural feather, since it is difficult to separate and counts
Amount is seldom, therefore the higher price in natural feather.Big suede is divided into several grades, big good suede fluffy degree and warmth retention property pole
It is good, it is applied to the processing of high-grade down products.
Washing is the important procedure in down fiber preparatory processing, is utilization and improves the product quality and safety
Basis, the native miscellaneous and grease by removing feather surface enables the quality of feather fiber and security reaches consumer will
Ask.The washing methods and process conditions of down fiber directly influence washing effect.At present, the method for natural feather washing is still mainly adopted
With chemical washing method, fat and greasy dirt unnecessary in tydrophilization down fiber in washing process, removing remain in natural feather fibre
Dirt and yellow enzyme spot in dimension, while strength protection is served to the keratin of down fiber, down fiber will not be produced
Chemical damage, it is possible to reduce down fiber washes damage, has the effect of antistatic and strong bactericidal concurrently.Gloss and bullet can be improved after washing
Property, hair color moistening is vivid fresh, and fat content is moderate.But the harm of chemical detergent is also it is well known that the table of early application
Face activating agent such as sodium alkyl benzene sulfonate (ABS) is not easily decomposed, and retention time is longer in the environment.Later people have used straight chain alkane instead
Base benzene sulfonic acid sodium salt (LAS), situation have change quickly.ABS and LAS is required for phosphate as increasing net agent.And phosphate is discharged into
Water body, is a major reason for causing eutrophication pollution.In addition, detergent can make oil product, the more chlorine into water body
The organic matters such as biphenyl disperse because of emulsification, and great difficulty is brought to wastewater treatment.
The content of the invention：
The technical problems to be solved by the invention be to provide it is a kind of it is safe to use, cleaning performance is good and can effectively protect
Protect big suede degreasing deodorization process of grey goose based on bioenzyme washing method of down fiber structure.
The technical problems to be solved by the invention are realized using following technical solution：
A kind of big suede degreasing deodorization process of grey goose based on bioenzyme washing method, comprises the following steps：
(1) pre-process：Big suede of grey goose is added in clear water, big suede of grey goose is fully infiltrated by stirring, soaking water
Temperature maintains 25-35 DEG C, soaking time 15-30min, then big suede of grey goose after immersion is pulled out, is rinsed after tiling with clear water
3-5min, tile thickness 5-10cm, that is, completes the pretreatment of big suede of grey goose；
(2) complex enzyme degreasing：Grey big suede of goose after pretreatment is transferred in enzyme washing lotion, big of grey goose is made by stirring
Suede is totally submerged in enzyme washing lotion, and the complex enzyme being made of lipase, amylase, acid protease is added in enzyme washing lotion, and enzyme is washed
The control of liquid pH value maintains 60-70 DEG C in 6-8, temperature, and enzyme washes time 35-45min, and enzyme pulls big suede of grey goose out after washing；
(3) clear water rinsings：Big suede of grey goose after compound enzyme washing is rinsed twice using clear water, it is unnecessary to drain
Moisture；
(4) deodorization and washing：Big suede of grey goose after a clear water rinses is transferred in deodorant liquid, grey goose is made by stirring
Big suede is totally submerged in deodorant liquid made of adding water by deodorant, and the control of deodorant liquid pH value maintains 45- in 6-8, temperature
55 DEG C, deodorization time 5-10min, pull big suede of grey goose after deodorization out；
(5) secondary clear water rinsing：Big suede of grey goose after deodorization and washing is rinsed twice using clear water, drains superfluous water
Point；
(6) it is dry：Big suede of grey goose after rinsing is transferred in dryer, is first warming up to preliminary drying 5- at 45-55 DEG C
10min, then rise to 70-80 DEG C drying to constant weight, that is, complete the washing of big suede of grey goose.
The lipase, amylase, the amount ratio of acid protease are 1-2:1-2:1-2, preferably 2:1:1.
Complex enzyme additive amount is 400-500u/g, preferably 400u/g in the enzyme washing lotion.
Deodorization agent concentration is 1-5g/L in the deodorant liquid.
The deodorant is made of the plant component of following parts by weight：Fresh 5-10 parts of Mi leaves, it is Folium sophorae 5-10 parts fresh,
1-5 parts of poloxamer188,1-5 parts of fresh wormwood leaf, 1-5 parts of fresh oriental wormwood grass, castor leaf 1-5 parts fresh, 1-5 parts of fresh pepper leaf, eucalyptus
0.05-0.5 parts of leaf oil, 0.05-0.5 parts of patchouli oil, its specific preparation method are：First by fresh Mi leaves, fresh Folium sophorae, fresh Chinese mugwort
Added after blade of grass, fresh oriental wormwood be careless, fresh castor leaf, fresh pepper leaf crush in the water of 2 times of gross weights, through power 1.5kW paste mill grindings
30-45min, filtering, gained filtrate is freeze-dried to the 1/3 of original volume, up to material II；Then by material I, material II,
Poloxamer188, eucalyptus oil and patchouli oil are sent into spray dryer after being sufficiently mixed, and dry gained particle is through ultramicro grinding
Micro mist is made in machine, up to deodorant.
Water-based builder is added in the pretreatment during cleaning and dipping, the mass ratio of clear water and water-based builder is 100-
200:5-10, preferably 200:5.
The water-based builder is through esterification system by sodium gluconate and hydroxyethyl cellulose, hydrolysis of polymaleic anhydride
Into its specific preparation method is：Clear water is added dropwise until being completely dissolved into sodium gluconate under stirring, and dilute sulfuric acid adjusting is added dropwise
Solution ph stabilization adds hydroxyethyl cellulose, adding water is completely dissolved hydroxyethyl cellulose, is heated to back in 5-5.5
Stream mode insulated and stirred 0.5-2h, then adds hydrolysis of polymaleic anhydride, and adding water again makes hydrolysis of polymaleic anhydride completely molten
Solution, continues the insulated and stirred 1-3h that flows back, and gained mixture reaches 65-75% through being concentrated under reduced pressure into solid content, and gained lotion is natural
It is sent into after being cooled to room temperature in freeze drier, micro mist is made through micronizer in dry obtained solid, up to water-based builder.
The sodium gluconate, hydroxyethyl cellulose, the mass ratio of hydrolysis of polymaleic anhydride are 5-10:0.5-3:1-5.
The beneficial effects of the invention are as follows：
(1) present invention tentatively cleans natural feather using water-based builder in pretreatment, is remained in effective removing
Dust on down fiber, and realize at the same time and the preliminary of grease on down fiber is removed, so as to cooperate with compound enzyme washing with aobvious
Write the cleaning performance improved to down fiber；
(2) present invention passes through the collaboration of lipase, amylase, acid protease using compound enzyme washing as main cleaning way
Effect is with fat and greasy dirt unnecessary in tydrophilization down fiber, so as to remove the dirt and yellow enzyme remained on down fiber
Spot；Strength protection is played to the keratin of down fiber at the same time, chemical damage will not be produced to down fiber, reduce cleaning
During down fiber wash damage, to assign natural feather gloss and elasticity make hair color moistening vivid fresh；
(3) deodorant of the present invention is cooperateed with to play deodouring effect using natural plant composition as raw material through various plants composition,
The natural feather after processing is carried light fragrance on the contrary completely without peculiar smell, avoid asking using contaminated wastewater existing for chemical classes deodorant
Topic, and improve the safety in utilization of deodorant.
Embodiment：
In order to make the technical means, the creative features, the aims and the efficiencies achieved by the present invention easy to understand, tie below
Specific embodiment is closed, the present invention is further explained.
Embodiment 1
(1) pre-process：Big suede of grey goose is added in clear water, big suede of grey goose is fully infiltrated by stirring, soaking water
Temperature maintains 25-35 DEG C, soaking time 15min, then big suede of grey goose after immersion is pulled out, is rinsed after tiling with clear water
5min, tile thickness 5-10cm, that is, completes the pretreatment of big suede of grey goose；
(2) complex enzyme degreasing：Grey big suede of goose after pretreatment is transferred in enzyme washing lotion, big of grey goose is made by stirring
Suede is totally submerged in enzyme washing lotion, and the complex enzyme being made of lipase, amylase, acid protease is added in enzyme washing lotion, and enzyme is washed
The control of liquid pH value maintains 60-70 DEG C in 6-8, temperature, and enzyme washes time 35min, and enzyme pulls big suede of grey goose out after washing；
(3) clear water rinsings：Big suede of grey goose after compound enzyme washing is rinsed twice using clear water, it is unnecessary to drain
Moisture；
(4) deodorization and washing：Big suede of grey goose after a clear water rinses is transferred in deodorant liquid, grey goose is made by stirring
Big suede is totally submerged in deodorant liquid made of adding water by deodorant, and the control of deodorant liquid pH value maintains 45- in 6-8, temperature
55 DEG C, deodorization time 10min, pull big suede of grey goose after deodorization out；
(5) secondary clear water rinsing：Big suede of grey goose after deodorization and washing is rinsed twice using clear water, drains superfluous water
Point；
(6) it is dry：Big suede of grey goose after rinsing is transferred in dryer, is first warming up to preliminary drying 5min at 45-55 DEG C, then
Rising to 70-80 DEG C, drying to constant weight, that is, completes the washing of big suede of grey goose.
Wherein, lipase, amylase, the amount ratio of acid protease are 2:1:1, complex enzyme additive amount is in enzyme washing lotion
400u/g, deodorization agent concentration is 2g/L in deodorant liquid.
The preparation of deodorant：First by the fresh Mi leaves of 10g, the fresh Folium sophoraes of 5g, the fresh wormwood leaves of 3g, the fresh oriental wormwood grass of 3g, the fresh castors of 2g
Sesame slices, 1g fresh pepper leaves are added in the water of 2 times of gross weights after crushing, through power 1.5kW paste mill grinding 30min, filtering, gained filter
Liquid is freeze-dried to the 1/3 of original volume, up to material II；Then by material I, material II, 5g poloxamer188,0.5g eucalyptus
Leaf oil and 0.3g patchouli oils are sent into spray dryer after being sufficiently mixed, and dry gained particle is made micro- through micronizer
Powder, up to deodorant.
Embodiment 2
(1) pre-process：Big suede of grey goose is added in clear water, big suede of grey goose is fully infiltrated by stirring, soaking water
Temperature maintains 25-35 DEG C, soaking time 15min, then big suede of grey goose after immersion is pulled out, is rinsed after tiling with clear water
5min, tile thickness 5-10cm, that is, completes the pretreatment of big suede of grey goose；
(2) complex enzyme degreasing：Grey big suede of goose after pretreatment is transferred in enzyme washing lotion, big of grey goose is made by stirring
Suede is totally submerged in enzyme washing lotion, and the complex enzyme being made of lipase, amylase, acid protease is added in enzyme washing lotion, and enzyme is washed
The control of liquid pH value maintains 60-70 DEG C in 6-8, temperature, and enzyme washes time 35min, and enzyme pulls big suede of grey goose out after washing；
(3) clear water rinsings：Big suede of grey goose after compound enzyme washing is rinsed twice using clear water, it is unnecessary to drain
Moisture；
(4) deodorization and washing：Big suede of grey goose after a clear water rinses is transferred in deodorant liquid, grey goose is made by stirring
Big suede is totally submerged in deodorant liquid made of adding water by deodorant, and the control of deodorant liquid pH value maintains 45- in 6-8, temperature
55 DEG C, deodorization time 10min, pull big suede of grey goose after deodorization out；
(5) secondary clear water rinsing：Big suede of grey goose after deodorization and washing is rinsed twice using clear water, drains superfluous water
Point；
(6) it is dry：Big suede of grey goose after rinsing is transferred in dryer, is first warming up to preliminary drying 5min at 45-55 DEG C, then
Rising to 70-80 DEG C, drying to constant weight, that is, completes the washing of big suede of grey goose.
Wherein, lipase, amylase, the amount ratio of acid protease are 2:1:1, complex enzyme additive amount is in enzyme washing lotion
400u/g, deodorization agent concentration is 2g/L in deodorant liquid.
The preparation of deodorant：First by the fresh Mi leaves of 5g, the fresh Folium sophoraes of 5g, the fresh wormwood leaves of 3g, the fresh oriental wormwood grass of 2g, the fresh castor-oil plants of 1g
Leaf, 1g fresh pepper leaves are added in the water of 2 times of gross weights after crushing, through power 1.5kW paste mill grinding 30min, filtering, gained filtrate
It is freeze-dried to the 1/3 of original volume, up to material II；Then by material I, material II, 3g poloxamer188,0.5g folium eucalyptis
Oil and 0.2g patchouli oils are sent into spray dryer after being sufficiently mixed, and micro mist is made through micronizer in dry gained particle,
Up to deodorant.
Embodiment 3
(1) pre-process：Big suede of grey goose is added in clear water, big suede of grey goose is fully infiltrated by stirring, soaking water
Temperature maintains 25-35 DEG C, soaking time 15min, then big suede of grey goose after immersion is pulled out, is rinsed after tiling with clear water
5min, tile thickness 5-10cm, that is, completes the pretreatment of big suede of grey goose；
(2) complex enzyme degreasing：Grey big suede of goose after pretreatment is transferred in enzyme washing lotion, big of grey goose is made by stirring
Suede is totally submerged in enzyme washing lotion, and the complex enzyme being made of lipase, amylase, acid protease is added in enzyme washing lotion, and enzyme is washed
The control of liquid pH value maintains 60-70 DEG C in 6-8, temperature, and enzyme washes time 35min, and enzyme pulls big suede of grey goose out after washing；
(3) clear water rinsings：Big suede of grey goose after compound enzyme washing is rinsed twice using clear water, it is unnecessary to drain
Moisture；
(4) deodorization and washing：Big suede of grey goose after a clear water rinses is transferred in deodorant liquid, grey goose is made by stirring
Big suede is totally submerged in deodorant liquid made of adding water by deodorant, and the control of deodorant liquid pH value maintains 45- in 6-8, temperature
55 DEG C, deodorization time 10min, pull big suede of grey goose after deodorization out；
(5) secondary clear water rinsing：Big suede of grey goose after deodorization and washing is rinsed twice using clear water, drains superfluous water
Point；
(6) it is dry：Big suede of grey goose after rinsing is transferred in dryer, is first warming up to preliminary drying 5min at 45-55 DEG C, then
Rising to 70-80 DEG C, drying to constant weight, that is, completes the washing of big suede of grey goose.
Wherein, lipase, amylase, the amount ratio of acid protease are 2:1:1, complex enzyme additive amount is in enzyme washing lotion
400u/g, deodorization agent concentration is 2g/L in deodorant liquid.
The preparation of deodorant：First by the fresh Mi leaves of 10g, the fresh Folium sophoraes of 5g, the fresh wormwood leaves of 3g, the fresh oriental wormwood grass of 3g, the fresh castors of 2g
Sesame slices, 1g fresh pepper leaves are added in the water of 2 times of gross weights after crushing, through power 1.5kW paste mill grinding 30min, filtering, gained filter
Liquid is freeze-dried to the 1/3 of original volume, up to material II；Then by material I, material II, 5g poloxamer188,0.5g eucalyptus
Leaf oil and 0.3g patchouli oils are sent into spray dryer after being sufficiently mixed, and dry gained particle is made micro- through micronizer
Powder, up to deodorant.
The preparation of water-based builder：Clear water is added dropwise until being completely dissolved into 10g sodium gluconates under stirring, and is added dropwise dilute
Sulfuric acid regulation solution pH stable adds 2g hydroxyethyl celluloses, adding water makes hydroxyethyl cellulose completely molten in 5-5.5
Solution, is heated to reflux state insulated and stirred 1h, then adds 3g hydrolysis of polymaleic anhydride, adding water again makes hydrolyzed polymaleic anhydride
Acid anhydride is completely dissolved, and continues the insulated and stirred 1h that flows back, and gained mixture reaches 65-75%, gained cream through being concentrated under reduced pressure into solid content
It is sent into after body cooled to room temperature in freeze drier, micro mist is made through micronizer in dry obtained solid, up to water-based
Builder.
Embodiment 4
(1) pre-process：Big suede of grey goose is added in clear water, big suede of grey goose is fully infiltrated by stirring, soaking water
Temperature maintains 25-35 DEG C, soaking time 15min, then big suede of grey goose after immersion is pulled out, is rinsed after tiling with clear water
5min, tile thickness 5-10cm, that is, completes the pretreatment of big suede of grey goose；
(2) complex enzyme degreasing：Grey big suede of goose after pretreatment is transferred in enzyme washing lotion, big of grey goose is made by stirring
Suede is totally submerged in enzyme washing lotion, and the complex enzyme being made of lipase, amylase, acid protease is added in enzyme washing lotion, and enzyme is washed
The control of liquid pH value maintains 60-70 DEG C in 6-8, temperature, and enzyme washes time 35min, and enzyme pulls big suede of grey goose out after washing；
(3) clear water rinsings：Big suede of grey goose after compound enzyme washing is rinsed twice using clear water, it is unnecessary to drain
Moisture；
(4) deodorization and washing：Big suede of grey goose after a clear water rinses is transferred in deodorant liquid, grey goose is made by stirring
Big suede is totally submerged in deodorant liquid made of adding water by deodorant, and the control of deodorant liquid pH value maintains 45- in 6-8, temperature
55 DEG C, deodorization time 10min, pull big suede of grey goose after deodorization out；
(5) secondary clear water rinsing：Big suede of grey goose after deodorization and washing is rinsed twice using clear water, drains superfluous water
Point；
(6) it is dry：Big suede of grey goose after rinsing is transferred in dryer, is first warming up to preliminary drying 5min at 45-55 DEG C, then
Rising to 70-80 DEG C, drying to constant weight, that is, completes the washing of big suede of grey goose.
Wherein, lipase, amylase, the amount ratio of acid protease are 2:1:1, complex enzyme additive amount is in enzyme washing lotion
400u/g, deodorization agent concentration is 2g/L in deodorant liquid.
The preparation of deodorant：First by the fresh Mi leaves of 5g, the fresh Folium sophoraes of 5g, the fresh wormwood leaves of 3g, the fresh oriental wormwood grass of 2g, the fresh castor-oil plants of 1g
Leaf, 1g fresh pepper leaves are added in the water of 2 times of gross weights after crushing, through power 1.5kW paste mill grinding 30min, filtering, gained filtrate
It is freeze-dried to the 1/3 of original volume, up to material II；Then by material I, material II, 3g poloxamer188,0.5g folium eucalyptis
Oil and 0.2g patchouli oils are sent into spray dryer after being sufficiently mixed, and micro mist is made through micronizer in dry gained particle,
Up to deodorant.
The preparation of water-based builder：Clear water is added dropwise until being completely dissolved into 8g sodium gluconates under stirring, and is added dropwise dilute
Sulfuric acid regulation solution pH stable adds 1g hydroxyethyl celluloses, adding water makes hydroxyethyl cellulose completely molten in 5-5.5
Solution, is heated to reflux state insulated and stirred 1h, then adds 2g hydrolysis of polymaleic anhydride, adding water again makes hydrolyzed polymaleic anhydride
Acid anhydride is completely dissolved, and continues the insulated and stirred 1.5h that flows back, and gained mixture reaches 65-75%, gained through being concentrated under reduced pressure into solid content
It is sent into after lotion cooled to room temperature in freeze drier, micro mist is made through micronizer in dry obtained solid, up to water
Property builder.
Reference examples 1
(1) pre-process：Big suede of grey goose is added in clear water, big suede of grey goose is fully infiltrated by stirring, soaking water
Temperature maintains 25-35 DEG C, soaking time 15min, then big suede of grey goose after immersion is pulled out, is rinsed after tiling with clear water
5min, tile thickness 5-10cm, that is, completes the pretreatment of big suede of grey goose；
(2) complex enzyme degreasing：Grey big suede of goose after pretreatment is transferred in enzyme washing lotion, big of grey goose is made by stirring
Suede is totally submerged in enzyme washing lotion, and lipase is added in enzyme washing lotion, and the control of enzyme washing lotion pH value maintains 60-70 in 6-8, temperature
DEG C, enzyme washes time 35min, and enzyme pulls big suede of grey goose out after washing；
(3) clear water rinsings：Big suede of grey goose after compound enzyme washing is rinsed twice using clear water, it is unnecessary to drain
Moisture；
(4) deodorization and washing：Big suede of grey goose after a clear water rinses is transferred in deodorant liquid, grey goose is made by stirring
Big suede is totally submerged in deodorant liquid made of adding water by deodorant, and the control of deodorant liquid pH value maintains 45- in 6-8, temperature
55 DEG C, deodorization time 10min, pull big suede of grey goose after deodorization out；
(5) secondary clear water rinsing：Big suede of grey goose after deodorization and washing is rinsed twice using clear water, drains superfluous water
Point；
(6) it is dry：Big suede of grey goose after rinsing is transferred in dryer, is first warming up to preliminary drying 5min at 45-55 DEG C, then
Rising to 70-80 DEG C, drying to constant weight, that is, completes the washing of big suede of grey goose.
Wherein, lipase additive amount is 400u/g in enzyme washing lotion, and deodorization agent concentration is 2g/L in deodorant liquid.
The preparation of deodorant：First by the fresh Mi leaves of 10g, the fresh Folium sophoraes of 5g, the fresh wormwood leaves of 3g, the fresh oriental wormwood grass of 3g, the fresh castors of 2g
Sesame slices, 1g fresh pepper leaves are added in the water of 2 times of gross weights after crushing, through power 1.5kW paste mill grinding 30min, filtering, gained filter
Liquid is freeze-dried to the 1/3 of original volume, up to material II；Then by material I, material II, 5g poloxamer188,0.5g eucalyptus
Leaf oil and 0.3g patchouli oils are sent into spray dryer after being sufficiently mixed, and dry gained particle is made micro- through micronizer
Powder, up to deodorant.
Reference examples 2
(1) pre-process：Big suede of grey goose is added in clear water, big suede of grey goose is fully infiltrated by stirring, soaking water
Temperature maintains 25-35 DEG C, soaking time 15min, then big suede of grey goose after immersion is pulled out, is rinsed after tiling with clear water
5min, tile thickness 5-10cm, that is, completes the pretreatment of big suede of grey goose；
(2) complex enzyme degreasing：Grey big suede of goose after pretreatment is transferred in enzyme washing lotion, big of grey goose is made by stirring
Suede is totally submerged in enzyme washing lotion, and the complex enzyme being made of lipase, amylase, acid protease is added in enzyme washing lotion, and enzyme is washed
The control of liquid pH value maintains 60-70 DEG C in 6-8, temperature, and enzyme washes time 35min, and enzyme pulls big suede of grey goose out after washing；
(3) clear water rinses：Big suede of grey goose after compound enzyme washing is rinsed twice using clear water, drains superfluous water
Point；
(4) it is dry：Big suede of grey goose after rinsing is transferred in dryer, is first warming up to preliminary drying 5min at 45-55 DEG C, then
Rising to 70-80 DEG C, drying to constant weight, that is, completes the washing of big suede of grey goose.
Wherein, lipase, amylase, the amount ratio of acid protease are 2:1:1, complex enzyme additive amount is in enzyme washing lotion
400u/g, deodorization agent concentration is 2g/L in deodorant liquid.
Embodiment 5
Technique described in embodiment 1-4, reference examples 1-2 is utilized respectively to being washed with batch big suede of equivalent ash goose, and is surveyed
Determine washing effect, the results are shown in Table 1.
The washing effect of the present invention of table 1 big suede of grey goose
| Group | Dust removal efficiency/% | Degreasing rate/% | Whiteness | Deodorizing rate/% |
| Embodiment 1 | 96.4 | 95.9 | 92.8 | 97.7 |
| Embodiment 2 | 96.2 | 96.5 | 93.1 | 97.9 |
| Embodiment 3 | 99.9 | 99.3 | 95.4 | 98.2 |
| Embodiment 4 | 99.9 | 99.4 | 95.6 | 98.3 |
| Reference examples 1 | 94.3 | 89.6 | 87.5 | 96.8 |
| Reference examples 2 | 93.9 | 94.2 | 91.3 | 65.6 |
The basic principles, main features and the advantages of the invention have been shown and described above.The technology of the industry
Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and the above embodiments and description only describe this
The principle of invention, without departing from the spirit and scope of the present invention, various changes and modifications of the present invention are possible, these changes
Change and improvement all fall within the protetion scope of the claimed invention.The claimed scope of the invention by appended claims and its
Equivalent thereof.
Claims (7)
1. big suede degreasing deodorization process of a kind of grey goose based on bioenzyme washing method, it is characterised in that comprise the following steps：
(1) pre-process：Big suede of grey goose is added in clear water, big suede of grey goose is fully infiltrated by stirring, immersion water temperature dimension
Hold at 25-35 DEG C, soaking time 15-30min, then big suede of grey goose after immersion is pulled out, 3- is rinsed with clear water after tiling
5min, tile thickness 5-10cm, that is, completes the pretreatment of big suede of grey goose；
(2) complex enzyme degreasing：Grey big suede of goose after pretreatment is transferred in enzyme washing lotion, makes big suede of grey goose complete by stirring
It is immersed in entirely in enzyme washing lotion, the complex enzyme being made of lipase, amylase, acid protease, enzyme washing lotion pH is added in enzyme washing lotion
Value control maintains 60-70 DEG C in 6-8, temperature, and enzyme washes time 35-45min, and enzyme pulls big suede of grey goose out after washing；
(3) clear water rinsings：Big suede of grey goose after compound enzyme washing is rinsed twice using clear water, drains superfluous water
Point；
(4) deodorization and washing：Big suede of grey goose after a clear water rinses is transferred in deodorant liquid, big of grey goose is made by stirring
Suede is totally submerged in deodorant liquid made of adding water by deodorant, and the control of deodorant liquid pH value maintains 45-55 DEG C in 6-8, temperature,
Deodorization time 5-10min, pulls big suede of grey goose out after deodorization；
(5) secondary clear water rinsing：Big suede of grey goose after deodorization and washing is rinsed twice using clear water, drains excessive moisture；
(6) it is dry：Big suede of grey goose after rinsing is transferred in dryer, is first warming up to preliminary drying 5-10min at 45-55 DEG C, then
Rising to 70-80 DEG C, drying to constant weight, that is, completes the washing of big suede of grey goose.
2. big suede degreasing deodorization process of the grey goose according to claim 1 based on bioenzyme washing method, it is characterised in that：Institute
It is 1-2 to state lipase, amylase, the amount ratio of acid protease:1-2:1-2.
3. big suede degreasing deodorization process of the grey goose according to claim 2 based on bioenzyme washing method, it is characterised in that：Institute
State the amount ratio preferably 2 of lipase, amylase, acid protease:1:1.
4. big suede degreasing deodorization process of the grey goose according to claim 1 based on bioenzyme washing method, it is characterised in that：Institute
It is 400-500u/g to state complex enzyme additive amount in enzyme washing lotion.
5. big suede degreasing deodorization process of the grey goose according to claim 4 based on bioenzyme washing method, it is characterised in that：Institute
State the preferred 400u/g of complex enzyme additive amount in enzyme washing lotion.
6. big suede degreasing deodorization process of the grey goose according to claim 1 based on bioenzyme washing method, it is characterised in that：Institute
It is 1-5g/L to state deodorization agent concentration in deodorant liquid.
7. big suede degreasing deodorization process of the grey goose according to claim 1 based on bioenzyme washing method, it is characterised in that：Institute
Deodorant is stated to be made of the plant component of following parts by weight：Fresh 5-10 parts of Mi leaves, Folium sophorae 5-10 parts fresh, poloxamer
407 1-5 parts, 1-5 parts of fresh wormwood leaf, 1-5 parts of fresh oriental wormwood grass, castor leaf 1-5 parts fresh, 1-5 parts of fresh pepper leaf, eucalyptus oil 0.05-
0.5 part, 0.05-0.5 parts of patchouli oil, its specific preparation method are：First by fresh Mi leaves, fresh Folium sophorae, fresh wormwood leaf, fresh mattress
Old careless, fresh castor leaf, fresh pepper leaf are added in the water of 2 times of gross weights after crushing, through power 1.5kW paste mill grinding 30-45min,
Filtering, gained filtrate is freeze-dried to the 1/3 of original volume, up to material II；Then by material I, material II, poloxamer
407th, it is sent into after eucalyptus oil and patchouli oil are sufficiently mixed in spray dryer, dry gained particle is made micro- through micronizer
Powder, up to deodorant.
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|---|---|---|---|---|
| CN110804506A (en) * | 2019-11-13 | 2020-02-18 | 领先生物农业股份有限公司 | Microbial wool detergent and using method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102444018A (en) * | 2011-10-26 | 2012-05-09 | 芜湖南翔羽绒有限公司 | Biochemical combination precision washing technology for eiderdown |
| CN103061153A (en) * | 2013-01-06 | 2013-04-24 | 安徽一隆羽绒有限公司 | Production process of sterilizing and mite-removing down |
-
2017
- 2017-11-14 CN CN201711121963.7A patent/CN107956131A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102444018A (en) * | 2011-10-26 | 2012-05-09 | 芜湖南翔羽绒有限公司 | Biochemical combination precision washing technology for eiderdown |
| CN103061153A (en) * | 2013-01-06 | 2013-04-24 | 安徽一隆羽绒有限公司 | Production process of sterilizing and mite-removing down |
Non-Patent Citations (3)
| Title |
|---|
| 中国石油化工集团公司人事教育部: "《多种经营企业产品手册》", 30 September 1998, 中国石化出版社 第1版 * |
| 周雍鑫等: "《润滑材料使用手册》", 30 April 1996, 上海科技技术出版社 第1版 * |
| 林春华等: "《简明表面处理工手册》", 28 February 1995, 机械工艺出版社 第1版 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110804506A (en) * | 2019-11-13 | 2020-02-18 | 领先生物农业股份有限公司 | Microbial wool detergent and using method thereof |
| CN110804506B (en) * | 2019-11-13 | 2021-06-01 | 领先生物农业股份有限公司 | Microbial wool detergent and using method thereof |
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