CN106187597A - A kind of fertilizer containing desulfurated plaster and preparation method and application - Google Patents

A kind of fertilizer containing desulfurated plaster and preparation method and application Download PDF

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Publication number
CN106187597A
CN106187597A CN201610547521.8A CN201610547521A CN106187597A CN 106187597 A CN106187597 A CN 106187597A CN 201610547521 A CN201610547521 A CN 201610547521A CN 106187597 A CN106187597 A CN 106187597A
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China
Prior art keywords
desulfurated plaster
fertilizer
parts
fertilizer containing
flyash
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201610547521.8A
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Chinese (zh)
Inventor
王胜
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Shandong Sunway Garden Technology Co Ltd
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Shandong Sunway Garden Technology Co Ltd
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Priority to CN201610547521.8A priority Critical patent/CN106187597A/en
Publication of CN106187597A publication Critical patent/CN106187597A/en
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    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/80Soil conditioners
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05DINORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
    • C05D3/00Calcareous fertilisers
    • C05D3/02Calcareous fertilisers from limestone, calcium carbonate, calcium hydrate, slaked lime, calcium oxide, waste calcium products

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Soil Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Fertilizers (AREA)

Abstract

The invention belongs to Saline-alkali Field Control technical field, it is specifically related to a kind of fertilizer containing desulfurated plaster and preparation method and application, by weight percentage, it includes following parts by weight of component to described fertilizer: desulfurated plaster 35 45 parts, feces of livestock and poultry and 20 30 parts of hay leaf, 5 10 parts of peat, pyrite 15 parts and 15 parts of flyash.Fertilizer prepared by the present invention is adapted to the improvement in salt-soda soil, and desalination is quick, and treatment cost is low, and using effect is notable.

Description

A kind of fertilizer containing desulfurated plaster and preparation method and application
Technical field
The invention belongs to Saline-alkali Field Control technical field, be specifically related to a kind of fertilizer containing desulfurated plaster and preparation thereof Method and application.
Background technology
Saline-alkali soil is solonchak and alkaline earth and various salinization, the general name of alkali-affected soil.Solonchak refers to soluble organic fraction in soil Content reaches to a certain degree, it is possible to the g and D of plant is produced the great soil group substantially endangered.Alkaline earth refers in soil containing big Amount commutativity ion, quantity reaches to endanger the degree of plant growing and growth, and makes the soil that soil property changes. The salinization of soil of soil refers to owing in soil, a large amount of of salt basic ion accumulate, the process that soil types gradually changes to saline-alkali soil, its Influence factor includes natural cause and anthropic factor.Easily there is the phenomenon that hardens in salt affected soil under normal circumstances, causes soil Porosity diminishes, and the gas permeability of soil and water penetration are deteriorated, and badly influence the metabolism of Soil Microorganism, reduce the work of various enzyme Property and carbon, the mineralization degree of nitrogen element, the conversion of soil with organic matter is slack-off, eventually results in soil the barrenst.Soil contains The a large amount of salt ions having also can badly influence the normal physiological function of salt-soda soil plant, suppresses its g and D.It addition, with The continuous aggravation of socioeconomic development and mankind's activity, salt-soda soil resource increasingly receives publicity, and irrational irrigation is made Degree also results in Pedotransfer function aggravation.Second Committee International Sustainable Development conference is just pointed out, the following meeting serious threat world Agricultural sustainable development is the salinization of soil in soil, desertification and the big problem of soil erosion 3.
Desulfurated plaster (English name desulfuration gypsum) is also known as flue gas desulfurization gypsum, sulfur Gypsum Fibrosum or FGD stone Cream, main component is the same with the natural gypsum, for calcium sulphate dihydrate CaSO4·2H2O, content >=93%.Desulfurated plaster is FGD process Side-product, FGD process is a technology using Calx-limestone to reclaim the sulfur dioxide in coal-fired or oily flue gas.Should Technology is Calx-limestone to be ground make serosity, make after dedusting containing SO2Flue gas removed by slurry wash device SO2.Lime slurry and SO2Reaction generates calcium sulfate and calcium sulfite, and calcium sulfite is oxidized changes into calcium sulfate, obtains industry By-product gypsum, referred to as desulfurated plaster.
Gypsum Fibrosum powder is one of five big gel rubber materials, occupies an important position, be widely used in building, build in national economy Numerous applications such as material, industry mould and art model, chemical industry and agricultural, food processing and medicine beauty treatment, are a kind of Important industrial raw materials.Desulfurization gypsum powder is the different of physics from the differentiation of general Gypsum Fibrosum powder, in desulfurization gypsum powder Possibly together with silicon dioxide, sodium oxide, calcium carbonate, calcium sulfite, limestone, calcium chloride, magnesium chloride etc..Compared with other Gypsum Fibrosum powder Relatively, desulfurization gypsum powder has renewable, and granularity is little, stable components, and objectionable impurities content is few, purity high.Currently mainly It is used for producing plasterboard together with the natural gypsum, is additionally widely used in terms of alkaline land improving.Its principle is to utilize Ion exchange is theoretical, replaces the sodium ion in soil colloid with the calcium ion in desulfurated plaster.
Summary of the invention
Invention broadly provides a kind of fertilizer containing desulfurated plaster and preparation method and application, preparation organic Fertilizer is adapted to the improvement in salt-soda soil, and desalination is quick, and treatment cost is low, and using effect is notable.Its technical scheme is as follows:
A kind of fertilizer containing desulfurated plaster, by weight percentage, it includes following parts by weight of component: desulfurated plaster 35-45 part, feces of livestock and poultry and hay leaf 20-30 part, peat 5-10 part, pyrite 1-5 part and flyash 1-5 part.
Preferably, described fertilizer also includes the acid-sludge of 5-10 weight portion.
Preferably, described fertilizer also includes the microbial bacterial agent of 1-3 weight portion.
Preferably, microbial bacterial agent is the mix bacterium agent of Glomus mosseae, Glomus etunicatum and bacillus subtilis.
Preferably, the bacterium solution addition of Glomus mosseae, Glomus etunicatum and bacillus subtilis is 2:1:1.
Preferably, by weight percentage, described fertilizer includes following parts by weight of component: desulfurated plaster 38-42 part, poultry Poultry manure and hay leaf 25-27 part, 8 parts of peat, pyrite 2 parts and 3 parts of flyash, acid-sludge 7 parts, microbial bacterial agent 2 parts.
Preferably, the effective ingredient of desulfurated plaster is CaSO4·2H2O, CaSO4·2H2Content >=93% of O.
The preparation method of a kind of fertilizer containing desulfurated plaster, comprises the following steps:
(1) desulfurated plaster, peat, pyrite, flyash are carried out air-drying pulverizing, and process of sieving;
(2) weigh feces of livestock and poultry and the hay leaf of formula ratio, add acid-sludge and the microbial bacterial agent of formula ratio, carry out close Seal ferment 15-20 days, turned over every 3-5 days and pushes away once, generated the mixture of corruption;
(3) adding the desulfurated plaster after pulverizing, peat, pyrite, flyash in the mixture of corruption, stirring mixing is all Even, obtain the fertilizer containing desulfurated plaster.
The application of a kind of fertilizer containing desulfurated plaster, concrete is that the described fertilizer containing desulfurated plaster is suitable for In the improvement to the saline-alkali soil that pH is 10-13.
Use above-mentioned fertilizer containing desulfurated plaster and preparation method and application, the invention have the advantages that
(1) flyash is the main garbage in thermal power plant, and annual China flyash annual emissions has surpassed hundred million, and produces Amount increases year by year.Local environment protection is brought the biggest pressure by the bulk deposition of flyash, the most also gives the life of people and moves The aspects such as the existence of plant, growth cause serious harm.And containing abundant weight, boron, sulfur, zinc, copper, calcium, magnesium, ferrum in flyash Deng trace element, and quality is loose the bigger space of existence, at the regulation soil moisture and pH value, increases and supplements soil nutrient Composition aspect effect is unique;
(2) mix bacterium agent in the present invention can increase vegetation to Na+Absorbtivity so that it is be gathered under ground portion, press down Salt manufacturing divides the transport to top, reduces relative amount, improves the ionic equilibrium in plant body, alleviate the murder by poisoning of salt ion, mixing The infection ability of microbial inoculum and promotion host plant growth aspect will be more preferable than inoculation single culture effect.
Detailed description of the invention
Embodiment 1
1. contain the fertilizer of desulfurated plaster
A kind of fertilizer containing desulfurated plaster, by weight percentage, it includes following parts by weight of component: desulfurated plaster 38 parts, feces of livestock and poultry and 25 parts of hay leaf, 8 parts of peat, pyrite 2 parts, 3 parts of flyash, acid-sludge 7 parts, microbial bacterial agent 2 parts.
Wherein, microbial bacterial agent be the bacterium solution addition of Glomus mosseae, Glomus etunicatum and bacillus subtilis be 2: 1:1。
2. the preparation method of fertilizer
(1) desulfurated plaster, peat, pyrite, flyash are carried out air-drying pulverizing, and process of sieving;
(2) weigh feces of livestock and poultry and the hay leaf of formula ratio, add acid-sludge and the microbial bacterial agent of formula ratio, carry out close Seal ferment 17 days, turned over every 4 days and pushes away once, generated the mixture of corruption;
(3) adding the desulfurated plaster after pulverizing, peat, pyrite, flyash in the mixture of corruption, stirring mixing is all Even, obtain the fertilizer containing desulfurated plaster.
Embodiment 2
1. contain the fertilizer of desulfurated plaster
A kind of fertilizer containing desulfurated plaster, by weight percentage, it includes following parts by weight of component: desulfurated plaster 35 parts, feces of livestock and poultry and 30 parts of hay leaf, 10 parts of peat, pyrite 5 parts, 1 part of flyash, acid-sludge 5 parts, microbial bacterial agent 1 part.
Wherein, microbial bacterial agent be the bacterium solution addition of Glomus mosseae, Glomus etunicatum and bacillus subtilis be 2: 1:1。
2. the preparation method of fertilizer
(1) desulfurated plaster, peat, pyrite, flyash are carried out air-drying pulverizing, and process of sieving;
(2) weigh feces of livestock and poultry and the hay leaf of formula ratio, add acid-sludge and the microbial bacterial agent of formula ratio, carry out close Seal ferment 20 days, turned over every 5 days and pushes away once, generated the mixture of corruption;
(3) adding the desulfurated plaster after pulverizing, peat, pyrite, flyash in the mixture of corruption, stirring mixing is all Even, obtain the fertilizer containing desulfurated plaster.
Embodiment 3
1. contain the fertilizer of desulfurated plaster
A kind of fertilizer containing desulfurated plaster, by weight percentage, it includes following parts by weight of component: desulfurated plaster 45 parts, feces of livestock and poultry and 20 parts of hay leaf, 5 parts of peat, pyrite 1 part, 5 parts of flyash, acid-sludge 10 parts, microbial bacterial agent 3 parts.
Wherein, microbial bacterial agent be the bacterium solution addition of Glomus mosseae, Glomus etunicatum and bacillus subtilis be 2: 1:1。
2. the preparation method of fertilizer
(1) desulfurated plaster, peat, pyrite, flyash are carried out air-drying pulverizing, and process of sieving;
(2) weigh feces of livestock and poultry and the hay leaf of formula ratio, add acid-sludge and the microbial bacterial agent of formula ratio, carry out close Seal ferment 15 days, turned over every 3 days and pushes away once, generated the mixture of corruption;
(3) adding the desulfurated plaster after pulverizing, peat, pyrite, flyash in the mixture of corruption, stirring mixing is all Even, obtain the fertilizer containing desulfurated plaster.
Performance detects
1. use the fertilizer of embodiment 1-3 that saline-alkali soil carries out lab simulation shower test, add up salinity after 20 days and become Change, the results are shown in Table 1.
Soil salt balance before and after table 1 improvement
As shown in Table 1, the fertilizer of embodiment 1-3 is used to after processing salt-soda soil, Na in soil+And Cl-Content is significantly Reduce, and Na+And Cl-For harm plant growing, the Main Factors of destruction Soil structure, they are greatly reduced, and can be plant Growth provide safety growing environment.
2. use the fertilizer of embodiment 1-3 that saline-alkali soil is improved, plant Plantula Brassicae chinensis during improvement, simultaneously normally Soil and without on the saline-alkali soil of fertilizer plant Plantula Brassicae chinensis, result of the test is as shown in table 2:
Table 2 soil improvement result
As shown in Table 2, fertilizer prepared by the present invention can reduce pH value and the electrical conductivity of soil, improves kind of a plant simultaneously Germination percentage, germination index and vitality index, be beneficial to use to salt-soda soil.
It will be apparent to those skilled in the art that can technical scheme as described above and design, make other various Corresponding change and deformation, and all these change and deformation all should belong to the protection domain of the claims in the present invention Within.

Claims (9)

1. containing the fertilizer of desulfurated plaster, by weight percentage, it includes following parts by weight of component: desulfurated plaster 35-45 part, feces of livestock and poultry and hay leaf 20-30 part, peat 5-10 part, pyrite 1-5 part and flyash 1-5 part.
Fertilizer containing desulfurated plaster the most according to claim 1, it is characterised in that: described fertilizer also includes 5-10 The acid-sludge of weight portion.
Fertilizer containing desulfurated plaster the most according to claim 2, it is characterised in that: described fertilizer also includes 1-3 The microbial bacterial agent of weight portion.
Fertilizer containing desulfurated plaster the most according to claim 3, it is characterised in that: microbial bacterial agent is Moses's sacculus Mould, Glomus etunicatum and the mix bacterium agent of bacillus subtilis.
Fertilizer containing desulfurated plaster the most according to claim 4, it is characterised in that: Glomus mosseae, children's set sacculus Mould and bacillus subtilis bacterium solution addition is 2:1:1.
Fertilizer containing desulfurated plaster the most according to claim 4, it is characterised in that: by weight percentage, described Fertilizer includes following parts by weight of component: desulfurated plaster 38-42 part, feces of livestock and poultry and hay leaf 25-27 part, 8 parts of peat, Huang Tie 2 parts of ore deposit and 3 parts of flyash, acid-sludge 7 parts, microbial bacterial agent 2 parts.
Fertilizer containing desulfurated plaster the most according to claim 1, it is characterised in that: the effective ingredient of desulfurated plaster is CaSO4·2H2O, CaSO4·2H2Content >=93% of O.
8. the method preparing the fertilizer containing desulfurated plaster as claimed in claim 6, it is characterised in that: include following Step:
(1) desulfurated plaster, peat, pyrite, flyash are carried out air-drying pulverizing, and process of sieving;
(2) weigh feces of livestock and poultry and the hay leaf of formula ratio, add acid-sludge and the microbial bacterial agent of formula ratio, carry out sealing and send out Ferment 15-20 days, turned over every 3-5 days and pushes away once, generated the mixture of corruption;
(3) in the mixture of corruption, add the desulfurated plaster after pulverizing, peat, pyrite, flyash, be uniformly mixed, Obtain the fertilizer containing desulfurated plaster.
9. the application of the fertilizer containing desulfurated plaster described in a claim 6, it is characterised in that: described containing desulfurization stone The fertilizer of cream is applicable to the improvement to the saline-alkali soil that pH is 10-13.
CN201610547521.8A 2016-07-12 2016-07-12 A kind of fertilizer containing desulfurated plaster and preparation method and application Withdrawn CN106187597A (en)

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Application Number Priority Date Filing Date Title
CN201610547521.8A CN106187597A (en) 2016-07-12 2016-07-12 A kind of fertilizer containing desulfurated plaster and preparation method and application

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Application Number Priority Date Filing Date Title
CN201610547521.8A CN106187597A (en) 2016-07-12 2016-07-12 A kind of fertilizer containing desulfurated plaster and preparation method and application

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107955624A (en) * 2017-12-07 2018-04-24 上海宝田新型建材有限公司 A kind of saline-alkali soil conditioner and application method
CN108300485A (en) * 2018-03-13 2018-07-20 鲁东大学 It is a kind of to be used to administer the soil conditioner in salt-soda soil and its preparation method and application

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107955624A (en) * 2017-12-07 2018-04-24 上海宝田新型建材有限公司 A kind of saline-alkali soil conditioner and application method
CN108300485A (en) * 2018-03-13 2018-07-20 鲁东大学 It is a kind of to be used to administer the soil conditioner in salt-soda soil and its preparation method and application

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Application publication date: 20161207