CN107955624A - A kind of saline-alkali soil conditioner and application method - Google Patents

A kind of saline-alkali soil conditioner and application method Download PDF

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Publication number
CN107955624A
CN107955624A CN201711286506.3A CN201711286506A CN107955624A CN 107955624 A CN107955624 A CN 107955624A CN 201711286506 A CN201711286506 A CN 201711286506A CN 107955624 A CN107955624 A CN 107955624A
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CN
China
Prior art keywords
parts
saline
soil
soil conditioner
alkali soil
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201711286506.3A
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Chinese (zh)
Inventor
周维
刘晓轩
曹黎颖
耿克达
胡家栋
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Shanghai Baotian New Building Materials Co Ltd
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Shanghai Baotian New Building Materials Co Ltd
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Priority to CN201711286506.3A priority Critical patent/CN107955624A/en
Publication of CN107955624A publication Critical patent/CN107955624A/en
Withdrawn legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K17/00Soil-conditioning materials or soil-stabilising materials
    • C09K17/40Soil-conditioning materials or soil-stabilising materials containing mixtures of inorganic and organic compounds
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05DINORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
    • C05D3/00Calcareous fertilisers
    • C05D3/04Calcareous fertilisers from blast-furnace slag or other slags containing lime or calcium silicates
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/80Soil conditioners
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2109/00MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE pH regulation

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Soil Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Pest Control & Pesticides (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Soil Conditioners And Soil-Stabilizing Materials (AREA)

Abstract

The present invention relates to technical field of land improvement, more particularly to a kind of saline-alkali soil conditioner and application method, which includes the raw material of following parts by weight:3~10 parts of power plant desulfurization gypsum, 2~10 parts of blast furnace ground-slag, acid-sludge 80~95, mass percentage are 1% 3~10 parts of citric acid solution, and when use is uniformly sprinkling upon salt affected soil surface in a certain order, and soil conditioner is uniformly mixed with soil.This product has been especially added with acid-sludge and citric acid solution is engaged, and can play the effect of reducing soil pH value within a short period of time, and have effects that to increase soil fertility;Contain the middle trace element needed for the plant growths such as abundant silicon-calcium-magnesium in blast furnace ground-slag, have the function of to improve stress resistance of plant and promote plant growth.This product has positive effect using solid waste as primary raw material, for resource regeneration and environmental protection, while raw material is easy to get, and preparation process is simple, and technique is controllable.

Description

A kind of saline-alkali soil conditioner and application method
Technical field
The present invention relates to technical field of land improvement, more particularly to a kind of saline-alkali soil conditioner and application method.
Background technology
Due to natural and artificial factor, the salt affected soil area in China is huge, and according to statistics, China's saline-alkali soil area reaches 99130000 hectares, as can which part saline-alkali soil is improved, become the soil of suitable farming, anticipate for China's agricultural production Justice is great.
The modification method of saline-alkali soil is very much, mainly has:(1) landform, soil removal and replacement are raised in Physical, prepartion of land, chesson Deng;(2) modifying agent such as chemical method, gypsuming, humic acid, peat;(3) bioanalysis, plants salt-tolerant plant or using biology Bacterial manure;(4) water conservancy law:Salt content is reduced by the method for salt discharge of pouring water.There are certain deficiency, such as soil to put down for the above method Whole to fail to solve the problems, such as that soil salt content is high at all, soil replacement method is of high cost, and humic acid, peat are valuable natural resources, no It is renewable, plantation salt-tolerant plant cycle length, the problems such as water conservancy law needs great lot of water resources.
For the features such as salt-soda soil salt content is high, pH value is high, the content of organic matter is low and soil texture is poor, workers and peasants are made full use of Industry discarded object is raw material, and certain organic acid of arranging in pairs or groups, prepares soil conditioner, can play reduction soil salt content, reduces pH Value, the effect of improving soil organic matter content and improve soil texture, has for salt affected soil improvement and follow-up utilization It is with practical value great.Aqueous citric acid solution is used merely, can not be further although the effect for reducing pH value can be played The salt content in soil is reduced, can not also change the characteristics of soil organic matter content is low and soil texture is poor
The content of the invention
The object of the present invention is to provide a kind of saline-alkali soil conditioner, which is discarded using a large amount of industrial or agricultural Thing, has advantage of low cost, and product has reduction soil salt content, reduces pH value, improves soil organic matter content and changes The effect of kind soil texture.
A kind of saline-alkali soil conditioner provided by the invention, in parts by weight, the saline-alkali soil conditioner raw material:Power plant 3~10 parts of desulfurated plaster, 0~10 part of blast furnace ground-slag, 80~95 parts of acid-sludge, mass percentage for 1% aqueous citric acid solution 3~ 10 parts.
Preferably, in parts by weight, the saline-alkali soil conditioner raw material:3~10 parts of power plant desulfurization gypsum, blast furnace ground-slag 2~10 parts, 80~95 parts of acid-sludge, mass percentage is 3~10 parts of 1% aqueous citric acid solution.Add blast furnace ground-slag and electricity Factory's desulfurated plaster is engaged, and the calcium ion in desulfurated plaster and blast furnace ground-slag can accelerate the sodium in saline-alkali soil to interact, drop Low soil salt content, while the crumb structure of soil can also be improved, increase soil porosity, accelerate salt discharge efficiency
The acid-sludge is 100 with the weight ratio that mass percentage is 1% aqueous citric acid solution:5-6.Since acid-sludge is acid Property, and containing abundant organic matter, have effects that to increase soil fertility;Acid-sludge is used cooperatively with aqueous citric acid solution, The effect of pH value is adjusted with can play for a long time in short term.Particularly when acid-sludge and mass percentage are 1% aqueous citric acid solution Weight ratio be 100:During 5-6, effect is more excellent.
Wherein, the power plant desulfurization gypsum is coal-burning power plant's wet process of FGD accessory substance, and water content is 10~30%, is done Calcium sulphate dihydrate CaSO in base4·2H2O content is not less than 90%.
Wherein, the blast furnace ground-slag is the discarded object that iron-smelting process produces, and is process by drying, iron removaling and grinding, It is more than 200 mesh of fineness, wherein SiO2Content is not less than 30%, and CaO content is not less than 35%, and content of MgO is not less than 5%.
Wherein, the acid-sludge is makes the discarded object that vinegar technique produces, water content 40~50%, the content of organic matter 40% with On.
Wherein, 1% citric acid solution, using citric acid and tap water as raw material, proportionally dissolves and stirs It is even.
It is a further object to provide a kind of application method of saline-alkali soil conditioner.
Wherein, the sowing amount of saline-alkali soil conditioner is 10~30 tons/mu.
Wherein, the application method is:Required raw material is ready to according to proportioning, according to desulfurated plaster, blast furnace ground-slag, The order of acid-sludge and citric acid solution imposes on soil surface successively, is uniformly mixed raw material with soil using machinery.
By the implementation of the present invention, following effect can be played:Soil salt content is reduced, reduces pH value, improving soil has The effect of machine matter content and improvement soil texture.
This product contains the effect of certain acidic materials can play reduction soil pH value within a short period of time;Desulfurization stone Calcium ion in cream and blast furnace ground-slag can be interacted with the sodium in saline-alkali soil, reduce soil salt content, while can also improve The crumb structure of soil, increases soil porosity, accelerates salt discharge efficiency;Acid-sludge contains abundant organic matter, has and improves soil The effect of fertility;Contain the middle trace element needed for the plant growths such as abundant silicon-calcium-magnesium in blast furnace ground-slag, have and improve plant Resistance and the function of promoting plant growth.This product is protected using solid waste as primary raw material for resource regeneration and environment Protector has positive effect, while raw material is easy to get, and preparation process is simple, and technique is controllable.
Embodiment
With reference to embodiment, the invention will be further described:
Embodiment 1 (no blast furnace ground-slag)
In parts by weight, 6 parts of power plant desulfurization gypsum, 89 parts of acid-sludge, mass percentage are molten for the citric acid of 1% concentration 3 parts of liquid is made into soil conditioner, is used according to the sowing amount of 15 tons/mu, by raw material according to desulfurated plaster, blast furnace ground-slag, acid-sludge Salt affected soil surface is imposed on successively with the order of citric acid solution, is uniformly mixed raw material with soil using machinery.
Embodiment 2
In parts by weight, 3 parts of power plant desulfurization gypsum, 2 parts of blast furnace ground-slag, 80 parts of acid-sludge, mass percentage are dense for 1% 10 parts of the citric acid solution of degree is made into soil conditioner, according to 15 tons/mu sowing amount use, by raw material according to desulfurated plaster, The order of blast furnace ground-slag, acid-sludge and citric acid solution imposes on salt affected soil surface successively, is mixed raw material with soil using machinery Uniformly.
Embodiment 3
In parts by weight, 10 parts of power plant desulfurization gypsum, 10 parts of blast furnace ground-slag, 95 parts of acid-sludge, mass percentage 1% 3 parts of the citric acid solution of concentration is made into soil conditioner, according to 20 tons/mu sowing amount use, by raw material according to desulfurated plaster, The order of blast furnace ground-slag, acid-sludge and citric acid solution imposes on salt affected soil surface successively, is mixed raw material with soil using machinery Uniformly.
Embodiment 4
In parts by weight, 6 parts of power plant desulfurization gypsum, 6 parts of blast furnace ground-slag, 89 parts of acid-sludge, mass percentage are dense for 1% 7 parts of the citric acid solution of degree is made into soil conditioner, is used according to the sowing amount of 20 tons/mu, by raw material according to desulfurated plaster, height The order of pulverized slag, acid-sludge and citric acid solution imposes on salt affected soil surface successively, is mixed raw material with soil using machinery It is even.
Embodiment 5
In parts by weight, 6 parts of power plant desulfurization gypsum, 6 parts of blast furnace ground-slag, 89 parts of acid-sludge, mass percentage are dense for 1% 5 parts of the citric acid solution of degree is made into soil conditioner, is used according to the sowing amount of 20 tons/mu, by raw material according to desulfurated plaster, height The order of pulverized slag, acid-sludge and citric acid solution imposes on salt affected soil surface successively, is mixed raw material with soil using machinery It is even.
Comparative example 1
In parts by weight, 5 parts of power plant desulfurization gypsum, 10 parts of blast furnace ground-slag, the citric acid of 1% concentration of mass percentage 5 parts of solution is made into soil conditioner, is used according to the sowing amount of 15 tons/mu, by raw material according to desulfurated plaster, blast furnace ground-slag and lemon The order of lemon acid solution imposes on salt affected soil surface successively, is uniformly mixed raw material with soil using machinery.
Test data
Applied and using mechanical by raw material on 800 flat saline-alkali soil with the material rate of comparative example 1 and embodiment 1-3 It is uniformly mixed with soil, was detected after 6 months, the front and rear correction data of salt affected soil improvement is as shown in table 1 below:
Table 1
As seen from the above table, using the saline-alkali soil conditioner of the present invention, soil salt content can be effectively reduced, reduces pH Value, improves soil organic matter content.
The above is presently preferred embodiments of the present invention, but the present invention should not be limited to disclosed in the embodiment Content.So every do not depart from the lower equivalent or modification completed of spirit disclosed in this invention, the model that the present invention protects is both fallen within Enclose.

Claims (9)

  1. A kind of 1. saline-alkali soil conditioner, it is characterised in that in parts by weight, the saline-alkali soil conditioner raw material:Power plant takes off 3~10 parts of sulphur gypsum, 0~10 part of blast furnace ground-slag, 80~95 parts of acid-sludge, mass percentage are 1% aqueous citric acid solution 3~10 Part.
  2. 2. saline-alkali soil conditioner according to claim 1, it is characterised in that it is characterized in that, in parts by weight, it is described Saline-alkali soil conditioner raw material:3~10 parts of power plant desulfurization gypsum, 2~10 parts of blast furnace ground-slag, 80~95 parts of acid-sludge, quality percentage Content is 3~10 parts of 1% aqueous citric acid solution.
  3. 3. saline-alkali soil conditioner according to claim 1, it is characterised in that it is characterized in that, the acid-sludge and quality hundred Point content is that the weight ratio of 1% aqueous citric acid solution is 100:5-6.
  4. 4. saline-alkali soil conditioner according to claim 1, it is characterised in that the power plant desulfurization gypsum is power plant desulfurization The discarded object that technique produces, water content are 10~30%, calcium sulphate dihydrate CaSO in butt4·2H2O content is not less than 90%.
  5. 5. saline-alkali soil conditioner according to claim 1, it is characterised in that the blast furnace ground-slag produces for iron-smelting process Discarded object, be process by drying, iron removaling and grinding, more than 200 mesh of fineness.
  6. 6. saline-alkali soil conditioner according to claim 1, it is characterised in that SiO in the blast furnace ground-slag2Content is not low In 30%, CaO content is not less than 35%, and content of MgO is not less than 5%.
  7. 7. saline-alkali soil conditioner according to claim 1, it is characterised in that:The acid-sludge produces useless for wine vinegar technique Gurry, water content 40~50%, the content of organic matter more than 40%.
  8. 8. the application method of any type alkali soil conditioner according to claim 1-7, it is characterised in that:The alkaline earth The sowing amount of earth modifying agent is 10~30 tons/mu.
  9. 9. application method according to claim 8, it is characterised in that:Required raw material is ready to according to proportioning, according to de- Sulphur gypsum, blast furnace ground-slag, the order of acid-sludge and citric acid solution impose on soil surface successively, are mixed raw material and soil using machinery Close uniform.
CN201711286506.3A 2017-12-07 2017-12-07 A kind of saline-alkali soil conditioner and application method Withdrawn CN107955624A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108690630A (en) * 2018-06-12 2018-10-23 蒙城县京徽蒙农业科技发展有限公司 A kind of soil conditioner and preparation method thereof based on livestock and poultry feces
GB2584126A (en) * 2019-05-22 2020-11-25 Geotech Soil Stabilisation Ltd Method of decommissioning a temporary structure

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106187597A (en) * 2016-07-12 2016-12-07 山东胜伟园林科技有限公司 A kind of fertilizer containing desulfurated plaster and preparation method and application

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106187597A (en) * 2016-07-12 2016-12-07 山东胜伟园林科技有限公司 A kind of fertilizer containing desulfurated plaster and preparation method and application

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
何兴东等: "《生态恢复理论与宁夏盐池植被恢复技术》", 31 May 2016, 南开大学出版社 *
柴立元等: "《冶金环保手册》", 30 April 2016, 中南大学出版社 *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108690630A (en) * 2018-06-12 2018-10-23 蒙城县京徽蒙农业科技发展有限公司 A kind of soil conditioner and preparation method thereof based on livestock and poultry feces
GB2584126A (en) * 2019-05-22 2020-11-25 Geotech Soil Stabilisation Ltd Method of decommissioning a temporary structure
GB2584126B (en) * 2019-05-22 2023-05-10 Geotech Soil Stabilisation Ltd Method of decommissioning a temporary structure

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