CN104188862A - Skin-protecting facial scrub and preparation method thereof - Google Patents
Skin-protecting facial scrub and preparation method thereof Download PDFInfo
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- CN104188862A CN104188862A CN201410430207.2A CN201410430207A CN104188862A CN 104188862 A CN104188862 A CN 104188862A CN 201410430207 A CN201410430207 A CN 201410430207A CN 104188862 A CN104188862 A CN 104188862A
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- water
- solution
- silk
- antiseptic
- skin protection
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- 238000002360 preparation method Methods 0.000 title claims abstract description 40
- 230000001815 facial effect Effects 0.000 title abstract 6
- 235000007164 Oryza sativa Nutrition 0.000 claims abstract description 134
- 235000009566 rice Nutrition 0.000 claims abstract description 134
- 238000005201 scrubbing Methods 0.000 claims abstract description 83
- 108010022355 Fibroins Proteins 0.000 claims abstract description 79
- 238000002156 mixing Methods 0.000 claims abstract description 13
- 239000007864 aqueous solution Substances 0.000 claims abstract description 9
- 241000209094 Oryza Species 0.000 claims description 133
- 239000000243 solution Substances 0.000 claims description 102
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 94
- 239000006071 cream Substances 0.000 claims description 83
- 239000010903 husk Substances 0.000 claims description 82
- 230000002421 anti-septic effect Effects 0.000 claims description 65
- 229920001661 Chitosan Polymers 0.000 claims description 39
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 claims description 39
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 36
- 238000003763 carbonization Methods 0.000 claims description 36
- 239000003292 glue Substances 0.000 claims description 35
- 239000000203 mixture Substances 0.000 claims description 24
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 claims description 24
- 239000003921 oil Substances 0.000 claims description 23
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 claims description 22
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 claims description 22
- 239000002537 cosmetic Substances 0.000 claims description 21
- 239000000835 fiber Substances 0.000 claims description 21
- 238000000034 method Methods 0.000 claims description 16
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 15
- 238000001816 cooling Methods 0.000 claims description 14
- 239000001913 cellulose Substances 0.000 claims description 12
- 229920002678 cellulose Polymers 0.000 claims description 12
- 230000008859 change Effects 0.000 claims description 12
- 150000001875 compounds Chemical class 0.000 claims description 12
- 238000000502 dialysis Methods 0.000 claims description 12
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 claims description 12
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 claims description 12
- 229940032094 squalane Drugs 0.000 claims description 12
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 claims description 11
- IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 claims description 11
- JOLVYUIAMRUBRK-UHFFFAOYSA-N 11',12',14',15'-Tetradehydro(Z,Z-)-3-(8-Pentadecenyl)phenol Natural products OC1=CC=CC(CCCCCCCC=CCC=CCC=C)=C1 JOLVYUIAMRUBRK-UHFFFAOYSA-N 0.000 claims description 11
- YLKVIMNNMLKUGJ-UHFFFAOYSA-N 3-Delta8-pentadecenylphenol Natural products CCCCCCC=CCCCCCCCC1=CC=CC(O)=C1 YLKVIMNNMLKUGJ-UHFFFAOYSA-N 0.000 claims description 11
- JOLVYUIAMRUBRK-UTOQUPLUSA-N Cardanol Chemical compound OC1=CC=CC(CCCCCCC\C=C/C\C=C/CC=C)=C1 JOLVYUIAMRUBRK-UTOQUPLUSA-N 0.000 claims description 11
- FAYVLNWNMNHXGA-UHFFFAOYSA-N Cardanoldiene Natural products CCCC=CCC=CCCCCCCCC1=CC=CC(O)=C1 FAYVLNWNMNHXGA-UHFFFAOYSA-N 0.000 claims description 11
- 244000178870 Lavandula angustifolia Species 0.000 claims description 11
- 235000010663 Lavandula angustifolia Nutrition 0.000 claims description 11
- 244000174681 Michelia champaca Species 0.000 claims description 11
- 235000021314 Palmitic acid Nutrition 0.000 claims description 11
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 11
- 239000004141 Sodium laurylsulphate Substances 0.000 claims description 11
- 235000021355 Stearic acid Nutrition 0.000 claims description 11
- 239000002253 acid Substances 0.000 claims description 11
- 150000007513 acids Chemical class 0.000 claims description 11
- PTFIPECGHSYQNR-UHFFFAOYSA-N cardanol Natural products CCCCCCCCCCCCCCCC1=CC=CC(O)=C1 PTFIPECGHSYQNR-UHFFFAOYSA-N 0.000 claims description 11
- 239000007766 cera flava Substances 0.000 claims description 11
- 239000012153 distilled water Substances 0.000 claims description 11
- 239000000428 dust Substances 0.000 claims description 11
- 239000003995 emulsifying agent Substances 0.000 claims description 11
- 239000000686 essence Substances 0.000 claims description 11
- 235000013312 flour Nutrition 0.000 claims description 11
- 239000003349 gelling agent Substances 0.000 claims description 11
- 229940075507 glyceryl monostearate Drugs 0.000 claims description 11
- 239000012535 impurity Substances 0.000 claims description 11
- 239000000787 lecithin Substances 0.000 claims description 11
- 235000010445 lecithin Nutrition 0.000 claims description 11
- 229940067606 lecithin Drugs 0.000 claims description 11
- 239000001788 mono and diglycerides of fatty acids Substances 0.000 claims description 11
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 claims description 11
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 11
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 11
- 229940055577 oleyl alcohol Drugs 0.000 claims description 11
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 claims description 11
- 150000002989 phenols Chemical class 0.000 claims description 11
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 11
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 11
- 239000003755 preservative agent Substances 0.000 claims description 11
- 230000002335 preservative effect Effects 0.000 claims description 11
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims description 11
- 235000019333 sodium laurylsulphate Nutrition 0.000 claims description 11
- 239000008117 stearic acid Substances 0.000 claims description 11
- 229940099259 vaseline Drugs 0.000 claims description 11
- 230000008569 process Effects 0.000 claims description 9
- 241000382353 Pupa Species 0.000 claims description 8
- 238000001035 drying Methods 0.000 claims description 8
- AMXOYNBUYSYVKV-UHFFFAOYSA-M lithium bromide Chemical compound [Li+].[Br-] AMXOYNBUYSYVKV-UHFFFAOYSA-M 0.000 claims description 8
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims description 4
- 239000001110 calcium chloride Substances 0.000 claims description 4
- 229910001628 calcium chloride Inorganic materials 0.000 claims description 4
- 238000010438 heat treatment Methods 0.000 claims description 4
- 230000007935 neutral effect Effects 0.000 claims description 4
- 239000008149 soap solution Substances 0.000 claims description 4
- 239000011734 sodium Substances 0.000 claims description 4
- 239000002904 solvent Substances 0.000 claims description 4
- -1 dialyse 3 Substances 0.000 claims description 3
- 230000000694 effects Effects 0.000 abstract description 34
- 239000000843 powder Substances 0.000 abstract description 5
- 240000007594 Oryza sativa Species 0.000 abstract 1
- 238000010000 carbonizing Methods 0.000 abstract 1
- 238000012216 screening Methods 0.000 abstract 1
- 235000019198 oils Nutrition 0.000 description 19
- 230000000844 anti-bacterial effect Effects 0.000 description 15
- 230000032683 aging Effects 0.000 description 12
- 210000000736 corneocyte Anatomy 0.000 description 11
- 230000002079 cooperative effect Effects 0.000 description 10
- 240000000560 Citrus x paradisi Species 0.000 description 6
- 230000001681 protective effect Effects 0.000 description 5
- 229930006000 Sucrose Natural products 0.000 description 4
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 4
- 235000013681 dietary sucrose Nutrition 0.000 description 4
- 238000002203 pretreatment Methods 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- 238000007789 sealing Methods 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 241000219122 Cucurbita Species 0.000 description 3
- 235000009852 Cucurbita pepo Nutrition 0.000 description 3
- 241000196324 Embryophyta Species 0.000 description 3
- JEIPFZHSYJVQDO-UHFFFAOYSA-N ferric oxide Chemical compound O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 3
- 239000011159 matrix material Substances 0.000 description 3
- 230000002087 whitening effect Effects 0.000 description 3
- GVJHHUAWPYXKBD-UHFFFAOYSA-N (±)-α-Tocopherol Chemical compound OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 description 2
- DHVLDKHFGIVEIP-UHFFFAOYSA-N 2-bromo-2-(bromomethyl)pentanedinitrile Chemical compound BrCC(Br)(C#N)CCC#N DHVLDKHFGIVEIP-UHFFFAOYSA-N 0.000 description 2
- 241000255789 Bombyx mori Species 0.000 description 2
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 description 2
- 239000004283 Sodium sorbate Substances 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 230000018044 dehydration Effects 0.000 description 2
- 238000006297 dehydration reaction Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000003020 moisturizing effect Effects 0.000 description 2
- 108090000623 proteins and genes Proteins 0.000 description 2
- 102000004169 proteins and genes Human genes 0.000 description 2
- LROWVYNUWKVTCU-STWYSWDKSA-M sodium sorbate Chemical compound [Na+].C\C=C\C=C\C([O-])=O LROWVYNUWKVTCU-STWYSWDKSA-M 0.000 description 2
- 235000019250 sodium sorbate Nutrition 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 239000000080 wetting agent Substances 0.000 description 2
- WSWCOQWTEOXDQX-MQQKCMAXSA-M (E,E)-sorbate Chemical compound C\C=C\C=C\C([O-])=O WSWCOQWTEOXDQX-MQQKCMAXSA-M 0.000 description 1
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 description 1
- OSDLLIBGSJNGJE-UHFFFAOYSA-N 4-chloro-3,5-dimethylphenol Chemical compound CC1=CC(O)=CC(C)=C1Cl OSDLLIBGSJNGJE-UHFFFAOYSA-N 0.000 description 1
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 1
- 241000207199 Citrus Species 0.000 description 1
- 229920000832 Cutin Polymers 0.000 description 1
- 241000628997 Flos Species 0.000 description 1
- 229920002752 Konjac Polymers 0.000 description 1
- 229930003427 Vitamin E Natural products 0.000 description 1
- RSWGJHLUYNHPMX-ONCXSQPRSA-N abietic acid Chemical compound C([C@@H]12)CC(C(C)C)=CC1=CC[C@@H]1[C@]2(C)CCC[C@@]1(C)C(O)=O RSWGJHLUYNHPMX-ONCXSQPRSA-N 0.000 description 1
- 239000003082 abrasive agent Substances 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 125000005211 alkyl trimethyl ammonium group Chemical group 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- 230000031709 bromination Effects 0.000 description 1
- 238000005893 bromination reaction Methods 0.000 description 1
- YMKDRGPMQRFJGP-UHFFFAOYSA-M cetylpyridinium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+]1=CC=CC=C1 YMKDRGPMQRFJGP-UHFFFAOYSA-M 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 235000020971 citrus fruits Nutrition 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 235000011389 fruit/vegetable juice Nutrition 0.000 description 1
- WIGCFUFOHFEKBI-UHFFFAOYSA-N gamma-tocopherol Natural products CC(C)CCCC(C)CCCC(C)CCCC1CCC2C(C)C(O)C(C)C(C)C2O1 WIGCFUFOHFEKBI-UHFFFAOYSA-N 0.000 description 1
- 230000009931 harmful effect Effects 0.000 description 1
- 208000006278 hypochromic anemia Diseases 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 239000002068 microbial inoculum Substances 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- 235000011837 pasties Nutrition 0.000 description 1
- 229960005323 phenoxyethanol Drugs 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- YGSDEFSMJLZEOE-UHFFFAOYSA-M salicylate Chemical compound OC1=CC=CC=C1C([O-])=O YGSDEFSMJLZEOE-UHFFFAOYSA-M 0.000 description 1
- 229960001860 salicylate Drugs 0.000 description 1
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 229940075554 sorbate Drugs 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 229940046009 vitamin E Drugs 0.000 description 1
- 235000019165 vitamin E Nutrition 0.000 description 1
- 239000011709 vitamin E Substances 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
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- Cosmetics (AREA)
Abstract
The invention relates to skin-protecting facial scrub and a preparation method thereof. Currently, skin-protecting facial scrub with unique and simple formula and a preparation method thereof do not exist. The skin-protecting facial scrub is characterized by being prepared from fibroin gel and hull carbonized powder in a dose ratio of (10ml:1g)-(10ml:1.5g). The preparation method comprises the following steps: (1) adding gel accelerant into a 4-10%w/v silk fibroin aqueous solution, uniformly mixing, standing at 20-80 DEG C to obtain fibroin gel; (2) carbonizing rice hulls at 160-220 DEG C for 30-100 hours, grinding into powder, and screening through a screen of 80-100 meshes; (3) homogenizing the fibroin gel and the hull carbonized powder in a dose ratio of (10ml:1g)-(10ml:1.5g) into a paste so as to obtain the skin-protecting facial scrub. The skin-protecting facial scrub is unique and simple in formula, and has a good scrubbing effect.
Description
Technical field
The present invention relates to a kind of skin protection scrubbing cream and preparation method thereof, belong to a kind of clean skin product, be mainly used in removing dirt and the dead bark of deep skin.
Background technology
Scrubbing cream is the clean skin product of oil-in-water type that contain even fine particle, is mainly used in removing dirt and the dead bark of deep skin.Commercially available scrubbing cream is made by cooperations such as insoluble solid abrasive material, oil content, moisture and surfactants conventionally at present, and surfactant has good scale removal effect, but belongs to synthetic chemical, and skin is had to certain harmful effect.
The scrubbing cream that now also has some types, if open day is on 08 21st, 2013, publication number is in the Chinese patent of CN103251536A, a kind of Exfoliating Scrub Fructus Luffae scrubbing cream is disclosed, this Exfoliating Scrub Fructus Luffae scrubbing cream comprises following component: macromolecule glue 0.5-0.6kg, distilled water 40-42kg, unfresh towel gourd flesh 9-10kg, Flos Chrysanthemi 1.8-2kg, olive oil 3-3.2kg, Compound Resisting microbial inoculum 0.2-0.25kg, unfresh towel gourd flesh has very thick Plant fiber, this scrubbing cream is worn into coarse powder by curing dry unfresh towel gourd flesh, product is fine and smooth not, easily skin is produced to damage, in addition, the formula of this scrubbing cream is complicated.And for example open day is on 06 18th, 2014, publication number is in the Chinese patent of CN103860438A, a kind of whitening scrubbing cream made from pomelo peel is disclosed, this whitening scrubbing cream adds pomelo peel juice mixing homogenizing by Pericarpium Citri grandis scrubbing cream, add a small amount of konjaku powder to pasty state, then in cold preservation below 10 ℃; Pericarpium Citri grandis scrubbing cream is made as follows: get fresh pomelo peel and clean, wind is opened, and earth separation in white in pomelo peel is removed, and pomelo peel thickness is in 1cm, by pomelo peel chopping, then grinds and causes 80 orders, and adding fineness was 80 object Colophonium, stirred; The frosted finish effect of this whitening scrubbing cream is poor, and does not have effect antibacterial, attract dirt.For another example open day is on October 16th, 2013, publication number is in the Chinese patent of CN103349642A, the table sugar scrubbing cream of the gentle Exfoliating Scrub of a kind of natural plant moisturizing is disclosed, the component that this table sugar scrubbing cream contains following percentage by weight: the table sugar of 55-75%, 10 ~ 20% wetting agent, 0.5 ~ 5% natural moisturizing agent, 0.5 ~ 5.0% natural plant wetting agent, 0.2 ~ 1.0% thickening agent and 0.01 ~ 3.0% anti-sensitizer, and complement to 100% by water, the frosted finish effect of this table sugar scrubbing cream is poor, does not also have effect antibacterial, attract dirt.
In sum, also do not have at present a kind of formula unique, simple, frosted finish effect is good, and human body skin is had to good affinity, and skin is had and repaired and protective effect, and the ability of attract dirt is strong, and has skin protection scrubbing cream of antibacterial action and preparation method thereof.
Summary of the invention
The object of the invention is to overcome above shortcomings in prior art; and provide a kind of formula unique, simple; frosted finish effect is good; human body skin is had to good affinity; skin is had and repaired and protective effect; the ability of attract dirt is strong, and has skin protection scrubbing cream of antibacterial action and preparation method thereof.
The present invention addresses the above problem adopted technical scheme: the feature of this skin protection scrubbing cream is: mainly silk extract gel and rice husk carbonized, consist of, the usage ratio of described silk extract gel and rice husk carbonized is 10ml: 1g～10ml: 1.5g.Make thus the formula of skin protection scrubbing cream unique, between silk extract gel and rice husk carbonized, can produce cooperative effect, not only strengthened frosted effect, also promoted effect antibacterial, attract dirt, not only can be good take out stains and be deposited in the corneocyte that skin surface is aging, and can take good care of the skin after clean in time.
As preferably, in skin protection scrubbing cream of the present invention, also contain one or more in cosmetic base composition, auxiliary element and antiseptic.
As preferably, cosmetic base composition of the present invention is one or more in stearic acid, palmitic acid, vaseline, white oil, cardanol, fatty alcohol-polyoxyethylene ether, oleyl alcohol, Cera Flava, squalane, glyceryl monostearate, hexadecanol, sodium lauryl sulphate Vinlub 73; Described auxiliary element is one or more in emulsifying agent, glycerol, essence, Oleum menthae, Oleum lavandula angustifolia, Oleum Rosae Rugosae, Michelia leap oil and lecithin; Described antiseptic is one or more in acids antiseptic, amide-type antiseptic, quaternary ammonium salt antiseptic, antiseptic phenols and compound preservative.
A preparation method for skin protection scrubbing cream, its feature is: described preparation method comprises the steps:
(1) in the silk fibroin water solution that is 4～10%w/v in concentration, add water-soluble silk glue albumen, concentration to water-soluble silk glue albumen is 0.1～0.8%w/v, and/or add water-soluble carboxymethyl chitosan as gel promoter, to the concentration of water-soluble carboxymethyl chitosan be 0.1～0.5%w/v; After evenly mixing, solution is standing under the condition of 20～80 ℃, change into as translucent silk extract gel to solution gel;
(2) clean rice hulls is laid in flat pottery pot, under the high temperature of 160～220 ℃, carbonization is 3～10 hours, after cooling, takes out, and is milled into immediately rice husk carbonized, and the rice husk carbonized of getting 80～100 mesh sieves is standby;
(3) by the silk extract gel of making and the homogeneous paste that changes into of rice husk carbonized, obtain skin protection scrubbing cream, the usage ratio of silk extract gel and rice husk carbonized is 10ml: 1g～10ml: 1.5g.
Make thus the technique of preparation method of the present invention simple, easy to prepare, take natural rice hulls as raw material, through high temperature dehydration, mill and form, clean, fine and smooth, except frosted effect, there is effect antibacterial, attract dirt.Fibroin albumen is the protein extracting from silkworm silk, and human body skin is had to good affinity, and skin is had and repaired and protective effect.Between rice husk carbonization power and silk extract gel, there is synergism, can mutually strengthen effect, make skin protection scrubbing cream can effectively take out stains and be deposited in the corneocyte that skin surface is aging, can take good care of in time again the skin after cleaning.
As preferably, in silk fibroin water solution of the present invention, the molecular weight of fibroin albumen is 1 * 10
4～35 * 10
4ten thousand, the molecular weight of described water-soluble silk glue albumen is 2 * 10
3～10 * 10
4ten thousand, the molecular weight of described water-soluble carboxymethyl chitosan is 5 * 10
3～10 * 10
4.
As preferably, the DSatO of water-soluble carboxymethyl chitosan of the present invention is that 0.3～0.65, DSatN is 0.1～0.4.
As preferably, in step of the present invention (2), select new rice hulls then, remove impurity, blow away dust, clear water is cleaned, and dries, thereby obtains clean rice hulls; With Muffle furnace, clean rice hulls is heated to carbonization, with whirlwind flour mill, the rice hulls after carbonization is milled into rice husk carbonized.
As preferably, in the homogeneity process of step of the present invention (3), add one or more in appropriate water, cosmetic base composition, auxiliary element and antiseptic.
As preferably, the silk fibroin water solution of step of the present invention (1) is adopted with the following method and is made:
Cocoon is through shelling cocoon, go pupa to obtain cocoon layer, the Na that is 0.5% with mass percent
2cO
3the concise cocoon layer of aqueous solution 2 times, each 30 minutes, 100 ℃ of concise temperature, bath raio 1:100, concise rear fully clean with distilled water, natural drying, obtains fibroin fiber; The CaCl that is 50% with mass percent
2aqueous solution dissolves fibroin fiber, 98 ℃ of solution temperatures, bath raio 1:25,5 minutes time; It is in 12,000～14,000 cellulose dialyzer that the solution obtaining after dissolving is poured into molecular components, dialyses 3 in flowing water, and the solution after dialysis is air-dry concentrated, obtains silk fibroin water solution;
Or: the calcium chloride that is 1:8:2 by mol ratio, water and dissolve with ethanol solution fibroin fiber, 70 ℃ of solution temperatures; bath raio 1:25; 10 minutes time, it is 12,000～14 that the solution obtaining after dissolving is poured into molecular components; in 000 cellulose dialyzer; dialyse in flowing water 3, and the solution after dialysis is air-dry concentrated, obtains silk fibroin water solution;
Or: Cocoon is through stripping cocoon, go pupa to obtain cocoon layer, the concise cocoon layer of the neutral soap solution that is 0.4% with mass percent 2 times, each 1 hour, 100 ℃ of concise temperature, bath raio 1:100, concise rear fully clean with distilled water, natural drying, obtain fibroin fiber, with lithium bromide, 3 yuan of solvents that second alcohol and water is mixed into the weight ratio of 45:53:2, heating for dissolving fibroin fiber at 60 ℃ of temperature, bath raio 1:50, it is 12 that the solution obtaining after dissolving is poured into molecular components, 000～14, in 000 cellulose dialyzer, in flowing water, dialyse 3, solution after dialysis is air-dry concentrated, obtain silk fibroin water solution.
As preferably, cosmetic base composition of the present invention is one or more in stearic acid, palmitic acid, vaseline, white oil, cardanol, fatty alcohol-polyoxyethylene ether, oleyl alcohol, Cera Flava, squalane, glyceryl monostearate, hexadecanol, sodium lauryl sulphate Vinlub 73; Described auxiliary element is one or more in emulsifying agent, glycerol, essence, Oleum menthae, Oleum lavandula angustifolia, Oleum Rosae Rugosae, Michelia leap oil and lecithin; Described antiseptic is one or more in acids antiseptic, amide-type antiseptic, quaternary ammonium salt antiseptic, antiseptic phenols and compound preservative.
The present invention compared with prior art; have the following advantages and effect: the formula of skin protection scrubbing cream is unique; rice husk carbonized has the effect of good frosted, antibacterial and attract dirt; fibroin albumen has good affinity to human body skin; skin is had and repaired and protective effect; between silk extract gel and rice husk carbonized, cooperative effect can be produced, effect can be mutually strengthened.The technique of preparation method of the present invention is simple, easy to prepare, take rice husk carbonization power and silk extract gel as primary raw material, rice husk carbonization power be take natural rice hulls as raw material, through high temperature dehydration, mill and form, clean, fine and smooth, source is abundant, course of processing environmental protection, fibroin albumen is the protein extracting from silkworm silk, human body skin is had to good affinity, skin is had and repaired and protective effect, take the skin protection scrubbing cream that rice husk carbonization power and silk extract gel make as primary raw material, can take out stains and be deposited in the corneocyte that skin surface is aging, can take good care of in time again the skin after cleaning.
The specific embodiment
Below by embodiment, the present invention is described in further detail, and following examples are explanation of the invention and the present invention is not limited to following examples.
Embodiment 1.
The preparation method of the skin protection scrubbing cream in the present embodiment comprises the steps.
(1) Cocoon is through shelling cocoon, going pupa to obtain cocoon layer.The Na that is 0.5% with mass percent
2cO
3the concise cocoon layer of aqueous solution 2 times, each 30 minutes, 100 ℃ of concise temperature, bath raio 1:100.Concise rear fully clean with distilled water, natural drying, obtains fibroin fiber.The CaCl that is 50% with mass percent
2aqueous solution dissolves fibroin fiber, and solution temperature is 98 ℃, and bath raio is 1:25, and the time is 5 minutes.The solution obtaining after dissolving is poured in cellulose dialyzer (molecular components 12,000～14,000), in flowing water, dialyse 3.Solution after dialysis is air-dry concentrated, obtain silk fibroin water solution.In the silk fibroin water solution that is 4%w/v in concentration, add water-soluble silk glue albumen (molecular weight 2 * 10
3), to the concentration of water-soluble silk glue albumen be 0.1%w/v, add water-soluble carboxymethyl chitosan (molecular weight 10 * 10
4, DSatO 0.65, DSatN 0.3), to the concentration of water-soluble carboxymethyl chitosan be 0.5%w/v, then standing under the condition of 60 ℃, become translucent silk extract gel to solution.
(2) select new rice hulls then, remove impurity, blow away dust, clear water is cleaned, and dries, and obtains clean rice hulls.Clean rice hulls after pre-treatment is laid in to flat pottery pot, and the carbonization of being convenient to be heated is even; Put into Muffle furnace, under 200 ℃ of high temperature, carbonization is 4.5 hours, after cooling, takes out, and is milled into rice husk carbonized immediately with whirlwind flour mill, and the rice husk carbonized dress sealing bag of getting 100 mesh sieves is standby.
(3) by the homogeneous paste that changes into of silk extract gel, rice husk carbonized and antiseptic, obtain skin protection scrubbing cream.
Concrete proportioning is:
Composition weight umber
Silk extract gel 90
Rice husk carbonized 10
Benzoate is appropriate
Essence is appropriate
The formula of this skin protection scrubbing cream is simple, and the gentle aging cutin layer of removing, can give full play to the peculiar skin care effect of fibroin albumen.
Embodiment 2.
The preparation method of the skin protection scrubbing cream in the present embodiment comprises the steps.
(1) calcium chloride that is 1:8:2 by mol ratio, water and dissolve with ethanol solution fibroin fiber, 70 ℃ of solution temperatures, bath raio 1:25,10 minutes time.The solution obtaining after dissolving is poured in cellulose dialyzer (molecular components 12,000～14,000), in flowing water, dialyse 3.Solution after dialysis is air-dry concentrated, obtain silk fibroin water solution.In the silk fibroin water solution that is 6%w/v in concentration, add water-soluble silk glue albumen (molecular weight 5 * 10
3), to the concentration of water-soluble silk glue albumen be 0.2%w/v, add water-soluble carboxymethyl chitosan (molecular weight 5 * 10
4, DSatO 0.5, DSatN 0.3), to the concentration of water-soluble carboxymethyl chitosan be 0.4%w/v, then standing under the condition of 60 ℃, become translucent silk extract gel to solution.
(2) select new rice hulls then, remove impurity, blow away dust, clear water is cleaned, and dries, and obtains clean rice hulls.Clean rice hulls after pre-treatment is laid in to flat pottery pot, and the carbonization of being convenient to be heated is even; Put into Muffle furnace, under 190 ℃ of high temperature, carbonization is 6 hours, after cooling, takes out, and is milled into rice husk carbonized immediately with whirlwind flour mill, and the rice husk carbonized dress sealing bag of getting 100 mesh sieves is standby.
(3) by silk extract gel, rice husk carbonized, other matrix components, the homogeneous paste that changes into of auxiliary element, obtain skin protection scrubbing cream.
Concrete proportioning is:
Composition weight umber
Silk extract gel 88
Rice husk carbonized 10
Glycerol 1.0
Vitamin E acetic acid fat 0.5
Ocean Citrus essential oil 0.5
Sodium sorbate is appropriate
Essence is appropriate
Distilled water is appropriate
The formula of this skin protection scrubbing cream has strengthened moisture-keeping function.
Embodiment 3.
The preparation method of the skin protection scrubbing cream in the present embodiment comprises the steps.
(1) Cocoon is through shelling cocoon, going pupa to obtain cocoon layer.The concise cocoon layer of the neutral soap solution that is 0.4% with mass percent 2 times, each 1 hour, 100 ℃ of concise temperature, bath raio 1:100.Concise rear fully clean with distilled water, natural drying, obtains fibroin fiber.3 yuan of solvents that are mixed into the weight ratio of 45:53:2 with lithium bromide, ethanol, water, heating for dissolving fibroin fiber at 60 ℃ of temperature.Bath raio 1:50.The solution obtaining after dissolving is poured in cellulose dialyzer (molecular components 12,000～14,000), in flowing water, dialyse 3.Solution after dialysis is air-dry concentrated, obtain silk fibroin water solution.In the silk fibroin water solution that is 10%w/v in concentration, add water-soluble silk glue albumen (molecular weight 6 * 10
4), to the concentration of water-soluble silk glue albumen be 0.5%w/v, add water-soluble carboxymethyl chitosan (molecular weight 1 * 10
4, DSatO 0.5, DSatN 0.4), to the concentration of water-soluble carboxymethyl chitosan be 0.1%w/v, standing under the condition of 60 ℃, become translucent silk extract gel to solution.
(2) select new rice hulls then, remove impurity, blow away dust, clear water is cleaned, and dries, and obtains clean rice hulls.Clean rice hulls after pre-treatment is laid in to flat pottery pot, and the carbonization of being convenient to be heated is even; Put into Muffle furnace, under 180 ℃ of high temperature, carbonization is 7 hours, after cooling, takes out, and is milled into rice husk carbonized immediately with whirlwind flour mill, and the rice husk carbonized dress sealing bag of getting 80 mesh sieves is standby.
(3) silk extract gel, rice husk carbonized, other matrix components, the homogeneous paste that changes into of auxiliary element, obtain skin protection scrubbing cream.
Concrete proportioning is:
Composition weight umber
Silk extract gel 85
Rice husk carbonized 14
Hexadecanol 0.5
Squalane 0.2
Vinlub 73 0.2
Essence is appropriate
Methyl dibromo glutaronitrile is appropriate
Sodium sorbate is appropriate
Distilled water is appropriate
The formula of this skin protection scrubbing cream has strengthened frosted effect.
Embodiment 4.
The preparation method of the skin protection scrubbing cream in the present embodiment comprises the steps.
(1) at 4～10%w/v silk fibroin water solution (molecular weight 1 * 10
4～35 * 10
4ten thousand), in, add water-soluble silk glue albumen (molecular weight 2 * 10
3～10 * 10
4ten thousand), to the concentration of water-soluble silk glue albumen be 0.1～0.8%w/v, add water-soluble carboxymethyl chitosan (molecular weight 5 * 10
3～10 * 10
4, DSatO 0.3～0.65, and DSatN 0.1～0.4) as gel promoter, concentration to water-soluble carboxymethyl chitosan is 0.1～0.5%w/v, after evenly mixing, solution is standing under 20～80 ℃ of conditions, change into as translucent silk extract gel to solution gel.
(2) select new rice hulls then, remove impurity, blow away dust, clear water is cleaned, and dries.Clean rice hulls after pre-treatment is laid in to flat pottery pot, and the carbonization of being convenient to be heated is even; Put into Muffle furnace, under 160～220 ℃ of high temperature, carbonization is 3～10 hours, after cooling, takes out, and is milled into rice husk carbonized immediately with whirlwind flour mill, and the rice husk carbonized dress sealing bag of getting 100 mesh sieves is standby.
(3) by the silk extract gel of making and the homogeneous paste that changes into of rice husk carbonized, obtain skin protection scrubbing cream, silk extract gel: rice husk carbonized=10ml: 1～10ml: 1.5g.
In homogeneity process, can add amount of water, to adjust the denseness of cream.Can also when emulsifying, add as required appropriate other cosmetic base compositions, auxiliary element and antiseptic.Other matrix components comprises stearic acid, palmitic acid, vaseline, white oil, cardanol, fatty alcohol-polyoxyethylene ether, oleyl alcohol, Cera Flava, squalane, glyceryl monostearate, hexadecanol, sodium lauryl sulphate Vinlub 73.Auxiliary element comprises emulsifying agent, glycerol, essence, Oleum menthae, Oleum lavandula angustifolia, Oleum Rosae Rugosae, Michelia leap oil, lecithin.Antiseptic can be benzoate, sorbate, the Salicylate of acids antiseptic, ethanol, parachlorometaxylenol, 2 of alkyl bromination quinoline, amide-type, 4,4 '-tri-chloros-carbanilide, hexadecylpyridinium chloride, methyl dibromo glutaronitrile and the phenoxyethanol of the alkyl trimethyl ammonium chloride of quaternary ammonium salt, the parabens of antiseptic phenols (first, second, third, butyl ester), compound preservative can be selected wherein one or more.
Embodiment 5.
The preparation method of the skin protection scrubbing cream in the present embodiment comprises the steps.
(1) in the silk fibroin water solution that is 5%w/v in concentration, add water-soluble silk glue albumen, concentration to water-soluble silk glue albumen is 0.2%w/v, add water-soluble carboxymethyl chitosan as gel promoter, concentration to water-soluble carboxymethyl chitosan is 0.3%w/v, after evenly mixing, solution is standing under the condition of 30 ℃, change into as translucent silk extract gel to solution gel.In silk fibroin water solution, the molecular weight of fibroin albumen is 7 * 10
4ten thousand, the molecular weight of water-soluble silk glue albumen is 8 * 10
4ten thousand, the molecular weight of water-soluble carboxymethyl chitosan is 1 * 10
4.The DSatO of water-soluble carboxymethyl chitosan is that 0.42, DSatN is 0.4.
(2) clean rice hulls is laid in flat pottery pot, under the high temperature of 170 ℃, carbonization is 10 hours, after cooling, takes out, and is milled into immediately rice husk carbonized, and the rice husk carbonized of getting 80 mesh sieves is standby.Generally, select new rice hulls then, remove impurity, blow away dust, clear water is cleaned, and dries, thereby obtains clean rice hulls; With Muffle furnace, clean rice hulls is heated to carbonization, with whirlwind flour mill, the rice hulls after carbonization is milled into rice husk carbonized.
(3) by the silk extract gel of making and the homogeneous paste that changes into of rice husk carbonized, obtain skin protection scrubbing cream, the usage ratio of silk extract gel and rice husk carbonized is 10ml: 1.3g.
In the homogeneity process of the present embodiment step (3), can add appropriate water, cosmetic base composition, one or more in auxiliary element and antiseptic, wherein, cosmetic base composition can be stearic acid, palmitic acid, vaseline, white oil, cardanol, fatty alcohol-polyoxyethylene ether, oleyl alcohol, Cera Flava, squalane, glyceryl monostearate, hexadecanol, one or more in sodium lauryl sulphate Vinlub 73, auxiliary element can be emulsifying agent, glycerol, essence, Oleum menthae, Oleum lavandula angustifolia, Oleum Rosae Rugosae, one or more in Michelia leap oil and lecithin, antiseptic can be acids antiseptic, amide-type antiseptic, quaternary ammonium salt antiseptic, one or more in antiseptic phenols and compound preservative.
The present embodiment also relates to the prepared skin protection scrubbing cream of a kind of as above preparation method, the formula of this skin protection scrubbing cream is unique, between silk extract gel and rice husk carbonized, can produce cooperative effect, not only strengthened frosted effect, also promoted effect antibacterial, attract dirt, not only can be good take out stains and be deposited in the corneocyte that skin surface is aging, and can take good care of the skin after clean in time.
Embodiment 6.
The preparation method of the skin protection scrubbing cream in the present embodiment comprises the steps.
(1) in the silk fibroin water solution that is 8%w/v in concentration, add water-soluble silk glue albumen, concentration to water-soluble silk glue albumen is 0.6%w/v, add water-soluble carboxymethyl chitosan as gel promoter, concentration to water-soluble carboxymethyl chitosan is 0.5%w/v, after evenly mixing, solution is standing under the condition of 50 ℃, change into as translucent silk extract gel to solution gel.In silk fibroin water solution, the molecular weight of fibroin albumen is 21 * 10
4ten thousand, the molecular weight of water-soluble silk glue albumen is 2 * 10
3ten thousand, the molecular weight of water-soluble carboxymethyl chitosan is 9 * 10
4.
(2) clean rice hulls is laid in flat pottery pot, under the high temperature of 210 ℃, carbonization is 5 hours, after cooling, takes out, and is milled into immediately rice husk carbonized, and the rice husk carbonized of getting 100 mesh sieves is standby.
(3) by the silk extract gel of making and the homogeneous paste that changes into of rice husk carbonized, obtain skin protection scrubbing cream, the usage ratio of silk extract gel and rice husk carbonized is 10ml: 1g.
The silk fibroin water solution of step in the present embodiment (1) is adopted with the following method and is made: Cocoon is through shelling cocoon, go pupa to obtain cocoon layer, the Na that is 0.5% with mass percent
2cO
3the concise cocoon layer of aqueous solution 2 times, each 30 minutes, 100 ℃ of concise temperature, bath raio 1:100, concise rear fully clean with distilled water, natural drying, obtains fibroin fiber; The CaCl that is 50% with mass percent
2aqueous solution dissolves fibroin fiber, 98 ℃ of solution temperatures, bath raio 1:25,5 minutes time; It is in 12,000～14,000 cellulose dialyzer that the solution obtaining after dissolving is poured into molecular components, dialyses 3 in flowing water, and the solution after dialysis is air-dry concentrated, obtains silk fibroin water solution.
The present embodiment also relates to the prepared skin protection scrubbing cream of a kind of as above preparation method, the formula of this skin protection scrubbing cream is unique, between silk extract gel and rice husk carbonized, can produce cooperative effect, not only strengthened frosted effect, also promoted effect antibacterial, attract dirt, not only can be good take out stains and be deposited in the corneocyte that skin surface is aging, and can take good care of the skin after clean in time.
Embodiment 7.
The preparation method of the skin protection scrubbing cream in the present embodiment comprises the steps.
(1) in the silk fibroin water solution that is 4%w/v in concentration, add water-soluble silk glue albumen as gel promoter, to the concentration of water-soluble silk glue albumen be 0.8%w/v, after evenly mixing, solution is standing under the condition of 20 ℃, change into as translucent silk extract gel to solution gel.In silk fibroin water solution, the molecular weight of fibroin albumen is 18 * 10
4ten thousand, the molecular weight of water-soluble silk glue albumen is 6 * 10
4ten thousand, the molecular weight of water-soluble carboxymethyl chitosan is 8 * 10
4.
(2) clean rice hulls is laid in flat pottery pot, under the high temperature of 190 ℃, carbonization is 7 hours, after cooling, takes out, and is milled into immediately rice husk carbonized, and the rice husk carbonized of getting 100 mesh sieves is standby.Generally, select new rice hulls then, remove impurity, blow away dust, clear water is cleaned, and dries, thereby obtains clean rice hulls; With Muffle furnace, clean rice hulls is heated to carbonization, with whirlwind flour mill, the rice hulls after carbonization is milled into rice husk carbonized.
(3) by the silk extract gel of making and the homogeneous paste that changes into of rice husk carbonized, obtain skin protection scrubbing cream, the usage ratio of silk extract gel and rice husk carbonized is 10ml: 1.25g.
In the homogeneity process of the present embodiment step (3), can add appropriate water, cosmetic base composition, one or more in auxiliary element and antiseptic, wherein, cosmetic base composition can be stearic acid, palmitic acid, vaseline, white oil, cardanol, fatty alcohol-polyoxyethylene ether, oleyl alcohol, Cera Flava, squalane, glyceryl monostearate, hexadecanol, one or more in sodium lauryl sulphate Vinlub 73, auxiliary element can be emulsifying agent, glycerol, essence, Oleum menthae, Oleum lavandula angustifolia, Oleum Rosae Rugosae, one or more in Michelia leap oil and lecithin, antiseptic can be acids antiseptic, amide-type antiseptic, quaternary ammonium salt antiseptic, one or more in antiseptic phenols and compound preservative.
The present embodiment also relates to the prepared skin protection scrubbing cream of a kind of as above preparation method, the formula of this skin protection scrubbing cream is unique, between silk extract gel and rice husk carbonized, can produce cooperative effect, not only strengthened frosted effect, also promoted effect antibacterial, attract dirt, not only can be good take out stains and be deposited in the corneocyte that skin surface is aging, and can take good care of the skin after clean in time.
Embodiment 8.
The preparation method of the skin protection scrubbing cream in the present embodiment comprises the steps.
(1) in the silk fibroin water solution that is 7%w/v in concentration, add water-soluble carboxymethyl chitosan as gel promoter, concentration to water-soluble carboxymethyl chitosan is 0.2%w/v, after evenly mixing, solution is standing under the condition of 70 ℃, change into as translucent silk extract gel to solution gel.In silk fibroin water solution, the molecular weight of fibroin albumen is 35 * 10
4ten thousand, the molecular weight of water-soluble silk glue albumen is 5 * 10
4ten thousand, the molecular weight of water-soluble carboxymethyl chitosan is 3 * 10
4.The DSatO of water-soluble carboxymethyl chitosan is that 0.3, DSatN is 0.25.
(2) clean rice hulls is laid in flat pottery pot, under the high temperature of 200 ℃, carbonization is 3 hours, after cooling, takes out, and is milled into immediately rice husk carbonized, and the rice husk carbonized of getting 80 mesh sieves is standby.Generally, select new rice hulls then, remove impurity, blow away dust, clear water is cleaned, and dries, thereby obtains clean rice hulls; With Muffle furnace, clean rice hulls is heated to carbonization, with whirlwind flour mill, the rice hulls after carbonization is milled into rice husk carbonized.
(3) by the silk extract gel of making and the homogeneous paste that changes into of rice husk carbonized, obtain skin protection scrubbing cream, the usage ratio of silk extract gel and rice husk carbonized is 10ml: 2g.
In the homogeneity process of the present embodiment step (3), can add appropriate water, cosmetic base composition, one or more in auxiliary element and antiseptic, wherein, cosmetic base composition can be stearic acid, palmitic acid, vaseline, white oil, cardanol, fatty alcohol-polyoxyethylene ether, oleyl alcohol, Cera Flava, squalane, glyceryl monostearate, hexadecanol, one or more in sodium lauryl sulphate Vinlub 73, auxiliary element can be emulsifying agent, glycerol, essence, Oleum menthae, Oleum lavandula angustifolia, Oleum Rosae Rugosae, one or more in Michelia leap oil and lecithin, antiseptic can be acids antiseptic, amide-type antiseptic, quaternary ammonium salt antiseptic, one or more in antiseptic phenols and compound preservative.
The present embodiment also relates to the prepared skin protection scrubbing cream of a kind of as above preparation method, the formula of this skin protection scrubbing cream is unique, between silk extract gel and rice husk carbonized, can produce cooperative effect, not only strengthened frosted effect, also promoted effect antibacterial, attract dirt, not only can be good take out stains and be deposited in the corneocyte that skin surface is aging, and can take good care of the skin after clean in time.
Embodiment 9.
The preparation method of the skin protection scrubbing cream in the present embodiment comprises the steps.
(1) in the silk fibroin water solution that is 10%w/v in concentration, add water-soluble silk glue albumen as gel promoter, to the concentration of water-soluble silk glue albumen be 0.5%w/v, after evenly mixing, solution is standing under the condition of 40 ℃, change into as translucent silk extract gel to solution gel.In silk fibroin water solution, the molecular weight of fibroin albumen is 31 * 10
4ten thousand, the molecular weight of water-soluble silk glue albumen is 3 * 10
4ten thousand, the molecular weight of water-soluble carboxymethyl chitosan is 5 * 10
3.
(2) clean rice hulls is laid in flat pottery pot, under the high temperature of 160 ℃, carbonization is 8 hours, after cooling, takes out, and is milled into immediately rice husk carbonized, and the rice husk carbonized of getting 100 mesh sieves is standby.
(3) by the silk extract gel of making and the homogeneous paste that changes into of rice husk carbonized, obtain skin protection scrubbing cream, the usage ratio of silk extract gel and rice husk carbonized is 10ml: 1.5g.
In the homogeneity process of the present embodiment step (3), can add appropriate water, cosmetic base composition, one or more in auxiliary element and antiseptic, wherein, cosmetic base composition can be stearic acid, palmitic acid, vaseline, white oil, cardanol, fatty alcohol-polyoxyethylene ether, oleyl alcohol, Cera Flava, squalane, glyceryl monostearate, hexadecanol, one or more in sodium lauryl sulphate Vinlub 73, auxiliary element can be emulsifying agent, glycerol, essence, Oleum menthae, Oleum lavandula angustifolia, Oleum Rosae Rugosae, one or more in Michelia leap oil and lecithin, antiseptic can be acids antiseptic, amide-type antiseptic, quaternary ammonium salt antiseptic, one or more in antiseptic phenols and compound preservative.
The silk fibroin water solution of step in the present embodiment (1) is adopted with the following method and is made: the calcium chloride that is 1:8:2 by mol ratio, water and dissolve with ethanol solution fibroin fiber, 70 ℃ of solution temperatures; bath raio 1:25; 10 minutes time, it is 12,000～14 that the solution obtaining after dissolving is poured into molecular components; in 000 cellulose dialyzer; dialyse in flowing water 3, and the solution after dialysis is air-dry concentrated, obtains silk fibroin water solution.
The present embodiment also relates to the prepared skin protection scrubbing cream of a kind of as above preparation method, the formula of this skin protection scrubbing cream is unique, between silk extract gel and rice husk carbonized, can produce cooperative effect, not only strengthened frosted effect, also promoted effect antibacterial, attract dirt, not only can be good take out stains and be deposited in the corneocyte that skin surface is aging, and can take good care of the skin after clean in time.
Embodiment 10.
The preparation method of the skin protection scrubbing cream in the present embodiment comprises the steps.
(1) in the silk fibroin water solution that is 7.5%w/v in concentration, add water-soluble silk glue albumen, concentration to water-soluble silk glue albumen is 0.1%w/v, add water-soluble carboxymethyl chitosan as gel promoter, concentration to water-soluble carboxymethyl chitosan is 0.4%w/v, after evenly mixing, solution is standing under the condition of 80 ℃, change into as translucent silk extract gel to solution gel.In silk fibroin water solution, the molecular weight of fibroin albumen is 15 * 10
4ten thousand, the molecular weight of water-soluble silk glue albumen is 10 * 10
4ten thousand, the molecular weight of water-soluble carboxymethyl chitosan is 7 * 10
4.The DSatO of water-soluble carboxymethyl chitosan is that 0.65, DSatN is 0.1.
(2) clean rice hulls is laid in flat pottery pot, under the high temperature of 220 ℃, carbonization is 4 hours, after cooling, takes out, and is milled into immediately rice husk carbonized, and the rice husk carbonized of getting 100 mesh sieves is standby.Generally, select new rice hulls then, remove impurity, blow away dust, clear water is cleaned, and dries, thereby obtains clean rice hulls; With Muffle furnace, clean rice hulls is heated to carbonization, with whirlwind flour mill, the rice hulls after carbonization is milled into rice husk carbonized.
(3) by the silk extract gel of making and the homogeneous paste that changes into of rice husk carbonized, obtain skin protection scrubbing cream, the usage ratio of silk extract gel and rice husk carbonized is 10ml: 1.4g.
The present embodiment also relates to the prepared skin protection scrubbing cream of a kind of as above preparation method, the formula of this skin protection scrubbing cream is unique, between silk extract gel and rice husk carbonized, can produce cooperative effect, not only strengthened frosted effect, also promoted effect antibacterial, attract dirt, not only can be good take out stains and be deposited in the corneocyte that skin surface is aging, and can take good care of the skin after clean in time.
Embodiment 11.
The preparation method of the skin protection scrubbing cream in the present embodiment comprises the steps.
(1) in the silk fibroin water solution that is 6%w/v in concentration, add water-soluble carboxymethyl chitosan as gel promoter, concentration to water-soluble carboxymethyl chitosan is 0.35%w/v, after evenly mixing, solution is standing under the condition of 45 ℃, change into as translucent silk extract gel to solution gel.In silk fibroin water solution, the molecular weight of fibroin albumen is 27 * 10
4ten thousand, the molecular weight of water-soluble silk glue albumen is 5 * 10
4ten thousand, the molecular weight of water-soluble carboxymethyl chitosan is 1 * 10
4.
(2) clean rice hulls is laid in flat pottery pot, under the high temperature of 170 ℃, carbonization is 3 hours, after cooling, takes out, and is milled into immediately rice husk carbonized, and the rice husk carbonized of getting 80 mesh sieves is standby.
(3) by the silk extract gel of making and the homogeneous paste that changes into of rice husk carbonized, obtain skin protection scrubbing cream, the usage ratio of silk extract gel and rice husk carbonized is 10ml: 1.3g.
In the homogeneity process of the present embodiment step (3), can add appropriate water, cosmetic base composition, one or more in auxiliary element and antiseptic, wherein, cosmetic base composition can be stearic acid, palmitic acid, vaseline, white oil, cardanol, fatty alcohol-polyoxyethylene ether, oleyl alcohol, Cera Flava, squalane, glyceryl monostearate, hexadecanol, one or more in sodium lauryl sulphate Vinlub 73, auxiliary element can be emulsifying agent, glycerol, essence, Oleum menthae, Oleum lavandula angustifolia, Oleum Rosae Rugosae, one or more in Michelia leap oil and lecithin, antiseptic can be acids antiseptic, amide-type antiseptic, quaternary ammonium salt antiseptic, one or more in antiseptic phenols and compound preservative.
The present embodiment also relates to the prepared skin protection scrubbing cream of a kind of as above preparation method, the formula of this skin protection scrubbing cream is unique, between silk extract gel and rice husk carbonized, can produce cooperative effect, not only strengthened frosted effect, also promoted effect antibacterial, attract dirt, not only can be good take out stains and be deposited in the corneocyte that skin surface is aging, and can take good care of the skin after clean in time.
Embodiment 12.
The preparation method of the skin protection scrubbing cream in the present embodiment comprises the steps.
(1) in the silk fibroin water solution that is 9%w/v in concentration, add water-soluble silk glue albumen, concentration to water-soluble silk glue albumen is 0.4%w/v, add water-soluble carboxymethyl chitosan as gel promoter, concentration to water-soluble carboxymethyl chitosan is 0.1%w/v, after evenly mixing, solution is standing under the condition of 60 ℃, change into as translucent silk extract gel to solution gel.In silk fibroin water solution, the molecular weight of fibroin albumen is 1 * 10
4ten thousand, the molecular weight of water-soluble silk glue albumen is 1 * 10
4ten thousand, the molecular weight of water-soluble carboxymethyl chitosan is 10 * 10
4.
(2) clean rice hulls is laid in flat pottery pot, under the high temperature of 180 ℃, carbonization is 6 hours, after cooling, takes out, and is milled into immediately rice husk carbonized, and the rice husk carbonized of getting 100 mesh sieves is standby.Generally, select new rice hulls then, remove impurity, blow away dust, clear water is cleaned, and dries, thereby obtains clean rice hulls; With Muffle furnace, clean rice hulls is heated to carbonization, with whirlwind flour mill, the rice hulls after carbonization is milled into rice husk carbonized.
(3) by the silk extract gel of making and the homogeneous paste that changes into of rice husk carbonized, obtain skin protection scrubbing cream, the usage ratio of silk extract gel and rice husk carbonized is 10ml: 1.1g.
In the homogeneity process of the present embodiment step (3), can add appropriate water, cosmetic base composition, one or more in auxiliary element and antiseptic, wherein, cosmetic base composition can be stearic acid, palmitic acid, vaseline, white oil, cardanol, fatty alcohol-polyoxyethylene ether, oleyl alcohol, Cera Flava, squalane, glyceryl monostearate, hexadecanol, one or more in sodium lauryl sulphate Vinlub 73, auxiliary element can be emulsifying agent, glycerol, essence, Oleum menthae, Oleum lavandula angustifolia, Oleum Rosae Rugosae, one or more in Michelia leap oil and lecithin, antiseptic can be acids antiseptic, amide-type antiseptic, quaternary ammonium salt antiseptic, one or more in antiseptic phenols and compound preservative.
The silk fibroin water solution of step in the present embodiment (1) is adopted with the following method and is made: Cocoon is through stripping cocoon, go pupa to obtain cocoon layer, the concise cocoon layer of the neutral soap solution that is 0.4% with mass percent 2 times, each 1 hour, 100 ℃ of concise temperature, bath raio 1:100, concise rear fully clean with distilled water, natural drying, obtain fibroin fiber, with lithium bromide, 3 yuan of solvents that second alcohol and water is mixed into the weight ratio of 45:53:2, heating for dissolving fibroin fiber at 60 ℃ of temperature, bath raio 1:50, it is 12 that the solution obtaining after dissolving is poured into molecular components, 000～14, in 000 cellulose dialyzer, in flowing water, dialyse 3, solution after dialysis is air-dry concentrated, obtain silk fibroin water solution.
The present embodiment also relates to the prepared skin protection scrubbing cream of a kind of as above preparation method, the formula of this skin protection scrubbing cream is unique, between silk extract gel and rice husk carbonized, can produce cooperative effect, not only strengthened frosted effect, also promoted effect antibacterial, attract dirt, not only can be good take out stains and be deposited in the corneocyte that skin surface is aging, and can take good care of the skin after clean in time.
Although the present invention with embodiment openly as above; but it is not in order to limit protection scope of the present invention; any technical staff who is familiar with this technology, not departing from change and the retouching of doing in the spirit and scope of the present invention, all should belong to protection scope of the present invention.
Claims (10)
1. a skin protection scrubbing cream, is characterized in that: mainly silk extract gel and rice husk carbonized, consist of, the usage ratio of described silk extract gel and rice husk carbonized is 10ml: 1g～10ml: 1.5g.
2. skin protection scrubbing cream according to claim 1, is characterized in that: in described skin protection scrubbing cream, also contain one or more in cosmetic base composition, auxiliary element and antiseptic.
3. skin protection scrubbing cream according to claim 2, is characterized in that: described cosmetic base composition is one or more in stearic acid, palmitic acid, vaseline, white oil, cardanol, fatty alcohol-polyoxyethylene ether, oleyl alcohol, Cera Flava, squalane, glyceryl monostearate, hexadecanol, sodium lauryl sulphate Vinlub 73; Described auxiliary element is one or more in emulsifying agent, glycerol, essence, Oleum menthae, Oleum lavandula angustifolia, Oleum Rosae Rugosae, Michelia leap oil and lecithin; Described antiseptic is one or more in acids antiseptic, amide-type antiseptic, quaternary ammonium salt antiseptic, antiseptic phenols and compound preservative.
4. a preparation method for skin protection scrubbing cream, is characterized in that: described preparation method comprises the steps:
(1) in the silk fibroin water solution that is 4～10%w/v in concentration, add water-soluble silk glue albumen, concentration to water-soluble silk glue albumen is 0.1～0.8%w/v, and/or add water-soluble carboxymethyl chitosan as gel promoter, to the concentration of water-soluble carboxymethyl chitosan be 0.1～0.5%w/v; After evenly mixing, solution is standing under the condition of 20～80 ℃, change into as translucent silk extract gel to solution gel;
(2) clean rice hulls is laid in flat pottery pot, under the high temperature of 160～220 ℃, carbonization is 3～10 hours, after cooling, takes out, and is milled into immediately rice husk carbonized, and the rice husk carbonized of getting 80～100 mesh sieves is standby;
(3) by the silk extract gel of making and the homogeneous paste that changes into of rice husk carbonized, obtain skin protection scrubbing cream, the usage ratio of silk extract gel and rice husk carbonized is 10ml: 1g～10ml: 1.5g.
5. the preparation method of skin protection scrubbing cream according to claim 4, is characterized in that: in described silk fibroin water solution, the molecular weight of fibroin albumen is 1 * 10
4～35 * 10
4ten thousand, the molecular weight of described water-soluble silk glue albumen is 2 * 10
3～10 * 10
4ten thousand, the molecular weight of described water-soluble carboxymethyl chitosan is 5 * 10
3～10 * 10
4.
6. the preparation method of skin protection scrubbing cream according to claim 4, is characterized in that: the DSatO of described water-soluble carboxymethyl chitosan is that 0.3～0.65, DSatN is 0.1～0.4.
7. the preparation method of skin protection scrubbing cream according to claim 4, is characterized in that: in described step (2), select new rice hulls then, remove impurity, blow away dust, clear water is cleaned, and dries, thereby obtains clean rice hulls; With Muffle furnace, clean rice hulls is heated to carbonization, with whirlwind flour mill, the rice hulls after carbonization is milled into rice husk carbonized.
8. the preparation method of skin protection scrubbing cream according to claim 4, is characterized in that: in the homogeneity process of described step (3), add one or more in appropriate water, cosmetic base composition, auxiliary element and antiseptic.
9. the preparation method of skin protection scrubbing cream according to claim 4, is characterized in that: the silk fibroin water solution of described step (1) is adopted with the following method and made:
Cocoon is through shelling cocoon, go pupa to obtain cocoon layer, the Na that is 0.5% with mass percent
2cO
3the concise cocoon layer of aqueous solution 2 times, each 30 minutes, 100 ℃ of concise temperature, bath raio 1:100, concise rear fully clean with distilled water, natural drying, obtains fibroin fiber; The CaCl that is 50% with mass percent
2aqueous solution dissolves fibroin fiber, 98 ℃ of solution temperatures, bath raio 1:25,5 minutes time; It is in 12,000～14,000 cellulose dialyzer that the solution obtaining after dissolving is poured into molecular components, dialyses 3 in flowing water, and the solution after dialysis is air-dry concentrated, obtains silk fibroin water solution;
Or: the calcium chloride that is 1:8:2 by mol ratio, water and dissolve with ethanol solution fibroin fiber, 70 ℃ of solution temperatures; bath raio 1:25; 10 minutes time, it is 12,000～14 that the solution obtaining after dissolving is poured into molecular components; in 000 cellulose dialyzer; dialyse in flowing water 3, and the solution after dialysis is air-dry concentrated, obtains silk fibroin water solution;
Or: Cocoon is through stripping cocoon, go pupa to obtain cocoon layer, the concise cocoon layer of the neutral soap solution that is 0.4% with mass percent 2 times, each 1 hour, 100 ℃ of concise temperature, bath raio 1:100, concise rear fully clean with distilled water, natural drying, obtain fibroin fiber, with lithium bromide, 3 yuan of solvents that second alcohol and water is mixed into the weight ratio of 45:53:2, heating for dissolving fibroin fiber at 60 ℃ of temperature, bath raio 1:50, it is 12 that the solution obtaining after dissolving is poured into molecular components, 000～14, in 000 cellulose dialyzer, in flowing water, dialyse 3, solution after dialysis is air-dry concentrated, obtain silk fibroin water solution.
10. the preparation method of skin protection scrubbing cream according to claim 8, is characterized in that: described cosmetic base composition is one or more in stearic acid, palmitic acid, vaseline, white oil, cardanol, fatty alcohol-polyoxyethylene ether, oleyl alcohol, Cera Flava, squalane, glyceryl monostearate, hexadecanol, sodium lauryl sulphate Vinlub 73; Described auxiliary element is one or more in emulsifying agent, glycerol, essence, Oleum menthae, Oleum lavandula angustifolia, Oleum Rosae Rugosae, Michelia leap oil and lecithin; Described antiseptic is one or more in acids antiseptic, amide-type antiseptic, quaternary ammonium salt antiseptic, antiseptic phenols and compound preservative.
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